{"id":13187,"date":"2017-02-22T07:15:16","date_gmt":"2017-02-21T23:15:16","guid":{"rendered":"\/\/www.gsbet888.com\/?p=13187"},"modified":"2019-08-02T18:53:31","modified_gmt":"2019-08-02T10:53:31","slug":"%e6%9d%be%e6%b2%b9%e9%86%87-%e9%a6%99%e6%b0%b4%e8%83%8c%e5%90%8e%e7%9a%84%e5%8c%96%e5%ad%a6","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/molecule\/2017\/02\/%e6%9d%be%e6%b2%b9%e9%86%87-%e9%a6%99%e6%b0%b4%e8%83%8c%e5%90%8e%e7%9a%84%e5%8c%96%e5%ad%a6.html","title":{"rendered":"\u677e\u6cb9\u9187\u2014\u9999\u6c34\u80cc\u540e\u7684\u5316\u5b66"},"content":{"rendered":"<p>\u677e\u6811\u662f\u4e00\u79cd\u5e38\u89c1\u7684\u690d\u7269\uff0c\u5177\u6709\u591a\u79cd\u5e94\u7528\u4ef7\u503c\u3002\u4ece\u7f8e\u7d22\u4e0d\u8fbe\u7c73\u4e9a\u7a7f\u8fc7\u57c3\u53ca\u5230\u5e0c\u814a\uff0c\u8fd9\u7247\u53e4\u8001\u571f\u5730\u4e0a\u7684\u4eba\u4eec\u5f88\u65e9\u5c31\u5f00\u59cb\u5229\u7528\u677e\u6811\u76ae\u548c\u677e\u8102\uff0c\u84b8\u998f\u677e\u8102\u53ef\u5f97\u5230\u4e24\u79cd\u4e3b\u8981\u7269\u8d28\uff1a\u677e\u8282\u6cb9\u548c\u677e\u9999\u3002\u524d\u8005\u968f\u7740\u84b8\u6c14\u51fa\u6765\uff0c\u662f\u4e00\u79cd\u523a\u6fc0\u6027\u6c14\u5473\u7684\u900f\u660e\u6db2\u4f53\uff0c\u4e3b\u8981\u7531\u4e00\u7cfb\u5217\u6325\u53d1\u6027\u841c\u70ef\u7ec4\u6210\u3002<\/p>\n<p>\u800c\u6211\u4eec\u4eca\u5929\u8981\u4ecb\u7ecd\u7684\u677e\u6cb9\u9187(<strong>Terpineol<\/strong>)\u5219\u662f\u901a\u8fc7\u5904\u7406\u677e\u8282\u6cb9\u91cc\u7684\u848e\u70ef\u5f97\u5230\u7684\u4e00\u79cd\u4e0d\u9971\u548c\u8f7b\u8d28\u6cb9\uff0c\u901a\u5e38\u60c5\u51b5\u4e0b\u6709\u7740\u5f3a\u70c8\u7684\u6c14\u5473\uff0c\u5f88\u65e9\u4e4b\u524d\u5c31\u7528\u4e8e\u9999\u6599\uff0c\u73b0\u5728\u4ecd\u5e7f\u6cdb\u7528\u4e8e\u9999\u6c34\u3001\u9999\u7cbe\u7684\u8c03\u914d\u3002<sup>[1]<\/sup><\/p>\n<p>\u4f5c\u4e3a\u4e00\u79cd\u9971\u542b\u201c\u9b54\u529b\u201d\u7684\u5962\u4f88\u54c1\uff0c\u8c03\u914d\u9999\u6c34\u8fd9\u95e8\u827a\u672f\u6700\u65e9\u5728\u7f8e\u7d22\u4e0d\u8fbe\u7c73\u4e9a\u548c\u57c3\u53ca\u53d1\u6e90\uff0c\u968f\u540e\u4f20\u5230\u5e0c\u814a\u548c\u7f57\u9a6c\uff0c\u5230\u4e2d\u4e16\u7eaa\u65f6\u963f\u62c9\u4f2f\u4eba\u5c24\u5176\u64c5\u957f\u8c03\u914d\u5f02\u57df\u98ce\u60c5\u7684\u9999\u6c34\u3002\u968f\u7740\u84b8\u998f\u7b49\u6280\u672f\u7684\u8fdb\u6b65\uff0c\u9999\u6c34\u5728\u610f\u5927\u5229\u6587\u827a\u590d\u5174\u65f6\u671f\u9887\u4e3a\u7e41\u8363\uff0c\u540e\u6765\u968f\u774019\u4e16\u7eaa\u5316\u5b66\u548c\u6709\u673a\u5408\u6210\u7684\u8fdb\u6b65\u3002\u5316\u5b66\u5de5\u4e1a\u7684\u8fc5\u901f\u53d1\u5c55\u4f7f\u5fb7\u56fd\u6210\u4e3a\u9999\u6c34\u751f\u4ea7\u4e2d\u5fc3\uff0c\u800c\u6cd5\u56fd\u6210\u4e3a\u9999\u6c34\u8c03\u914d\u4e2d\u5fc3\u3002\u5230\u8fbe21\u4e16\u7eaa\u7684\u4eca\u5929\uff0c\u6cd5\u56fd\u3001\u745e\u58eb\u3001\u5fb7\u56fd\u3001\u7f8e\u56fd\u548c\u65e5\u672c\u90fd\u5728\u9999\u6c34\u4e1a\u5360\u636e\u7740\u91cd\u8981\u5730\u4f4d\u3002<sup>[2]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/1-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13188 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/1-6.png\" width=\"626\" height=\"216\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/1-6.png 626w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/1-6-300x104.png 300w\" sizes=\"(max-width: 626px) 100vw, 626px\" \/><\/a><\/p>\n<p>\u5929\u7136\u4ea7\u7269\u91cc\u8fb9\u7684\u5355\u841c\u662f\u597d\u591a\u5305\u62ec\u67d1\u6a58\u7c7b\u6c34\u679c\u3001\u677e\u6811\u3001\u8584\u8377\u7b49\u5728\u5185\u7684\u690d\u7269\u3001\u6c34\u679c\u53d1\u51fa\u9999\u5473\u7684\u539f\u56e0\u3002\u65e9\u5728\u4e00\u767e\u591a\u5e74\u524d\uff0c\u5316\u5b66\u5bb6\u5c31\u5f00\u59cb\u7814\u7a76\u8fd9\u7c7b\u7269\u8d28\uff0c\u5176\u4e2d\u6c34\u5408\u841c\u54c1(Terpin hydrate)\u572819\u4e16\u7eaa\u7684\u6700\u540e\u51e0\u5341\u5e74\u6fc0\u8d77\u4e86\u5316\u5b66\u5bb6\u7684\u6781\u5927\u5174\u8da3\uff0c\u56f0\u60d1\u4ed6\u4eec\u7684\u4e0d\u4ec5\u4ec5\u662f\u5176\u7ec4\u6210\uff0c\u8fd8\u6709\u5b83\u5bb9\u6613\u4ece\u7c97\u677e\u8282\u6cb9\u4e2d\u6790\u51fa\u7eaf\u51c0\u6676\u4f53\u8fd9\u4e00\u6027\u8d28\u3002\u5176\u4e2d\u6709\u4e24\u4f4d\u79d1\u5b66\u5bb6\u4e0d\u5f97\u4e0d\u63d0\uff0cWilliam Henry Perkin, Jr.\u5408\u6210\u9999\u8c46\u7d20\uff0c\u800c\u4ed6\u7684\u7236\u4eb2William, Sr.\u53d1\u73b0\u4e86\u82ef\u80fa\u7d2b\u2014\u201419\u4e16\u7eaa\u4e00\u79cd\u91cd\u8981\u7684\u67d3\u6599\u3002\u513f\u5b50\u5f88\u597d\u5730\u7ee7\u627f\u4e86\u7236\u4eb2\u5bf9\u4e8e\u672a\u77e5\u4e8b\u7269\u63a2\u7d22\u7684\u70ed\u60c5\uff0c\u5e76\u81f4\u529b\u4e8e\u5408\u6210\u548c\u786e\u5b9a\u4e86\u591a\u79cd\u841c\u70ef\u7684\u7ed3\u6784\u3002<sup>[3]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/2-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13189 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/2-6.png\" width=\"530\" height=\"603\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/2-6.png 530w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/2-6-264x300.png 264w\" sizes=\"(max-width: 530px) 100vw, 530px\" \/><\/a><\/p>\n<p>\u5408\u6210\u8def\u7ebf\u4e2d\u4e24\u6b21\u5e94\u7528\u4e86\u683c\u5f0f\u53cd\u5e94\uff0c\u7b2c\u4e00\u6b21\u662f\u683c\u5f0f\u53cd\u5e94\u7ecf\u5178\u7684\u7528\u9014\u5373\u4e0e\u7fb0\u57fa\u4eb2\u6838\u52a0\u6210\u5f62\u6210\u53d4\u9187\uff0c\u7b2c\u4e8c\u6b21\u7a0d\u8fc7\u91cf\u7684\u683c\u5f0f\u8bd5\u5242\u5148\u4e0e\u916f\u53cd\u5e94\u5f62\u6210\u916e\uff0c\u8fdb\u800c\u518d\u52a0\u6210\u5f97\u5230\u677e\u6cb9\u9187\u3002\u9178\u5904\u7406\u677e\u6cb9\u9187\u5f97\u5230\u6676\u4f53\u7684\u6c34\u5408\u841c\u4e8c\u9187\uff0c\u5728KHSO<sub>4<\/sub>\u4f5c\u7528\u4e0b\u8131\u6c34\u5f97\u5230\u67e0\u6aac\u7cbe\u6cb9\u3002\u5408\u6210\u677e\u6cb9\u9187\u8fc7\u7a0b\u4e2d\uff0c\u683c\u6c0f\u53cd\u5e94\u53d1\u6325\u4e86\u4e3e\u8db3\u8f7b\u91cd\u7684\u4f5c\u7528\uff0c\u4e8b\u5b9e\u4e0a\uff0c1912\u5e74\u6458\u5f97\u201c\u8bfa\u5956\u201d\u6842\u51a0\u7684\u683c\u5f0f\u53cd\u5e94\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u7684\u91cd\u8981\u5730\u4f4d\u4ece\u672a\u52a8\u6447\u8fc7<sup>[4]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/3-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-13190 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/3-6.png\" width=\"563\" height=\"469\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/3-6.png 563w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/02\/3-6-300x250.png 300w\" sizes=\"(max-width: 563px) 100vw, 563px\" \/><\/a><\/p>\n<p>1950\u5e74\u7684\u8bfa\u8d1d\u5c14\u5956\u6388\u4e88\u4e86Diels-Alder\u53cd\u5e94\uff0c1990\u5e74\u7684\u201c\u8bfa\u5956\u201d\u6388\u4e88\u4e86\u5bf9\u6709\u673a\u5408\u6210\u7406\u8bba\u6709\u7740\u5353\u8d8a\u8d21\u732e\u7684\u5408\u6210\u5927\u5e08E. J. Corey\u3002\u5176\u5b9e\uff0c\u5bf9\u677e\u6cb9\u9187\u5206\u5b50\u8fdb\u884c\u201c\u9006\u5408\u6210\u5206\u6790\u201d\u540e\uff0c\u7b14\u8005\u53d1\u73b0\u5229\u7528D-A\u53cd\u5e94\u6784\u5efa\u516d\u5143\u73af\uff0c\u518d\u5229\u7528\u683c\u5f0f\u53cd\u5e94\u5c31\u53ef\u4ee5\u5408\u6210\u677e\u6cb9\u9187\uff0c\u7136\u800c\u7efc\u5408\u8003\u8651\u591a\u79cd\u56e0\u7d20\u540e\uff0c\u5b9e\u9645\u5de5\u4e1a\u751f\u4ea7\u5374\u4e0d\u662f\u5982\u6b64\u3002<\/p>\n<p>\u672c\u6587\u4e3b\u8981\u4ecb\u7ecd\u4e86\u677e\u6cb9\u9187\u4f5c\u4e3a\u9999\u6c34\u7684\u539f\u6599\u4e4b\u4e00\uff0c\u80cc\u540e\u9c9c\u4e3a\u4eba\u77e5\u7684\u5316\u5b66\u77e5\u8bc6\u3002\u770b\u4f3c\u4e0d\u8d77\u773c\u7684\u7b80\u5355\u5206\u5b50\u5728\u751f\u6d3b\u4e2d\u53d1\u6325\u4e86\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u80cc\u540e\u8fd8\u8574\u85cf\u4e86\u8bb8\u591a\u5316\u5b66\u77e5\u8bc6\uff0c\u8fd9\u4e5f\u6b63\u662f\u5316\u5b66\u7684\u9b45\u529b\u6240\u5728\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] K.B.G. Torssell, <em>Natural Product Chemistry<\/em>,2nd Ed.,<strong>1997<\/strong>, pp.251-312.<\/p>\n[2] E.T.Morris,<em>Scents of Time.Perfume from Ancient Egypt to the 21<sup>st<\/sup> Century<\/em>, Bulfinch Press,New York,<strong>1999<\/strong>.<\/p>\n[3] W. H. Perkin, Jr., Synthesis of Terpin,InactiveTerpineol ,and Diterpene, <em>J.Chem.Soc.<\/em><strong>1904<\/strong>,85,654-671.<\/p>\n[4] D.Seyferth, <em>Organometallics<\/em><strong>2009<\/strong>, 28, 1598\u20131605.<\/p>\n<p>&nbsp;<\/p>\n<div class=\"post_content clearfix\"><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/div>\n","protected":false},"excerpt":{"rendered":"\u677e\u6811\u662f\u4e00\u79cd\u5e38\u89c1\u7684\u690d\u7269\uff0c\u5177\u6709\u591a\u79cd\u5e94\u7528\u4ef7\u503c\u3002\u4ece\u7f8e\u7d22\u4e0d\u8fbe\u7c73\u4e9a\u7a7f\u8fc7\u57c3\u53ca\u5230\u5e0c\u814a\uff0c\u8fd9\u7247\u53e4\u8001\u571f\u5730\u4e0a\u7684\u4eba\u4eec\u5f88\u65e9\u5c31\u5f00\u59cb\u5229\u7528\u677e\u6811\u76ae\u548c\u677e\u8102\uff0c\u84b8\u998f\u677e\u8102\u53ef\u5f97\u5230\u4e24\u79cd\u4e3b\u8981\u7269\u8d28\uff1a\u677e\u8282\u6cb9\u548c\u677e\u9999\u3002\u524d\u8005\u968f\u7740\u84b8\u6c14\u51fa\u6765\uff0c\u662f\u4e00\u79cd\u523a\u6fc0\u6027\u6c14\u5473\u7684\u900f\u660e\u6db2\u4f53\uff0c\u4e3b\u8981\u7531\u4e00\u7cfb\u5217\u6325\u53d1\u6027\u841c\u70ef\u7ec4\u6210\u3002 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\u5929\u7136\u4ea7\u7269\u91cc\u8fb9\u7684\u5355\u841c\u662f\u597d\u591a\u5305\u62ec\u67d1\u6a58\u7c7b\u6c34\u679c\u3001\u677e\u6811\u3001\u8584\u8377\u7b49\u5728\u5185\u7684\u690d\u7269\u3001\u6c34\u679c\u53d1\u51fa\u9999\u5473\u7684\u539f\u56e0\u3002\u65e9\u5728\u4e00\u767e\u591a\u5e74\u524d\uff0c\u5316\u5b66\u5bb6\u5c31\u5f00\u59cb\u7814\u7a76\u8fd9\u7c7b\u7269\u8d28\uff0c\u5176\u4e2d\u6c34\u5408\u841c\u54c1(Terpin hydrate)\u572819\u4e16\u7eaa\u7684\u6700\u540e\u51e0\u5341\u5e74\u6fc0\u8d77\u4e86\u5316\u5b66\u5bb6\u7684\u6781\u5927\u5174\u8da3\uff0c\u56f0\u60d1\u4ed6\u4eec\u7684\u4e0d\u4ec5\u4ec5\u662f\u5176\u7ec4\u6210\uff0c\u8fd8\u6709\u5b83\u5bb9\u6613\u4ece\u7c97\u677e\u8282\u6cb9\u4e2d\u6790\u51fa\u7eaf\u51c0\u6676\u4f53\u8fd9\u4e00\u6027\u8d28\u3002\u5176\u4e2d\u6709\u4e24\u4f4d\u79d1\u5b66\u5bb6\u4e0d\u5f97\u4e0d\u63d0\uff0cWilliam Henry Perkin, Jr.\u5408\u6210\u9999\u8c46\u7d20\uff0c\u800c\u4ed6\u7684\u7236\u4eb2William, Sr.\u53d1\u73b0\u4e86\u82ef\u80fa\u7d2b\u2014\u201419\u4e16\u7eaa\u4e00\u79cd\u91cd\u8981\u7684\u67d3\u6599\u3002\u513f\u5b50\u5f88\u597d\u5730\u7ee7\u627f\u4e86\u7236\u4eb2\u5bf9\u4e8e\u672a\u77e5\u4e8b\u7269\u63a2\u7d22\u7684\u70ed\u60c5\uff0c\u5e76\u81f4\u529b\u4e8e\u5408\u6210\u548c\u786e\u5b9a\u4e86\u591a\u79cd\u841c\u70ef\u7684\u7ed3\u6784\u3002[3] 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1950\u5e74\u7684\u8bfa\u8d1d\u5c14\u5956\u6388\u4e88\u4e86Diels-Alder\u53cd\u5e94\uff0c1990\u5e74\u7684\u201c\u8bfa\u5956\u201d\u6388\u4e88\u4e86\u5bf9\u6709\u673a\u5408\u6210\u7406\u8bba\u6709\u7740\u5353\u8d8a\u8d21\u732e\u7684\u5408\u6210\u5927\u5e08E. J. Corey\u3002\u5176\u5b9e\uff0c\u5bf9\u677e\u6cb9\u9187\u5206\u5b50\u8fdb\u884c\u201c\u9006\u5408\u6210\u5206\u6790\u201d\u540e\uff0c\u7b14\u8005\u53d1\u73b0\u5229\u7528D-A\u53cd\u5e94\u6784\u5efa\u516d\u5143\u73af\uff0c\u518d\u5229\u7528\u683c\u5f0f\u53cd\u5e94\u5c31\u53ef\u4ee5\u5408\u6210\u677e\u6cb9\u9187\uff0c\u7136\u800c\u7efc\u5408\u8003\u8651\u591a\u79cd\u56e0\u7d20\u540e\uff0c\u5b9e\u9645\u5de5\u4e1a\u751f\u4ea7\u5374\u4e0d\u662f\u5982\u6b64\u3002 \u672c\u6587\u4e3b\u8981\u4ecb\u7ecd\u4e86\u677e\u6cb9\u9187\u4f5c\u4e3a\u9999\u6c34\u7684\u539f\u6599\u4e4b\u4e00\uff0c\u80cc\u540e\u9c9c\u4e3a\u4eba\u77e5\u7684\u5316\u5b66\u77e5\u8bc6\u3002\u770b\u4f3c\u4e0d\u8d77\u773c\u7684\u7b80\u5355\u5206\u5b50\u5728\u751f\u6d3b\u4e2d\u53d1\u6325\u4e86\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u80cc\u540e\u8fd8\u8574\u85cf\u4e86\u8bb8\u591a\u5316\u5b66\u77e5\u8bc6\uff0c\u8fd9\u4e5f\u6b63\u662f\u5316\u5b66\u7684\u9b45\u529b\u6240\u5728\u3002 &nbsp; \u53c2\u8003\u6587\u732e [1] K.B.G. Torssell, Natural Product Chemistry,2nd Ed.,1997, pp.251-312. [2] E.T.Morris,Scents of Time.Perfume from Ancient Egypt to the 21st Century, Bulfinch Press,New York,1999. [3] W. H. Perkin, Jr., Synthesis of Terpin,InactiveTerpineol ,and Diterpene, J.Chem.Soc.1904,85,654-671. 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