{"id":17349,"date":"2017-12-27T06:01:50","date_gmt":"2017-12-26T22:01:50","guid":{"rendered":"\/\/www.gsbet888.com\/?p=17349"},"modified":"2019-08-02T18:52:10","modified_gmt":"2019-08-02T10:52:10","slug":"%e5%8c%96%e5%ad%a6%e7%a9%ba%e9%97%b42017%e5%b9%b4%e4%ba%ba%e6%b0%94%e8%ae%b0%e4%ba%8b%e6%8e%92%e8%a1%8c%e6%a6%9c","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemnews\/2017\/12\/%e5%8c%96%e5%ad%a6%e7%a9%ba%e9%97%b42017%e5%b9%b4%e4%ba%ba%e6%b0%94%e8%ae%b0%e4%ba%8b%e6%8e%92%e8%a1%8c%e6%a6%9c.html","title":{"rendered":"\u5316\u5b66\u7a7a\u95f42017\u5e74\u4eba\u6c14\u8bb0\u4e8b\u6392\u884c\u699c"},"content":{"rendered":"<blockquote><p><strong>2017\u5e74<\/strong>\u4e0d\u77e5\u4e0d\u89c9\u5df2\u7ecf\u53c8\u8981\u7ed3\u675f\u4e86\uff0c\u5316\u5b66\u7a7a\u95f4\u4e5f\u8d70\u5b8c\u4e86\u7b2c\u56db\u4e2a\u5e74\u5934\uff0c\u5c0f\u7f16\u4e5f\u7ec8\u4e8e\u535a\u58eb\u6bd5\u4e1a\uff0c\u8e0f\u51fa\u4e86\u8d70\u51fa\u5b66\u6821\uff0c\u8e0f\u5165\u793e\u4f1a\u7684\u7b2c\u4e00\u6b65\u3002\u5728\u8fc7\u53bb\u7684\u8fd9\u4e00\u5e74\uff0c\u611f\u8c22\u5e7f\u5927\u8bfb\u8005\u7684\u652f\u6301\uff0c\u65e0\u8bba\u662f\u5316\u5b66\u7a7a\u95f4\u7684\u8bbf\u95ee\u91cf\uff0c\u8fd8\u662f\u5fae\u4fe1\u516c\u4f17\u53f7\u5173\u6ce8\u4eba\u6570\u4ee5\u53ca\u6211\u4eec\u7684QQ\u7fa4\uff08\u6b22\u8fce\u5404\u4f4d\u52a0\u5165\uff0c\u6f5c\u6c34\u5192\u6ce1\uff09\uff0c\u90fd\u6709\u975e\u5e38\u5e73\u7a33\u7684\u63d0\u5347\u3002\u548c\u53bb\u5e74\u76f8\u6bd4\uff0c\u5728\u5185\u5bb9\u4e0a\uff0c\u4eca\u5e74\u8fd8\u6536\u5230\u4e86\u5f88\u591a\u6765\u81ea\u8bfb\u8005\u7684\u6295\u7a3f\uff0c\u8ba9\u6211\u4eec\u7684\u5185\u5bb9\u66f4\u52a0\u4e30\u5bcc\u548c\u591a\u5143\u5316\u3002\u5e0c\u671b\u4eca\u540e\u4e5f\u80fd\u6709\u66f4\u591a\u7684\u5bf9\u5316\u5b66\u611f\u5174\u8da3\u7684\u4eba\u80fd\u591f\u52a0\u5165\u6211\u4eec\uff0c\u4e00\u8d77\u4ea4\u6d41\uff0c\u4e00\u8d77\u5ba3\u4f20\u5316\u5b66\uff01<\/p><\/blockquote>\n<p>&nbsp;<\/p>\n<p>\u5728\u65b0\u5e74\u5f00\u59cb\u4e4b\u524d\uff0c\u6211\u4eec\u5c31\u5bf9\u8fc7\u53bb\u4e00\u5e74\u7684\u4eba\u6c14\u8bb0\u4e8b\u505a\u4e00\u4e2a\u56de\u987e\u5427\uff1a\u603b\u4f53\u6765\u8bf4\uff0c\u5f88\u591a\u4ee5\u524d\u7684\u5e16\u5b50\uff0c\u5c24\u5176\u662f\u5b9e\u7528\u6027\u5f3a\u7684\u5e16\u5b50\uff08\u5316\u5b66\u53cd\u5e94\uff0c\u5316\u5b66\u5bb6\u7b49\uff09\u4f1a\u53cd\u590d\u88ab\u68c0\u7d22\u70b9\u51fb\u9605\u8bfb\uff0c\u8fd9\u4e2a\u73b0\u8c61\u8ba9\u672c\u7f51\u7ad9\u7684\u5c0f\u7f16\u4eec\u5907\u53d7\u9f13\u52b1\uff08\u53bb\u5e74\u751a\u81f3\u662f\u524d\u5e74\u4eba\u6c14\u6392\u884c\u9ad8\u7684\u5e16\u5b50\uff0c\u8fd9\u6b21\u4f9d\u7136\u5728\u5217\uff09\u3002\u800c\u4eba\u6c14\u5316\u5b66\u5bb6\u7684\u641c\u7d22\u6392\u540d\u4e5f\u96c6\u4e2d\u5728\u4e00\u4e9b\u975e\u5e38\u70ed\u95e8\u9886\u57df\u7684\u5316\u5b66\u5bb6\u3002\u76f8\u6bd4\u4e8e\u8fd9\u4e9b\u6570\u636e\u5e93\u7c7b\u578b\u7684\u5e16\u5b50\uff0c\u4e00\u4e9b\u6bd4\u8f83\u65b0\u9c9c\u7684\u7814\u7a76\u8bba\u6587\u4ecb\u7ecd\u5e16\u7684\u56de\u987e\u9605\u8bfb\u91cf\u5e76\u4e0d\u9ad8\uff0c\u8fd9\u4e5f\u662f\u60c5\u7406\u4e4b\u4e2d\u3002\u53e6\u5916\u8fd9\u6b21\u7edf\u8ba1\u4ec5\u9650\u4e8e\u7f51\u7ad9\u7684\u70b9\u51fb\u91cf\uff08\u5fae\u4fe1\u516c\u4f17\u53f7\u672a\u8ba1\u7b97\u5728\u5185\uff09\u3002<\/p>\n<p>\uff08\u7531\u4e8e\u5316\u5b66\u7a7a\u95f4\u8bbf\u95ee\u91cf\u4e0d\u65ad\u6500\u5347\uff0c\u6211\u4eec\u57289\u6708\u5e95\u6362\u4e86\u4e00\u4e2a\u66f4\u5f3a\u5927\u7684\u670d\u52a1\u5668\uff0c\u56e0\u6b64\u8fd9\u6b21\u7edf\u8ba1\u53ea\u662f\u4ece10\u6708\u523012\u6708\u4e24\u4e2a\u6708\u7684\u8bbf\u95ee\u91cf\uff09<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<h4>\u4eba\u6c14\u53cd\u5e94\u6392\u884c\u699cTOP 5\uff1a<\/h4>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-17351 alignleft\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/1-2-1.png\" alt=\"\" width=\"97\" height=\"64\" \/><\/p>\n<p><a class=\"wpp-post-title\" href=\"\/\/www.gsbet888.com\/reactions\/2014\/01\/%e5%85%89%e5%bb%b6%e5%8f%8d%e5%ba%94%ef%bc%88mitsunobu%e5%8f%8d%e5%ba%94%ef%bc%89.html\" target=\"_blank\" rel=\"noopener\">\u5149\u5ef6\u53cd\u5e94\uff08Mitsunobu\u53cd\u5e94\uff09<\/a>\u00a0<span class=\"post-stats\"><span class=\"wpp-views\">1391 views<\/span>\u00a0<\/span><\/p>\n<p>\u7531\u4ef2\u9187\u548c\u5076\u6c2e\u4e8c\u7532\u9178\u4e8c\u4e59\u916f(DEAD)\u3001\u4e09\u82ef\u57fa\u81a6(Ph3P)\u3001\u82ef\u7532\u9178\u53cd\u5e94\u901a\u8fc7\u7acb\u4f53\u7ffb\u8f6c<b>(S<\/b><b>N<\/b><b>2)<\/b>\u751f\u6210\u76f8\u5e94\u7684\u82ef\u7532\u9178\u916f\u884d\u751f\u7269\u3001\u63a5\u7740\u78b1\u6027\u6c34\u89e3\u53ef\u4ee5\u8f6c\u53d8\u6210\u9187\u5316\u5408\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17352 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/ol-ol11.gif\" alt=\"\" width=\"427\" height=\"75\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-17353 alignleft\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/2-2-1.png\" alt=\"\" width=\"91\" height=\"67\" \/>\u00a0<a href=\"\/\/www.gsbet888.com\/reactions\/%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94\/2014\/04\/pccpdc%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94-pccpdc-oxidation.html\">PCC\/PDC\u6c27\u5316\u53cd\u5e94<\/a>\u00a0 \u00a0<span class=\"post-stats\"><span class=\"wpp-views\">1035 views<\/span>\u00a0<\/span><\/p>\n<p>\u4f7f\u7528<strong>\u6c2f\u94ec\u9178\u5421\u5576\u76d0 (Pyridinium Chlorochromate; PCC)<\/strong>\u6216\u662f<strong>\u4e8c\u6c2f\u94ec\u9178\u5421\u5576\u76d0 <\/strong><strong>(Pyridinium\u00a0 Dichromate; PDC)<\/strong>\u5bf9\u9187\u8fdb\u884c\u6c27\u5316\u53cd\u5e94\u80fd\u591f\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3001\u5bf9\u542b\u6709\u4e0d\u7a33\u5b9a\u53d6\u4ee3\u57fa\u56e2\u7684\u5e95\u7269\u4e5f\u9002\u7528\u3002\u76f8\u5bf9\u5e94<a href=\"http:\/\/www.chem-station.com\/user-cgi-bin\/odoos\/ps_search.cgi?act=jump&amp;access=1&amp;url=http%3a%2f%2fwww%2echem%2dstation%2ecom%2fodoos%2fdata%2fol%2don%2d11%2ehtm\">Jones\u6c27\u5316<\/a>\u6216<a href=\"http:\/\/www.chem-station.com\/user-cgi-bin\/odoos\/ps_search.cgi?act=jump&amp;access=1&amp;url=http%3a%2f%2fwww%2echem%2dstation%2ecom%2fodoos%2fdata%2fol%2don%2d12%2ehtm\">Sarett-Collins\u6c27\u5316<\/a>\u53ef\u4ee5\u5f97\u5230\u916e\u3001\u8fd9\u7c7b\u8bd5\u5242\u3001\u5c24\u5176\u4f7f\u7528PCC\u53ef\u4ee5\u5f97\u5230\u919b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17354 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/ol-al31.gif\" alt=\"\" width=\"331\" height=\"123\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-17355 alignleft\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/3-2-1.png\" alt=\"\" width=\"92\" height=\"66\" \/><\/p>\n<p><a class=\"wpp-post-title\" href=\"\/\/www.gsbet888.com\/reactions\/2014\/06\/%e5%ae%89%e6%81%af%e9%a6%99%e7%bc%a9%e5%90%88%e5%8f%8d%e5%ba%94benzoin-condensation.html\" target=\"_blank\" rel=\"noopener\">\u5b89\u606f\u9999\u7f29\u5408\u53cd\u5e94(Benzoin Condensation)<\/a>\u00a0 \u00a0<span class=\"post-stats\"><span class=\"wpp-views\">975 views<\/span>\u00a0<\/span><\/p>\n<p>\u4e8c\u5f53\u91cf\u7684\u82b3\u919b\uff0c\u5728\u6c30\u57fa\u6e90\u4eb2\u6838\u50ac\u5316\u5242\u7684\u5b58\u5728\u4e0b\uff0c\u81ea\u8eab\u8fdb\u884c\u7f29\u5408\u53cd\u5e94\uff0c\u5f62\u6210\u5b89\u606f\u9999\u4ea7\u7269\u7684\u53cd\u5e94\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17356 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/ar-ol11.gif\" alt=\"\" width=\"313\" height=\"74\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-17357 alignleft\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/4-2-1.png\" alt=\"\" width=\"95\" height=\"66\" \/><\/p>\n<ul>\n<li><a class=\"wpp-post-title\" href=\"\/\/www.gsbet888.com\/reactions\/2014\/01\/%e6%b2%9f%e5%90%95%e6%9c%a8%ef%bc%8d%e8%b5%ab%e5%85%8b%e5%8f%8d%e5%ba%94%ef%bc%88mizoroki%ef%bc%8dheck%e5%8f%8d%e5%ba%94%ef%bc%89.html\" target=\"_blank\" rel=\"noopener\">\u6c9f\u5415\u6728\uff0d\u8d6b\u514b\u53cd\u5e94\uff08Mizoroki\uff0dHeck\u53cd\u5e94\uff09<\/a>\u00a0 \u00a0<span class=\"post-stats\"><span class=\"wpp-views\">883 views<\/span><\/span><\/li>\n<li>\u8d6b\u514b\u53cd\u5e94(Heck\u53cd\u5e94)\u662f\u5229\u7528Pd(0)\u50ac\u5316\u5242\u3001\u4f7f\u82b3\u57fa\u5364\u5316\u7269\u6216\u70ef\u57fa\u5364\u5316\u7269\u548c\u672b\u7aef\u70ef\u70c3\u5076\u8054\u7684\u4e00\u79cd\u5076\u8054\u53cd\u5e94\u3002\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u548c\u6536\u7387\u975e\u5e38\u597d\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17361 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/X-ene11.gif\" alt=\"\" width=\"385\" height=\"63\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-17359 alignleft\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/5-1-1.png\" alt=\"\" width=\"94\" height=\"64\" \/><\/p>\n<p><a href=\"\/\/www.gsbet888.com\/reactions\/2014\/01\/%e6%88%b4%e6%96%af%ef%bc%8d%e9%a9%ac%e4%b8%81%e6%b0%a7%e5%8c%96%e5%89%82%ef%bc%88dess-martin-oxidation%ef%bc%89.html\">\u6234\u65af-\u9a6c\u4e01\u6c27\u5316\u5242 \uff08Dess-Martin Oxidation\uff09<\/a>\u00a0 \u00a0<span class=\"post-stats\"><span class=\"wpp-views\">802 views<\/span><\/span><\/p>\n<p align=\"left\">\u6234\u65af\uff0d\u9a6c\u4e01\u6c27\u5316\u5242<b>Dess-Martin periodinane (DMP)<\/b>\u53ef\u4ee5\u6c27\u5316\u9187\u5316\u5408\u7269\u3002\u53cd\u5e94\u5728\u5ba4\u6e29\u5feb\u901f\u8fdb\u884c\uff0c\u53ef\u4ee5\u5c06\u4f2f\u9187\u6c27\u5316\u6210\u919b\u3002\u5bf9\u8f83\u5927\u4f4d\u963b\u7684\u9187\u3001\u53ca\u5728\u03b1\u4f4d\u6709\u4e0d\u5bf9\u79f0\u4e2d\u5fc3\u7684\u5916\u6d88\u65cb\u6df7\u5408\u7269\uff08\u6bd4\u5982\u7fb0\u57fa\u5316\u5408\u7269\uff09\u3001\u6216\u03b1,\u03b2-\u4e0d\u9971\u548c\u919b\u7684\u5408\u6210\u975e\u5e38\u6709\u6548\u3002\u6240\u4ee5\u672c\u53cd\u5e94\u88ab\u5e94\u7528\u5728\u591a\u79cd\u590d\u6742\u5316\u5408\u7269\u7684\u5408\u6210\u4e2d\u3002<\/p>\n<p align=\"left\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-17362 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2017\/12\/ol-al-4.gif\" alt=\"\" width=\"356\" height=\"107\" \/><\/p>\n<p><strong>\u5176\u4ed6\u4eba\u6c14\u53cd\u5e94\uff08TOP 6-10\uff09<\/strong><\/p>\n<ul>\n<li>\n<h4><a href=\"\/\/www.gsbet888.com\/reactions\/2017\/05\/%e4%bf%9e%e6%b0%8f%e7%b3%96%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94%ef%bc%88yu-glycosylation%ef%bc%89.html\">\u4fde\u6c0f\u7cd6\u57fa\u5316\u53cd\u5e94\uff08Yu Glycosylation\uff09<\/a> 782 views<\/h4>\n<\/li>\n<li>\n<h4><a class=\"wpp-post-title\" href=\"\/\/www.gsbet888.com\/reactions\/%e7%8e%af%e5%8c%96%e5%8f%8d%e5%ba%94\/2014\/02\/post-515.html\" target=\"_blank\" rel=\"noopener\">\u72c4\u5c14\u65af\u2013\u963f\u5c14\u5fb7\u53cd\u5e94(Diels-Alder Reaction)<\/a>\u00a0 \u00a0<span class=\"post-stats\"><span class=\"wpp-views\">781 views<\/span>\u00a0<\/span><\/h4>\n<\/li>\n<li>\n<h4><span class=\"post-stats\"><span class=\"wpp-views\"><a href=\"\/\/www.gsbet888.com\/reactions\/%e7%bc%a9%e5%90%88%e5%8f%8d%e5%ba%94\/2015\/05\/%e7%bc%a9%e5%90%88%e5%89%82condensation-reagent.html\">\u7f29\u5408\u5242\uff08Condensation\uff09<\/a>730 views<\/span><\/span><\/h4>\n<\/li>\n<li>\n<h4><span class=\"post-stats\"><span class=\"wpp-views\"><a 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