{"id":14049,"date":"2017-05-16T08:37:40","date_gmt":"2017-05-16T00:37:40","guid":{"rendered":"\/\/www.gsbet888.com\/?p=14049"},"modified":"2019-08-02T18:53:14","modified_gmt":"2019-08-02T10:53:14","slug":"%e6%ad%a6%e7%94%b0%e7%83%af%e5%90%88%e6%88%90-takeda-olefination","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2017\/05\/%e6%ad%a6%e7%94%b0%e7%83%af%e5%90%88%e6%88%90-takeda-olefination.html","title":{"rendered":"\u6b66\u7530\u70ef\u5408\u6210 Takeda Olefination"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>\u786b\u4ee3\u7f29\u919b\u4e0e2\u4ef7\u7684\u4e8c\u8302\u949b\u751f\u6210\u6709\u673a\u949b\u4e2d\u95f4\u4f53\u540e\uff0c\u4e0e\u7fb0\u57fa\u5316\u5408\u7269\u53cd\u5e94\u5408\u6210\u70ef\u70c3\u7684\u624b\u6cd5\u3002<\/p>\n<p>\u8be5\u53cd\u5e94\u4e2d\u867d\u71362\u4ef7\u7684\u4e8c\u8302\u949b\u8bd5\u5242\u7684\u914d\u5236\u6bd4\u8f83\u82b1\u65f6\u95f4\uff0c\u4f46\u662f\u53cd\u5e94\u5e95\u7269\u786b\u4ee3\u7f29\u919b\u662f\u4e00\u4e2a\u6bd4\u8f83\u6613\u5f97\u7684\u539f\u6599\u3002\u76f8\u6bd4\u4e8e\u7c7b\u4f3c\u7684\u53cd\u5e94\uff1a<a href=\"\/\/www.gsbet888.com\/reactions\/\u6709\u673a\u91d1\u5c5e\u53cd\u5e94-reactions\/2014\/06\/tebbe-\u8bd5\u5242-tebbe-reagent.html\">Tebbe\u8bd5\u5242\u3001<\/a>\u00a0<a href=\"\/\/www.gsbet888.com\/reactions\/\u7f29\u5408\u53cd\u5e94\/2014\/09\/post-2825.html\">Petasis\u53cd\u5e94<\/a>\u3001<a href=\"http:\/\/www.chem-station.com\/en\/reactions-2\/2015\/03\/takai-lombardo-reaction.html\">Takai-Lombardo Reaction<\/a>\uff0c\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u66f4\u5e7f\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Horikawa, Y.; Watanabe, M.; Fujiwara, T.; Takeda, T.\u00a0<em>J. Am. Chem. Soc.<\/em>\u00a0<strong>1997<\/strong>,\u00a0<em>119<\/em>, 1127. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja962240d\">10.1021\/ja962240d<\/a><\/li>\n<li>Rahim, M. A.; Fujiwara, T.; Takeda, T.\u00a0<em>Tetrahedron<\/em><strong>2000<\/strong>,\u00a0<em>56<\/em>, 763. doi:<a href=\"http:\/\/dx.doi.org\/10.1016\/S0040-4020(99)01091-1\">10.1016\/S0040-4020(99)01091-1<\/a><\/li>\n<li>Rahim, M. A.; Sasaki, H.; Saito, J.; Fujiwara, T.; Takeda, T.\u00a0<em>Chem. Commun.<\/em><strong>2001<\/strong>, 625. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1039\/B010156G\">10.1039\/B010156G<\/a><\/li>\n<li>Hartley, R. C.; McKiernan, G. J.\u00a0<em>JCS Perkin Trans. 1<\/em><strong>2002<\/strong>, 2763. doi:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1039\/B009709H\">10.1039\/B009709H<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14051 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_2.gif\" alt=\"\" width=\"320\" height=\"237\" \/><\/a><\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>Ciquatoxin\u7684\u5408\u6210\u7814\u7a76[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_3.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14052 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_3.gif\" alt=\"\" width=\"464\" height=\"101\" \/><\/a><\/p>\n<p>alstoscholarine\u7684\u5168\u5408\u6210[2]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_4.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14053 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Takeda_olefin_4.gif\" alt=\"\" width=\"410\" height=\"101\" \/><\/a><\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] Uehara, H.; Oishi, T.; Inoue, M.; Shoji, M.; Nagumo, Y.; Kosaka, M.; Brazidec, J.-Y.; Hirama, M.\u00a0<em>Tetrahedron<\/em><strong>\u00a02002<\/strong>,\u00a0<em>58<\/em>, 6493. doi:<a href=\"http:\/\/dx.doi.org\/10.1016\/S0040-4020(02)00660-9\">10.1016\/S0040-4020(02)00660-9<\/a><br \/>\n[2] Gerfaud, T.; Xie, C.; Neuville, L.; Zhu, J.\u00a0<em>Angew. Chem. Int. Ed.<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>50<\/em>, 3954. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.201100257\">10.1002\/anie.201100257<\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u95a2\u9023\u53cd\u5fdc<\/h4>\n<ul class=\"list\">\n<li><a href=\"http:\/\/www.chem-station.com\/en\/reactions-2\/2015\/03\/takai-lombardo-reaction.html\">Takai-Lombardo Reaction<\/a><\/li>\n<\/ul>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n<p>&nbsp;<\/p>\n<h4>\u5173\u8054\u4e66\u7c4d\uff08\u65e5\u672c\u4e9a\u9a6c\u900a\u4ef7\u683c\uff09<\/h4>\n<div class=\"amazonjs_item amazonjs_book\">\n<div class=\"amazonjs_image\"><a class=\"amazonjs_link\" title=\"Modern Carbonyl Olefination: Methods and Applications\" href=\"https:\/\/www.amazon.co.jp\/Modern-Carbonyl-Olefination-Methods-Applications\/dp\/352730634X?SubscriptionId=AKIAJUGVCC4IFT7YJWNA&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=352730634X\" target=\"_blank\" rel=\"noopener noreferrer\" data-role=\"amazonjs_product\" data-asin=\"352730634X\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/images-fe.ssl-images-amazon.com\/images\/I\/41JGa8cvTGL._SL160_.jpg\" alt=\"Modern Carbonyl Olefination: Methods and Applications\" width=\"114\" height=\"160\" \/><\/a><\/div>\n<div class=\"amazonjs_info\">\n<h4><a class=\"amazonjs_link\" title=\"Modern Carbonyl Olefination: Methods and Applications\" href=\"https:\/\/www.amazon.co.jp\/Modern-Carbonyl-Olefination-Methods-Applications\/dp\/352730634X?SubscriptionId=AKIAJUGVCC4IFT7YJWNA&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=352730634X\" target=\"_blank\" rel=\"noopener noreferrer\" data-role=\"amazonjs_product\" data-asin=\"352730634X\">Modern Carbonyl Olefination: Methods and Applications<\/a><\/h4>\n<ul>\n<li class=\"amazonjs_price\" title=\"\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306f\u8868\u793a\u3055\u308c\u305f\u65e5\u4ed8\/\u6642\u523b\u306e\u6642\u70b9\u306e\u3082\u306e\u3067\u3042\u308a\u3001\u5909\u66f4\u3055\u308c\u308b\u5834\u5408\u304c\u3042\u308a\u307e\u3059\u3002\u5546\u54c1\u306e\u8ca9\u58f2\u306b\u304a\u3044\u3066\u306f\u3001\u8cfc\u5165\u306e\u6642\u70b9\u3067 [Amazon.co.jp \u307e\u305f\u306f Javari.jp] \u306b\u8868\u793a\u3055\u308c\u3066\u3044\u308b\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306e\u60c5\u5831\u304c\u9069\u7528\u3055\u308c\u307e\u3059\u3002\">\u4ef7\u683c\uffe5 22,482\u65e5\u5143(2017\/05\/11 11:38)<\/li>\n<li>\u51fa\u7248\u65e52004\/03\/05<\/li>\n<li>\u5546\u54c1\u987a\u4f4d478,740\u4f4d<\/li>\n<li>\u9875\u7801\u6570 365\u9875<\/li>\n<li>ISBN-10352730634X<\/li>\n<li>ISBN-139783527306343<\/li>\n<li>\u51fa\u7248\u516c\u53f8Wiley-VCH<\/li>\n<\/ul>\n<\/div>\n<div class=\"amazonjs_footer\"><\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u786b\u4ee3\u7f29\u919b\u4e0e2\u4ef7\u7684\u4e8c\u8302\u949b\u751f\u6210\u6709\u673a\u949b\u4e2d\u95f4\u4f53\u540e\uff0c\u4e0e\u7fb0\u57fa\u5316\u5408\u7269\u53cd\u5e94\u5408\u6210\u70ef\u70c3\u7684\u624b\u6cd5\u3002 \u8be5\u53cd\u5e94\u4e2d\u867d\u71362\u4ef7\u7684\u4e8c\u8302\u949b\u8bd5\u5242\u7684\u914d\u5236\u6bd4\u8f83\u82b1\u65f6\u95f4\uff0c\u4f46\u662f\u53cd\u5e94\u5e95\u7269\u786b\u4ee3\u7f29\u919b\u662f\u4e00\u4e2a\u6bd4\u8f83\u6613\u5f97\u7684\u539f\u6599\u3002\u76f8\u6bd4\u4e8e\u7c7b\u4f3c\u7684\u53cd\u5e94\uff1aTebbe\u8bd5\u5242\u3001\u00a0Petasis\u53cd\u5e94\u3001Takai-Lombardo Reaction\uff0c\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u66f4\u5e7f\u3002 &nbsp; \u57fa\u672c\u6587\u732e Horikawa, Y.; Watanabe, M.; Fujiwara, T.; Takeda, T.\u00a0J. Am. Chem. Soc.\u00a01997,\u00a0119, 1127. DOI:\u00a010.1021\/ja962240d Rahim, M. A.; Fujiwara, T.; Takeda, T.\u00a0Tetrahedron2000,\u00a056, 763. doi:10.1016\/S0040-4020(99)01091-1 Rahim, M. A.; Sasaki, H.; Saito, J.; Fujiwara, T.; Takeda, T.\u00a0Chem. Commun.2001, 625. DOI:\u00a010.1039\/B010156G Hartley, R. C.; McKiernan, G. J.\u00a0JCS Perkin Trans. 12002, 2763. doi:\u00a010.1039\/B009709H &nbsp; \u53cd\u5e94\u673a\u7406 \u53cd\u5e94\u5b9e\u4f8b Ciquatoxin\u7684\u5408\u6210\u7814\u7a76[1] alstoscholarine\u7684\u5168\u5408\u6210[2] \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1] Uehara, H.; Oishi, T.; Inoue, M.; Shoji, M.; Nagumo, Y.; Kosaka, M.; Brazidec, J.-Y.; Hirama, M.\u00a0Tetrahedron\u00a02002,\u00a058, 6493. doi:10.1016\/S0040-4020(02)00660-9 [2] Gerfaud, T.; Xie, C.; Neuville, L.; Zhu, J.\u00a0Angew. Chem. Int. Ed.\u00a02011,\u00a050, 3954. DOI:\u00a010.1002\/anie.201100257 &nbsp; \u95a2\u9023\u53cd\u5fdc Takai-Lombardo Reaction \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01 &nbsp; \u5173\u8054\u4e66\u7c4d\uff08\u65e5\u672c\u4e9a\u9a6c\u900a\u4ef7\u683c\uff09 Modern Carbonyl Olefination: Methods and Applications [&hellip;]","protected":false},"author":5,"featured_media":14050,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[74,1819,1818],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/2014-08-21_14-23-53.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-3EB","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/14049"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=14049"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/14049\/revisions"}],"predecessor-version":[{"id":27432,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/14049\/revisions\/27432"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/14050"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=14049"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=14049"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=14049"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}