{"id":18123,"date":"2018-03-02T10:09:34","date_gmt":"2018-03-02T02:09:34","guid":{"rendered":"\/\/www.gsbet888.com\/?p=18123"},"modified":"2019-08-02T18:51:54","modified_gmt":"2019-08-02T10:51:54","slug":"%e6%9c%89%e6%9c%ba%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e6%b5%81%e6%b6%b2%e7%94%b5%e6%b1%a0%e7%9a%84%e6%96%b0%e8%bf%9b%e5%b1%95%ef%bc%9a%e4%bd%8e%e8%81%9a%e7%89%a9%e6%b4%bb%e6%80%a7%e7%89%a9%e8%b4%a8","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2018\/03\/%e6%9c%89%e6%9c%ba%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e6%b5%81%e6%b6%b2%e7%94%b5%e6%b1%a0%e7%9a%84%e6%96%b0%e8%bf%9b%e5%b1%95%ef%bc%9a%e4%bd%8e%e8%81%9a%e7%89%a9%e6%b4%bb%e6%80%a7%e7%89%a9%e8%b4%a8.html","title":{"rendered":"\u6709\u673a\u6c27\u5316\u8fd8\u539f\u6d41\u6db2\u7535\u6c60\u7684\u65b0\u8fdb\u5c55\uff1a\u4f4e\u805a\u7269\u6d3b\u6027\u7269\u8d28\u7684\u5229\u7528"},"content":{"rendered":"<p>\u672c\u6587\u6765\u81ea<a href=\"https:\/\/www.chem-station.com\/blog\/2018\/01\/orfbnew.html\">\u65e5\u6587\u7248<\/a>\uff0c\u7ffb\u8bd1\u6295\u7a3f Suming<\/p>\n<p>\u57282017\u5e74\uff0cHelms\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u79cd\u4f7f\u7528\u4f4e\u805a\u7269\u4f5c\u4e3a\u6d3b\u6027\u6750\u6599\u7684\u65b9\u6cd5\uff0c\u4ee5\u9632\u6b62\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u4e2d\u51fa\u73b0\u7535\u89e3\u6db2\u6e17\u6d41\u7684\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u3002<\/p>\n<blockquote><p>Macromolecular Design Strategies for Preventing Active-Material Crossover in Non-Aqueous All-Organic Redox-Flow Batteries\u201d Doris, S. E.; Ward, A. L.; Baskin, A.; Frischmann, P. D.; Gavvalapalli, N.; Ch\u00e9nard, E.; Sevov, C. S.; Prendergast, D.; Moore, J. S.; Helms, B. A.\u00a0Angew. Chem. Int. Ed.\u00a02017,\u00a056, 1595\u20131599. DOI:\u00a010.1002\/anie.201610582<\/p><\/blockquote>\n<p>&nbsp;<\/p>\n<h4><strong>\u8bfe\u9898\u8bbe\u8ba1 <\/strong><\/h4>\n<p>\u6211\u4eec\u5e0c\u671b\u80fd\u901a\u8fc7\u6709\u6548\u7684\u5229\u7528\u98ce\u80fd\u3001\u592a\u9633\u80fd\u7b49\u81ea\u7136\u80fd\u6e90\uff0c\u6765\u5f00\u53d1\u5927\u89c4\u6a21\u7684\u50a8\u80fd\u7cfb\u7edf\u3002\u800c\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u56e0\u4e3a\u5176\u5177\u6709\u53ef\u81ea\u7531\u8c03\u8282\u89c4\u6a21\u7684\u7279\u70b9\uff0c\u56e0\u800c\u5b83\u5f88\u9002\u5408\u957f\u671f\u50a8\u5b58\u3002\u4e3a\u4e86\u9a8c\u8bc1\u6b64\u76ee\u7684\u6211\u4eec\u4e5f\u8fdb\u884c\u4e86\u76f8\u5173\u7684\u6f14\u793a\u5b9e\u9a8c\u3002\u4e0d\u8fc7\uff0c\u6b63\u6781\uff08\u8d1f\u6781\uff09\u6d3b\u6027\u7269\u8d28\u7a7f\u900f\u9694\u677f\u5e76\u8fdb\u5165\u8d1f\u6781\uff08\u6b63\u6781\uff09\u7684\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u662f\u5404\u79cd\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u6240\u5171\u6709\u7684\u95ee\u9898\u3002\u8fd1\u6765\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5f88\u591a\u901a\u8fc7\u5229\u7528\u805a\u5408\u7269\u4f5c\u4e3a\u6d3b\u6027\u6750\u6599\u6765\u6291\u5236\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u7684\u65b9\u6cd5\uff0c\u4f46\u662f\uff0c\u9ad8\u5206\u5b50\u6d3b\u6027\u7269\u8d28\u5728\u6d41\u52a8\u88c5\u7f6e\u5185\u6709\u53ef\u80fd\u53d1\u751f\u5835\u585e\uff0c\u53ef\u80fd\u4f1a\u56e0\u4e3a\u5176\u6709\u7c98\u6027\u7684\u539f\u56e0\u800c\u65e0\u6cd5\u8fdb\u884c\u9ad8\u6548\u7684\u6d41\u52a8\u3002\u5982\u4f55\u517c\u5bb9\u4f7f\u7528\u5ec9\u4ef7\u4e14\u4f4e\u7c98\u5ea6\u7684\u6d3b\u6027\u7269\u8d28\u548c\u4fbf\u5b9c\u7684\u5206\u79bb\u5668\u6765\u5b9e\u73b0\u76ee\u7684\uff0c\u5c31\u6210\u4e86\u6211\u4eec\u7684\u6240\u8981\u7814\u7a76\u7684\u8bfe\u9898\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u5b9e\u73b0\u9014\u5f84\uff1a\u6d3b\u6027\u7269\u8d28\u7684\u4f4e\u805a\u5316 <\/strong><strong>\u00a0<\/strong><\/h4>\n<p>Helms\u7b49\u4eba\u5728\u5206\u79bb\u5668\u4e2d\u4f7f\u7528\u5177\u67091nm\u4ee5\u4e0b\u5b54\u5f84\u7684\u5fae\u5b54\u819c\uff0c\u5373\u4f7f\u662f\u4e0e\u4e09\u805a\u4f53\u4e00\u6837\u5927\u5c0f\u7684\u5206\u5b50\u4e5f\u53ef\u4ee5\u7528\u4f5c\u6d3b\u6027\u7269\u8d28\u800c\u4e0d\u4f1a\u5f15\u8d77\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u3002\u4ed6\u4eec\u5408\u6210\u4e86\u5d4c\u5165\u4e59\u57fa\u7d2b\u9aa8\u67b6\u7684\u5355\u4f53\u548c\u5be1\u805a\u4f53[\u4e8c\u805a\u4f53\uff0c\u4e09\u805a\u4f53]\uff0c\u5e76\u53ef\u4ee5\u5728-0.75V\u7684\u7535\u4f4d\u4e0b\u53ef\u9006\u5730\u8fd8\u539f\uff080.1 M LiPF6\u00a0in acetontrile\uff09\uff0c\u53e6\u5916\u8fd8\u4f30\u7b97\u51fa\u5355\u4f53\u3001\u4e8c\u805a\u4f53\u548c\u4e09\u805a\u4f53\u7684\u5c3a\u5bf8\u5206\u522b\u57288.8nm,12.3nm\u548c16.8nm\u5de6\u53f3\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18125 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3.png\" alt=\"\" width=\"918\" height=\"255\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3.png 918w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3-300x83.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3-768x213.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/2-3-680x189.png 680w\" sizes=\"(max-width: 918px) 100vw, 918px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u5b9e\u9a8c\u7ed3\u679c <\/strong><\/h4>\n<p>\u4e3a\u4e86\u6d4b\u8bd5\u6291\u5236\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u7684\u6548\u679c\uff0c\u4ed6\u4eec\u6d4b\u91cf\u4e86\u6e17\u900f\u591a\u805a\u4f53\u6d3b\u6027\u6750\u6599\u9694\u819c\u7684\u6269\u6563\u7cfb\u6570\uff08Dsol\uff09\u548c\u5728\u90a3\u4e9b\u6eb6\u5242\u4e2d\u6269\u6563\u7cfb\u6570\uff08Dell\uff09\u7684\u6bd4\u503c\uff08Dsol\/Dell\uff09\u3002\u8be5\u503c\u662f\u663e\u793a\u901a\u8fc7\u5206\u79bb\u5668\u800c\u4e0d\u662f\u5728\u6eb6\u5242\u4e2d\u6269\u6563\u901f\u5ea6\u7684\u6307\u6807\uff0c\u5f53\u901a\u8fc7\u6d4b\u91cf\u4e0e\u5b54\u5f84\u4e3a1nm\u6216\u66f4\u5c0f\u7684\u5b54\u4ea4\u8054\u5236\u5907\u7684\u5177\u6709\u575a\u56fa\u7ed3\u6784\u7684\u805a\u5408\u7269\u819c\uff08Cross-linked Polymers of Intrinsic Microporosity, Cross-linked PIM-1[3b]\uff09 \u6765\u6d4b\u91cf\u6d3b\u6027\u6750\u6599\u7684Dsol \/ Deff\u503c\u65f6\uff0c\u53ef\u5f97\u5355\u4f53\u7684\u8be5\u503c\u4e3a14200\uff0c\u800c\u4e8c\u805a\u4f53\u548c\u4e09\u805a\u4f53(297000, 85000)\u7684\u503c\u4e5f\u90fd\u5728\u6781\u9650\u503c\u4ee5\u4e0a\uff0c\u6240\u4ee5\u4f4e\u805a\u7269\u6d3b\u6027\u7269\u8d28\u5f88\u96be\u6e17\u900f\u901a\u8fc7\u819c\u3002\u53e6\u5916\uff0c\u4f5c\u8005\u53d1\u73b0\u5728\u4f7f\u7528\u5b54\u5f84\u4e3a28nm\u7684\u4e2d\u5b54\u819c\uff08Celgard\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u5728\u4e24\u79cd\u60c5\u51b5\u4e0bDsol \/ Deff\u7684\u503c\u662f\u5747\u4e3a\u7ea630\u5de6\u53f3\uff0c\u548c\u4f4e\u805a\u7269\u4ea4\u8054\u7684PIM-1\u7ec4\u5408\u80fd\u591f\u63a7\u5236\u79bb\u5b50\u6e17\u900f\u6027\u3002\u4ed6\u4eec\u8fdb\u4e00\u6b65\u5408\u6210\u4e86\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\u7684\u4e09\u805a\u6d3b\u6027\u7269\u8d28\uff0c\u73b0\u5b9e\u5b83\u4eec\u5747\u53ef\u4ee5\u5404\u81ea\u7684\u8fdb\u884c\u53ef\u9006\u7684\u8fd8\u539f\u548c\u6c27\u5316\u53cd\u5e94\uff0c\u5e76\u4e14\u5bf9\u4e8e\u4ea4\u8054PIM-1\u819c\u7684\u4e0d\u900f\u6027\u4e5f\u5f88\u9ad8\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18126 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3.png\" alt=\"\" width=\"883\" height=\"208\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3.png 883w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3-300x71.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3-768x181.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/3-3-680x160.png 680w\" sizes=\"(max-width: 883px) 100vw, 883px\" \/><\/a><\/p>\n<h4><strong>\u5173\u4e8e\u4f5c\u8005<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/4-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18127 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/4-3.png\" alt=\"\" width=\"240\" height=\"322\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/4-3.png 240w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/4-3-224x300.png 224w\" sizes=\"(max-width: 240px) 100vw, 240px\" \/><\/a><\/p>\n<ul>\n<li>PI Dr.\u00a0Brett A. Helms\u00a0(Lawrence Berkeley National Laboratory)<\/li>\n<li>2015-Present Co-Founder, Sepion Technologies<\/li>\n<li>2012-Present Career Staff Scientist, Lawrence Berkeley National Lab.<\/li>\n<li>2007-2012 \u00a0\u00a0 Staff Scientist, Lawrence Berkeley National Lab<\/li>\n<li>2006-2007 \u00a0\u00a0 Postdoctoral Fellow with Prof. E.W. Meijer,TechnischeUniversiteit, Eindhoven, The Netherlands<\/li>\n<li>2000-2006 \u00a0\u00a0 Ph.D. in Chemistry with Prof. Jean M. J. Fr\u00e9chet,\u00a0UC BerkeleyPI\u00a0Brett A. Helms\u535a\u58eb\uff08\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\uff09<\/li>\n<li>2015\u5e74\uff0c\u6210\u4e3aSepion\u79d1\u6280\u516c\u53f8\u8054\u5408\u521b\u59cb\u4eba<\/li>\n<li>2007-2012\u5e74\uff0c\u4e8e\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u505a\u79d1\u5b66\u5bb6<\/li>\n<li>2006-2007\u5e74\uff0c\u4e8e\u8377\u5170\u57c3\u56e0\u970d\u6e29\u5de5\u4e1a\u5927\u5b66\u505a\u535a\u58eb\u540e\uff08 EW Meijer\u6559\u6388\uff09<\/li>\n<li>2000-2006\u5e74\uff0c\u4e8e\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u83b7\u5f97\u5316\u5b66\u4e13\u4e1a\u535a\u58eb\uff08Jean M. J.Fr\u00e9chet\u6559\u6388\uff09<\/li>\n<li>1996-2000\u5e74\uff0c\u4e8eB.S.\u4e0e\u54c8\u7ef4\u00b7\u7a46\u5fb7\u5b66\u9662\u7684Shenda M. Baker\u6559\u6388\u5408\u4f5c<\/li>\n<\/ul>\n<p>\u6458\u81ea<a href=\"http:\/\/foundry.lbl.gov\/helmsgroup\/index.html\">Helms Group HP<\/a>\u4e3b\u9875<\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ol>\n<li>(a) Noack, J.; Roznyatovskaya, N.; Herr, T.; Fischer, P.<em>\u00a0Angew. Chem. Int. Ed.<\/em><strong>2015<\/strong>,\u00a0<em>54<\/em>, 9776. DOI:\u00a0<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201410823\/abstract\">10.1002\/anie.201410823<\/a>\u00a0(b)\u00a0Dunn, B.; Kamath, H.; Tarascon, J.-M.\u00a0<em>Science<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>334<\/em>, 928. DOI:\u00a0<a href=\"http:\/\/science.sciencemag.org\/content\/334\/6058\/928.long\">10.1126\/science.1212741<\/a>\u00a0(c) Arenas, L. F.; Ponce de Le\u00f3n, C.; Walsh, F. C.<em>\u00a0<\/em><em>J. Energy Storage<\/em>\u00a0<strong>2017<\/strong>,\u00a0<em>11<\/em>, 119. DOI:<a href=\"http:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2352152X16301736\">10.1016\/j.est.2017.02.007<\/a><\/li>\n<li>(a)\u00a0Nagarjuna, G.; Hui, J.; Cheng, K. J.; Lichtenstein, T.; Shen, M.; Moore, J. S.; Rodr\u00edguez-L\u00f3pez, <em>J. Am. Chem. Soc<\/em>.\u00a0<strong>2014<\/strong>,\u00a0<em>136<\/em>, 16309-16316. DOI:\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja508482e\">10.1021\/ja508482e\u00a0<\/a>(b) Sukegawa, T.; Masuko, I, Oyaizu, K. Nishide, H.\u00a0<em>Macromolecules<\/em><em>\u00a0<\/em><strong>2014<\/strong>,\u00a0<em>47<\/em>, 8611\u20138617. DOI:<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ma501632t\">\u00a010.1021\/ma501632t<\/a>\u00a0(c)\u00a0Janoschka, T.; Martin, N.; Martin, U.; Friebe, C.; Morgenstern, S.; Hiller, H.; Hanger, M. D.; Schubert, U. S.\u00a0<em>Nature<\/em>\u00a0<strong>2015<\/strong>,\u00a0<em>527<\/em>, 78. DOI:\u00a0<a href=\"https:\/\/www.nature.com\/articles\/nature15746\">10.1038\/nature15746\u00a0<\/a>(d) Montoto, E. C.; Nagarjuna, G.; Hui, J.; Burgess, M.; Sekerak, N. M.; Hern\u00e0ndez-Burgos, K.; Wei, T-S.;Kneer, M.; Grolman, J.; Cheng, K. J.; Lewis, J. A.; Moore, J. S.; Rodr\u00edguez-L\u00f3pez, J.\u00a0<em>J. Am. Chem. Soc<\/em>.\u00a0<strong>2016<\/strong>,\u00a0<em>138<\/em>, 13230\u201313237. DOI:\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6b06365\">10.1021\/jacs.6b06365<\/a><\/li>\n<li>(a) McKeown, N. B. and coworkers,<em> Chem. Commun<\/em>.<strong>2004<\/strong>, 230. DOI:\u00a0<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2004\/cc\/b311764b#!divAbstract\">10.1039\/b311764b<\/a>\u00a0(b) Doris, S. E.; Ward, A. L.; Frischmann, P. E.; Li, L.; Helms, B. A.\u00a0<em>J. Mater. Chem. A\u00a0<\/em><strong>2016<\/strong>,\u00a0<em>4<\/em>, 16946\u201316952. DOI:\u00a0<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2016\/ta\/c6ta06401a#!divAbstract\">10.1039\/c6ta06401a<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong> \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01 <\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u6765\u81ea\u65e5\u6587\u7248\uff0c\u7ffb\u8bd1\u6295\u7a3f Suming \u57282017\u5e74\uff0cHelms\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u79cd\u4f7f\u7528\u4f4e\u805a\u7269\u4f5c\u4e3a\u6d3b\u6027\u6750\u6599\u7684\u65b9\u6cd5\uff0c\u4ee5\u9632\u6b62\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u4e2d\u51fa\u73b0\u7535\u89e3\u6db2\u6e17\u6d41\u7684\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u3002 Macromolecular Design Strategies for Preventing Active-Material Crossover in Non-Aqueous All-Organic Redox-Flow Batteries\u201d Doris, S. E.; Ward, A. L.; Baskin, A.; Frischmann, P. D.; Gavvalapalli, N.; Ch\u00e9nard, E.; Sevov, C. S.; Prendergast, D.; Moore, J. S.; Helms, B. A.\u00a0Angew. Chem. Int. Ed.\u00a02017,\u00a056, 1595\u20131599. DOI:\u00a010.1002\/anie.201610582 &nbsp; \u8bfe\u9898\u8bbe\u8ba1 \u6211\u4eec\u5e0c\u671b\u80fd\u901a\u8fc7\u6709\u6548\u7684\u5229\u7528\u98ce\u80fd\u3001\u592a\u9633\u80fd\u7b49\u81ea\u7136\u80fd\u6e90\uff0c\u6765\u5f00\u53d1\u5927\u89c4\u6a21\u7684\u50a8\u80fd\u7cfb\u7edf\u3002\u800c\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u56e0\u4e3a\u5176\u5177\u6709\u53ef\u81ea\u7531\u8c03\u8282\u89c4\u6a21\u7684\u7279\u70b9\uff0c\u56e0\u800c\u5b83\u5f88\u9002\u5408\u957f\u671f\u50a8\u5b58\u3002\u4e3a\u4e86\u9a8c\u8bc1\u6b64\u76ee\u7684\u6211\u4eec\u4e5f\u8fdb\u884c\u4e86\u76f8\u5173\u7684\u6f14\u793a\u5b9e\u9a8c\u3002\u4e0d\u8fc7\uff0c\u6b63\u6781\uff08\u8d1f\u6781\uff09\u6d3b\u6027\u7269\u8d28\u7a7f\u900f\u9694\u677f\u5e76\u8fdb\u5165\u8d1f\u6781\uff08\u6b63\u6781\uff09\u7684\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u662f\u5404\u79cd\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u6240\u5171\u6709\u7684\u95ee\u9898\u3002\u8fd1\u6765\uff0c\u5df2\u7ecf\u62a5\u9053\u4e86\u5f88\u591a\u901a\u8fc7\u5229\u7528\u805a\u5408\u7269\u4f5c\u4e3a\u6d3b\u6027\u6750\u6599\u6765\u6291\u5236\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u7684\u65b9\u6cd5\uff0c\u4f46\u662f\uff0c\u9ad8\u5206\u5b50\u6d3b\u6027\u7269\u8d28\u5728\u6d41\u52a8\u88c5\u7f6e\u5185\u6709\u53ef\u80fd\u53d1\u751f\u5835\u585e\uff0c\u53ef\u80fd\u4f1a\u56e0\u4e3a\u5176\u6709\u7c98\u6027\u7684\u539f\u56e0\u800c\u65e0\u6cd5\u8fdb\u884c\u9ad8\u6548\u7684\u6d41\u52a8\u3002\u5982\u4f55\u517c\u5bb9\u4f7f\u7528\u5ec9\u4ef7\u4e14\u4f4e\u7c98\u5ea6\u7684\u6d3b\u6027\u7269\u8d28\u548c\u4fbf\u5b9c\u7684\u5206\u79bb\u5668\u6765\u5b9e\u73b0\u76ee\u7684\uff0c\u5c31\u6210\u4e86\u6211\u4eec\u7684\u6240\u8981\u7814\u7a76\u7684\u8bfe\u9898\u3002 &nbsp; \u5b9e\u73b0\u9014\u5f84\uff1a\u6d3b\u6027\u7269\u8d28\u7684\u4f4e\u805a\u5316 \u00a0 Helms\u7b49\u4eba\u5728\u5206\u79bb\u5668\u4e2d\u4f7f\u7528\u5177\u67091nm\u4ee5\u4e0b\u5b54\u5f84\u7684\u5fae\u5b54\u819c\uff0c\u5373\u4f7f\u662f\u4e0e\u4e09\u805a\u4f53\u4e00\u6837\u5927\u5c0f\u7684\u5206\u5b50\u4e5f\u53ef\u4ee5\u7528\u4f5c\u6d3b\u6027\u7269\u8d28\u800c\u4e0d\u4f1a\u5f15\u8d77\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u3002\u4ed6\u4eec\u5408\u6210\u4e86\u5d4c\u5165\u4e59\u57fa\u7d2b\u9aa8\u67b6\u7684\u5355\u4f53\u548c\u5be1\u805a\u4f53[\u4e8c\u805a\u4f53\uff0c\u4e09\u805a\u4f53]\uff0c\u5e76\u53ef\u4ee5\u5728-0.75V\u7684\u7535\u4f4d\u4e0b\u53ef\u9006\u5730\u8fd8\u539f\uff080.1 M LiPF6\u00a0in acetontrile\uff09\uff0c\u53e6\u5916\u8fd8\u4f30\u7b97\u51fa\u5355\u4f53\u3001\u4e8c\u805a\u4f53\u548c\u4e09\u805a\u4f53\u7684\u5c3a\u5bf8\u5206\u522b\u57288.8nm,12.3nm\u548c16.8nm\u5de6\u53f3\u3002 &nbsp; \u5b9e\u9a8c\u7ed3\u679c \u4e3a\u4e86\u6d4b\u8bd5\u6291\u5236\u4ea4\u53c9\u6e17\u6d41\u73b0\u8c61\u7684\u6548\u679c\uff0c\u4ed6\u4eec\u6d4b\u91cf\u4e86\u6e17\u900f\u591a\u805a\u4f53\u6d3b\u6027\u6750\u6599\u9694\u819c\u7684\u6269\u6563\u7cfb\u6570\uff08Dsol\uff09\u548c\u5728\u90a3\u4e9b\u6eb6\u5242\u4e2d\u6269\u6563\u7cfb\u6570\uff08Dell\uff09\u7684\u6bd4\u503c\uff08Dsol\/Dell\uff09\u3002\u8be5\u503c\u662f\u663e\u793a\u901a\u8fc7\u5206\u79bb\u5668\u800c\u4e0d\u662f\u5728\u6eb6\u5242\u4e2d\u6269\u6563\u901f\u5ea6\u7684\u6307\u6807\uff0c\u5f53\u901a\u8fc7\u6d4b\u91cf\u4e0e\u5b54\u5f84\u4e3a1nm\u6216\u66f4\u5c0f\u7684\u5b54\u4ea4\u8054\u5236\u5907\u7684\u5177\u6709\u575a\u56fa\u7ed3\u6784\u7684\u805a\u5408\u7269\u819c\uff08Cross-linked Polymers of Intrinsic Microporosity, Cross-linked PIM-1[3b]\uff09 \u6765\u6d4b\u91cf\u6d3b\u6027\u6750\u6599\u7684Dsol \/ Deff\u503c\u65f6\uff0c\u53ef\u5f97\u5355\u4f53\u7684\u8be5\u503c\u4e3a14200\uff0c\u800c\u4e8c\u805a\u4f53\u548c\u4e09\u805a\u4f53(297000, 85000)\u7684\u503c\u4e5f\u90fd\u5728\u6781\u9650\u503c\u4ee5\u4e0a\uff0c\u6240\u4ee5\u4f4e\u805a\u7269\u6d3b\u6027\u7269\u8d28\u5f88\u96be\u6e17\u900f\u901a\u8fc7\u819c\u3002\u53e6\u5916\uff0c\u4f5c\u8005\u53d1\u73b0\u5728\u4f7f\u7528\u5b54\u5f84\u4e3a28nm\u7684\u4e2d\u5b54\u819c\uff08Celgard\uff09\u7684\u60c5\u51b5\u4e0b\uff0c\u5728\u4e24\u79cd\u60c5\u51b5\u4e0bDsol \/ Deff\u7684\u503c\u662f\u5747\u4e3a\u7ea630\u5de6\u53f3\uff0c\u548c\u4f4e\u805a\u7269\u4ea4\u8054\u7684PIM-1\u7ec4\u5408\u80fd\u591f\u63a7\u5236\u79bb\u5b50\u6e17\u900f\u6027\u3002\u4ed6\u4eec\u8fdb\u4e00\u6b65\u5408\u6210\u4e86\u4e24\u79cd\u5177\u6709\u4e0d\u540c\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\u7684\u4e09\u805a\u6d3b\u6027\u7269\u8d28\uff0c\u73b0\u5b9e\u5b83\u4eec\u5747\u53ef\u4ee5\u5404\u81ea\u7684\u8fdb\u884c\u53ef\u9006\u7684\u8fd8\u539f\u548c\u6c27\u5316\u53cd\u5e94\uff0c\u5e76\u4e14\u5bf9\u4e8e\u4ea4\u8054PIM-1\u819c\u7684\u4e0d\u900f\u6027\u4e5f\u5f88\u9ad8\u3002 \u5173\u4e8e\u4f5c\u8005 PI Dr.\u00a0Brett A. Helms\u00a0(Lawrence Berkeley National Laboratory) 2015-Present Co-Founder, Sepion Technologies 2012-Present Career Staff Scientist, Lawrence Berkeley National Lab. 2007-2012 \u00a0\u00a0 Staff Scientist, Lawrence Berkeley National Lab 2006-2007 \u00a0\u00a0 Postdoctoral Fellow with Prof. E.W. Meijer,TechnischeUniversiteit, Eindhoven, The Netherlands [&hellip;]","protected":false},"author":8,"featured_media":18124,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[2213,2214,1827],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/1-3.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-4Ij","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18123"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=18123"}],"version-history":[{"count":5,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18123\/revisions"}],"predecessor-version":[{"id":27155,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18123\/revisions\/27155"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/18124"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=18123"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=18123"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=18123"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}