{"id":13740,"date":"2017-04-14T16:12:57","date_gmt":"2017-04-14T08:12:57","guid":{"rendered":"\/\/www.gsbet888.com\/?p=13740"},"modified":"2019-08-02T18:53:21","modified_gmt":"2019-08-02T10:53:21","slug":"however%e7%9a%84%e4%bd%bf%e7%94%a8%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/%e5%8c%96%e5%ad%a6%e4%b8%8e%e8%8b%b1%e8%af%ad\/2017\/04\/however%e7%9a%84%e4%bd%bf%e7%94%a8%e6%96%b9%e6%b3%95.html","title":{"rendered":"however\u7684\u4f7f\u7528\u65b9\u6cd5"},"content":{"rendered":"<p>\u526f\u8bcd\u201chowever\u201d\u662f\u6700\u5e38\u88ab\u65e5\u672c\u4eba\u6240\u9519\u8bef\u4f7f\u7528\u7684\u5355\u8bcd\u4e4b\u4e00\u3002\u8fd9\u4e9b\u9519\u8bef\u7684\u4f7f\u7528\u53ef\u4ee5\u88ab\u5206\u4e3a\u5f88\u591a\u79cd\u7c7b\uff0c\u4f46\u6b64\u6587\u4e3b\u8981\u8ba8\u8bba\u7684\u662f\u8bed\u6cd5\u95ee\u9898\u3002<\/p>\n<div class=\"post_content clearfix\">\n<p>\u201chowever\u201d\u4e3b\u8981\u6709\u4e24\u4e2a\u610f\u601d\uff0c\u5206\u522b\u7b49\u540c\u4e8e\u201cbut\u201d\u548c\u201cin whatever way\u201d\u3002\u867d\u7136\u5728\u524d\u8005\u7684\u60c5\u51b5\u4e0b\u201chowever\u201d\u5fc5\u987b\u4f5c\u4e3a\u526f\u8bcd\u5b58\u5728\uff0c\u4f46\u6b63\u50cf\u4e0b\u6587\u53e5\u4e2d\u90a3\u6837\uff0c<strong>\u9519\u5c06\u5176\u4f5c\u4e3a\u8fde\u8bcd\u6765\u4f7f\u7528\u7684\u4f8b\u5b50\u4e5f\u65f6\u6709\u53d1\u751f<\/strong>\u3002<\/p>\n<ul>\n<li>[\u8bef] I would like to go to a movie,\u00a0<strong>however<\/strong>\u00a0I have no money.<\/li>\n<li>[\u6b63] I would like to go to a movie,\u00a0<strong>but<\/strong>\u00a0I have no money.<\/li>\n<li>[\u6b63] I would like to go to a movie.\u00a0<strong>However,<\/strong>\u00a0I have no money.<\/li>\n<\/ul>\n<ul>\n<li>[\u8bef] The argument given in Ref. [3] may be correct,\u00a0<strong>however<\/strong>\u00a0it is not convincing.<\/li>\n<li>[\u6b63] The argument given in Ref. [3] may be correct,\u00a0<strong>but<\/strong>\u00a0it is not convincing.<\/li>\n<li>[\u6b63] The argument given in Ref. [3] may be correct.\u00a0<strong>However,<\/strong>\u00a0it is not convincing.<\/li>\n<li>[\u6b63]\u00a0<strong>Although\/While\/<\/strong>\u00a0the argument given in Ref. [3] may be correct, it is not convincing.<\/li>\n<\/ul>\n<p><span style=\"font-size: 12px\">\u4e0a\u8ff0\u7684\u6b63\u786e\u4f8b\u53e5\u4e2d\uff0c\u201cbut\u201d\u3001\u201calthough\u201d\u3001\u201cwhile\u201d\u5747\u4f5c\u4e3a\u6b63\u786e\u7684\u8fde\u8bcd\u5b58\u5728\uff0c\u800c\u201chowever\u201d\u5219\u662f\u526f\u8bcd\u3002<\/span><\/p>\n<\/div>\n<h4>\u5316\u5b66\u8bba\u6587\u4e2d\u7684\u300chowever\u300d\u7684\u4f7f\u7528\u5b9e\u4f8b<\/h4>\n<blockquote><p>Compared to other hydrofunctionalization methods,\u00a0<strong>however<\/strong>, transition metal-catalyzed hydrothiolation is relatively underexplored, likely due to sulfur\u2019s strong coordinating ability and ensuing catalyst deactivation.<br \/>\n\u5f15\u7528:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jacs.6b07142\">10.1021\/jacs.6b07142<\/a><\/p><\/blockquote>\n<blockquote><p>Over 160 chiral vicinal bromochlorinated natural products have been identified<strong>; however,<\/strong>\u00a0a lack of synthetic methods for the selective incorporation of halogens into organic molecules has hindered their synthesis.\u3000\u5f15\u7528\uff1a<a href=\"http:\/\/dx.doi.org\/10.1021\/jacs.5b08398\">10.1021\/jacs.5b08398<\/a><\/p><\/blockquote>\n<blockquote><p>There was good agreement between our observations and computational predictions. No reaction or low yields were seen for substrates\u00a0<strong>7a<\/strong>\u2013<strong>7e<\/strong>\u00a0(entries 1\u20135).\u00a0<strong>However,<\/strong>\u00a0when the calculated DG and the oxidative addition barrier were favourable, substantial formation of product\u00a0<strong>8a<\/strong>\u00a0was observed (entries 6 and 7) \u5f15\u7528\uff1a<a href=\"http:\/\/dx.doi.org\/10.1038\/nature14615\">10.1038\/nature14615<\/a><\/p><\/blockquote>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-13541\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago.jpg\" alt=\"\" width=\"1456\" height=\"538\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago.jpg 1456w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago-300x111.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago-768x284.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/03\/enago-680x251.jpg 680w\" sizes=\"(max-width: 1456px) 100vw, 1456px\" \/><\/a><\/p>\n<p style=\"text-align: right\">\u672c\u6587\u51fa\u81ea<a href=\"https:\/\/www.enago.cn\/\">\u00a0Enago\u5b66\u672f\u82f1\u8bedacademy<\/a>\uff08\u65e5\u6587\u7248\uff09<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u526f\u8bcd\u201chowever\u201d\u662f\u6700\u5e38\u88ab\u65e5\u672c\u4eba\u6240\u9519\u8bef\u4f7f\u7528\u7684\u5355\u8bcd\u4e4b\u4e00\u3002\u8fd9\u4e9b\u9519\u8bef\u7684\u4f7f\u7528\u53ef\u4ee5\u88ab\u5206\u4e3a\u5f88\u591a\u79cd\u7c7b\uff0c\u4f46\u6b64\u6587\u4e3b\u8981\u8ba8\u8bba\u7684\u662f\u8bed\u6cd5\u95ee\u9898\u3002 \u201chowever\u201d\u4e3b\u8981\u6709\u4e24\u4e2a\u610f\u601d\uff0c\u5206\u522b\u7b49\u540c\u4e8e\u201cbut\u201d\u548c\u201cin whatever way\u201d\u3002\u867d\u7136\u5728\u524d\u8005\u7684\u60c5\u51b5\u4e0b\u201chowever\u201d\u5fc5\u987b\u4f5c\u4e3a\u526f\u8bcd\u5b58\u5728\uff0c\u4f46\u6b63\u50cf\u4e0b\u6587\u53e5\u4e2d\u90a3\u6837\uff0c\u9519\u5c06\u5176\u4f5c\u4e3a\u8fde\u8bcd\u6765\u4f7f\u7528\u7684\u4f8b\u5b50\u4e5f\u65f6\u6709\u53d1\u751f\u3002 [\u8bef] I would like to go to a movie,\u00a0however\u00a0I have no money. [\u6b63] I would like to go to a movie,\u00a0but\u00a0I have no money. [\u6b63] I would like to go to a movie.\u00a0However,\u00a0I have no money. [\u8bef] The argument given in Ref. [3] may be correct,\u00a0however\u00a0it is not convincing. [\u6b63] The argument given in Ref. [3] may be correct,\u00a0but\u00a0it is not convincing. [\u6b63] The argument given in Ref. [3] may be correct.\u00a0However,\u00a0it is not convincing. [\u6b63]\u00a0Although\/While\/\u00a0the argument given in Ref. [3] may be correct, it is not convincing. \u4e0a\u8ff0\u7684\u6b63\u786e\u4f8b\u53e5\u4e2d\uff0c\u201cbut\u201d\u3001\u201calthough\u201d\u3001\u201cwhile\u201d\u5747\u4f5c\u4e3a\u6b63\u786e\u7684\u8fde\u8bcd\u5b58\u5728\uff0c\u800c\u201chowever\u201d\u5219\u662f\u526f\u8bcd\u3002 \u5316\u5b66\u8bba\u6587\u4e2d\u7684\u300chowever\u300d\u7684\u4f7f\u7528\u5b9e\u4f8b Compared to other hydrofunctionalization methods,\u00a0however, transition metal-catalyzed hydrothiolation is relatively underexplored, likely due to sulfur\u2019s strong [&hellip;]","protected":false},"author":3,"featured_media":13741,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1844],"tags":[1773,1774],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/04\/2017-01-14_09-29-41.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-3zC","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/13740"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=13740"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/13740\/revisions"}],"predecessor-version":[{"id":27460,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/13740\/revisions\/27460"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/13741"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=13740"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=13740"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=13740"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}