{"id":15812,"date":"2017-10-25T06:17:38","date_gmt":"2017-10-24T22:17:38","guid":{"rendered":"\/\/www.gsbet888.com\/?p=15812"},"modified":"2019-08-02T18:52:42","modified_gmt":"2019-08-02T10:52:42","slug":"tauber-%e5%92%94%e5%94%91%e5%90%88%e6%88%90","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e7%8e%af%e5%8c%96%e5%8f%8d%e5%ba%94\/2017\/10\/tauber-%e5%92%94%e5%94%91%e5%90%88%e6%88%90.html","title":{"rendered":"T\u00e4\u00fcber \u5494\u5511\u5408\u6210"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>T\u00e4\u00fcber \u5494\u5511\u5408\u6210(T\u00e4\u00fcber Carbazole Synthesis)\u662f\u5728\u9178(\u7a00\u76d0\u9178\u3001\u7a00\u786b\u9178)\u50ac\u5316\u4e0e\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5c062,2\u2032-\u4e8c\u6c28\u57fa\u8054\u82ef\u8fdb\u884c\u5173\u73af\u53cd\u5e94\uff0c\u5f62\u6210\u5494\u5511\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u57281890\u5e74\u7531\u5fb7\u56fdBerlin \u5927\u5b66(Universit\u00e4t Berlin)\u7684E. T\u00e4\u00fcber\u9996\u6b21\u62a5\u9053\u3002(\u5c01\u9762\u56fe)<\/p>\n<p>1953\u5e74\uff0cLeditschke\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u5c06\u50ac\u5316\u5242\u6269\u5c55\u81f3\u6d53\u78f7\u9178[4]\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/2-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15814 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/2-2.png\" alt=\"\" width=\"648\" height=\"132\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/2-2.png 648w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/2-2-300x61.png 300w\" sizes=\"(max-width: 648px) 100vw, 648px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>1991\u5e74\uff0cOlah\u9996\u6b21\u5bf9\u4e0a\u8ff0\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u6539\u8fdb\uff0c\u5728\u9002\u5f53\u6eb6\u5242\u4e2d\uff0c\u91c7\u7528\u5168\u6c1f\u78fa\u9178\u6811\u8102Nafion-H\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u56de\u6d41\u6761\u4ef6\u4e0b\uff0c\u8fdb\u884c\u5494\u5511\u7684\u5408\u6210[8]\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/3-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15815 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/3-2.png\" alt=\"\" width=\"574\" height=\"173\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/3-2.png 574w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/3-2-300x90.png 300w\" sizes=\"(max-width: 574px) 100vw, 574px\" \/><\/a><\/p>\n<p>2011\u5e74\uff0cCho\u7814\u7a76\u53d1\u73b0\u91c7\u75280.4 M HCl\u53ca\u4e8c\u5641\u70f7\u4f5c\u4e3a\u6eb6\u5242\u53ef\u4ee5\u4f7f\u8be5\u53cd\u5e94\u5728\u8f83\u4e3a\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002\u76ee\u524d\uff0c\u8be5\u53cd\u5e94\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u7c7b\u5494\u5511\u73af\u5316\u5408\u7269\u53ca\u5494\u5511\u7c7b\u836f\u7269\u7684\u5408\u6210[9]\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/4-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15816 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/4-2.png\" alt=\"\" width=\"527\" height=\"164\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/4-2.png 527w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/4-2-300x93.png 300w\" sizes=\"(max-width: 527px) 100vw, 527px\" \/><\/a><\/p>\n<p><strong>\u57fa\u672c\u6587\u732e<\/strong><\/p>\n<ul>\n<li>[1] E. T\u00e4\u00fcber, Ber., 1890, 23, 3266. doi: <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cber.189002302284\/full\">10.1002\/cber.189002302284.<\/a><\/li>\n<li>[2] E. T\u00e4\u00fcber, Ber., 1891, 24, 197. doi: <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cber.18910240138\/full\">10.1002\/cber.18910240138.<\/a><\/li>\n<li>[3] E.T\u00e4\u00fcber, R. Loewenherz, Ber., 1891, 24, 1033. doi: <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cber.189102401190\/full\">10.1002\/cber.189102401190.<\/a><\/li>\n<li>[4] H. Leditschke, Chem. Ber., 1953, 86, 522. doi: <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cber.19530860415\/full\">10.1002\/cber.19530860415.<\/a><\/li>\n<li>[5] D.A. Patrick, D.W. Boykin, W.D. Wilson, F. A. Tanious, J. Spychala, B. C. Bender, J. E. Hall, C. C. Dykstra, K. A. Ohemeng, R. R. Tidwell, Eur. J. Med. Chem., 1997, 32, 781. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0223523499800646\">10.1016\/S0223-5234(99)80064-6.<\/a><\/li>\n<li>[6] L. Racan\u00e9, H. \u010ci\u010dak, Z. Mihali\u0107, \u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">G. Karminski-Zamola<\/a><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316#aff3\">c<\/a>,\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">V. Trali\u0107-Kulenovi\u0107<\/a>, Tetrahedron, 2011, 67, 2760. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">10.1016\/j.tet.2011.02.037.<\/a><\/li>\n<li>[7] M. Tashiro, Y. Fukuda, T. Yamato, Heterocycles, 1981, 16, 771. doi: <a href=\"https:\/\/www.heterocycles.jp\/newlibrary\/payments\/form\/09609\/PDF\">10.3987\/R-1981-05-0771.<\/a><\/li>\n<li>[8] T. Yamato, C. Hideshima, K. Suehiro,\u00a0<a href=\"http:\/\/booksc.org\/g\/Kazuaki\">K.<\/a> <a href=\"http:\/\/booksc.org\/g\/Tashiro\">Tashiro<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/Masashi\">M.<\/a> <a href=\"http:\/\/booksc.org\/g\/Prakash\">Prakash<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/G.%20K.%20Surya\">G. K. Surya<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/George%20A.\">G. A.<\/a> <a href=\"http:\/\/booksc.org\/g\/Olah\">Olah<\/a>,\u00a0J. Org. Chem., 1991, 56, 6248. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo00021a057\">10.1021\/jo00021a057.<\/a><\/li>\n<li>[9] B. Y. Lim, M. K. Choi, C. G. Cho, Tetrahedron Lett., 2011, 52, 6015. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040403911015115\">10.1016\/j.tetlet.2011.09.001.<\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p>&nbsp;<\/p>\n<p><strong><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/5-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15817 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/5-2-680x550.png\" alt=\"\" width=\"680\" height=\"550\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/5-2-680x550.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/5-2-300x243.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/5-2.png 739w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/a><br \/>\n<\/strong><\/p>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u6297\u80ba\u56ca\u866b\u80ba\u708e\u6d3b\u6027\u7684\u53cc\u6b63\u79bb\u5b50\u5494\u5511\u7684\u5408\u6210[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15818 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1-680x149.png\" alt=\"\" width=\"680\" height=\"149\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1-680x149.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1-300x66.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1-768x168.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/6-1.png 784w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/a><\/p>\n<p>Nafion-H\u50ac\u5316\u7684\u5494\u5511\u5408\u6210[2]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15819 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/7.png\" alt=\"\" width=\"602\" height=\"138\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/7.png 602w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/7-300x69.png 300w\" sizes=\"(max-width: 602px) 100vw, 602px\" \/><\/a><\/p>\n<p>\u4e8c\u567b\u5511\u73af\u7a20\u5408\u5494\u5511\u73af\u7684\u5408\u6210[3]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/8.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-15820 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/8.png\" alt=\"\" width=\"439\" height=\"164\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/8.png 439w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/8-300x112.png 300w\" sizes=\"(max-width: 439px) 100vw, 439px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p>\u5c062,2\u2032-\u4e8c\u6c28\u57fa\u8054\u82b3(1eq.)\u52a0\u5165\u5230\u88c5\u670985% H<sub>3<\/sub>PO<sub>4<\/sub> (\u7ef4\u6301\u5e95\u7269\u6d53\u5ea6\u4e3a0.1M) \u7684\u5706\u5e95\u70e7\u74f6\u4e2d\uff0c\u63d2\u5165\u56de\u6d41\u51b7\u51dd\u7ba1\u3002\u5c06\u4e0a\u8ff0\u5747\u76f8\u6df7\u5408\u7269\u5728200<sup>o<\/sup>C\u4e0b\u8fdb\u884c\u52a0\u70ed\uff0c\u76f4\u81f3\u53cd\u5e94\u5b8c\u6210\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u53cd\u5e94\u6db2\u51b7\u5374\u540e\uff0c\u52a0\u6c34\u8fdb\u884c\u7a00\u91ca\uff0c\u518d\u6ef4\u52a0\u6c28\u6c34\u8fdb\u884c\u4e2d\u548c\uff0c\u5c06\u4ea7\u751f\u7684\u6c89\u6dc0\u5145\u5206\u8fc7\u6ee4\u6d17\u6da4\u540e\uff0c\u5bf9\u7c97\u4ea7\u7269\u91c7\u7528\u91cd\u7ed3\u6676\u8fdb\u884c\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<h4><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/h4>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n[1] D.A. Patrick, D.W. Boykin, W.D. Wilson, F. A. Tanious, J. Spychala, B. C. Bender, J. E. Hall, C. C. Dykstra, K. A. Ohemeng, R. R. Tidwell, Eur. J. Med. Chem., 1997, 32, 781. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0223523499800646\">10.1016\/S0223-5234(99)80064-6.<\/a><\/p>\n[2] T. Yamato, C. Hideshima, K. Suehiro,\u00a0<a href=\"http:\/\/booksc.org\/g\/Kazuaki\">K.<\/a> <a href=\"http:\/\/booksc.org\/g\/Tashiro\">Tashiro<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/Masashi\">M.<\/a> <a href=\"http:\/\/booksc.org\/g\/Prakash\">Prakash<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/G.%20K.%20Surya\">G. K. Surya<\/a>,\u00a0<a href=\"http:\/\/booksc.org\/g\/George%20A.\">G. A.<\/a> <a href=\"http:\/\/booksc.org\/g\/Olah\">Olah<\/a>,\u00a0J. Org. Chem., 1991, 56, 6248. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo00021a057\">10.1021\/jo00021a057.<\/a><\/p>\n[3] L. Racan\u00e9, H. \u010ci\u010dak, Z. Mihali\u0107, \u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">G. Karminski-Zamola<\/a><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316#aff3\">c<\/a>,\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">V. Trali\u0107-Kulenovi\u0107<\/a>, Tetrahedron, 2011, 67, 2760. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040402011002316\">10.1016\/j.tet.2011.02.037.<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01 <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 T\u00e4\u00fcber \u5494\u5511\u5408\u6210(T\u00e4\u00fcber Carbazole Synthesis)\u662f\u5728\u9178(\u7a00\u76d0\u9178\u3001\u7a00\u786b\u9178)\u50ac\u5316\u4e0e\u9ad8\u6e29\u6761\u4ef6\u4e0b\u5c062,2\u2032-\u4e8c\u6c28\u57fa\u8054\u82ef\u8fdb\u884c\u5173\u73af\u53cd\u5e94\uff0c\u5f62\u6210\u5494\u5511\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u57281890\u5e74\u7531\u5fb7\u56fdBerlin \u5927\u5b66(Universit\u00e4t Berlin)\u7684E. T\u00e4\u00fcber\u9996\u6b21\u62a5\u9053\u3002(\u5c01\u9762\u56fe) 1953\u5e74\uff0cLeditschke\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\uff0c\u5c06\u50ac\u5316\u5242\u6269\u5c55\u81f3\u6d53\u78f7\u9178[4]\u3002 &nbsp; 1991\u5e74\uff0cOlah\u9996\u6b21\u5bf9\u4e0a\u8ff0\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u6539\u8fdb\uff0c\u5728\u9002\u5f53\u6eb6\u5242\u4e2d\uff0c\u91c7\u7528\u5168\u6c1f\u78fa\u9178\u6811\u8102Nafion-H\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u56de\u6d41\u6761\u4ef6\u4e0b\uff0c\u8fdb\u884c\u5494\u5511\u7684\u5408\u6210[8]\u3002 2011\u5e74\uff0cCho\u7814\u7a76\u53d1\u73b0\u91c7\u75280.4 M HCl\u53ca\u4e8c\u5641\u70f7\u4f5c\u4e3a\u6eb6\u5242\u53ef\u4ee5\u4f7f\u8be5\u53cd\u5e94\u5728\u8f83\u4e3a\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002\u76ee\u524d\uff0c\u8be5\u53cd\u5e94\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u7c7b\u5494\u5511\u73af\u5316\u5408\u7269\u53ca\u5494\u5511\u7c7b\u836f\u7269\u7684\u5408\u6210[9]\u3002 \u57fa\u672c\u6587\u732e [1] E. T\u00e4\u00fcber, Ber., 1890, 23, 3266. doi: 10.1002\/cber.189002302284. [2] E. T\u00e4\u00fcber, Ber., 1891, 24, 197. doi: 10.1002\/cber.18910240138. [3] E.T\u00e4\u00fcber, R. Loewenherz, Ber., 1891, 24, 1033. doi: 10.1002\/cber.189102401190. [4] H. Leditschke, Chem. Ber., 1953, 86, 522. doi: 10.1002\/cber.19530860415. [5] D.A. Patrick, D.W. Boykin, W.D. Wilson, F. A. Tanious, J. Spychala, B. C. Bender, J. E. Hall, C. C. Dykstra, K. A. Ohemeng, R. R. Tidwell, Eur. J. Med. Chem., 1997, 32, 781. doi: 10.1016\/S0223-5234(99)80064-6. [6] L. Racan\u00e9, H. \u010ci\u010dak, Z. Mihali\u0107, \u00a0G. Karminski-Zamolac,\u00a0V. Trali\u0107-Kulenovi\u0107, Tetrahedron, 2011, 67, 2760. doi: 10.1016\/j.tet.2011.02.037. [7] M. Tashiro, Y. Fukuda, [&hellip;]","protected":false},"author":21,"featured_media":15902,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[9],"tags":[2023,2024,2025,637],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/09\/ce1721fb8a5daaf788d8db377351b139.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-472","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/15812"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=15812"}],"version-history":[{"count":12,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/15812\/revisions"}],"predecessor-version":[{"id":27319,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/15812\/revisions\/27319"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/15902"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=15812"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=15812"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=15812"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}