{"id":18561,"date":"2018-04-08T10:18:02","date_gmt":"2018-04-08T02:18:02","guid":{"rendered":"\/\/www.gsbet888.com\/?p=18561"},"modified":"2019-08-02T18:51:45","modified_gmt":"2019-08-02T10:51:45","slug":"noyori-%e7%8e%af%e5%8c%96%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e7%8e%af%e5%8c%96%e5%8f%8d%e5%ba%94\/2018\/04\/noyori-%e7%8e%af%e5%8c%96%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Noyori \u73af\u5316\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"

\u6982\u8981<\/strong><\/h4>\n

1971\u5e74\uff0c\u65e5\u672c\u540d\u53e4\u5c4b\u5927\u5b66(Nagoya University)\u5316\u5b66\u7cfb\u7684\u91ce\u4f9d\u826f\u6cbb(Noyori Ryoji)\u7814\u7a76\u5ba4\u5728\u9996\u6b21\u62a5\u9053\u4e86\u7fb0\u57fa\u94c1\u914d\u5408\u7269Fe2<\/sub>(CO)9<\/sub>\u4fc3\u8fdb\u7684\u03b1,\u03b3-\u4e8c\u6eb4\u4ee3\u916e\u4e0e1,3-\u4e8c\u70ef\u4e4b\u95f4\u7684\u73af\u5316\u5076\u8054\u53cd\u5e94[1]<\/sup>\u30021973\u5e74\uff0c\u8be5\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\u82b3\u57fa\u70ef\u70c3\u540c\u6837\u53ef\u4ee5\u53c2\u4e0e\u8be5\u53cd\u5e94,\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u82b3\u57fa\u70ef\u70c3\u6784\u578b\u5b8c\u5168\u4fdd\u6301[2]-[3]<\/sup>\u3002
\n<\/a><\/p>\n

1977\u5e74\uff0cNoyori\u7b49\u8fdb\u4e00\u6b65\u5c06\u5e95\u7269\u6269\u5c55\u81f3\u9170\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u4ece\u800c\u6210\u529f\u83b7\u5f973-(2H)-\u544b\u5583\u916e\u7c7b\u5316\u5408\u7269[4]<\/sup>\u3002<\/p>\n

\"\"<\/a><\/p>\n

1978\u5e74\uff0c\u8be5\u7814\u7a76\u7ec4\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5c55\u81f3\u4e94\u5143\u82b3\u9999\u6742\u73af\u53ca\u70ef\u80fa\u7c7b\u5316\u5408\u7269[5]-[6]<\/sup>\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u4e0a\u8ff0\u53cd\u5e94\u7edf\u79f0\u4e3aNoyori\u73af\u5316\u5076\u8054\u53cd\u5e94(Noyori cyclocoupling)\uff0c\u53c8\u79f0\u4e3aNoyori\u73af\u5316\u53cd\u5e94(Noyori annulation)\u3002\u8be5\u53cd\u5e94\u4e3a\u73af\u620a\u916e\u3001\u73af\u5e9a\u70ef\u916e\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u6cd5\u3002\u73b0\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u5929\u7136\u4ea7\u7269\u5168\u5408\u6210\u7684\u5173\u952e\u6b65\u9aa4[7]-[10]<\/sup>\u3002<\/p>\n

\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n