{"id":12515,"date":"2016-12-22T09:17:49","date_gmt":"2016-12-22T01:17:49","guid":{"rendered":"\/\/www.gsbet888.com\/?p=12515"},"modified":"2019-08-02T18:53:42","modified_gmt":"2019-08-02T10:53:42","slug":"%e7%a1%bc%e6%b0%a2%e5%8c%96%e9%94%8c-zinc-borohydride","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2016\/12\/%e7%a1%bc%e6%b0%a2%e5%8c%96%e9%94%8c-zinc-borohydride.html","title":{"rendered":"\u787c\u6c22\u5316\u950c Zinc Borohydride"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p><strong>\u787c\u6c22\u5316\u950cZn(BH<sub>4<\/sub>)<sub>2<\/sub><\/strong>\u662f\u7531ZnCl<sub>2<\/sub>\u4e0eNaBH<sub>4<\/sub>\u5236\u5907\u7684\u4e00\u79cd\u8fd8\u539f\u5242\u3002\u8be5\u8fd8\u539f\u5242\u53ef\u4ee5\u4f18\u5148\u8fdb\u884c1,2-\u8fd8\u539f\u3002\u540c\u65f6\uff0c\u5728\u4e00\u4e2a\u57fa\u56e2\u4e2d\u540c\u65f6\u5b58\u5728\u4e24\u4e2a\u7fb0\u57fa\uff08\u916e\u6216\u8005\u919b\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u76f8\u6bd4\u4e8e\u5171\u8f6d\u916e\u6765\u8bf4\uff0c\u975e\u5171\u8f6d\u7684\u916e\u7fb0\u57fa\u4f1a\u88ab\u9009\u62e9\u6027\u4f18\u5148\u8fd8\u539f\u3002<\/p>\n<p>\u53e6\u5916\u5982\u679c\u6709\u5bfc\u5411\u6027\u5b98\u80fd\u56e2\u7684\u5e95\u7269\uff0c\u53ef\u4ee5\u901a\u8fc7\u5f62\u6210<strong>Felkin-Anh Model<\/strong><strong>\u53d1\u751f<\/strong>\u975e\u5bfe\u6620\u5f02\u6784\u9009\u62e9\u7684\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Kotsuki, H.; Yoshimura, N.; Ushio, Y.; Ohtsuka, T.; Ochi, M. <em>Chem.\u00a0Lett.<\/em><strong>1986<\/strong>, 1003. doi:<a href=\"http:\/\/dx.doi.org\/10.1246\/cl.1986.1003\">10.1246\/cl.1986.1003<\/a><\/li>\n<li>Oishi, T.; Nakata, T.<em> Acc. Chem. Res.<\/em> <strong>1984<\/strong>,\u00a0<em>17<\/em>, 338. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ar00105a007\">10.1021\/ar00105a007<\/a><\/li>\n<li>Ranu, B. C. <em>Synlett<\/em> <strong>1993<\/strong>, 885. DOI: <a href=\"http:\/\/dx.doi.org\/10.1055\/s-1993-22640\">10.1055\/s-1993-22640<\/a><\/li>\n<li>Narashimhan, S.; Balakumar, R. <em>Aldrichimica Acta<\/em> <strong>1998<\/strong>,\u00a0<em>31<\/em>, 19. <a href=\"https:\/\/www.erowid.org\/archive\/rhodium\/pdf\/zinc.borohydride.pdf\">[PDF]<\/a><\/li>\n<li>Oishi, T.; Nakata, T.<em> e-EROS<\/em> DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/047084289X.rz004\">10.1002\/047084289X.rz004<\/a><\/li>\n<li>Gama, I. L. <em>Synlett<\/em> <strong>2012<\/strong>, <em>23<\/em>,\u00a0642. DOI: <a href=\"http:\/\/dx.doi.org\/10.1055\/s-0031-1290334\">10.1055\/s-0031-1290334<\/a><\/li>\n<\/ul>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u975e\u5bfe\u6620\u9009\u62e9\u6027\u7684\u53d1\u751f\u53ef\u4ee5\u53c2\u8003<strong>Felkin-Anh Model<\/strong>\u3002<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-12517 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/12\/ZnBH4_2.gif\" width=\"328\" height=\"205\" \/><\/p>\n<h4>\u76f8\u5173\u94fe\u63a5<\/h4>\n<ul>\n<li><a href=\"http:\/\/ja.wikipedia.org\/wiki\/%E3%83%92%E3%83%89%E3%83%AA%E3%83%89%E9%82%84%E5%85%83\">\u6c22\u5316\u8fd8\u539f \u2013 Wikipedia<\/a><\/li>\n<\/ul>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u787c\u6c22\u5316\u950cZn(BH4)2\u662f\u7531ZnCl2\u4e0eNaBH4\u5236\u5907\u7684\u4e00\u79cd\u8fd8\u539f\u5242\u3002\u8be5\u8fd8\u539f\u5242\u53ef\u4ee5\u4f18\u5148\u8fdb\u884c1,2-\u8fd8\u539f\u3002\u540c\u65f6\uff0c\u5728\u4e00\u4e2a\u57fa\u56e2\u4e2d\u540c\u65f6\u5b58\u5728\u4e24\u4e2a\u7fb0\u57fa\uff08\u916e\u6216\u8005\u919b\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u76f8\u6bd4\u4e8e\u5171\u8f6d\u916e\u6765\u8bf4\uff0c\u975e\u5171\u8f6d\u7684\u916e\u7fb0\u57fa\u4f1a\u88ab\u9009\u62e9\u6027\u4f18\u5148\u8fd8\u539f\u3002 \u53e6\u5916\u5982\u679c\u6709\u5bfc\u5411\u6027\u5b98\u80fd\u56e2\u7684\u5e95\u7269\uff0c\u53ef\u4ee5\u901a\u8fc7\u5f62\u6210Felkin-Anh Model\u53d1\u751f\u975e\u5bfe\u6620\u5f02\u6784\u9009\u62e9\u7684\u8fd8\u539f\u53cd\u5e94\u3002 \u57fa\u672c\u6587\u732e Kotsuki, H.; Yoshimura, N.; Ushio, Y.; Ohtsuka, T.; Ochi, M. Chem.\u00a0Lett.1986, 1003. doi:10.1246\/cl.1986.1003 Oishi, T.; Nakata, T. Acc. Chem. Res. 1984,\u00a017, 338. DOI: 10.1021\/ar00105a007 Ranu, B. C. Synlett 1993, 885. DOI: 10.1055\/s-1993-22640 Narashimhan, S.; Balakumar, R. Aldrichimica Acta 1998,\u00a031, 19. [PDF] Oishi, T.; Nakata, T. e-EROS DOI: 10.1002\/047084289X.rz004 Gama, I. L. Synlett 2012, 23,\u00a0642. DOI: 10.1055\/s-0031-1290334 \u53cd\u5e94\u673a\u7406 \u975e\u5bfe\u6620\u9009\u62e9\u6027\u7684\u53d1\u751f\u53ef\u4ee5\u53c2\u8003Felkin-Anh Model\u3002 \u53cd\u5e94\u5b9e\u4f8b \u76f8\u5173\u94fe\u63a5 \u6c22\u5316\u8fd8\u539f \u2013 Wikipedia \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01","protected":false},"author":5,"featured_media":12516,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2,91],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/12\/2015-01-05_15-00-54.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-3fR","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/12515"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=12515"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/12515\/revisions"}],"predecessor-version":[{"id":27537,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/12515\/revisions\/27537"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/12516"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=12515"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=12515"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=12515"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}