{"id":18561,"date":"2018-04-08T10:18:02","date_gmt":"2018-04-08T02:18:02","guid":{"rendered":"\/\/www.gsbet888.com\/?p=18561"},"modified":"2019-08-02T18:51:45","modified_gmt":"2019-08-02T10:51:45","slug":"noyori-%e7%8e%af%e5%8c%96%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e7%8e%af%e5%8c%96%e5%8f%8d%e5%ba%94\/2018\/04\/noyori-%e7%8e%af%e5%8c%96%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Noyori \u73af\u5316\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>1971\u5e74\uff0c\u65e5\u672c\u540d\u53e4\u5c4b\u5927\u5b66(Nagoya University)\u5316\u5b66\u7cfb\u7684\u91ce\u4f9d\u826f\u6cbb(Noyori Ryoji)\u7814\u7a76\u5ba4\u5728\u9996\u6b21\u62a5\u9053\u4e86\u7fb0\u57fa\u94c1\u914d\u5408\u7269Fe<sub>2<\/sub>(CO)<sub>9<\/sub>\u4fc3\u8fdb\u7684\u03b1,\u03b3-\u4e8c\u6eb4\u4ee3\u916e\u4e0e1,3-\u4e8c\u70ef\u4e4b\u95f4\u7684\u73af\u5316\u5076\u8054\u53cd\u5e94<sup>[1]<\/sup>\u30021973\u5e74\uff0c\u8be5\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\u82b3\u57fa\u70ef\u70c3\u540c\u6837\u53ef\u4ee5\u53c2\u4e0e\u8be5\u53cd\u5e94,\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u82b3\u57fa\u70ef\u70c3\u6784\u578b\u5b8c\u5168\u4fdd\u6301<sup>[2]-[3]<\/sup>\u3002<a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/1-1.png\"><br \/>\n<\/a><\/p>\n<p>1977\u5e74\uff0cNoyori\u7b49\u8fdb\u4e00\u6b65\u5c06\u5e95\u7269\u6269\u5c55\u81f3\u9170\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u4ece\u800c\u6210\u529f\u83b7\u5f973-(2H)-\u544b\u5583\u916e\u7c7b\u5316\u5408\u7269<sup>[4]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18563 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1.png\" alt=\"\" width=\"1126\" height=\"249\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1.png 1126w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1-300x66.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1-768x170.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/2-1-680x150.png 680w\" sizes=\"(max-width: 1126px) 100vw, 1126px\" \/><\/a><\/p>\n<p>1978\u5e74\uff0c\u8be5\u7814\u7a76\u7ec4\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5c55\u81f3\u4e94\u5143\u82b3\u9999\u6742\u73af\u53ca\u70ef\u80fa\u7c7b\u5316\u5408\u7269<sup>[5]-[6]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/3-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18564 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/3-1.png\" alt=\"\" width=\"723\" height=\"279\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/3-1.png 723w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/3-1-300x116.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/3-1-680x262.png 680w\" sizes=\"(max-width: 723px) 100vw, 723px\" \/><\/a><\/p>\n<p>\u4e0a\u8ff0\u53cd\u5e94\u7edf\u79f0\u4e3aNoyori\u73af\u5316\u5076\u8054\u53cd\u5e94(Noyori cyclocoupling)\uff0c\u53c8\u79f0\u4e3aNoyori\u73af\u5316\u53cd\u5e94(Noyori annulation)\u3002\u8be5\u53cd\u5e94\u4e3a\u73af\u620a\u916e\u3001\u73af\u5e9a\u70ef\u916e\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u6cd5\u3002\u73b0\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u5929\u7136\u4ea7\u7269\u5168\u5408\u6210\u7684\u5173\u952e\u6b65\u9aa4<sup>[7]-[10]<\/sup>\u3002<\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] R. Noyori, S. Makino, H. Takaya, J. Am. Chem. Soc. 1971, 93, 1272. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja00734a046\">10.1021\/ja00734a046.<\/a><\/li>\n<li>[2] R. Noyori, K. Yokoyama, Y. Hayakawa, J. Am. Chem. Soc. 1973, 95, 2722. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja00789a073\">10.1021\/ja00789a073.<\/a><\/li>\n<li>[3] Y. Hayakawa, K. Yokoyama, and R. Noyori, J. Am. Chem. Soc., 1978,100,1791. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a022\">10.1021\/ja00474a022.\u00a0<\/a><\/li>\n<li>[4] Y. Hayakawa, H. Takaya, S. Makino, N. Hayakawa, R. Noyori,\u00a0Bull. Chem. Soc. Jpn. 1977, 50, 1990. doi: <a href=\"http:\/\/www.journal.csj.jp\/doi\/abs\/10.1246\/bcsj.50.1990\">10.1246\/bcsj.50.1990.<\/a><\/li>\n<li>[5] M. Takaya, S. Makino, Y. Hayakawa, R. Noyori, J. Am. Chem. Soc. 1978, 100, 1765. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a019\">10.1021\/ja00474a019.\u00a0<\/a><\/li>\n<li>[6] Y. Hayakawa, K. Yokoyama, R. Noyori, J Am. Chem. Soc. 1978,100, 1799. doi:\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a023\">10.1021 \/ ja00474a023.<\/a><\/li>\n<li>[7] J. L. Paparin, C. Cr\u00e9visy, Tetrahedron Lett. 2000, 41, 2343. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040403900001982\">10.1016\/S0040-4039(00)00198-2.<\/a><\/li>\n<li>[8] H. Takaya, Y. Hayakawa, S. Makino, R. Noyori, J. Am. Chem. Soc., 1978,100,\u00a01778.doi:<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a020\">10.1021 \/ ja00474a020.<\/a><\/li>\n<li>[9] Y. Hayakawa, Y. Baba, S. Makino, R. Noyori, J. Am. Chem. Soc., 1978, 100,1786. doi:<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a021\"> 10.1021\/ja00474a021.\u00a0<\/a><\/li>\n<li>[10] R. Noyori, T. Souchi, Y. Hayakawa, J. Org. Chem., 1975, 40, 2681. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo00906a024\">10.1021\/jo00906a024.<\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/4-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18565 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/4-1.png\" alt=\"\" width=\"633\" height=\"593\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/4-1.png 633w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/4-1-300x281.png 300w\" sizes=\"(max-width: 633px) 100vw, 633px\" \/><\/a><\/p>\n<ul>\n<li>[1] R. Noyori, Y. Hayakawa, S. Makino, N. Hayakawa, and H. Takaya, Tetrahedron Lett. 1978,19, 2091. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040403901947586\">10.1016\/S0040-4039(01)94758-6.<\/a><\/li>\n<li>[2] R. Noyori, Y. Hayakawa, M. Funakura, H. Takaya, S. Murai, R. Kobayashi, S.\u00a0Tsutsumi, J. Am. Chem. Soc. 1972, 94, 7202. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja00775a084\">10.1021\/ja00775a084<\/a>.<\/li>\n<li>[3] R. Noyori, Y. Hayakawa, H. Takaya, S. Murai, R. Kobayashi, N. Sonoda, J. Am.\u00a0Chem. Soc., 1978, 100, 1759. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a018\">10.1021\/ja00474a018.<\/a><\/li>\n<li>[4] H. E. Alper, C. H. Keung, J. Org. Chem 1972, 37, 2566. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo00981a011\">10.1021\/jo00981a011.<\/a><\/li>\n<li>[5] B. Czauderna , K. H. Jogun, J. J. Stezow ski, B. F\u00f6hlisch, J. Am. Chem. Soc. 1976, 98, 6696. doi:<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja00437a044\">10.1021\/ja00437a044.\u00a0 <\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u5417\u5549\u73af\u620a\u916e\u7684\u5408\u6210[1] [2]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-18566 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1.png\" alt=\"\" width=\"845\" height=\"243\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1.png 845w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1-300x86.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1-768x221.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/5-1-680x196.png 680w\" sizes=\"(max-width: 845px) 100vw, 845px\" \/><\/a><\/p>\n<p>(\u00b1)-\u03b1-cuparenone\u578b\u841c\u70ef\u7684\u5408\u6210[3]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18567 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1.png\" alt=\"\" width=\"895\" height=\"194\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1.png 895w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1-300x65.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1-768x166.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/6-1-680x147.png 680w\" sizes=\"(max-width: 895px) 100vw, 895px\" \/><\/a><\/p>\n<p>muscarine\u751f\u7269\u78b1\u7684\u5408\u6210[4] [5]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18568 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1.png\" alt=\"\" width=\"1114\" height=\"199\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1.png 1114w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1-300x54.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1-768x137.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/7-1-680x121.png 680w\" sizes=\"(max-width: 1114px) 100vw, 1114px\" \/><\/a><\/p>\n<p>pseudoisocytidine\u7684\u5408\u6210[6]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-18569 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8.png\" alt=\"\" width=\"985\" height=\"325\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8.png 985w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8-300x99.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8-768x253.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/04\/8-680x224.png 680w\" sizes=\"(max-width: 985px) 100vw, 985px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p>\u5c06Fe<sub>2<\/sub>(CO)<sub>9<\/sub> (1.2 eq.) \u88c5\u5165\u539a\u58c1\u53cd\u5e94\u5b89\u74ff\u4e2d\uff0c\u5e76\u4e0e\u56fa\u5b9a\u6709\u6a61\u80f6\u585e\u7684\u4e09\u901a\u6d3b\u585e\u53ca\u6c2e\u6c14\u7ba1\u7ebf\u8fdb\u884c\u8fde\u63a5\u3002\u5c06\u5176\u53cd\u590d\u8fdb\u884c\u62bd\u771f\u7a7a-\u5145\u6c2e\u6c14\u64cd\u4f5c\u4e94\u6b21\u3002\u518d\u7528\u6ce8\u5c04\u5668\u52a0\u5165\u65e0\u6c34benzene (\u7ef4\u6301\u5e95\u7269\u6d53\u5ea6\u4e3a2M)\u30011,3-\u4e8c\u70ef (10 eq.)\u53ca\u03b1,\u03b3-\u4e8c\u6eb4\u4ee3\u916e(1 eq.) \u3002\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u572860-90<sup>o<\/sup>C\u4e0b\u52a0\u70ed\u6405\u62cc\uff0c\u76f4\u81f3\u53cd\u5e94\u5b8c\u6210\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u53cd\u5e94\u6db2\u51b7\u5374\u81f3\u5ba4\u6e29\u3002\u901a\u8fc7\u7845\u85fb\u571f\u8fc7\u6ee4\u9664\u53bb\u5f62\u6210\u7684\u6c89\u6dc0\uff0c\u5c06\u6ee4\u6db2\u8fdb\u884c\u51cf\u538b\u6d53\u7f29\uff0c\u9664\u53bb\u6eb6\u5242\u3002\u5bf9\u7c97\u4ea7\u7269\u91c7\u7528\u5236\u5907TLC\u8fdb\u884c\u5206\u79bb\u7eaf\u5316\u540e\uff0c\u83b7\u5f97\u76f8\u5e94\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<h4><strong>\u5b9e\u9a8c\u5b9e\u9a8c\u5b89\u5168\u987b\u77e5<\/strong><\/h4>\n<p>\u5c0f\u7f16\u90d1\u91cd\u63d0\u793a\uff1a<strong>\u91d1\u5c5e\u7fb0\u57fa\u5316\u5408\u7269\u6709\u5267\u6bd2\uff0c\u5176\u6bd2\u6027\u8fdc\u5927\u4e8e\u6c22\u6c30\u9178\u53ca\u6c30\u5316\u7269\uff0c\u76ee\u524d\u5c1a\u65e0\u7279\u6548\u89e3\u6bd2\u5242\u3002\u53cd\u5e94\u9700\u8981\u5728\u901a\u98ce\u6781\u4e3a\u4f18\u826f\u7684\u901a\u98ce\u6a71\u5185\u5c0f\u5fc3\u64cd\u4f5c\uff0c\u5e76\u4f69\u6234\u9632\u6bd2\u9762\u5177\u53ca<\/strong><strong>SSG(silver shield gloves)<\/strong><strong>\u9632\u5316\u624b\u5957\u3002<\/strong><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] Y. Hayakawa, K. Yokoyama, R. Noyori, J Am. Chem. Soc. 1978,100, 1799. doi:\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00474a023\">10.1021 \/ ja00474a023.<\/a><\/li>\n<li>[2] R. Noyori, Acc. Chem. Res. 1979, 12, 61. doi: <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ar50134a003\">10.1021\/ar50134a003.<\/a><\/li>\n<li>[3]Y. Hayakawa, F. Shimizu, R. Noyori, Tetrahedron Lett. 1978,19, 993. doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040403901854332\">10.1016\/S0040-4039(01)85433-2.<\/a><\/li>\n<li>[4]Y. Hayakawa, H. Takaya, S. Makino, N. Hayakawa, R. Noyori,\u00a0Bull. Chem. Soc. Jpn. 1977, 50, 1990. doi: <a href=\"http:\/\/www.journal.csj.jp\/doi\/abs\/10.1246\/bcsj.50.1990\">10.1246\/bcsj.50.1990.<\/a><\/li>\n<li>[5]Y. Hayakawa, H. Takaya, S. Makino, N. Hayakawa, R. Noyori,\u00a0J.Am. Chem. Soc. 1973, 95, 4103. doi:<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/ja00793a076\"> 10.1021\/ja00793a076.<\/a><\/li>\n<li>[6] T. Sato, R. Ito, Y. Hayakawa, R. Noyori. Tetrahedron Lett.,1978, 19, 1829.doi: <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0040403901946829\">10.1016\/S0040-4039(01)94682-9.<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong> \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01 <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 1971\u5e74\uff0c\u65e5\u672c\u540d\u53e4\u5c4b\u5927\u5b66(Nagoya University)\u5316\u5b66\u7cfb\u7684\u91ce\u4f9d\u826f\u6cbb(Noyori Ryoji)\u7814\u7a76\u5ba4\u5728\u9996\u6b21\u62a5\u9053\u4e86\u7fb0\u57fa\u94c1\u914d\u5408\u7269Fe2(CO)9\u4fc3\u8fdb\u7684\u03b1,\u03b3-\u4e8c\u6eb4\u4ee3\u916e\u4e0e1,3-\u4e8c\u70ef\u4e4b\u95f4\u7684\u73af\u5316\u5076\u8054\u53cd\u5e94[1]\u30021973\u5e74\uff0c\u8be5\u8bfe\u9898\u7ec4\u7814\u7a76\u53d1\u73b0\u82b3\u57fa\u70ef\u70c3\u540c\u6837\u53ef\u4ee5\u53c2\u4e0e\u8be5\u53cd\u5e94,\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u82b3\u57fa\u70ef\u70c3\u6784\u578b\u5b8c\u5168\u4fdd\u6301[2]-[3]\u3002 1977\u5e74\uff0cNoyori\u7b49\u8fdb\u4e00\u6b65\u5c06\u5e95\u7269\u6269\u5c55\u81f3\u9170\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u4ece\u800c\u6210\u529f\u83b7\u5f973-(2H)-\u544b\u5583\u916e\u7c7b\u5316\u5408\u7269[4]\u3002 1978\u5e74\uff0c\u8be5\u7814\u7a76\u7ec4\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5c55\u81f3\u4e94\u5143\u82b3\u9999\u6742\u73af\u53ca\u70ef\u80fa\u7c7b\u5316\u5408\u7269[5]-[6]\u3002 \u4e0a\u8ff0\u53cd\u5e94\u7edf\u79f0\u4e3aNoyori\u73af\u5316\u5076\u8054\u53cd\u5e94(Noyori cyclocoupling)\uff0c\u53c8\u79f0\u4e3aNoyori\u73af\u5316\u53cd\u5e94(Noyori annulation)\u3002\u8be5\u53cd\u5e94\u4e3a\u73af\u620a\u916e\u3001\u73af\u5e9a\u70ef\u916e\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u6cd5\u3002\u73b0\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u79cd\u5929\u7136\u4ea7\u7269\u5168\u5408\u6210\u7684\u5173\u952e\u6b65\u9aa4[7]-[10]\u3002 \u57fa\u672c\u6587\u732e [1] R. Noyori, S. Makino, H. Takaya, J. Am. Chem. Soc. 1971, 93, 1272. doi: 10.1021\/ja00734a046. [2] R. Noyori, K. Yokoyama, Y. Hayakawa, J. Am. Chem. Soc. 1973, 95, 2722. doi: 10.1021\/ja00789a073. [3] Y. Hayakawa, K. Yokoyama, and R. Noyori, J. Am. Chem. Soc., 1978,100,1791. doi: 10.1021\/ja00474a022.\u00a0 [4] Y. Hayakawa, H. Takaya, S. Makino, N. Hayakawa, R. Noyori,\u00a0Bull. Chem. Soc. Jpn. 1977, 50, 1990. doi: 10.1246\/bcsj.50.1990. [5] M. Takaya, S. Makino, Y. Hayakawa, R. Noyori, J. Am. Chem. Soc. 1978, 100, 1765. doi: 10.1021\/ja00474a019.\u00a0 [6] Y. Hayakawa, K. Yokoyama, R. Noyori, J Am. Chem. Soc. 1978,100, 1799. doi:\u00a010.1021 \/ ja00474a023. 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