{"id":1435,"date":"2014-05-27T08:42:34","date_gmt":"2014-05-27T00:42:34","guid":{"rendered":"\/\/www.gsbet888.com\/?p=1435"},"modified":"2019-08-02T18:56:50","modified_gmt":"2019-08-02T10:56:50","slug":"%e5%85%8b%e8%8e%b1%e9%97%a8%e6%a3%ae%e8%bf%98%e5%8e%9f-clemmensen-reduction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e8%bf%98%e5%8e%9f%e5%8f%8d%e5%ba%94\/2014\/05\/%e5%85%8b%e8%8e%b1%e9%97%a8%e6%a3%ae%e8%bf%98%e5%8e%9f-clemmensen-reduction.html","title":{"rendered":"\u514b\u83b1\u95e8\u68ee\u8fd8\u539f Clemmensen Reduction"},"content":{"rendered":"<ul>\n<li>\u6982\u8981<\/li>\n<\/ul>\n<p>\u6d53\u76d0\u9178\u56de\u6d41\u4e0b\uff0c\u7528\u950c\u6c5e\u9f50\u5c06\u919b\u6216\u916e\u4e2d\u7684\u7fb0\u57fa\u8fd8\u539f\u4e3a\u4e9a\u7532\u57fa\u7684\u5316\u5b66\u53cd\u5e94\u3002\u5c24\u5176\u662f\u4e0e\u82b3\u9999\u73af\u5171\u8f6d\u7684\u916e\u80fd\u88ab\u8fd8\u539f\u3002<\/p>\n<p>\u975e\u6c34\u6eb6\u6db2\u7684\u6761\u4ef6\u4e0b\uff0c\u7528\u6c2f\u5316\u6c22\u7684\u919a\u6eb6\u6db2\uff0c\u751a\u81f3\u80fd\u8fd8\u539f\u975e\u5171\u8f6d\u7684\u7fb0\u57fa\u3002\u8fd9\u79cd\u60c5\u51b5\u53ea\u9700\u8981\u7528\u91d1\u5c5e\u950c\u5c31\u53ef\u4ee5\uff0c\u4e0d\u9700\u8981\u7528\u5230\u6bd2\u6027\u9ad8\u7684\u6c5e\u5408\u91d1\u3002<\/p>\n<p>\u751a\u81f3\u4e0d\u9700\u8981\u91d1\u5c5e\u7684\u60c5\u51b5\u4e0b\uff0c\u7528\u7535\u89e3\u6761\u4ef6\u4e5f\u80fd\u4fc3\u4f7f\u53cd\u5e94\u53d1\u751f\u3002<\/p>\n<p>\u672c\u53cd\u5e94\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u800c\u4e0e\u4e4b\u76f8\u5bf9\u5e94\u7684\u6709\u78b1\u6027\u73af\u5883\u4e0b\u7684\u6c83\u5c14\u592b-\u51ef\u897f\u7eb3\u8fd8\u539f\u53cd\u5e94\uff0c\u4ee5\u53ca\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u96f7\u5c3c\u954d\u8131\u786b\u8fd8\u539f\u53cd\u5e94\u3002<\/p>\n<ul>\n<li>\u57fa\u672c\u6587\u732e<\/li>\n<\/ul>\n<p>\u30fb Clemmensen, E. <em>Ber.<\/em> <strong><span style=\"color: #ff6600\">1913<\/span><\/strong>, <em>46<\/em>, 1837.<br \/>\n\u30fb Clemmensen, E. <em>Ber.<\/em> <strong><span style=\"color: #ff6600\">1914<\/span><\/strong>, <em>47<\/em>, 51.<br \/>\n\u30fb Clemmensen, E. <em>Ber.<\/em> <strong><span style=\"color: #ff6600\">1914<\/span><\/strong>, <em>47<\/em>, 681.<br \/>\n\u30fb Martin, E. L. <em>Org. React.<\/em> <strong><span style=\"color: #ff6600\">1942<\/span><\/strong>, <em>1<\/em>, 155.<br \/>\n\u30fb Nakabayashi T. <em>J. Am. Chem. Soc.<\/em> <strong><span style=\"color: #ff6600\">1960<\/span><\/strong>, <em>82<\/em>, 3900. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ja01500a029\"><span style=\"color: #336600\">10.1021\/ja01500a029 <\/span><\/a><br \/>\n\u30fb Buchanan, J. G. St. C.; Woodgate, P. D. <em>Quart. Rev.<\/em> <strong><span style=\"color: #ff6600\">1969<\/span><\/strong>, <em>23<\/em>, 522.<br \/>\n\u30fb Vedejs, E. <em>Org. React.<\/em> <strong><span style=\"color: #ff6600\">1975<\/span><\/strong>, <em>22<\/em>, 401.<br \/>\n\u30fb Yamamura, S.; Nishiyama, S. <em>Comprehensive Organic Synthesis<\/em> <strong><span style=\"color: #ff6600\">1991<\/span><\/strong>, <em>8<\/em>, 309.<\/p>\n<ul>\n<li>\u53cd\u5e94\u673a\u7406<\/li>\n<\/ul>\n<p>\u53cd\u5e94\u5728\u950c\u6c5e\u9f50\u7684\u8868\u9762\u53d1\u751f\u3002\u5177\u4f53\u7684\u53cd\u5e94\u673a\u7406\u76f4\u5230\u73b0\u5728\u4ecd\u4e0d\u660e\u4e86\uff0c\u5728\u6b64\u63d0\u51fa\u4e00\u79cd\u53ef\u80fd\u6027\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/05\/24.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-1442\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/05\/24.gif\" alt=\"2\" width=\"505\" height=\"81\" \/><\/a><\/p>\n<ul>\n<li>\u53cd\u5e94\u5b9e\u4f8b<\/li>\n<\/ul>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/05\/32.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-1443\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/05\/32.gif\" alt=\"3\" width=\"329\" height=\"57\" \/><\/a><\/p>\n<ul>\n<li>\u5b9e\u9a8c\u6b65\u9aa4<\/li>\n<li>\u5b9e\u9a8c\u6280\u5de7<\/li>\n<li>\u53c2\u8003\u6587\u732e<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u6d53\u76d0\u9178\u56de\u6d41\u4e0b\uff0c\u7528\u950c\u6c5e\u9f50\u5c06\u919b\u6216\u916e\u4e2d\u7684\u7fb0\u57fa\u8fd8\u539f\u4e3a\u4e9a\u7532\u57fa\u7684\u5316\u5b66\u53cd\u5e94\u3002\u5c24\u5176\u662f\u4e0e\u82b3\u9999\u73af\u5171\u8f6d\u7684\u916e\u80fd\u88ab\u8fd8\u539f\u3002 \u975e\u6c34\u6eb6\u6db2\u7684\u6761\u4ef6\u4e0b\uff0c\u7528\u6c2f\u5316\u6c22\u7684\u919a\u6eb6\u6db2\uff0c\u751a\u81f3\u80fd\u8fd8\u539f\u975e\u5171\u8f6d\u7684\u7fb0\u57fa\u3002\u8fd9\u79cd\u60c5\u51b5\u53ea\u9700\u8981\u7528\u91d1\u5c5e\u950c\u5c31\u53ef\u4ee5\uff0c\u4e0d\u9700\u8981\u7528\u5230\u6bd2\u6027\u9ad8\u7684\u6c5e\u5408\u91d1\u3002 \u751a\u81f3\u4e0d\u9700\u8981\u91d1\u5c5e\u7684\u60c5\u51b5\u4e0b\uff0c\u7528\u7535\u89e3\u6761\u4ef6\u4e5f\u80fd\u4fc3\u4f7f\u53cd\u5e94\u53d1\u751f\u3002 \u672c\u53cd\u5e94\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u800c\u4e0e\u4e4b\u76f8\u5bf9\u5e94\u7684\u6709\u78b1\u6027\u73af\u5883\u4e0b\u7684\u6c83\u5c14\u592b-\u51ef\u897f\u7eb3\u8fd8\u539f\u53cd\u5e94\uff0c\u4ee5\u53ca\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u96f7\u5c3c\u954d\u8131\u786b\u8fd8\u539f\u53cd\u5e94\u3002 \u57fa\u672c\u6587\u732e \u30fb Clemmensen, E. Ber. 1913, 46, 1837. \u30fb Clemmensen, E. Ber. 1914, 47, 51. \u30fb Clemmensen, E. Ber. 1914, 47, 681. \u30fb Martin, E. L. Org. React. 1942, 1, 155. \u30fb Nakabayashi T. J. Am. Chem. Soc. 1960, 82, 3900. DOI: 10.1021\/ja01500a029 \u30fb Buchanan, J. G. St. C.; Woodgate, P. D. Quart. Rev. 1969, 23, 522. \u30fb Vedejs, E. Org. React. 1975, 22, 401. \u30fb Yamamura, S.; Nishiyama, S. Comprehensive Organic Synthesis 1991, 8, 309. \u53cd\u5e94\u673a\u7406 \u53cd\u5e94\u5728\u950c\u6c5e\u9f50\u7684\u8868\u9762\u53d1\u751f\u3002\u5177\u4f53\u7684\u53cd\u5e94\u673a\u7406\u76f4\u5230\u73b0\u5728\u4ecd\u4e0d\u660e\u4e86\uff0c\u5728\u6b64\u63d0\u51fa\u4e00\u79cd\u53ef\u80fd\u6027\u3002 \u53cd\u5e94\u5b9e\u4f8b \u5b9e\u9a8c\u6b65\u9aa4 \u5b9e\u9a8c\u6280\u5de7 \u53c2\u8003\u6587\u732e","protected":false},"author":4,"featured_media":1441,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[91],"tags":[991,48,205],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/05\/13.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-n9","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/1435"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=1435"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/1435\/revisions"}],"predecessor-version":[{"id":28201,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/1435\/revisions\/28201"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/1441"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=1435"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=1435"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=1435"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}