{"id":14220,"date":"2017-07-06T11:05:37","date_gmt":"2017-07-06T03:05:37","guid":{"rendered":"\/\/www.gsbet888.com\/?p=14220"},"modified":"2019-08-02T18:53:11","modified_gmt":"2019-08-02T10:53:11","slug":"%e6%b3%a2%e7%93%a6%e7%bd%97%e5%a4%ab%e5%8f%8d%e5%ba%94-povarov-reaction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2017\/07\/%e6%b3%a2%e7%93%a6%e7%bd%97%e5%a4%ab%e5%8f%8d%e5%ba%94-povarov-reaction.html","title":{"rendered":"\u6ce2\u74e6\u7f57\u592b\u53cd\u5e94 Povarov Reaction"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>\u919b\u3001\u82ef\u80fa\u3001\u5bcc\u7535\u5b50\u70ef\u70c3\u7684\u4e09\u7ec4\u5206\u7f29\u5408\u53cd\u5e94\u751f\u6210\u56db\u53d6\u4ee3\u7684\u56db\u6c22\u55b9\u5549\u884d\u751f\u7269\u7684\u624b\u6cd5\u3002<a href=\"\/\/www.gsbet888.com\/reactions\/\u52a0\u6210\u53cd\u5e94\/2016\/07\/post-10087.html\">Hetero\u00a0Diels-Alder\u53cd\u5e94<\/a>\u7684\u4e00\u79cd\u3002\u8fdb\u800c\u6c27\u5316\u540e\u5f97\u5230\u55b9\u5549\u884d\u751f\u7269\u3002<\/p>\n<div id=\"_clearly_component__next_pages_container\"><\/div>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Povarov, L. S.; Mikhailov, B. M. <em>Izv. Akad. Nauk SSR, Ser. Khim.<\/em> <strong>1963<\/strong>, 953.<\/li>\n<li>Povarov, L. S.; Grigos, V. I.; Mikhailov, B. M.<em> Izv. Akad. Nauk SSR, Ser. Khim.<\/em><strong>1963<\/strong>, 2039.<\/li>\n<li>Povarov, L. S. <em>Russ. Chem. Rev.<\/em> <strong>1967<\/strong>, <em>36<\/em>, 656.<\/li>\n<li>Buonora, P.; Olsenb, J.-C.; Oh, T. <em>Tetrahedron<\/em> <strong>2001<\/strong>, <em>57<\/em>, 6099. doi:<a href=\"http:\/\/dx.doi.org\/10.1016\/S0040-4020(01)00438-0\">10.1016\/S0040-4020(01)00438-0<\/a><\/li>\n<li>Kouznetsov, V. V. <em>Tetrahedron<\/em> <strong>2009<\/strong>, <em>65<\/em>, 2721. doi:<a href=\"http:\/\/dx.doi.org\/10.1016\/j.tet.2008.12.059\">10.1016\/j.tet.2008.12.059<\/a><\/li>\n<li>Bello, D.; Ramon, R.; Lavilla, R. <em>Curr. Org. Chem.<\/em> <strong>2010<\/strong>, <em>14<\/em>, 332.<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u82ef\u80fa\u4e0e\u82ef\u7532\u919b\u7f29\u5408\u751f\u6210\u7684\u4e9a\u80fa\uff0c\u5728\u7528\u8def\u6613\u65af\u9178\uff08\u5982\u4e09\u6c1f\u5316\u787c\uff09\u6d3b\u5316\u540e\u4e0e\u5bcc\u7535\u5b50\u70ef\u70c3\u53d1\u751f\u4eb2\u7535\u52a0\u6210\uff0c\u5f97\u5230\u7fb0\u57fa\u6c27\u9393\u79bb\u5b50\uff0c\u5e76\u4e0e\u82b3\u73af\u53d1\u751f\u4eb2\u7535\u82b3\u9999\u53d6\u4ee3\u73af\u5316\uff0c\u518d\u7ecf\u6d88\u9664\uff0c\u5f97\u6700\u540e\u4ea7\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14222 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Povarov_2.gif\" alt=\"\" width=\"509\" height=\"201\" \/><\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>\u4e0d\u5bf9\u79f0\u83f2\u54af\u5549\u7684\u5408\u6210[1]\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14223 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Povarov_3.gif\" alt=\"\" width=\"575\" height=\"122\" \/><\/p>\n<p>Camptothecin\u7684\u5408\u6210\u7814\u7a76[2]\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14224 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/05\/Povarov_4.gif\" alt=\"\" width=\"413\" height=\"277\" \/><\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] De, K.; Legros, J.; Crousse, B.; Chandrasekaran, S.; Bonnet-Delpon, D. <em>Org. Biomol. Chem.<\/em> <strong>2011<\/strong>, <em>9<\/em>, 347. DOI: <a href=\"http:\/\/dx.doi.org\/10.1039\/C0OB00496K\">10.1039\/C0OB00496K<\/a><br \/>\n[2] Twin, H.; Batey, R. A. <em>Org. Lett.<\/em> <strong>2004<\/strong>, <em>6<\/em>, 4913. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ol0479848\">10.1021\/ol0479848<\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u919b\u3001\u82ef\u80fa\u3001\u5bcc\u7535\u5b50\u70ef\u70c3\u7684\u4e09\u7ec4\u5206\u7f29\u5408\u53cd\u5e94\u751f\u6210\u56db\u53d6\u4ee3\u7684\u56db\u6c22\u55b9\u5549\u884d\u751f\u7269\u7684\u624b\u6cd5\u3002Hetero\u00a0Diels-Alder\u53cd\u5e94\u7684\u4e00\u79cd\u3002\u8fdb\u800c\u6c27\u5316\u540e\u5f97\u5230\u55b9\u5549\u884d\u751f\u7269\u3002 \u57fa\u672c\u6587\u732e Povarov, L. S.; Mikhailov, B. M. Izv. Akad. Nauk SSR, Ser. Khim. 1963, 953. Povarov, L. S.; Grigos, V. I.; Mikhailov, B. M. Izv. Akad. Nauk SSR, Ser. Khim.1963, 2039. Povarov, L. S. Russ. Chem. Rev. 1967, 36, 656. Buonora, P.; Olsenb, J.-C.; Oh, T. Tetrahedron 2001, 57, 6099. doi:10.1016\/S0040-4020(01)00438-0 Kouznetsov, V. V. Tetrahedron 2009, 65, 2721. doi:10.1016\/j.tet.2008.12.059 Bello, D.; Ramon, R.; Lavilla, R. Curr. Org. Chem. 2010, 14, 332. &nbsp; \u53cd\u5e94\u673a\u7406 \u82ef\u80fa\u4e0e\u82ef\u7532\u919b\u7f29\u5408\u751f\u6210\u7684\u4e9a\u80fa\uff0c\u5728\u7528\u8def\u6613\u65af\u9178\uff08\u5982\u4e09\u6c1f\u5316\u787c\uff09\u6d3b\u5316\u540e\u4e0e\u5bcc\u7535\u5b50\u70ef\u70c3\u53d1\u751f\u4eb2\u7535\u52a0\u6210\uff0c\u5f97\u5230\u7fb0\u57fa\u6c27\u9393\u79bb\u5b50\uff0c\u5e76\u4e0e\u82b3\u73af\u53d1\u751f\u4eb2\u7535\u82b3\u9999\u53d6\u4ee3\u73af\u5316\uff0c\u518d\u7ecf\u6d88\u9664\uff0c\u5f97\u6700\u540e\u4ea7\u7269\u3002 \u53cd\u5e94\u5b9e\u4f8b \u4e0d\u5bf9\u79f0\u83f2\u54af\u5549\u7684\u5408\u6210[1] Camptothecin\u7684\u5408\u6210\u7814\u7a76[2] \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1] De, K.; Legros, J.; Crousse, B.; Chandrasekaran, S.; Bonnet-Delpon, D. Org. Biomol. Chem. 2011, 9, 347. DOI: 10.1039\/C0OB00496K [2] Twin, H.; Batey, R. A. Org. 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