{"id":18869,"date":"2018-06-12T06:21:11","date_gmt":"2018-06-11T22:21:11","guid":{"rendered":"\/\/www.gsbet888.com\/?p=18869"},"modified":"2019-08-02T18:51:39","modified_gmt":"2019-08-02T10:51:39","slug":"%e5%8f%b2%e4%b8%80%e5%ae%89%e7%8e%af%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94-%ef%bc%88%e4%ba%94%ef%bc%89-%e5%9c%a8%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2018\/06\/%e5%8f%b2%e4%b8%80%e5%ae%89%e7%8e%af%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94-%ef%bc%88%e4%ba%94%ef%bc%89-%e5%9c%a8%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8.html","title":{"rendered":"\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u53cd\u5e94 \uff08\u4e94\uff09\u2014\u5728\u5408\u6210\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u6295\u7a3f\u4f5c\u8005 \u5b59\u82cf\u8d5f<\/strong><\/p>\n

\u5728\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/strong><\/h4>\n
    \n
  1. \u624b\u6027\u916e\u50ac\u5316\u5242\u7684\u9009\u62e9\u548c\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u5728\u5168\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/strong><\/li>\n<\/ol>\n

    1.1 Ketone 1<\/strong><\/p>\n

    Ketone 1<\/strong>\u662f\u5728\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u53cd\u5e94\u4e2d\u6700\u5e38\u7528\u7684\u624b\u6027\u916e\u50ac\u5316\u5242\u3002<\/p>\n

    1.1.1 Ketone 1<\/strong>\u7684\u53cd\u5e94<\/strong><\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2 Ketone 1<\/strong>\u5728\u5408\u6210\u4e0a\u7684\u5e94\u7528<\/strong><\/p>\n

    1.1.2.1 (-)-mesembrine<\/strong>\u7684\u5408\u6210<\/strong><\/p>\n

    \u73af\u70f7\u916e\u5f88\u5bb9\u6613\u901a\u8fc7\u52a0\u5165\u82b3\u57faGrignard\u8bd5\u5242\u548c\u73af\u6c27\u5316\u53cd\u5e94\uff0c\u518d\u8fdb\u884c\u8131\u6c34\u8f6c\u5316\u4e3a\u82b3\u57fa\u53d6\u4ee3\u7684\u73af\u70ef\u70c31<\/sup>\uff0c\u53d7\u6b64\u60f3\u6cd5\u7684\u542f\u53d1\uff0c(-)-mesembrine\u7684\u5408\u6210\u5f97\u4ee5\u4ee5\u66f4\u77ed\u7684\u8def\u7ebf\u5b8c\u6210\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2.2 ent<\/em><\/strong>-(-)-Nigellamine A2<\/strong>\u7684\u4e0d\u5bf9\u79f0\u5408\u6210<\/strong><\/p>\n

    \u5728ent<\/em><\/strong>-(-)-Nigellamine A2<\/strong>\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u8fc7\u7a0b\u4e2d\u5229\u7528\u4e86\u4e00\u6b65<\/strong>\u9ad8\u5ea6\u9009\u62e9\u6027\u7684\u73af\u6c27\u5316\u53cd\u5e94\uff0c\u5f53\u7528\u624b\u6027\u916e\u50ac\u5316\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u6761\u4ef6\u5904\u7406\u8be5\u53cd\u5e94\u7269\u65f6\uff0c\u5b9e\u9645\u4e0a\u5728\u4e09\u4e2a\u53cd\u5e94\u6027\u53cc\u91cd\u7269\u4e4b\u95f4\u8fdb\u884c\u7ade\u4e89\u3002\u53ef\u80fdC2-\u9187\u53ef\u80fd\u4f7fC3-C4\u70ef\u70c3\u5931\u6d3b\uff0c\u5e76\u4e14\u916e\u50ac\u5316\u5242\u5bf9\u8be5\u5206\u5b50\u4e2d\u7684\u56db\u53d6\u4ee3\u70ef\u70c3\u4e0d\u5177\u6709\u53cd\u5e94\u6027\uff0c\u56e0\u6b64\uff0c\u8fd9\u79cd\u5355\u73af\u6c27\u5316\u4ea7\u7269\u662f\u53cd\u5e94\u7684\u552f\u4e00\u4ea7\u72692<\/sup>\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2.3 ent<\/em><\/strong>-Nakorone<\/strong>\u7684\u4eff\u751f\u5408\u6210<\/strong><\/p>\n

    \u4e3a\u4e86\u5b8c\u6210\u4e09\u73af\u5316\u5408\u7269nakorone\u7684\u5168\u5408\u6210\uff0c\u5408\u6210\u8def\u7ebf\u4e2d\u5229\u7528\u4e86\u53f2\u4e00\u5b89\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u6765\u4ea7\u751f\u591a\u73af\u6c27\u5316\u7269\u5206\u5b50\uff0c\u4e4b\u540e\u518d\u8fdb\u884c\u4e32\u8054\u53cd\u5e94\u6784\u7b51\u4e09\u73af\u7684\u5206\u5b50\u9aa8\u67b63<\/sup>\u3002\u5728\u94af\u50ac\u5316\u7684\u8fd8\u539f\u8131\u78fa\u5316\u540e\uff0c\u5f97\u5230\u7684\u73af\u620a\u4e8c\u70ef\u7ecf\u5386\u4e86TMSOTf\u5f15\u53d1\u7684\u73af\u5316\u8fc7\u7a0b\uff0c\u968f\u540e\u81ed\u6c27\u5206\u89e3\u4e86\u4e19\u4e8c\u70ef\u5e76\u8131\u7845\u70f7\u5316\uff0c\u6210\u529f\u5408\u6210\u4e86\u4e09\u73af\u76ee\u6807\u5206\u5b50\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2.4 \u7684\u5168\u5408\u6210\u4e2d\u591a\u70ef\u70c3\u4e32\u8054\u73af\u5316\u53cd\u5e94<\/strong><\/p>\n

    \u56db\u73af\u6c27\u5316\u7269\u7684\u524d\u4f53\u662f\u901a\u8fc7\u4f7f\u7528\u53f2\u4e00\u5b89\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u53cd\u5e94\u5f97\u5230\u7684\uff0c\u7528CSA\u5904\u7406\u4e4b\u540e\uff0c\u5728\u5206\u5b50\u7684\u4e24\u4fa7\u5206\u522b\u53d1\u751f\u4e32\u8054\u73af\u5316\u53cd\u5e94\u5f97\u5230\u6240\u9700\u7684\u56db\u73af\u4ea7\u7269\uff0c\u5e76\u4e14\u4ea7\u7387\u4e5f\u5f88\u9ad84<\/sup>\uff0c<\/sup>5<\/sup>\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2.5 Polyepoxides<\/strong>\u7684<\/strong>endo-<\/strong>\u6210\u73af\u8fc7\u7a0b<\/strong><\/p>\n

    \u8fd9\u662f\u4e00\u4e2aBF3<\/sub>\u50ac\u5316\u4e0b\u7684\u591a\u70ef\u70c3\u4e32\u8054\u73af\u5316\u53cd\u5e94\uff0c\u53cd\u5e94\u7684\u5e95\u7269\u6709\u5f88\u591a\u79cd\uff0c\u5305\u62ec\u9999\u53f6\u9187\uff0c\u6cd5\u5462\u9187\u548c\u9999\u53f6\u57fa\u9999\u53f6\u9187\u7b49\uff0c\u8fd9\u4e2a\u53cd\u5e94\u7684\u4ea7\u7269\u5177\u6709\u5f88\u9ad8\u7684\u7acb\u4f53\u4e13\u4e00\u6027\uff0c\u8fd9\u4e3a\u6211\u4eec\u5408\u6210\u591a\u73af\u7684\u919a\u7c7b\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u5f88\u6709\u6548\u7684\u7b56\u75656-9<\/sup>\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.1.2.6 \u53ef\u4ee5\u8fdb\u884c\u6c34\u5f15\u53d1\u7684\u4e32\u8054\u53cd\u5e94\u7684\u591a\u73af\u6c27\u5316\u7269<\/strong><\/p>\n

    \u5728\u88ab\u91d1\u5c5e\u9502\u548c\u6db2\u6c28\u8fd8\u539f\u540e\uff0c\u5206\u5b50\u4e2d\u7684\u78b3\u78b3\u4e09\u952e\u88ab\u8f6c\u5316\u6210\u5f62\u6210\u8bb8\u591a\u53cc\u952e\uff0c\u5728\u7ecf\u8fc7\u6c34\u5f15\u53d1\u7684\u4e32\u8054\u53cd\u5e94\u751f\u6210\u591a\u73af\u919a\u7c7b\u5316\u5408\u7269\uff0c\u6700\u7ec8\u4ea7\u7269\u4ee553\uff05\u7684\u5206\u79bb\u4ea7\u7387\u83b7\u5f9710<\/sup>\u3002<\/p>\n

    \"\"<\/a><\/p>\n

    1.2 Ketone 2b<\/strong><\/p>\n

    \"\"<\/a><\/p>\n

     <\/p>\n

    1.3 Ketone 3a<\/strong>\u548c<\/strong>3g<\/strong><\/p>\n

    \"\"<\/a><\/p>\n

    1.4 ketone5c<\/strong><\/p>\n

    \"\"<\/a><\/p>\n

      \n
    1. \u7528\u4e8e\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u7684\u5168\u90e8\u7684\u624b\u6027\u916e\u50ac\u5316\u5242<\/strong><\/li>\n<\/ol>\n

      \"\"<\/a><\/p>\n

      3.\u00a0 \u603b\u7ed3<\/strong><\/p>\n

      \u53f2\u4e00\u5b89\u8bfe\u9898\u7ec4\u57281996\u5e74\u62a5\u9053\u4e86\u7b2c\u4e00\u4f8b\u78b3\u6c34\u5316\u5408\u7269\u57fa\u7684\u624b\u6027\u916e\u50ac\u5316\u7684\u70ef\u70c3\u7684\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u53cd\u5e94\uff0c\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4f7f\u7528\u7684Oxone\u5c06\u624b\u6027\u916e\u6c27\u5316\u6210\u8fc7\u6c27\u5316\u916e\uff0c\u4e4b\u540e\u8fc7\u6c27\u5316\u916e\u518d\u548c\u53cc\u952e\u53d1\u751f\u73af\u6c27\u5316\u53cd\u5e94\u5f97\u5230\u73af\u6c27\u5316\u5408\u7269\u3002\u5728\u6d4b\u8bd5\u4e86\u4f17\u591a\u6eb6\u5242\u4e4b\u540e\u7684\u7814\u7a76\u53d1\u73b0\uff0cMeCN\u662f\u53cd\u5e94\u7684\u6700\u4f73\u6eb6\u5242\uff0c\u5e76\u4e14\u53cd\u5e94\u5bf9\u4e8e\u4e09\u53d6\u4ee3\u7684\u53cc\u952e\u548c\u53cd\u5f0f\u53cc\u952e\u7279\u522b\u6709\u6548\uff0c\u7740\u4f7f\u5f97\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u53cd\u5e94\u53ef\u4ee5\u4f5c\u4e3aJacobsen\u6c27\u5316\u548cSharpless AE\u7684\u4e92\u8865\u53cd\u5e94\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u70ef\u4e19\u57fa\u9187\u6765\u8bf4\u5c24\u4e3a\u5982\u6b64\u3002\u6b64\u5916\uff0c\u8fd9\u4e2a\u53cd\u5e94\u53ef\u4ee5\u9002\u5e94\u4f17\u591a\u70ef\u70c3\u7684\u884d\u751f\u7269\uff0c\u4f46\u662f\u67d0\u4e9b\u53cd\u5e94\u6761\u4ef6\u5bf9\u73af\u6c27\u5316\u8fc7\u7a0b\u7684\u5f71\u54cd\u4f1a\u7279\u522b\u5927\uff0c\u4f8b\u5982\u6e29\u5ea6\uff0cpH\u548c\u53cd\u5e94\u65f6\u95f4\u3002\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u6700\u91cd\u8981\u7684\u526f\u53cd\u5e94\u662f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u53d1\u751f\u7684Baeyer-Villiger\u91cd\u6392\u53cd\u5e94\uff0c\u4f46\u662f\u5bf9\u4e8epH\u7684\u63a7\u5236\u53ef\u4ee5\u6709\u6548\u6291\u5236\u8fd9\u4e2a\u53cd\u5e94\u3002\u603b\u7684\u6765\u8bf4\uff0c\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u53cd\u5e94\u5177\u6709\u4f17\u591a\u7684\u4f18\u70b9\uff0c\u4f8b\u5982\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u7acb\u4f53\u9009\u62e9\u6027\u5f88\u597d\uff0c\u4fbf\u4e8e\u53cd\u5e94\u540e\u5904\u7406\u7b49\uff0c\u662f\u4e00\u4e2a\u5728\u5408\u6210\u4e2d\u5e38\u88ab\u4f7f\u7528\u7684\u53cd\u5e94\u3002<\/p>\n

       <\/p>\n

      \u53c2\u8003\u6587\u732e<\/strong><\/h4>\n
        \n
      1. J. Org. Chem<\/em>., 2005, 70<\/strong> (19), pp 7711\u20137714, DOI: 10.1021\/jo0511039<\/li>\n
      2. J. Am. Chem. Soc<\/em>., 2006, 128<\/strong>, 7428-7429, DOI:10.1021\/ja061559n<\/li>\n
      3. J. Am. Chem. Soc<\/em>., 2007, 129<\/strong> (5), pp 1050\u20131051, DOI: 10.1021\/ja068826+<\/li>\n
      4. J. Am. Chem. Soc.<\/em>, 2000, 122<\/strong> (19), pp 4831\u20134832, DOI: 10.1021\/ja000842y<\/li>\n
      5. J. Am. Chem. So<\/em>c., 2000, 122<\/strong> (38), pp 9328\u20139329, DOI: 10.1021\/ja0024901<\/li>\n
      6. Org. Lett.<\/em>, 2000, 2<\/strong> (18), pp 2917\u20132919, DOI: 10.1021\/ol0064009<\/li>\n
      7. Org. Lett<\/em>., 2000, 2<\/strong> (18), pp 2917\u20132919, DOI: 10.1021\/jo0110092<\/li>\n
      8. Org. Lett.<\/em>, 2000, 2<\/strong> (18), pp 2917\u20132919, DOI: 10.1021\/ol034539o<\/li>\n
      9. J. Am. Chem. Soc<\/em>., 2005, 127<\/strong> (13), pp 4586\u20134587, DOI: 10.1021\/ja050013i<\/strong><\/li>\n
      10. Science,<\/em> 2007, 317<\/strong>, 1189, DOI:1126\/science.1146421<\/li>\n<\/ol>\n

        \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u6295\u7a3f\u4f5c\u8005 \u5b59\u82cf\u8d5f \u5728\u5408\u6210\u4e2d\u7684\u5e94\u7528 \u624b\u6027\u916e\u50ac\u5316\u5242\u7684\u9009\u62e9\u548c\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u5728\u5168\u5408\u6210\u4e2d\u7684\u5e94\u7528 1.1 Ketone 1 Ketone 1\u662f\u5728\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u53cd\u5e94\u4e2d\u6700\u5e38\u7528\u7684\u624b\u6027\u916e\u50ac\u5316\u5242\u3002 1.1.1 Ketone 1\u7684\u53cd\u5e94 1.1.2 Ketone 1\u5728\u5408\u6210\u4e0a\u7684\u5e94\u7528 1.1.2.1 (-)-mesembrine\u7684\u5408\u6210 \u73af\u70f7\u916e\u5f88\u5bb9\u6613\u901a\u8fc7\u52a0\u5165\u82b3\u57faGrignard\u8bd5\u5242\u548c\u73af\u6c27\u5316\u53cd\u5e94\uff0c\u518d\u8fdb\u884c\u8131\u6c34\u8f6c\u5316\u4e3a\u82b3\u57fa\u53d6\u4ee3\u7684\u73af\u70ef\u70c31\uff0c\u53d7\u6b64\u60f3\u6cd5\u7684\u542f\u53d1\uff0c(-)-mesembrine\u7684\u5408\u6210\u5f97\u4ee5\u4ee5\u66f4\u77ed\u7684\u8def\u7ebf\u5b8c\u6210\u3002 1.1.2.2 ent-(-)-Nigellamine A2\u7684\u4e0d\u5bf9\u79f0\u5408\u6210 \u5728ent-(-)-Nigellamine A2\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u8fc7\u7a0b\u4e2d\u5229\u7528\u4e86\u4e00\u6b65\u9ad8\u5ea6\u9009\u62e9\u6027\u7684\u73af\u6c27\u5316\u53cd\u5e94\uff0c\u5f53\u7528\u624b\u6027\u916e\u50ac\u5316\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u6761\u4ef6\u5904\u7406\u8be5\u53cd\u5e94\u7269\u65f6\uff0c\u5b9e\u9645\u4e0a\u5728\u4e09\u4e2a\u53cd\u5e94\u6027\u53cc\u91cd\u7269\u4e4b\u95f4\u8fdb\u884c\u7ade\u4e89\u3002\u53ef\u80fdC2-\u9187\u53ef\u80fd\u4f7fC3-C4\u70ef\u70c3\u5931\u6d3b\uff0c\u5e76\u4e14\u916e\u50ac\u5316\u5242\u5bf9\u8be5\u5206\u5b50\u4e2d\u7684\u56db\u53d6\u4ee3\u70ef\u70c3\u4e0d\u5177\u6709\u53cd\u5e94\u6027\uff0c\u56e0\u6b64\uff0c\u8fd9\u79cd\u5355\u73af\u6c27\u5316\u4ea7\u7269\u662f\u53cd\u5e94\u7684\u552f\u4e00\u4ea7\u72692\u3002 1.1.2.3 ent-Nakorone\u7684\u4eff\u751f\u5408\u6210 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AE\u7684\u4e92\u8865\u53cd\u5e94\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u70ef\u4e19\u57fa\u9187\u6765\u8bf4\u5c24\u4e3a\u5982\u6b64\u3002\u6b64\u5916\uff0c\u8fd9\u4e2a\u53cd\u5e94\u53ef\u4ee5\u9002\u5e94\u4f17\u591a\u70ef\u70c3\u7684\u884d\u751f\u7269\uff0c\u4f46\u662f\u67d0\u4e9b\u53cd\u5e94\u6761\u4ef6\u5bf9\u73af\u6c27\u5316\u8fc7\u7a0b\u7684\u5f71\u54cd\u4f1a\u7279\u522b\u5927\uff0c\u4f8b\u5982\u6e29\u5ea6\uff0cpH\u548c\u53cd\u5e94\u65f6\u95f4\u3002\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u6700\u91cd\u8981\u7684\u526f\u53cd\u5e94\u662f\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u53d1\u751f\u7684Baeyer-Villiger\u91cd\u6392\u53cd\u5e94\uff0c\u4f46\u662f\u5bf9\u4e8epH\u7684\u63a7\u5236\u53ef\u4ee5\u6709\u6548\u6291\u5236\u8fd9\u4e2a\u53cd\u5e94\u3002\u603b\u7684\u6765\u8bf4\uff0c\u53f2\u4e00\u5b89\u73af\u6c27\u5316\u53cd\u5e94\u5177\u6709\u4f17\u591a\u7684\u4f18\u70b9\uff0c\u4f8b\u5982\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u7acb\u4f53\u9009\u62e9\u6027\u5f88\u597d\uff0c\u4fbf\u4e8e\u53cd\u5e94\u540e\u5904\u7406\u7b49\uff0c\u662f\u4e00\u4e2a\u5728\u5408\u6210\u4e2d\u5e38\u88ab\u4f7f\u7528\u7684\u53cd\u5e94\u3002   \u53c2\u8003\u6587\u732e J. Org. Chem., 2005, 70 (19), pp 7711\u20137714, DOI: 10.1021\/jo0511039 J. Am. Chem. Soc., 2006, 128, 7428-7429, DOI:10.1021\/ja061559n J. Am. Chem. Soc., 2007, 129 (5), pp 1050\u20131051, DOI: 10.1021\/ja068826+ J. Am. Chem. Soc., 2000, 122 (19), pp 4831\u20134832, DOI: 10.1021\/ja000842y J. Am. Chem. Soc., 2000, 122 (38), pp 9328\u20139329, DOI: 10.1021\/ja0024901 Org. Lett., 2000, 2 (18), pp 2917\u20132919, DOI: […]","protected":false},"author":8,"featured_media":18846,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[414,1271],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/05\/cv-1.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-4Ul","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18869"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=18869"}],"version-history":[{"count":8,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18869\/revisions"}],"predecessor-version":[{"id":27103,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/18869\/revisions\/27103"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/18846"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=18869"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=18869"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=18869"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}