\u201cTotal Synthesis and Absolute Configuration of Macrocidin\u2005A, a Cyclophane Tetramic Acid Natural Product\u201d
\nYoshinari, T.; Ohmori, K.; Schrems, M. G.; Pfaltz, A.; Suzuki, K. Angew. Chem. Int. Ed.<\/i> 2010<\/b>, 49<\/i>, 881. DOI: 10.1002\/anie.200906362<\/a><\/p><\/blockquote>\n
\u4e00\u822c\u6765\u8bf4\u73af\u5316\u53cd\u5e94\u96be\u4ee5\u8fdb\u884c\u7684\u539f\u56e0\u5927\u81f4\u662f\uff0c\u53cd\u5e94\u6027\u4e0d\u591f\uff0c\u5176\u4ed6\u7684\u526f\u53cd\u5e94\u66f4\u5feb\uff0c\u6216\u8005\u6784\u8c61\u9650\u5236\u7b49\u3002\u8fd9\u56de\u7ec8\u76d8\u8fd0\u7528\u5230\u7c7b\u4f3cDieckmannh\u73af\u5316<\/a>\u53cd\u5e94\uff0c\u4e3a\u4e86\u5408\u6210\u76ee\u6807\u7684\u5927\u73af\u9aa8\u67b6\u7684\u7ed3\u6784\uff0c\u800c\u53cd\u5e94\u6ca1\u6709\u987a\u5229\u8fdb\u884c\uff0c\u5f88\u5927\u7684\u53ef\u80fd\u5c31\u662f\u7531\u4e8e\u6784\u8c61\u9650\u5236<\/strong>\u3002<\/p>\n
![\"\"](\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/next_move_9a_1-e1503747680339-300x253.png\")
<\/p>\n![\"\"](\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/next_move_9a_2-e1503747778954-300x223.png\")
<\/p>\n![\"\"](\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/next_move_9a_3-e1503747867146.png\")
<\/p>\n\u8fd9\u6b21\u4f60\u7b54\u5bf9\u4e86\u4e48\uff1f<\/p>\n
\u76f8\u5173\u6587\u732e<\/h4>\n\n- CCDC 756980<\/li>\n
- Fukase, K.; Hashida, M.; Kusumoto, S. Tetrahedron Lett.<\/i> 1991<\/b>, 32<\/i>, 3557. doi:10.1016\/0040-4039(91)80832-Q<\/a><\/li>\n<\/ol>\n
\u5916\u90e8\u94fe\u63a5<\/h4>\n\n- \u82b3\u9999\u65cf\u30a2\u30df\u30c9\u306e\u30b3\u30f3\u30d5\u30a9\u30e1\u30fc\u30b7\u30e7\u30f3\u5236\u5fa1\u6cd5\u307e\u3068\u3081<\/a>\uff08\u6c17\u307e\u307e\u306b\u5275\u85ac\u5316\u5b66\uff09<\/li>\n
- Peptide \u00a0bond \u2013 Wikipedia<\/a><\/li>\n
- \u9234\u6728\u30fb\u5927\u68ee\u7814\u7a76\u5ba4<\/a><\/li>\n<\/ul>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u7cfb\u5217\u5185\u5bb9\u662f\u4e3a\u5e2e\u52a9\u5927\u5bb6\u80fd\u591f\u76f4\u9762\u5168\u5408\u6210\u4e2d\u5e94\u514b\u670d\u7684\u56f0\u96be\u800c\u7f16\u5199\u7684\u3002\u5217\u4e3e\u4e86\u4e00\u4e9b\u5728\u5168\u5408\u6210\u8fc7\u7a0b\u4e2d\u9047\u5230\u7684\u68d8\u624b\u95ee\u9898\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u91c7\u7528\u4e86\u5c0f\u95ee\u7b54\u7684\u5f62\u5f0f\u4ecb\u7ecd\u7ed9\u5927\u5bb6\u3002 \u7b2c9\u56de\u5c0f\u7f16\u51c6\u5907\u4ecb\u7ecd\u4e0b\u3001Andreas Pfaltz\u4e0e\u94c3\u6728 \u542f\u4ecb\uff08Suzuki\u00a0Keisuke\uff09\u7b49\u4eba\u7684Macrocidin A\u7684\u5168\u5408\u6210\uff082010\uff09\u3002 \u5f80\u671f\u5185\u5bb9\u56de\u987e\u8bf7\u6233\u6211\uff5e \u7b2c\u4e00\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e8c\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e09\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u56db\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e94\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u516d\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e03\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u516b\u56de \u95ee\u9898 \u89e3\u6790 \u7b2c\u4e5d\u56de \u95ee\u9898 \u8be5\u7bc7\u7684\u539f\u6587\u732e\u5982\u4e0b\u6240\u793a \u201cTotal Synthesis and Absolute Configuration of Macrocidin\u2005A, a Cyclophane Tetramic Acid Natural Product\u201d Yoshinari, T.; Ohmori, K.; Schrems, M. G.; Pfaltz, A.; Suzuki, K. Angew. Chem. Int. Ed. 2010, 49, 881. 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\u5916\u90e8\u94fe\u63a5<\/h4>\n\n- \u82b3\u9999\u65cf\u30a2\u30df\u30c9\u306e\u30b3\u30f3\u30d5\u30a9\u30e1\u30fc\u30b7\u30e7\u30f3\u5236\u5fa1\u6cd5\u307e\u3068\u3081<\/a>\uff08\u6c17\u307e\u307e\u306b\u5275\u85ac\u5316\u5b66\uff09<\/li>\n
- Peptide \u00a0bond \u2013 Wikipedia<\/a><\/li>\n
- \u9234\u6728\u30fb\u5927\u68ee\u7814\u7a76\u5ba4<\/a><\/li>\n<\/ul>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u7cfb\u5217\u5185\u5bb9\u662f\u4e3a\u5e2e\u52a9\u5927\u5bb6\u80fd\u591f\u76f4\u9762\u5168\u5408\u6210\u4e2d\u5e94\u514b\u670d\u7684\u56f0\u96be\u800c\u7f16\u5199\u7684\u3002\u5217\u4e3e\u4e86\u4e00\u4e9b\u5728\u5168\u5408\u6210\u8fc7\u7a0b\u4e2d\u9047\u5230\u7684\u68d8\u624b\u95ee\u9898\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u91c7\u7528\u4e86\u5c0f\u95ee\u7b54\u7684\u5f62\u5f0f\u4ecb\u7ecd\u7ed9\u5927\u5bb6\u3002 \u7b2c9\u56de\u5c0f\u7f16\u51c6\u5907\u4ecb\u7ecd\u4e0b\u3001Andreas Pfaltz\u4e0e\u94c3\u6728 \u542f\u4ecb\uff08Suzuki\u00a0Keisuke\uff09\u7b49\u4eba\u7684Macrocidin A\u7684\u5168\u5408\u6210\uff082010\uff09\u3002 \u5f80\u671f\u5185\u5bb9\u56de\u987e\u8bf7\u6233\u6211\uff5e \u7b2c\u4e00\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e8c\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e09\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u56db\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e94\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u516d\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u4e03\u56de\u00a0\u95ee\u9898\u00a0\u89e3\u6790 \u7b2c\u516b\u56de \u95ee\u9898 \u89e3\u6790 \u7b2c\u4e5d\u56de \u95ee\u9898 \u8be5\u7bc7\u7684\u539f\u6587\u732e\u5982\u4e0b\u6240\u793a \u201cTotal Synthesis and Absolute Configuration of Macrocidin\u2005A, a Cyclophane Tetramic Acid Natural Product\u201d Yoshinari, T.; Ohmori, K.; Schrems, M. G.; Pfaltz, A.; Suzuki, K. Angew. Chem. Int. Ed. 2010, 49, 881. 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G.; Pfaltz, A.; Suzuki, K. Angew. Chem. Int. Ed. 2010, 49, 881. 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