{"id":11855,"date":"2016-11-01T08:14:30","date_gmt":"2016-11-01T00:14:30","guid":{"rendered":"\/\/www.gsbet888.com\/?p=11855"},"modified":"2019-08-02T18:53:52","modified_gmt":"2019-08-02T10:53:52","slug":"%e6%9c%89%e6%9c%ba%e5%8f%a0%e6%b0%ae%e5%8c%96%e5%90%88%e7%89%a9%ef%bc%883%ef%bc%89%ef%bc%9a%e5%8f%a0%e6%b0%ae%e5%8c%96%e8%af%95%e5%89%82","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2016\/11\/%e6%9c%89%e6%9c%ba%e5%8f%a0%e6%b0%ae%e5%8c%96%e5%90%88%e7%89%a9%ef%bc%883%ef%bc%89%ef%bc%9a%e5%8f%a0%e6%b0%ae%e5%8c%96%e8%af%95%e5%89%82.html","title":{"rendered":"\u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\uff083\uff09\uff1a\u53e0\u6c2e\u5316\u8bd5\u5242"},"content":{"rendered":"

\u53e0\u6c2e\u7cfb\u5217\u5df2\u7ecf\u4ecb\u7ecd\u4e86\u4e24\u7bc7\u6587\u7ae0\uff0c\u5206\u522b\u662f\u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\uff081\uff09\uff1a\u53d1\u5c55\u5386\u53f2\u53ca\u57fa\u672c\u6027\u8d28<\/a>\uff0c\u4ee5\u53ca\u975e\u5e38\u975e\u5e38\u975e\u5e38\u91cd\u8981\u7684\uff01 \u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\uff082\uff09\uff1a\u7206\u70b8\u6027<\/a>\u3002\u8fd9\u4e00\u6b21\uff0c\u5c0f\u7f16\u51c6\u5907\u4ecb\u7ecd\u4e0b\u53e0\u6c2e\u5316\u5408\u7269\u5230\u5e95\u662f\u5982\u4f55\u5236\u5907\u7684\uff0c\u4ee5\u53ca\u6bd4\u8f83\u5177\u6709\u4ee3\u8868\u6027\u7684\u300c\u53e0\u6c2e\u5bfc\u5165\u5242\u300d\uff08\u53e0\u6c2e\u5316\u8bd5\u5242\uff09<\/strong>\u3002<\/p>\n

\u4ee3\u8868\u6027\u7684\u53e0\u6c2e\u5bfc\u5165\u5242<\/h4>\n
\n
\u53e0\u6c2e\u94a0<\/strong><\/li>\n<\/ul>\n
\u4f7f\u7528\u6700\u5e7f\u6700\u666e\u904d\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u8981\u5c5e\u53e0\u6c2e\u94a0\uff08Sodium azide\uff09<\/strong>\uff0c\u5e74\u751f\u4ea7\u91cf\u5927\u6982\u67091000\u5428\u3002\u5176\u5b9e\u8be5\u8bd5\u5242\u65e9\u5728\u5f88\u4e45\u524d\u5c31\u5df2\u7ecf\u6709\u62a5\u9053\u4e86\uff0c\u6700\u521d\u53ef\u4ee5\u8ffd\u6eaf\u52301892\u5e74\u7684Wislicenus\u5408\u6210\u6cd5<\/strong>\uff0c\u5373\u6c28\u57fa\u94a0\u4e0e\u4e00\u6c27\u5316\u4e8c\u6c2e\u53cd\u5e94\u7684\u624b\u6cd5\u3002\u4e4b\u540e\u3001\u57281908\u5e74\uff0cCurtius\u30fbThiele\u62a5\u9053\u4e86\u4ee5\u4e59\u9187\u4e3a\u539f\u6599\uff0c\u5e76\u4e14\u4f7f\u7528\u4e9a\u785d\u9178\u916f\u8fdb\u884c\u53cd\u5e94\u7684\u5408\u6210\u6cd5\uff08\u4e0b\u56fe\uff09\u3002<\/p>\n
$\"%e5%9b%b32\"$ <\/p>\n
\u6700\u65e9\u7684\u4e24\u79cd\u53e0\u6c2e\u94a0\u7684\u5408\u6210\u6cd5<\/p>\n
\n
\u53e0\u6c2e\u4e09\u7532\u57fa\u7845\u70f7<\/b><\/li>\n<\/ul>\n
\u53e0\u6c2e\u4e09\u7532\u57fa\u7845\u70f7(\u00a0Trimethylsilyl Azide: TMSA)<\/strong>\u662f\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u300c\u53ef\u6eb6\u300d\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u5e74\u4ea7\u91cf10\u5428\u5de6\u53f3\u3002\u4e0e\u53e0\u6c2e\u94a0\u76f8\u6bd4\uff0c\u5176\u5177\u6709\u53ef\u6eb6\u4e8e\u76f8\u5bf9\u975e\u6781\u6027\u6eb6\u5242\u7684\u7279\u5f81\u3002\u5e76\u4e14\u5236\u5907\u4e5f\u5341\u5206\u7b80\u5355\uff0c\u4ec5\u4ec5\u53ea\u9700\u8981\u628aTMSCl\u4e0eNaN3\u6df7\u5408\u5c31\u80fd\u591f\u5f97\u5230\u3002\u5f53\u7136\u76f8\u6bd4\u4e8e\u53e0\u6c2e\u5316\u94a0\u6765\u8bf4\u4ef7\u683c\u65b9\u9762\u80af\u5b9a\u66f4\u8d35\u4e86\u3002<\/p>\n
$\"%e5%9b%b33\"$ <\/p>\n
\n
\u53e0\u6c2e\u78f7\u9178\u4e8c\u82ef\u916f<\/strong><\/li>\n<\/ul>\n
\u53e0\u6c2e\u78f7\u9178\u4e8c\u82ef\u916f(Diphenylphosphoryl Azide\uff1a DPPA)<\/strong>\u662f\u5b89\u5168<\/strong>\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u3002\u8be5\u8bd5\u5242\u53ef\u4ee5\u628a\u7fa7\u9178\u6216\u8005\u7f9f\u57fa\u76f4\u63a5\u8f6c\u6362\u6210\u9170\u57fa\u53e0\u6c2e\u30fb\u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\u3002\u5f00\u53d1\u8fd9\u4e2a\u8bd5\u5242\u7684\u662f\u65e5\u672c\u4eba\uff0c\u5869\u5165\u5b5d\u4e4b\u6559\u6388\uff08\u540d\u53e4\u5c4b\u5e02\u7acb\u5927\u5b66\u4e0e\u540d\u57ce\u5927\u5b66\u540d\u8a89\u6559\u6388\uff09\uff0c\u5229\u7528DPPA\u5de5\u4e1a\u5236\u5907\u4e09\u7532\u57fa\u7845\u70f7\u5316\u91cd\u6c2e\u7532\u70f7\u4ee5\u53ca\u7845\u70f7\u5316\u5408\u7269\u5df2\u7ecf\u975e\u5e38\u6210\u719f\u5b89\u5168\u3002\u800cDPPA\u7684\u5236\u5907\u6cd5\u4e5f\u5f88\u7b80\u5355\uff0c\u5728\u5bf9\u5e94\u7684\u78f7\u9178\u6c2f\u5316\u7269\u4e2d\u52a0\u5165\u53e0\u6c2e\u94a0\u5373\u53ef\u3002<\/p>\n
$\"%e5%9b%b34\"$ <\/p>\n
\n
\u4e09\u4e01\u57fa\u9521\u53e0\u6c2e\u5316\u7269\u548c\u53e0\u6c2e\u5316\u56db\u4e01\u57fa\u94f5<\/strong><\/li>\n<\/ul>\n
\u4e0a\u8ff0\u4e09\u79cd\u53e0\u6c2e\u5316\u8bd5\u5242\u662f\u6700\u5e38\u7528\u7684\u4e09\u79cd\uff0c\u9664\u6b64\u4ee5\u5916\u8fd8\u6709\u4ee5\u4e0b\u51e0\u79cd\u4e0d\u592a\u5e38\u7528\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u5c0f\u7f16\u5728\u8fd9\u91cc\u4e00\u5e76\u4ecb\u7ecd\u4e0b\u3002\u5176\u4e2d\u4e4b\u4e00\u7684\u662f\u4e09\u4e01\u57fa\u9521\u53e0\u6c2e<\/strong>\uff08Tributyltin Azide: TBSnA\uff09<\/strong>\u3002\u867d\u7136\u542b\u9521\u5316\u5408\u7269\u90fd\u6709\u6bd2\uff0c\u4f46\u662f\u8be5\u8bd5\u5242\u7684\u5e74\u4ea7\u91cf\u786e\u60ca\u4eba\u7684\u6709100\u5428\u5de6\u53f3\u3002\u53e0\u6c2e\u5316\u56db\u4e01\u57fa\u94f5<\/strong>\uff08Tetrabutylammonium Azide: TBAA\uff09<\/strong>\u53ef\u4ee5\u7528\u4e8e\u76f8\u8f6c\u79fb\u50ac\u5316\u4e2d\uff0c\u5e76\u4e14\u6eb6\u5242\u7684\u9009\u62e9\u4e0a\u53ef\u4ee5\u4f7f\u7528THF\uff0c\u8fd9\u4e9b\u662f\u5b83\u7684\u4e24\u5927\u7279\u70b9\uff0c\u5e74\u4ea7\u91cf\u57281\u5428\u5de6\u53f3\u3002<\/p>\n
$\"2016-10-15_03-25-42\"$ <\/p>\n
\n
\u53e0\u6c2e\u56db\u7532\u57fa\u80cd\u5316\u5408\u7269<\/strong><\/li>\n<\/ul>\n
\u53e0\u6c2e\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidinium azide:TMGA\uff09<\/strong>^{[4]<\/sup>\u53ef\u4ee5\u7a33\u5b9a\u6b63\u79bb\u5b50\uff0c\u4f5c\u4e3a\u4eb2\u6838\u6027\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u5177\u6709\u5f88\u597d\u7684\u6d3b\u6027\u3002<\/p>\n}
$\"2016-10-15_03-29-21\"$ <\/p>\n
\n
\u4e59\u57fa\u53e0\u6c2e\u918b\u9178\u916f<\/strong><\/li>\n<\/ul>\n
Azidoacetic acid ethylester: AAE<\/strong>\u4e3b\u8981\u7528\u4e8e\u6742\u73af\u5408\u6210\u6cd5\u4e2d\uff0c\u5c24\u5176\u662f\u5728\u6742\u73af\u4e0a\u5bfc\u5165\u53e0\u6c2e\uff0c\u53cd\u5e94\u6d3b\u6027\u9ad8\uff0c\u4fbf\u5229\u3002\u5e74\u4ea7\u91cf\u5728100kg\u5de6\u53f3\u3002\u5230\u8fd9\u4e2a\u5316\u5408\u7269\u4e3a\u6b62\uff0c\u5c0f\u7f16\u4ecb\u7ecd\u7684\u90fd\u662f\u4eb2\u6838\u6027\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u3002<\/p>\n
$\"2016-10-15_03-29-40\"$ <\/p>\n
\n
\u201cN_{3<\/sub>^{+<\/sup>\u201d\u578b\u53e0\u6c2e\u5316\u8bd5\u5242<\/strong><\/li>\n<\/ul>\n\u4ee5\u4e0b\u4e09\u79cd\u53e0\u6c2e\u5316\u8bd5\u5242\u662f\u4f5c\u4e3a\u4eb2\u7535\u5b50\u8bd5\u5242\u5bfc\u5165\u7684\u8bd5\u5242\u3002Azide iodinane<\/strong>\u6839\u636eR\u57fa\u56e2\u7684\u4e0d\u540c\u53cd\u5e94\u6d3b\u6027\u4e5f\u6709\u5dee\u5f02\uff0c\u4f5c\u4e3a\u4eb2\u7535\u6027\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u4e0e\u4eb2\u6838\u8bd5\u5242\u53cd\u5e94\u5bfc\u5165\u53e0\u6c2e\u30024-acetamidobenzenesulfonyl azide<\/strong> \u540c\u6837\u4e5f\u662f\u4e0e\u4eb2\u6838\u8bd5\u5242\u8fdb\u884c\u53cd\u5e94\uff0c\u4e00\u770b\u7ed3\u6784\u5c31\u77e5\u9053\u662f\u7532\u82ef\u78fa\u9170\u57fa\u53e0\u6c2e\u5316\u7269\u7684\u884d\u751f\u7269\u3002\u6700\u5f8c\u306b\u30012-azido-1,3-dimethylimidazolinium hexafluorophosphate<\/strong>\u662f\u975e\u5e38\u5f3a\u7684\u4eb2\u7535\u5b50\u53e0\u6c2e\u5316\u8bd5\u5242\u3002<\/p>\n
<\/p>\n
\u8fd9\u4e00\u6b21\uff0c\u4e3b\u8981\u4ecb\u7ecd\u4e86\u4e00\u4e0b\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u4e0b\u96c6\u9884\u544a\uff1a\u53e0\u6c2e\u5316\u53cd\u5e94\uff0c\u656c\u8bf7\u7ee7\u7eed\u5173\u6ce8\u3002\u3001<\/p>\n
<\/p>\n}}
\u5173\u8054\u6587\u732e<\/h4>\n\n
Wislicenus, W. Ber. Dtsch. Chem. Ges.<\/i> 1892<\/b> , 25<\/i> , 2084.<\/li>\n
(a) Curtius, T. Ber. Dtsch. Chem. Ges.<\/i> 1890<\/b> , 23 <\/i>, 3023. (b) Thiele, J. Ber. Dtsch. Chem. Ges.<\/i> 1908<\/b>, 41<\/i>, 2681.<\/li>\n
Birkofer, L.; Wegner, P. Org. Synth.<\/i> 1970<\/b> , 50<\/i> , 107. DOI:\u00a010.15227\/orgsyn.050.0107<\/a><\/li>\n
(a)\u00a0 Papa, A. J. J. Org. Chem.<\/i> 1966<\/b>, 31, 1426. DOI:10.1021\/jo01343a026<\/a>\u00a0(b) B\u0142aszczyk, R. Synlett<\/i>, 2008<\/b>, 299. DOI:\u00a010.1055\/s-2007-1000842<\/a><\/li>\n<\/ol>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u53e0\u6c2e\u7cfb\u5217\u5df2\u7ecf\u4ecb\u7ecd\u4e86\u4e24\u7bc7\u6587\u7ae0\uff0c\u5206\u522b\u662f\u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\uff081\uff09\uff1a\u53d1\u5c55\u5386\u53f2\u53ca\u57fa\u672c\u6027\u8d28\uff0c\u4ee5\u53ca\u975e\u5e38\u975e\u5e38\u975e\u5e38\u91cd\u8981\u7684\uff01\u6709\u673a\u53e0\u6c2e\u5316\u5408\u7269\uff082\uff09\uff1a\u7206\u70b8\u6027\u3002\u8fd9\u4e00\u6b21\uff0c\u5c0f\u7f16\u51c6\u5907\u4ecb\u7ecd\u4e0b\u53e0\u6c2e\u5316\u5408\u7269\u5230\u5e95\u662f\u5982\u4f55\u5236\u5907\u7684\uff0c\u4ee5\u53ca\u6bd4\u8f83\u5177\u6709\u4ee3\u8868\u6027\u7684\u300c\u53e0\u6c2e\u5bfc\u5165\u5242\u300d\uff08\u53e0\u6c2e\u5316\u8bd5\u5242\uff09\u3002 \u4ee3\u8868\u6027\u7684\u53e0\u6c2e\u5bfc\u5165\u5242 \u53e0\u6c2e\u94a0 \u4f7f\u7528\u6700\u5e7f\u6700\u666e\u904d\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u8981\u5c5e\u53e0\u6c2e\u94a0\uff08Sodium azide\uff09\uff0c\u5e74\u751f\u4ea7\u91cf\u5927\u6982\u67091000\u5428\u3002\u5176\u5b9e\u8be5\u8bd5\u5242\u65e9\u5728\u5f88\u4e45\u524d\u5c31\u5df2\u7ecf\u6709\u62a5\u9053\u4e86\uff0c\u6700\u521d\u53ef\u4ee5\u8ffd\u6eaf\u52301892\u5e74\u7684Wislicenus\u5408\u6210\u6cd5\uff0c\u5373\u6c28\u57fa\u94a0\u4e0e\u4e00\u6c27\u5316\u4e8c\u6c2e\u53cd\u5e94\u7684\u624b\u6cd5\u3002\u4e4b\u540e\u3001\u57281908\u5e74\uff0cCurtius\u30fbThiele\u62a5\u9053\u4e86\u4ee5\u4e59\u9187\u4e3a\u539f\u6599\uff0c\u5e76\u4e14\u4f7f\u7528\u4e9a\u785d\u9178\u916f\u8fdb\u884c\u53cd\u5e94\u7684\u5408\u6210\u6cd5\uff08\u4e0b\u56fe\uff09\u3002 \u6700\u65e9\u7684\u4e24\u79cd\u53e0\u6c2e\u94a0\u7684\u5408\u6210\u6cd5 \u53e0\u6c2e\u4e09\u7532\u57fa\u7845\u70f7 \u53e0\u6c2e\u4e09\u7532\u57fa\u7845\u70f7(\u00a0Trimethylsilyl Azide: TMSA)\u662f\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u300c\u53ef\u6eb6\u300d\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u5e74\u4ea7\u91cf10\u5428\u5de6\u53f3\u3002\u4e0e\u53e0\u6c2e\u94a0\u76f8\u6bd4\uff0c\u5176\u5177\u6709\u53ef\u6eb6\u4e8e\u76f8\u5bf9\u975e\u6781\u6027\u6eb6\u5242\u7684\u7279\u5f81\u3002\u5e76\u4e14\u5236\u5907\u4e5f\u5341\u5206\u7b80\u5355\uff0c\u4ec5\u4ec5\u53ea\u9700\u8981\u628aTMSCl\u4e0eNaN3\u6df7\u5408\u5c31\u80fd\u591f\u5f97\u5230\u3002\u5f53\u7136\u76f8\u6bd4\u4e8e\u53e0\u6c2e\u5316\u94a0\u6765\u8bf4\u4ef7\u683c\u65b9\u9762\u80af\u5b9a\u66f4\u8d35\u4e86\u3002 \u53e0\u6c2e\u78f7\u9178\u4e8c\u82ef\u916f \u53e0\u6c2e\u78f7\u9178\u4e8c\u82ef\u916f(Diphenylphosphoryl Azide\uff1a 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\u4e0a\u8ff0\u4e09\u79cd\u53e0\u6c2e\u5316\u8bd5\u5242\u662f\u6700\u5e38\u7528\u7684\u4e09\u79cd\uff0c\u9664\u6b64\u4ee5\u5916\u8fd8\u6709\u4ee5\u4e0b\u51e0\u79cd\u4e0d\u592a\u5e38\u7528\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u5c0f\u7f16\u5728\u8fd9\u91cc\u4e00\u5e76\u4ecb\u7ecd\u4e0b\u3002\u5176\u4e2d\u4e4b\u4e00\u7684\u662f\u4e09\u4e01\u57fa\u9521\u53e0\u6c2e\uff08Tributyltin Azide: TBSnA\uff09\u3002\u867d\u7136\u542b\u9521\u5316\u5408\u7269\u90fd\u6709\u6bd2\uff0c\u4f46\u662f\u8be5\u8bd5\u5242\u7684\u5e74\u4ea7\u91cf\u786e\u60ca\u4eba\u7684\u6709100\u5428\u5de6\u53f3\u3002\u53e0\u6c2e\u5316\u56db\u4e01\u57fa\u94f5\uff08Tetrabutylammonium Azide: TBAA\uff09\u53ef\u4ee5\u7528\u4e8e\u76f8\u8f6c\u79fb\u50ac\u5316\u4e2d\uff0c\u5e76\u4e14\u6eb6\u5242\u7684\u9009\u62e9\u4e0a\u53ef\u4ee5\u4f7f\u7528THF\uff0c\u8fd9\u4e9b\u662f\u5b83\u7684\u4e24\u5927\u7279\u70b9\uff0c\u5e74\u4ea7\u91cf\u57281\u5428\u5de6\u53f3\u3002 \u53e0\u6c2e\u56db\u7532\u57fa\u80cd\u5316\u5408\u7269 \u53e0\u6c2e\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidinium azide:TMGA\uff09[4]\u53ef\u4ee5\u7a33\u5b9a\u6b63\u79bb\u5b50\uff0c\u4f5c\u4e3a\u4eb2\u6838\u6027\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u5177\u6709\u5f88\u597d\u7684\u6d3b\u6027\u3002 \u4e59\u57fa\u53e0\u6c2e\u918b\u9178\u916f Azidoacetic acid ethylester: AAE\u4e3b\u8981\u7528\u4e8e\u6742\u73af\u5408\u6210\u6cd5\u4e2d\uff0c\u5c24\u5176\u662f\u5728\u6742\u73af\u4e0a\u5bfc\u5165\u53e0\u6c2e\uff0c\u53cd\u5e94\u6d3b\u6027\u9ad8\uff0c\u4fbf\u5229\u3002\u5e74\u4ea7\u91cf\u5728100kg\u5de6\u53f3\u3002\u5230\u8fd9\u4e2a\u5316\u5408\u7269\u4e3a\u6b62\uff0c\u5c0f\u7f16\u4ecb\u7ecd\u7684\u90fd\u662f\u4eb2\u6838\u6027\u7684\u53e0\u6c2e\u5316\u8bd5\u5242\u3002 \u201cN3+\u201d\u578b\u53e0\u6c2e\u5316\u8bd5\u5242 \u4ee5\u4e0b\u4e09\u79cd\u53e0\u6c2e\u5316\u8bd5\u5242\u662f\u4f5c\u4e3a\u4eb2\u7535\u5b50\u8bd5\u5242\u5bfc\u5165\u7684\u8bd5\u5242\u3002Azide iodinane\u6839\u636eR\u57fa\u56e2\u7684\u4e0d\u540c\u53cd\u5e94\u6d3b\u6027\u4e5f\u6709\u5dee\u5f02\uff0c\u4f5c\u4e3a\u4eb2\u7535\u6027\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u4e0e\u4eb2\u6838\u8bd5\u5242\u53cd\u5e94\u5bfc\u5165\u53e0\u6c2e\u30024-acetamidobenzenesulfonyl azide \u540c\u6837\u4e5f\u662f\u4e0e\u4eb2\u6838\u8bd5\u5242\u8fdb\u884c\u53cd\u5e94\uff0c\u4e00\u770b\u7ed3\u6784\u5c31\u77e5\u9053\u662f\u7532\u82ef\u78fa\u9170\u57fa\u53e0\u6c2e\u5316\u7269\u7684\u884d\u751f\u7269\u3002\u6700\u5f8c\u306b\u30012-azido-1,3-dimethylimidazolinium hexafluorophosphate\u662f\u975e\u5e38\u5f3a\u7684\u4eb2\u7535\u5b50\u53e0\u6c2e\u5316\u8bd5\u5242\u3002 \u8fd9\u4e00\u6b21\uff0c\u4e3b\u8981\u4ecb\u7ecd\u4e86\u4e00\u4e0b\u53e0\u6c2e\u5316\u8bd5\u5242\uff0c\u4e0b\u96c6\u9884\u544a\uff1a\u53e0\u6c2e\u5316\u53cd\u5e94\uff0c\u656c\u8bf7\u7ee7\u7eed\u5173\u6ce8\u3002\u3001 \u5173\u8054\u6587\u732e Wislicenus, W. Ber. Dtsch. Chem. Ges. 1892 , 25 , 2084. (a) Curtius, T. Ber. Dtsch. Chem. Ges. 1890 , 23 , 3023. (b) Thiele, J. Ber. Dtsch. Chem. Ges. 1908, 41, 2681. Birkofer, L.; Wegner, P. Org. Synth. 1970 , 50 , 107. DOI:\u00a010.15227\/orgsyn.050.0107 (a)\u00a0 Papa, A. J. J. Org. Chem. 1966, 31, 1426. DOI:10.1021\/jo01343a026\u00a0(b) B\u0142aszczyk, R. Synlett, 2008, 299. 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