{"id":17313,"date":"2017-12-28T07:19:25","date_gmt":"2017-12-27T23:19:25","guid":{"rendered":"\/\/www.gsbet888.com\/?p=17313"},"modified":"2019-08-02T18:52:11","modified_gmt":"2019-08-02T10:52:11","slug":"chem-sci-%e4%bb%a5%e9%85%ae%e4%bd%9c%e4%b8%ba%e5%af%bc%e5%90%91%e5%9f%ba%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7sp3-c-h%e6%b0%9f%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2017\/12\/chem-sci-%e4%bb%a5%e9%85%ae%e4%bd%9c%e4%b8%ba%e5%af%bc%e5%90%91%e5%9f%ba%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7sp3-c-h%e6%b0%9f%e5%8c%96%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Chem. Sci.\u00a0\u4ee5\u916e\u4f5c\u4e3a\u5bfc\u5411\u57fa\u7684\u533a\u57df\u9009\u62e9\u6027sp3 C-H\u6c1f\u5316\u53cd\u5e94"},"content":{"rendered":"<p><strong>\u7ea6\u7ff0\u30fb\u970d\u666e\u91d1\u65af\u5927\u5b66\u7684<a href=\"\/\/www.gsbet888.com\/chemists\/2017\/12\/thomas-lectka.html\">Thomas Lectka<\/a>\u7b49\u4eba\u3001\u4f7f\u7528\u201c\u65e0\u5904\u4e0d\u5728\u201d\u7684\u5b98\u80fd\u56e2\u916e\u4f5c\u4e3a\u5bfc\u5411\u57fa\u56e2\u3001\u6210\u529f\u5b9e\u73b0\u4e86\u5bf9\u521a\u6027\u73af\u72b6\u5316\u5408\u7269\u7684<em>sp<sup>3<\/sup><\/em> C-H\u533a\u57df\u9009\u62e9\u6027\u6c1f\u5316\u53cd\u5e94\u3002<\/strong><\/p>\n<blockquote><p>\u201cKetones as directing groups in photocatalytic <em>sp<sup>3<\/sup><\/em> C-H fluorination\u201d<br \/>\nBume, D. D.; Pitts, C. R.; Ghorbani, F.; Harry, S. A.; Capilato, J. N.; Siegler, M. A.; Lectka, T. * <em>Chem. Sci.<\/em>\u00a0<strong>2017<\/strong>, <em>8<\/em>, 6918-6923. doi:<a href=\"http:\/\/dx.doi.org\/10.1039\/C7SC02703F\">10.1039\/C7SC02703F<\/a><\/p><\/blockquote>\n<h4>\u8bfe\u9898\u8bbe\u5b9a<\/h4>\n<p>\u4f4d\u7f6e\u9009\u62e9\u6027\u7684<em>sp<sup>3<\/sup><\/em> C-H\u6c1f\u5316\u53cd\u5e94\u7684\u62a5\u9053\u5b9e\u4f8b\u76ee\u524d\u6765\u8bf4\u5e76\u4e0d\u591a\u3002\u800c\u5728\u5df2\u62a5\u9053\u7684\u53cd\u5e94\u6761\u4ef6\u4e2d\uff0c\u90fd\u4e3b\u8981\u96c6\u4e2d\u5728\u672c\u8eab\u53cd\u5e94\u6027\u9ad8\u7684C-H\u952e\u6216\u8005\u7acb\u4f53\u4e0a\u6bd4\u8f83\u5bb9\u6613\u4e0e\u53cd\u5e94\u6d3b\u6027\u4e2d\u95f4\u63a5\u8fd1\u7684C-H\u952e\uff0c\u4ee5\u53ca\u4e00\u4e9b\u5e38\u7528\u7684\u5bfc\u5411\u57fa\u56e2\u5bfc\u5411\u7684C-H\u952e\u7684\u53d8\u6362\u3002<\/p>\n<p>\u4e00\u822c\u6765\u8bf4\uff0c\u79bb\u5438\u7535\u5b50\u57fa\u56e2\u8d8a\u8fdc\uff0c\u8d8a\u662f\u5bcc\u7535\u5b50\u7684C-H\u952e\u66f4\u5bb9\u6613\u53d1\u751fC-H\u5747\u88c2\u53cd\u5e94\u751f\u6210\u6d3b\u6027\u81ea\u7531\u57fa\u3002\u7136\u800c\uff0c\u5728\u4eca\u5e74\u65e9\u4e9b\u7684\u4e00\u7bc7JACS\u4e2d\uff0c<strong><a href=\"\/\/www.gsbet888.com\/chemists\/2017\/12\/thomas-lectka.html\">Thomas Lectka<\/a><\/strong>\u7b49\u4eba\u4f7f\u7528\u5438\u7535\u5b50\u57fa\u70ef\u916e\u4f5c\u4e3a\u5bfc\u5411\u57fa\u56e2\uff0c\u5df2\u7ecf\u53d1\u73b0\u591a\u73af\u841c\u7c7b\u5316\u5408\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\u5149\u5316\u5b66C-H\u6c1f\u5316\u53cd\u5e94\u662f\u53ef\u884c\u7684[1]\u3002\u5728\u5f53\u65f6\u540c\u6761\u4ef6\u4e0b\uff0c\u5355\u5355\u7528\u916e\u505a\u5bfc\u5411\u57fa\u56e2\uff0c\u53cd\u5e94\u5e76\u6ca1\u6709\u80fd\u591f\u9009\u62e9\u6027\u8fdb\u884c\uff08\u53ea\u8fdb\u884c\u4e86\u975e\u9009\u62e9\u6027\u7684\u6c1f\u5316\uff09\u3002<\/p>\n<p>\u800c\u4eca\u5929\u4ecb\u7ecd\u7684\u8fd9\u7bc7\u6587\u7ae0\u5c31\u662f\u89e3\u51b3\u4e86\u8fd9\u4e00\u9057\u7559\u8bfe\u9898\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u89e3\u51b3\u624b\u6cd5<\/h4>\n<p>\u4f5c\u8005\u8ba4\u4e3a\u5f53\u5728300nm\u7684UV\u7167\u5c04\u6761\u4ef6\u4e0b\u6fc0\u53d1\u5e95\u7269\u548c\u6c1f\u6e90\u672c\u8eab\u65f6\uff0c\u662f\u5bfc\u81f4\u53d1\u751f\u4e0d\u5e0c\u671b\u7684\u975e\u9009\u62e9\u6027\u53cd\u5e94\u7684\u539f\u56e0\uff0c\u56e0\u6b64\u4ed6\u4eec\u8c03\u6574\u5149\u6e90\uff0c\u901a\u8fc7\u52a0\u5165\u53ef\u4ee5\u5728\u53ef\u89c1\u5149\u4e0b\u6fc0\u53d1\u7684\u5149\u654f\u5242\uff0c\u671f\u671b\u5728\u66f4\u6e29\u548c\u7684\u53ef\u89c1\u5149\u6761\u4ef6\u4e0b\u80fd\u591f\u5b9e\u73b0\u9009\u62e9\u6027\u7684C-H\u6c1f\u5316\u53cd\u5e94\u3002\u8fd9\u4e2a\u5149\u654f\u5242\u7684\u6dfb\u52a0\u662f\u4e4b\u524dJACS[1]\u4e2d\u6240\u6ca1\u6709\u7684\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u6709\u6548\u6027\u9a8c\u8bc1<\/h4>\n<h5>\u2460\u5173\u4e8e\u53cd\u5e94\u6761\u4ef6<\/h5>\n<p>\u5149\u654f\u5242\u7684\u7b5b\u9009\u663e\u793a\uff0c\u5df2\u77e5\u4e3a\u4e09\u91cd\u6001\u654f\u5316\u5242\u7684Benzil\uff08\u4e8c\u82ef\u57fa\u4e59\u4e8c\u916e\uff09\u4ea7\u7387\u6700\u9ad8\u3002\u5173\u4e8e\u6c1f\u6e90\u7684\u7b5b\u9009\u53d1\u73b0\uff0cSelectfluor\u6700\u4f73\uff0c\u800c\u4f7f\u7528\u5e38\u7528\u7684NFSI\u548cN-\u6c1f\u4ee3\u5421\u5576\u9393\u76d0\u7b49\u6c1f\u6e90\uff0c\u4e0d\u80fd\u5f97\u5230\u6240\u9700\u7684\u6c1f\u5316\u7269\u3002\u540c\u65f6\u968f\u7740Selectfluor\u7684\u6dfb\u52a0\u91cf\u589e\u52a0\uff0c\u9009\u62e9\u6027\u964d\u4f4e\u3002<\/p>\n<p>\u5149\uff0c\u5149\u654f\u5242\uff0c\u6c1f\u5316\u5242\u7f3a\u4e00\u4e0d\u53ef\u3002\u5728\u7a7a\u6c14\u4e0b\u53cd\u5e94\u65e0\u6cd5\u8fdb\u884c\u3002\u5728\u6697\u5904\u65e0\u5149\u7167\u5c04\u7684\u56de\u6d41\u52a0\u70ed\u6761\u4ef6\u4e0b\u65e0\u6cd5\u9009\u62e9\u6027\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff0c\u53ea\u6709trace\u91cf\u7684\u6c1f\u5316\u4f53\u751f\u6210\u3002<\/p>\n<h5>\u2461\u5e95\u7269\u62d3\u5c55<\/h5>\n<p>\u4f5c\u8005\u4f7f\u7528\u6807\u9898\u56fe\u4e2d\u6240\u793a\u7684\u6761\u4ef6\u8fdb\u884c\u4e86\u5e95\u7269\u7684\u4e00\u822c\u6027\u8ba8\u8bba\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-medium wp-image-17315\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_3-e1512891541100-300x281.png\" alt=\"\" width=\"300\" height=\"281\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_3-e1512891541100-300x281.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_3-e1512891541100.png 365w\" sizes=\"(max-width: 300px) 100vw, 300px\" \/><\/p>\n<p>\u603b\u7ed3\u6765\u8bf4\u6709\u4ee5\u4e0b\u7279\u5f81\u53ef\u5bfb\u3002<\/p>\n<ul>\n<li>\u533a\u57df\u9009\u62e9\u6027\u6c1f\u5316\u9002\u7528\u4e8e\u5177\u6709\u591a\u73af\u521a\u6027\u9aa8\u67b6\u7684\u5e95\u7269\u3002<\/li>\n<li>\u53cd\u5e94\u53d1\u751f\u5728\u6709\u916e\u7fb0\u57fa\u76845\u5143\u73af\u30fb6\u5143\u73af\u7684\u5e95\u7269\u4e2d\u3002\u4f46\u662f\u8be5\u6761\u4ef6\u4e0d\u9002\u75281\u7ea7C-H\u6c1f\u5316\u3002<\/li>\n<li>\u8be5\u6761\u4ef6\u4e0d\u9002\u7528\u4e8e\u4e59\u82ef\u5e95\u7269\u3002\u56e0\u6b64\u916e\u7fb0\u57fa\u88ab\u8ba4\u4e3a\u5728\u672c\u6761\u4ef6\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\u3002<\/li>\n<li>\u916e\u7fb0\u57fa\u65e0\u8bba\u5728\u73af\u5185\u8fd8\u662f\u73af\u5916\u90fd\u9002\u7528\u3002\u800c\u916e\u7fb0\u57fa\u7684\u671d\u5411\u4e0d\u540c\u7684\u65f6\u5019\uff0c\u5982\u4e0b\u56fe\u6240\u793a\uff0c\u4f1a\u4ea7\u751f\u533a\u57df\u9009\u62e9\u6027\u5f02\u6784\u4f53\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17316 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_2-e1512891597308.png\" alt=\"\" width=\"458\" height=\"228\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_2-e1512891597308.png 458w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_2-e1512891597308-300x149.png 300w\" sizes=\"(max-width: 458px) 100vw, 458px\" \/><\/p>\n<ul>\n<li>\u521a\u6027\u6784\u8c61\u6709\u5229\u4e8e\u9009\u62e9\u6027\u7684\u4ea7\u751f\uff0c\u76f8\u5bf9\u7684\u7ebf\u6027\u94fe\u72b6\u916e\u5bfc\u5411\u7684\u5e95\u7269\u5f88\u96be\u5b9e\u73b0\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u5e95\u7269\u662f2-\u5e9a\u916e\u7684\u60c5\u51b5\u4e0b\uff0c\u4f1a\u4ea7\u751f\u03b2\uff1a\u03b3\uff1a\u03b4\uff1d1 : 2.3 : 1.3\u7684\u533a\u57df\u9009\u62e9\u6027\u6c1f\u5316\u5f02\u6784\u4f53\u3002\u75282-\u7678\u916e\u548c2-\u5341\u4e8c\u70f7\u916e\u4f1a\u5f62\u6210\u66f4\u590d\u6742\u7684\u6df7\u5408\u7269\u3002<\/li>\n<\/ul>\n<h5>\u2462\u5173\u4e8e\u53cd\u5e94\u673a\u7406<\/h5>\n<p>\u5728\u4ee5\u524d\u62a5\u9053\u7684\u70ef\u916e\u4f5c\u4e3a\u53d6\u5411\u57fa\u56e2\u7684\u53cd\u5e94\u6761\u4ef6[1]\u4e2d\uff0c\u4f5c\u8005\u8ba4\u4e3a\u9009\u62e9\u6027\u7684\u4ea7\u751f\u5728\u5206\u5b50\u5185\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u8fc7\u7a0b\u4e2d\u3002\u4f46\u662f\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u4f5c\u8005\u53d1\u73b0<\/p>\n<ol>\n<li>\u5728\u5bf9\u5206\u5b50\u5185HAT\u6709\u5229\u7684\u7a00\u91ca\u6761\u4ef6\u4e0b\uff0c\u5bf9\u76f4\u94fe\u916e\u5e95\u7269\u7684\u9009\u62e9\u6027\u4e5f\u5e76\u6ca1\u6709\u5f97\u5230\u6539\u5584<\/li>\n<li>Benzil\u4e09\u91cd\u6001\u80fd\u91cf\uff0853 kcal\/mol\uff09\u4e0d\u8db3\u4ee5\u5f15\u8d77\u4e09\u91cd\u6001-\u4e09\u91cd\u6001\u80fd\u91cf\u8f6c\u79fb\uff0880 kcal\/mol\uff09\u5230\u8102\u80aa\u65cf\u916e\u3002<\/li>\n<\/ol>\n<p>\u901a\u8fc7\u8fd9\u4e24\u70b9\uff0c\u4f5c\u8005\u5426\u5b9a\u4e86HAT\u8fc7\u7a0b\u7684\u4ecb\u5bfc\u53ef\u80fd\u3002<\/p>\n<p>\u4f5c\u8005\u8ba4\u4e3a\uff1a\u5149\u654f\u5242Benzil\u53ef\u4ee5\u4fc3\u8fdb\u4ece\u5e95\u7269\u5230Selectflour\u7684\u80fd\u91cf\u8f6c\u79fb\uff0c\u4ece\u800c\u4ea7\u751f\u6c2e\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\uff0c\u4f5c\u4e3a\u6c27\u5316\u5242\u4f5c\u7528\uff0c\u5f15\u8d77\u7535\u5b50\u79fb\u52a8\u30fbProton\u79fb\u52a8\uff0c\u4ece\u800c\u63a8\u52a8\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u800c\u5b9e\u9645\u4e0a\uff0c\u5728\u65e0\u5149\u7167\u4e0b\uff0c\u4f7f\u7528\u540c\u6837\u53ef\u4ee5\u751f\u6210\u6c2e\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\u7684Selectfluor\uff0bBEt<sub>3<\/sub>\u6761\u4ef6\uff0c\u4e5f\u80fd\u5f97\u5230\u4e0e\u672c\u53cd\u5e94\u540c\u6837\u7684\u9009\u62e9\u6027\u3002\uff08\u4e0b\u56fe\u6240\u793a\uff09<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17317 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_4-e1512891726694.png\" alt=\"\" width=\"502\" height=\"119\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_4-e1512891726694.png 502w, https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/light_C-H_F_4-e1512891726694-300x71.png 300w\" sizes=\"(max-width: 502px) 100vw, 502px\" 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C. R.; Bume, D. D.; Harry, S. A.; Siegler, M. A.; Lectka. T. <em>J. Am. Chem. Soc.<\/em><strong>2017<\/strong>, <em>139<\/em>, 2208. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/jacs.7b00335\">10.1021\/jacs.7b00335<\/a><\/li>\n<li>Davis, H. J.; Phipps, R. J. <em>Chem. Sci.<\/em> <strong>2017<\/strong>, <em>8<\/em>, 864. doi:<a href=\"http:\/\/dx.doi.org\/10.1039\/C6SC04157D\">10.1039\/C6SC04157D<\/a><\/li>\n<\/ol>\n<h4>\u5173\u8054\u4e66\u7c4d<\/h4>\n<div class=\"amazonjs_item amazonjs_book\">\n<div class=\"amazonjs_image\"><a class=\"amazonjs_link\" title=\"C-H Bond Activation in Organic Synthesis\" href=\"https:\/\/www.amazon.co.jp\/C-H-Bond-Activation-Organic-Synthesis\/dp\/1138894117?SubscriptionId=AKIAI6Q3RDQBU2J6P3JQ&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=1138894117\" target=\"_blank\" rel=\"noopener\" data-role=\"amazonjs_product\" data-asin=\"1138894117\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/images-fe.ssl-images-amazon.com\/images\/I\/417IrSZW9OL._SL160_.jpg\" alt=\"C-H Bond Activation in Organic Synthesis\" width=\"106\" height=\"160\" \/><\/a><\/div>\n<div class=\"amazonjs_info\">\n<h4><a class=\"amazonjs_link\" title=\"C-H Bond Activation in Organic Synthesis\" href=\"https:\/\/www.amazon.co.jp\/C-H-Bond-Activation-Organic-Synthesis\/dp\/1138894117?SubscriptionId=AKIAI6Q3RDQBU2J6P3JQ&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=1138894117\" target=\"_blank\" rel=\"noopener\" data-role=\"amazonjs_product\" data-asin=\"1138894117\">C-H Bond Activation in Organic Synthesis<\/a><\/h4>\n<ul>\n<li class=\"amazonjs_price\" title=\"\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306f\u8868\u793a\u3055\u308c\u305f\u65e5\u4ed8\/\u6642\u523b\u306e\u6642\u70b9\u306e\u3082\u306e\u3067\u3042\u308a\u3001\u5909\u66f4\u3055\u308c\u308b\u5834\u5408\u304c\u3042\u308a\u307e\u3059\u3002\u5546\u54c1\u306e\u8ca9\u58f2\u306b\u304a\u3044\u3066\u306f\u3001\u8cfc\u5165\u306e\u6642\u70b9\u3067 [Amazon.co.jp \u307e\u305f\u306f Javari.jp] \u306b\u8868\u793a\u3055\u308c\u3066\u3044\u308b\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306e\u60c5\u5831\u304c\u9069\u7528\u3055\u308c\u307e\u3059\u3002\"><b>\u53c2\u8003\u4fa1\u683c<\/b><span class=\"amazonjs_listprice\">\uffe5 7,966<\/span><br \/>\n<b>\u4fa1\u683c<\/b>\uffe5 7,363(2017\/12\/23 21:52\u6642\u70b9)<\/li>\n<li><b>\u51fa\u7248\u65e5<\/b>2017\/11\/22<\/li>\n<li><b>\u30da\u30fc\u30d1\u30fc\u30d0\u30c3\u30af<\/b>328\u30da\u30fc\u30b8<\/li>\n<li><b>ISBN-10<\/b>1138894117<\/li>\n<li><b>ISBN-13<\/b>9781138894112<\/li>\n<li><b>\u51fa\u7248\u793e<\/b>CRC Press<\/li>\n<\/ul>\n<\/div>\n<p><a class=\"amazonjs_review\" title=\"C-H Bond Activation in Organic Synthesis \u30ab\u30b9\u30bf\u30de\u30fc\u30ec\u30d3\u30e5\u30fc\" href=\"https:\/\/www.amazon.jp\/reviews\/iframe?akid=AKIAI6Q3RDQBU2J6P3JQ&amp;alinkCode=xm2&amp;asin=1138894117&amp;atag=chemstation-22&amp;exp=2017-12-24T12%3A52%3A32Z&amp;v=2&amp;sig=p%252B8Xd2IXqop4rG9Ld7QCypMTXjjRh1QvAyYYBxxo7FU%253D&amp;TB_iframe=true&amp;height=500&amp;width=600\" target=\"_blank\" rel=\"noopener\">\u30ab\u30b9\u30bf\u30de\u30fc\u30ec\u30d3\u30e5\u30fc\u3092\u898b\u308b<\/a><\/p>\n<div class=\"amazonjs_footer\"><\/div>\n<\/div>\n<div class=\"amazonjs_item amazonjs_book\">\n<div class=\"amazonjs_image\"><a class=\"amazonjs_link\" title=\"New Fluorinated Carbons: Fundamentals and Applications: Progress in Fluorine Science Series\" href=\"https:\/\/www.amazon.co.jp\/New-Fluorinated-Carbons-Fundamentals-Applications\/dp\/0128034793?SubscriptionId=AKIAI6Q3RDQBU2J6P3JQ&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=0128034793\" target=\"_blank\" rel=\"noopener\" data-role=\"amazonjs_product\" data-asin=\"0128034793\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/images-fe.ssl-images-amazon.com\/images\/I\/51mIlfNbxtL._SL160_.jpg\" alt=\"New Fluorinated Carbons: Fundamentals and Applications: Progress in Fluorine Science Series\" width=\"106\" height=\"160\" \/><\/a><\/div>\n<div class=\"amazonjs_info\">\n<h4><a class=\"amazonjs_link\" title=\"New Fluorinated Carbons: Fundamentals and Applications: Progress in Fluorine Science Series\" href=\"https:\/\/www.amazon.co.jp\/New-Fluorinated-Carbons-Fundamentals-Applications\/dp\/0128034793?SubscriptionId=AKIAI6Q3RDQBU2J6P3JQ&amp;tag=chemstation-22&amp;linkCode=xm2&amp;camp=2025&amp;creative=165953&amp;creativeASIN=0128034793\" target=\"_blank\" rel=\"noopener\" data-role=\"amazonjs_product\" data-asin=\"0128034793\">New Fluorinated Carbons: Fundamentals and Applications: Progress in Fluorine Science Series<\/a><\/h4>\n<ul>\n<li class=\"amazonjs_price\" title=\"\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306f\u8868\u793a\u3055\u308c\u305f\u65e5\u4ed8\/\u6642\u523b\u306e\u6642\u70b9\u306e\u3082\u306e\u3067\u3042\u308a\u3001\u5909\u66f4\u3055\u308c\u308b\u5834\u5408\u304c\u3042\u308a\u307e\u3059\u3002\u5546\u54c1\u306e\u8ca9\u58f2\u306b\u304a\u3044\u3066\u306f\u3001\u8cfc\u5165\u306e\u6642\u70b9\u3067 [Amazon.co.jp \u307e\u305f\u306f Javari.jp] \u306b\u8868\u793a\u3055\u308c\u3066\u3044\u308b\u4fa1\u683c\u304a\u3088\u3073\u767a\u9001\u53ef\u80fd\u6642\u671f\u306e\u60c5\u5831\u304c\u9069\u7528\u3055\u308c\u307e\u3059\u3002\"><b>\u53c2\u8003\u4fa1\u683c<\/b><span class=\"amazonjs_listprice\">\uffe5 21,021<\/span><br \/>\n<b>\u4fa1\u683c<\/b>\uffe5 20,413(2017\/12\/23 21:52\u6642\u70b9)<\/li>\n<li><b>\u51fa\u7248\u65e5<\/b>2016\/09\/27<\/li>\n<li><b>\u5546\u54c1\u30e9\u30f3\u30ad\u30f3\u30b0<\/b>339,313\u4f4d<\/li>\n<li><b>\u30da\u30fc\u30d1\u30fc\u30d0\u30c3\u30af<\/b>442\u30da\u30fc\u30b8<\/li>\n<li><b>ISBN-10<\/b>0128034793<\/li>\n<li><b>ISBN-13<\/b>9780128034798<\/li>\n<li><b>\u51fa\u7248\u793e<\/b>Elsevier<\/li>\n<\/ul>\n<\/div>\n<p><a class=\"amazonjs_review\" title=\"New Fluorinated Carbons: Fundamentals and Applications: Progress in Fluorine Science Series \u30ab\u30b9\u30bf\u30de\u30fc\u30ec\u30d3\u30e5\u30fc\" href=\"https:\/\/www.amazon.jp\/reviews\/iframe?akid=AKIAI6Q3RDQBU2J6P3JQ&amp;alinkCode=xm2&amp;asin=0128034793&amp;atag=chemstation-22&amp;exp=2017-12-24T12%3A52%3A32Z&amp;v=2&amp;sig=Ps5n%252BnLQVf2XSM%252FvlaGlCOPgALXu%252BJJyD6y0A3FiAd4%253D&amp;TB_iframe=true&amp;height=500&amp;width=600\" target=\"_blank\" rel=\"noopener\">\u30ab\u30b9\u30bf\u30de\u30fc\u30ec\u30d3\u30e5\u30fc\u3092\u898b\u308b<\/a><\/p>\n<div class=\"amazonjs_footer\"><\/div>\n<\/div>\n<div id=\"ts-fab-below\" class=\"ts-fab-wrapper\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/div>\n","protected":false},"excerpt":{"rendered":"\u7ea6\u7ff0\u30fb\u970d\u666e\u91d1\u65af\u5927\u5b66\u7684Thomas Lectka\u7b49\u4eba\u3001\u4f7f\u7528\u201c\u65e0\u5904\u4e0d\u5728\u201d\u7684\u5b98\u80fd\u56e2\u916e\u4f5c\u4e3a\u5bfc\u5411\u57fa\u56e2\u3001\u6210\u529f\u5b9e\u73b0\u4e86\u5bf9\u521a\u6027\u73af\u72b6\u5316\u5408\u7269\u7684sp3 C-H\u533a\u57df\u9009\u62e9\u6027\u6c1f\u5316\u53cd\u5e94\u3002 \u201cKetones as directing groups in photocatalytic sp3 C-H fluorination\u201d Bume, D. D.; Pitts, C. R.; Ghorbani, F.; Harry, S. A.; Capilato, J. N.; Siegler, M. A.; Lectka, T. * Chem. Sci.\u00a02017, 8, 6918-6923. doi:10.1039\/C7SC02703F \u8bfe\u9898\u8bbe\u5b9a \u4f4d\u7f6e\u9009\u62e9\u6027\u7684sp3 C-H\u6c1f\u5316\u53cd\u5e94\u7684\u62a5\u9053\u5b9e\u4f8b\u76ee\u524d\u6765\u8bf4\u5e76\u4e0d\u591a\u3002\u800c\u5728\u5df2\u62a5\u9053\u7684\u53cd\u5e94\u6761\u4ef6\u4e2d\uff0c\u90fd\u4e3b\u8981\u96c6\u4e2d\u5728\u672c\u8eab\u53cd\u5e94\u6027\u9ad8\u7684C-H\u952e\u6216\u8005\u7acb\u4f53\u4e0a\u6bd4\u8f83\u5bb9\u6613\u4e0e\u53cd\u5e94\u6d3b\u6027\u4e2d\u95f4\u63a5\u8fd1\u7684C-H\u952e\uff0c\u4ee5\u53ca\u4e00\u4e9b\u5e38\u7528\u7684\u5bfc\u5411\u57fa\u56e2\u5bfc\u5411\u7684C-H\u952e\u7684\u53d8\u6362\u3002 \u4e00\u822c\u6765\u8bf4\uff0c\u79bb\u5438\u7535\u5b50\u57fa\u56e2\u8d8a\u8fdc\uff0c\u8d8a\u662f\u5bcc\u7535\u5b50\u7684C-H\u952e\u66f4\u5bb9\u6613\u53d1\u751fC-H\u5747\u88c2\u53cd\u5e94\u751f\u6210\u6d3b\u6027\u81ea\u7531\u57fa\u3002\u7136\u800c\uff0c\u5728\u4eca\u5e74\u65e9\u4e9b\u7684\u4e00\u7bc7JACS\u4e2d\uff0cThomas Lectka\u7b49\u4eba\u4f7f\u7528\u5438\u7535\u5b50\u57fa\u70ef\u916e\u4f5c\u4e3a\u5bfc\u5411\u57fa\u56e2\uff0c\u5df2\u7ecf\u53d1\u73b0\u591a\u73af\u841c\u7c7b\u5316\u5408\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\u5149\u5316\u5b66C-H\u6c1f\u5316\u53cd\u5e94\u662f\u53ef\u884c\u7684[1]\u3002\u5728\u5f53\u65f6\u540c\u6761\u4ef6\u4e0b\uff0c\u5355\u5355\u7528\u916e\u505a\u5bfc\u5411\u57fa\u56e2\uff0c\u53cd\u5e94\u5e76\u6ca1\u6709\u80fd\u591f\u9009\u62e9\u6027\u8fdb\u884c\uff08\u53ea\u8fdb\u884c\u4e86\u975e\u9009\u62e9\u6027\u7684\u6c1f\u5316\uff09\u3002 \u800c\u4eca\u5929\u4ecb\u7ecd\u7684\u8fd9\u7bc7\u6587\u7ae0\u5c31\u662f\u89e3\u51b3\u4e86\u8fd9\u4e00\u9057\u7559\u8bfe\u9898\u3002 &nbsp; \u89e3\u51b3\u624b\u6cd5 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R.; Bume, D. D.; Harry, S. A.; Siegler, M. A.; Lectka. T. J. Am. Chem. Soc.2017, 139, 2208. DOI: 10.1021\/jacs.7b00335 Davis, H. J.; Phipps, R. J. Chem. Sci. 2017, 8, 864. 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