{"id":10266,"date":"2016-06-22T09:18:53","date_gmt":"2016-06-22T01:18:53","guid":{"rendered":"\/\/www.gsbet888.com\/?p=10266"},"modified":"2019-08-02T18:54:16","modified_gmt":"2019-08-02T10:54:16","slug":"post-10266","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2016\/06\/post-10266.html","title":{"rendered":"\u82b3\u9999\u65cf\u5316\u5408\u7269\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94\uff1a\u7b2c\u4e09\u79cd\u624b\u6cd5"},"content":{"rendered":"<p>\u4eca\u5e74\u5e74\u521d\uff0c\u5c0f\u7f16\u4ecb\u7ecd\u4e86\u4e00\u7bc7\u78b1\u91d1\u5c5e\u50ac\u5316\u7684C-H\u952e\u7684\u76f4\u63a5\u7845\u57fa\u5316\u53cd\u5e94\uff0c\u4e0d\u77e5\u9053\u5927\u5bb6\u662f\u5426\u8fd8\u8bb0\u5f97\uff08<a href=\"\/\/www.gsbet888.com\/%E5%8C%96%E5%AD%A6%E6%9D%82%E8%AE%B0\/recentpaper\/2016\/01\/post-8151.html\">\u8bb0\u4e8b\uff1a\u4ec0\u4e48\uff1f\u78b1\u91d1\u5c5e\u53d1\u751f\u7684\u7845\u57fa\u5316\u53cd\u5e94!<\/a>\uff09\u3002\u90a3\u7bc7\u6587\u7ae0\u6253\u7834\u4e86\u5e38\u89c4\u7684\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u4f20\u7edf\uff0c\u53ea\u662f\u5229\u7528\u78b1\u91d1\u5c5e\uff08KO<em>t<\/em>-Bu\uff09\u5c31\u53ef\u4ee5\u8fbe\u5230\u7845\u57fa\u5316\u7684\u76ee\u7684\uff0c\u662f\u4e00\u4e2a\u5341\u5206\u6709\u7a81\u7834\u6027\u7684\u7814\u7a76\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u65e5\u672c\u7406\u5316\u7814\u7a76\u6240\u4faf\u6559\u6388\uff08\u6211\u4eecchem-station\u505a\u8fc7\u4faf\u8001\u5e08\u7684\u4e13\u8bbf-<a href=\"\/\/www.gsbet888.com\/interview\/cchemist\/2014\/11\/post-3341.html\">\u7b51\u68a6\u5316\u5b66\u952e\u7684\u81ea\u7531\u5207\u65ad\u3001\u81ea\u7531\u6784\u5efa<\/a>\uff0c\u6709\u5174\u8da3\u7684\u53ef\u4ee5\u70b9\u5f00\u94fe\u63a5\u56de\u987e\u4e0b\uff09\u5728\u8fd9\u4e2a\u57fa\u7840\u4e0a\u66f4\u8fdb\u4e00\u6b65\uff0c\u76f4\u63a5<strong>\u4e0d\u9700\u8981\u4f7f\u7528\u4efb\u4f55\u91d1\u5c5e<\/strong>\u5c31\u53ef\u4ee5\u8fbe\u5230C-H\u7845\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u672c\u6587\u5c0f\u7f16\u6574\u7406\u4e86\u4e00\u4e0b\u6700\u8fd1\u51e0\u5e74\u7684\u5177\u6709\u4ee3\u8868\u6027\u7684\u4e09\u79cd\u76f4\u63a5\u7845\u57fa\u5316\u53cd\u5e94\u624b\u6cd5\uff0c\u5e76\u4e14\u91cd\u70b9\u4ecb\u7ecd\u4e00\u4e0b\u4faf\u8001\u5e08\u7684\u8fd9<strong>\u7b2c\u4e09\u79cd\u65b9\u6cd5<\/strong>\uff1a\u787c\u50ac\u5316\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n<blockquote><p>Ma, Y.; \u00a0Wang, B.; Zhang, L.; Hou,\u00a0Z.\u00a0<i>J. Am. Chem. Soc.<\/i>,\u00a0<b>2016<\/b>, 138, 3663. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/jacs.6b01349\">10.1021\/jacs.6b01349<\/a><\/p><\/blockquote>\n<p>&nbsp;<\/p>\n<h4>\u7b2c\u4e00\u79cd\u65b9\u6cd5\uff1a\u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u7684\u624b\u6cd5<\/h4>\n<p>\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u7684\u82b3\u73af\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94\uff0c\u662f\u8fd1\u5e74\u6765\u6bd4\u8f83\u70ed\u95e8\u7684\u7814\u7a76<sup>[1]<\/sup>\u3002\u5728\u591a\u79cd\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u7845\u57fa\u5316\u53cd\u5e94\u4e2d\uff0c\u5c0f\u7f16\u8ba4\u4e3a\u6bd4\u8f83\u5177\u6709\u4ee3\u8868\u6027\u7684\u662f2014\u5e74\uff0c\u7f8e\u56fd\u52a0\u5dde\u4f2f\u514b\u5229\u5206\u6821\u7684<a href=\"\/\/www.gsbet888.com\/chemists\/2014\/10\/%E7%BA%A6%E7%BF%B0%E3%83%BBf%E3%83%BB%E5%93%88%E7%89%B9%E7%BB%B4%E5%B8%8C-john-f-hartwig.html\">Hartwig\u6559\u6388<\/a>\u7b49\u4eba\u5229\u7528Rh\u50ac\u5316\u5242\u50ac\u5316\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94<sup>[2]<\/sup>\u3002<\/p>\n<p>\u5982\u4e0b\u56fe1(a)\u6240\u793a\uff0c\u8be5\u53cd\u5e94\u4f7f\u7528<strong>L1<\/strong>\u4f5c\u4e3a\u91d1\u5c5e\u7684\u914d\u4f53\u3001(TMSO)<sub>2<\/sub>MeSiH\u4f5c\u4e3a\u7845\u57fa\u5316\u53cd\u5e94\u8bd5\u5242\uff0c\u53e6\u5916\u73af\u5df1\u70ef\u4e3a\u6c22\u6c14\u53d7\u4f53\uff0c\u5b9e\u73b0\u4e86\u82b3\u9999\u73af\u4e0a\u4f4d\u963b\u6700\u5c0f\u5f97\u4f4d\u7f6e\u7684\u7845\u57fa\u5316\u53cd\u5e94\u3002\u5728\u8fd9\u4e4b\u540e\uff0c\u4ed6\u4eec\u53c8\u5f00\u53d1\u51fa\u4e86\u5229\u7528\u65b0\u7684Ir\u50ac\u5316\u5242\u50ac\u5316\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94<sup>[3]<\/sup>\u3002\u4e0eRh\u50ac\u5316\u5242\u76f8\u6bd4\u5177\u6709\u66f4\u5e7f\u6cdb\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\uff0c\u80fd\u591f\u9002\u7528\u4e8e\u542b\u6709\u5364\u7d20\u7684\u5e95\u7269\u6216\u8005\u6742\u73af\u5e95\u7269(\u56fe\u00a01(b))\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-10268 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-15-08.png\" alt=\"2016-06-06_19-15-08\" width=\"817\" height=\"390\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-15-08.png 817w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-15-08-300x143.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-15-08-768x367.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-15-08-680x325.png 680w\" sizes=\"(max-width: 817px) 100vw, 817px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe1. \u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94<\/p>\n<h4>\u7b2c\u4e8c\u79cd\u624b\u6cd5\uff1a\u5229\u7528\u78b1\u91d1\u5c5eKO<em>t<\/em>-Bu\u7684\u624b\u6cd5<\/h4>\n<p>2015\u5e74\uff0c\u7f8e\u56fd\u52a0\u5dde\u7406\u5de5\u7684<a title=\"\u30d6\u30e9\u30a4\u30a2\u30f3\u30fb\u30b9\u30c8\u30eb\u30c4 Brian M. Stoltz\" href=\"\/\/www.gsbet888.com\/chemists\/2016\/02\/brian-m-stoltz.html\">Stoltz<\/a>\u548c<a title=\"\u30ed\u30d0\u30fc\u30c8\u30fb\u30b0\u30e9\u30d6\u30b9 Robert H. Grubbs\" href=\"http:\/\/www.chem-station.com\/chemist-db\/archives\/2008\/10\/-robert-h-grubbs.php\">Grubbs<\/a>\u6559\u6388\u7684\u7814\u7a76\u7ec4\u62a5\u9053\u4e86\u4ec5\u4ec5\u4f7f\u7528KO<em>t<\/em>-Bu\u5b9e\u73b0\u7684\u82b3\u9999\u6742\u73af\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94\uff08<a href=\"\/\/www.gsbet888.com\/%E5%8C%96%E5%AD%A6%E6%9D%82%E8%AE%B0\/recentpaper\/2016\/01\/post-8151.html\">\u8bb0\u4e8b\uff1a\u4ec0\u4e48\uff1f\u78b1\u91d1\u5c5e\u53d1\u751f\u7684\u7845\u57fa\u5316\u53cd\u5e94!<\/a>\uff09<sup>[4]<\/sup>\u3002\u8be5\u65b9\u6cd5\u4ec5\u4ec5\u5229\u7528\u50ac\u5316\u91cf\u7684KO<em>t<\/em>-Bu\uff0c\u5229\u7528Et<sub>3<\/sub>SiH\u4f5c\u4e3a\u7845\u57fa\u5316\u8bd5\u5242\uff0c\u5bf9N-\u7532\u57fa\u5432\u54da\u5b9e\u73b0\u4e862\u4f4d\u9009\u62e9\u6027\u7684\u7845\u57fa\u5316(\u56fe 2)\u3002<\/p>\n<p>\u672c\u53cd\u5e94\u88ab\u8ba4\u4e3a\u662f\u901a\u8fc7\u81ea\u7531\u57fa\u53cd\u5e94\u673a\u7406\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5c24\u5bcc\u7535\u5b50\u7684\u82b3\u9999\u6742\u73af\u5316\u5408\u7269\u7684\u7845\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-10269 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-18-39.png\" alt=\"2016-06-06_19-18-39\" width=\"518\" height=\"121\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-18-39.png 518w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-18-39-300x70.png 300w\" sizes=\"(max-width: 518px) 100vw, 518px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe2. 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-10270 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-21-05.png\" alt=\"2016-06-06_19-21-05\" width=\"659\" height=\"157\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-21-05.png 659w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-21-05-300x71.png 300w\" sizes=\"(max-width: 659px) 100vw, 659px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe3 \u6c22\u5bf9\u787c\u914d\u4f4d\u5f62\u6210\u590d\u5408\u4f53<strong>X<\/strong><\/p>\n<p style=\"text-align: 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https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-11-300x64.png 300w\" sizes=\"(max-width: 458px) 100vw, 458px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe4. 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-10272 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-21.png\" alt=\"2016-06-06_19-22-21\" width=\"508\" height=\"404\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-21.png 508w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-21-300x239.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-21-150x120.png 150w\" sizes=\"(max-width: 508px) 100vw, 508px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe5. 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srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-32.png 792w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-32-300x36.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-32-768x92.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/06\/2016-06-06_19-22-32-680x82.png 680w\" sizes=\"(max-width: 792px) 100vw, 792px\" \/><\/p>\n<p style=\"text-align: center\">\u56fe 6. \u6742\u539f\u5b50\u53d6\u4ee3\u7684\u7845\u5316\u5408\u7269\u7684\u5408\u6210<\/p>\n<h4>\u603b\u7ed3<\/h4>\n<p>\u8fd9\u4e00\u6b21\u6211\u4eec\u4ecb\u7ecd\u4e86\u4e0d\u5229\u4e8e\u4efb\u4f55\u91d1\u5c5e\u7684\u787c\u50ac\u5316\u7684\u7845\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u7684\u4f18\u70b9\u867d\u7136\u662f\u663e\u800c\u6613\u89c1\u7684\uff0c\u4f46\u662f\u5e76\u4e0d\u80fd\u5b8c\u5168\u53d6\u4ee3\u91d1\u5c5e\u50ac\u5316\u7684\u7845\u57fa\u5316\u53cd\u5e94\u3002\u867d\u7136\u8be5\u53cd\u5e94\u5bf9\u7845\u57fa\u5316\u8bd5\u5242\u7684\u9002\u7528\u6027\u5f88\u5e7f\uff0c\u4f46\u662f\u7531\u4e8e\u5e95\u7269\u9650\u5236\u5728\u82ef\u80fa\u884d\u751f\u7269\uff0c\u8fd9\u662f\u8be5\u6587\u7ae0\u7684\u4e00\u4e2a\u5f31\u70b9\u3002<\/p>\n<p>\u4f46\u662f\uff0c\u5bf9\u4e8eC-H\u7845\u57fa\u5316\u53cd\u5e94\u6765\u8bf4\u672c\u6587\u4e2d\u5229\u7528\u6b63\u7535\u6027\u7684\u7845\u6d3b\u6027\u4e2d\u95f4\u4f53\u8fd9\u4e00\u4e2a\u65b9\u6cd5\u662f\u5341\u5206\u5c11\u89c1\u7684\uff0c\u6216\u8bb8\u8fd9\u5c06\u4e3a\u4ee5\u540e\u7684\u8fdb\u4e00\u6b65\u7684\u787c\u50ac\u5316\u7845\u57fa\u5316\u53cd\u5e94\u63d0\u4f9b\u4e00\u6247\u5927\u95e8\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li>Cheng, C.; Hartwig, J. F. <em>Chem. Rev<\/em>. <strong>2015<\/strong>, <em>115<\/em>, 8946. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/cr5006414\">10.1021\/cr5006414<\/a><\/li>\n<li>Cheng, C.; Hartwig, J. F. <em>Science<\/em> <strong>2014<\/strong>, <em>136<\/em>, 12064. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ja505844k\">10.1021\/ja505844k<\/a><\/li>\n<li>Cheng, C.; Hartwig, J. F. <em>J. Am. Chem. Soc.<\/em> <strong>2015<\/strong>, <em>137<\/em>, 592. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja505844k\">10.1021\/ja505844k<\/a><\/li>\n<li>Toutov, A. A.; Liu, W. B.; Betz, K. N.; Fedorov, A.; Stoltz, B. M.; Grubbs, R. H. <em>Nature<\/em> <strong>2015<\/strong>, <em>518<\/em>, 80. Di:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1038\/nature14126\">10.1038\/nature14126<\/a><\/li>\n<li>(a) Blackwell, J. M.; Foster, K. L.; Beck, V. H.; Piers, W. E. <em>J. Org. Chem.<\/em> <strong>1999<\/strong>, <em>64<\/em>, 4887. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/jo9903003\">10.1021\/jo9903003<\/a>(b) Parks, D. J.; Blackwell, M.; Piers, W. E. <em>J. Org. Chem.<\/em> <strong>2000<\/strong>, <em>65<\/em>, 3090. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/jo991828a\">10.1021\/jo991828a<\/a> (c) Piers, W. E.; Marwitz, A. J. V.; Mercier, L. G. <em>Inorg. Chem.<\/em> <strong>2011<\/strong>, <em>50<\/em>, 12252. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ic2006474\">10.1021\/ic2006474<\/a> (d) Houghton, A. Y.; Hurmalainen, J.; Mansikkamaki, A.; Piers, W. E.; Tuononen, H. M. <em>Nat. Chem.<\/em> <strong>2014<\/strong>, <em>6<\/em>, 983. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1038\/nchem.2063\">10.1038\/nchem.2063<\/a><\/li>\n<li>Ma, Y.; \u00a0Wang, B.; Zhang, L.; Hou,\u00a0Z.\u00a0<i>J. Am. Chem. Soc.<\/i>,\u00a0<b>2016<\/b>, 138, 3663. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/jacs.6b01349\">10.1021\/jacs.6b01349<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u4eca\u5e74\u5e74\u521d\uff0c\u5c0f\u7f16\u4ecb\u7ecd\u4e86\u4e00\u7bc7\u78b1\u91d1\u5c5e\u50ac\u5316\u7684C-H\u952e\u7684\u76f4\u63a5\u7845\u57fa\u5316\u53cd\u5e94\uff0c\u4e0d\u77e5\u9053\u5927\u5bb6\u662f\u5426\u8fd8\u8bb0\u5f97\uff08\u8bb0\u4e8b\uff1a\u4ec0\u4e48\uff1f\u78b1\u91d1\u5c5e\u53d1\u751f\u7684\u7845\u57fa\u5316\u53cd\u5e94!\uff09\u3002\u90a3\u7bc7\u6587\u7ae0\u6253\u7834\u4e86\u5e38\u89c4\u7684\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u4f20\u7edf\uff0c\u53ea\u662f\u5229\u7528\u78b1\u91d1\u5c5e\uff08KOt-Bu\uff09\u5c31\u53ef\u4ee5\u8fbe\u5230\u7845\u57fa\u5316\u7684\u76ee\u7684\uff0c\u662f\u4e00\u4e2a\u5341\u5206\u6709\u7a81\u7834\u6027\u7684\u7814\u7a76\u3002 \u6700\u8fd1\uff0c\u65e5\u672c\u7406\u5316\u7814\u7a76\u6240\u4faf\u6559\u6388\uff08\u6211\u4eecchem-station\u505a\u8fc7\u4faf\u8001\u5e08\u7684\u4e13\u8bbf-\u7b51\u68a6\u5316\u5b66\u952e\u7684\u81ea\u7531\u5207\u65ad\u3001\u81ea\u7531\u6784\u5efa\uff0c\u6709\u5174\u8da3\u7684\u53ef\u4ee5\u70b9\u5f00\u94fe\u63a5\u56de\u987e\u4e0b\uff09\u5728\u8fd9\u4e2a\u57fa\u7840\u4e0a\u66f4\u8fdb\u4e00\u6b65\uff0c\u76f4\u63a5\u4e0d\u9700\u8981\u4f7f\u7528\u4efb\u4f55\u91d1\u5c5e\u5c31\u53ef\u4ee5\u8fbe\u5230C-H\u7845\u57fa\u5316\u53cd\u5e94\u3002 \u672c\u6587\u5c0f\u7f16\u6574\u7406\u4e86\u4e00\u4e0b\u6700\u8fd1\u51e0\u5e74\u7684\u5177\u6709\u4ee3\u8868\u6027\u7684\u4e09\u79cd\u76f4\u63a5\u7845\u57fa\u5316\u53cd\u5e94\u624b\u6cd5\uff0c\u5e76\u4e14\u91cd\u70b9\u4ecb\u7ecd\u4e00\u4e0b\u4faf\u8001\u5e08\u7684\u8fd9\u7b2c\u4e09\u79cd\u65b9\u6cd5\uff1a\u787c\u50ac\u5316\u7684C-H\u7845\u57fa\u5316\u53cd\u5e94\u3002 Ma, Y.; \u00a0Wang, B.; Zhang, L.; Hou,\u00a0Z.\u00a0J. Am. Chem. Soc.,\u00a02016, 138, 3663. 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F. Chem. Rev. 2015, 115, 8946. DOI:\u00a010.1021\/cr5006414 Cheng, C.; Hartwig, J. F. Science 2014, 136, 12064. DOI: 10.1021\/ja505844k Cheng, C.; Hartwig, J. F. J. Am. Chem. Soc. 2015, 137, 592. DOI:\u00a010.1021\/ja505844k Toutov, A. A.; Liu, W. B.; Betz, K. N.; Fedorov, A.; Stoltz, B. M.; Grubbs, R. H. Nature 2015, 518, 80. 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