\u4e2a\u4eba\u7ecf\u5386<\/strong><\/p>\n2011\u5e749\u6708\uff1a \u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u836f\u5b66\u90e8\u83b7\u836f\u5b66\u535a\u58eb\u5b66\u4f4d \uff08\u6307\u5bfc\u8001\u5e08\uff1a Masakatsu Shibasaki\u6559\u6388\u548cMotomu Kanai\u6559\u6388\uff09<\/p>\n
2011\u5e7410\u6708\uff0d2012\u5e7410\u6708\uff1a \u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u836f\u5b66\u90e8JSPS\u535a\u58eb\u540e\uff08\u6307\u5bfc\u8001\u5e08\uff1a\u00a0Motomu Kanai\u6559\u6388\uff09<\/p>\n
2012\u5e7411\u6708\uff0d2016\u5e745\u6708\uff1a \u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u5316\u5b66\u7cfb\u535a\u58eb\u540e\uff08Stephen Buchwald\u6559\u6388\uff09<\/p>\n
2016\u5e745\u6708\uff0d\u81f3\u4eca\uff0c\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u3001\u8bfe\u9898\u7ec4\u957f\u3001\u535a\u5bfc<\/p>\n
\u4ee5\u7b2c\u4e00\u4f5c\u8005\u5df2\u5728Nature<\/i>\u3001<\/i>Science<\/i>\u3001<\/i>Nature Chemistry<\/i>\u3001<\/i>JACS<\/i>\u3001<\/i>ACIE<\/i>\u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u53d1\u8868\u8bba\u65877\u7bc7\u3002\u00a0<\/strong><\/p>\n\u83b7\u5956\u7ecf\u5386<\/strong><\/p>\n2010 \u00a0 \u00a0\u56fd\u5bb6\u4f18\u79c0\u81ea\u8d39\u7559\u5b66\u751f\u5956<\/p>\n
2008-2011\u00a0\u00a0\u00a0 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u535a\u58eb\u8bfe\u7a0b\u548c\u535a\u58eb\u540e\u5956\u5b66\u91d1(DC2\u548cPD)<\/p>\n
2011-2013\u00a0\u00a0\u00a0 \u65e5\u672c\u6587\u90e8\u7701\u5956\u5b66\u91d1<\/p>\n
\n
\u4ee3\u8868\u6027<\/strong>\u8bba<\/strong>\u6587<\/strong><\/p>\n1) Y. Cai, X.-T. Yang, S.-Q. Zhang, F. Li, Y.-Q. Li, L.-X. Ruan, X. Hong*, S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>*<\/p>\n\u201cCopper-Catalyzed Enantioselective Markovnikov Protoboration of a-Olefins Enabled by a Buttressed N-Heterocyclic Carbene Ligand\u201d<\/p>\n
\u00a0 \u00a0 Angew. Chem. Int. Ed.<\/em> 2018<\/strong>, 57, 1376-1380.<\/p>\n2\uff09Y. Cai, F. Li, Y.-Q. Li, W.-B. Zhang, F.-H. Liu*, S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>*<\/p>\n\u201cBase metal-catalyzed alcohol C\u2013C couplings under hydrogen transfer conditions\u201d (invited review)<\/p>\n
\u00a0 \u00a0 Tetrahedron Letters<\/em>, 2018<\/strong>, 59<\/em>, 1073-1079.<\/p>\n3\uff09S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>, Z. Wong, S. L. Buchwald*<\/p>\n\u201cCopper-Catalyzed Enantioselective Stereodivergent Synthesis of Amino Alcohols\u201d<\/p>\n
Nature <\/em>2016<\/strong>, 532,<\/em> 353\u2013356.<\/p>\n4) Y. Yang\u2020,<\/u> S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>\u2020, D. Niu, P. Liu, S. L. Buchwald*<\/p>\n\u201cCatalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines\u201d<\/p>\n
Science <\/em>2015<\/strong>, 349<\/em>, 62\u201366. (\u2020: Co-first author<\/strong>)<\/p>\n(Highlighted in Chemistry World <\/em>and Chemical & Engineering News<\/em>)<\/p>\n5) S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>,<\/u> S. L. Buchwald*<\/p>\n\u201cCopper-catalysed Selective Hydroamination Reactions of Alkynes\u201d<\/p>\n
Nature Chemistry <\/em>2015<\/strong>, 7<\/em>, 38\u201344. (Highlighted in Nature<\/em>. Nature<\/em> 517, 280\u2013281)<\/p>\n6) S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>,<\/u> S. L. Buchwald*<\/p>\n\u201cPalladium-Catalyzed Intramolecular C\u2013H Difluoroalkylation: Synthesis of Substituted 3,3-Difluoro-2-oxindoles\u201d<\/p>\n
Angew. Chem. Int. Ed. <\/em>2015<\/strong>, 54<\/em>, 1646-1650.<\/p>\n7) S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>,<\/u> X.-F. Wei, Y. Shimizu, M. Kanai*<\/p>\n\u201cCopper(I)-Catalyzed Enantioselective Incorporation of Ketones to Cyclic Hemiaminals for the Synthesis of Versatile Alkaloid Precursor\u201d<\/p>\n
J. Am. Chem. Soc. <\/em>2012<\/strong>, 134<\/em>, 17019-17022.<\/p>\n8) S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>,<\/u> M. Kanai* and M. Shibasaki*<\/p>\n\u201cAsymmetric Synthesis of Dihydropyranones from Ynones by Sequential Copper(I)-Catalyzed Direct Aldol and Silver(I)-Catalyzed Oxy-Michael\u00a0Reactions\u201d<\/p>\n
Angew. Chem. Int. Ed. <\/em>2012, <\/strong>51<\/em>, 3932-3935.<\/em><\/p>\n9) S<\/u><\/strong>.<\/u><\/strong>-L<\/u><\/strong>.<\/u><\/strong> Shi<\/u><\/strong>,<\/u> L.-W. Xu, K. Oisaki, M. Kanai* and M. Shibasaki*<\/p>\n\u201cIdentification of Modular Chiral Bisphosphines Effective for Cu(I)-Catalyzed Asymmetric Allylation and Propargylation of Ketones\u201d<\/p>\n
J. Am. Chem. Soc.<\/em> 2010<\/strong>, 132<\/em>, 6638-6639.<\/p>\n <\/p>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u8bfe\u9898\u7ec4\u4fe1\u606f \u65bd\u4e16\u826f\u8bfe\u9898\u7ec4\u96b6\u5c5e\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u3002 \u7814\u7a76\u65b9\u5411\uff1a\u65b0\u578b\u9ad8\u6548\u5b9e\u7528\u7684\u6709\u673a\u65b9\u6cd5\u5b66\u7814\u7a76\uff0c\u4fa7\u91cd\u4e8e\u624b\u6027\u5408\u6210\u548c\u50ac\u5316\u53cd\u5e94 \u65b0\u578b\u529f\u80fd\u624b\u6027\u805a\u5408\u7269\u5408\u6210\u3002 \u4eba\u624d\u9700\u6c42 \u73b0\u56e0\u79d1\u7814\u5de5\u4f5c\u9700\u8981\u62db\u8058\u535a\u58eb\u540e\/\u7814\u7a76\u52a9\u7406\u591a\u540d(\u957f\u671f\u6709\u6548)\u3002\u5177\u4f53\u8981\u6c42\u5982\u4e0b\uff1a \u535a\u58eb\u540e\uff1a 1\u3001\u535a\u58eb\u6bd5\u4e1a\u4e24\u5e74\u4e4b\u5185\uff0c\u6709\u673a\u5316\u5b66\u6216\u9ad8\u5206\u5b50\u5316\u5b66\u4e13\u4e1a\uff1b 2\u3001\u6709\u8f83\u5f3a\u7684\u6709\u673a\u5408\u6210\u3001\u4e0d\u5bf9\u79f0\u50ac\u5316\u3001\u91d1\u5c5e\u6709\u673a\u50ac\u5316\u6216\u624b\u6027\u805a\u5408\u7269\u7814\u7a76\u80cc\u666f\uff0c\u80fd\u72ec\u7acb\u5b8c\u6210\u76f8\u5173\u8bfe\u9898\u7814\u7a76\uff0c\u4e2d\u82f1\u6587\u79d1\u6280\u8bba\u6587\u8bfb\u5199\u80fd\u529b\u4f18\u5f02\uff1b 3\u3001\u8eab\u5fc3\u5065\u5eb7\uff0c\u5de5\u4f5c\u52e4\u594b\u3001\u8e0f\u5b9e\uff0c\u6709\u8f83\u5f3a\u7684\u6c9f\u901a\u80fd\u529b\u548c\u56e2\u961f\u534f\u4f5c\u7cbe\u795e\uff1b \u52a9\u7406\u7814\u7a76\u5458\u6216\u7814\u7a76\u52a9\u7406\uff1a 1\u3001\u535a\u58eb\u6216\u8f83\u4f18\u79c0\u7684\u7855\u58eb\uff0c\u6709\u673a\u5316\u5b66\u3001\u9ad8\u5206\u5b50\u5316\u5b66\u53ca\u76f8\u5173\u4e13\u4e1a\uff0c\u6709\u624e\u5b9e\u7684\u6709\u673a\u5316\u5b66\u5b9e\u9a8c\u57fa\u7840\u548c\u7406\u8bba\u80cc\u666f\uff0c\u6709\u8f83\u5f3a\u7684\u4e2d\u82f1\u6587\u79d1\u6280\u8bba\u6587\u8bfb\u5199\u80fd\u529b\uff1b 2\u3001\u8eab\u5fc3\u5065\u5eb7\uff0c\u5de5\u4f5c\u52e4\u594b\u3001\u8e0f\u5b9e\uff0c\u6709\u56e2\u961f\u534f\u4f5c\u7cbe\u795e\uff1b \u5de5\u8d44\u5f85\u9047\u6839\u636e\u4e0a\u6d77\u6709\u673a\u6240\u76f8\u5173\u89c4\u5b9a\u4ece\u4f18\u8003\u8651\u5e76\u6839\u636e\u5de5\u4f5c\u4e1a\u7ee9\u53d1\u653e\u6d25\u8d34\u3002 \u6709\u610f\u5e94\u8058\u8005\u8bf7\u5c06\u4e2a\u4eba\u7b80\u5386\u548c\u5de5\u4f5c\u5c0f\u7ed3\uff08\u8bf7\u6ce8\u660e\u53ef\u5230\u5c97\u65f6\u95f4\uff09\u53d1\u81f3shiliangshi@sioc.ac.cn \u6b22\u8fce\u52a0\u76df\uff01 \u65bd\u4e16\u826f\u7814\u7a76\u5458 \u4e2a\u4eba\u7ecf\u5386 2011\u5e749\u6708\uff1a \u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u836f\u5b66\u90e8\u83b7\u836f\u5b66\u535a\u58eb\u5b66\u4f4d \uff08\u6307\u5bfc\u8001\u5e08\uff1a Masakatsu Shibasaki\u6559\u6388\u548cMotomu Kanai\u6559\u6388\uff09 2011\u5e7410\u6708\uff0d2012\u5e7410\u6708\uff1a \u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u836f\u5b66\u90e8JSPS\u535a\u58eb\u540e\uff08\u6307\u5bfc\u8001\u5e08\uff1a\u00a0Motomu Kanai\u6559\u6388\uff09 2012\u5e7411\u6708\uff0d2016\u5e745\u6708\uff1a \u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u5316\u5b66\u7cfb\u535a\u58eb\u540e\uff08Stephen Buchwald\u6559\u6388\uff09 2016\u5e745\u6708\uff0d\u81f3\u4eca\uff0c\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u3001\u8bfe\u9898\u7ec4\u957f\u3001\u535a\u5bfc \u4ee5\u7b2c\u4e00\u4f5c\u8005\u5df2\u5728Nature\u3001Science\u3001Nature Chemistry\u3001JACS\u3001ACIE\u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u53d1\u8868\u8bba\u65877\u7bc7\u3002\u00a0 \u83b7\u5956\u7ecf\u5386 2010 \u00a0 \u00a0\u56fd\u5bb6\u4f18\u79c0\u81ea\u8d39\u7559\u5b66\u751f\u5956 2008-2011\u00a0\u00a0\u00a0 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u535a\u58eb\u8bfe\u7a0b\u548c\u535a\u58eb\u540e\u5956\u5b66\u91d1(DC2\u548cPD) 2011-2013\u00a0\u00a0\u00a0 \u65e5\u672c\u6587\u90e8\u7701\u5956\u5b66\u91d1 \u4ee3\u8868\u6027\u8bba\u6587 1) Y. Cai, X.-T. Yang, S.-Q. Zhang, F. Li, Y.-Q. Li, L.-X. Ruan, X. Hong*, S.-L. Shi* \u201cCopper-Catalyzed Enantioselective Markovnikov Protoboration of a-Olefins Enabled by a Buttressed N-Heterocyclic Carbene Ligand\u201d \u00a0 \u00a0 Angew. Chem. Int. Ed. 2018, 57, 1376-1380. 2\uff09Y. Cai, F. Li, Y.-Q. Li, W.-B. Zhang, F.-H. Liu*, S.-L. Shi* \u201cBase metal-catalyzed alcohol C\u2013C couplings under hydrogen transfer conditions\u201d (invited review) \u00a0 \u00a0 Tetrahedron Letters, […]","protected":false},"author":5,"featured_media":18390,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[868],"tags":[2006],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/03\/7dd4c3f74f006b34bb1d70d7adebd54e-17.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-4MA","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18388"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=18388"}],"version-history":[{"count":11,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18388\/revisions"}],"predecessor-version":[{"id":31863,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18388\/revisions\/31863"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/18390"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=18388"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=18388"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=18388"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
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