{"id":19172,"date":"2018-06-29T06:04:31","date_gmt":"2018-06-28T22:04:31","guid":{"rendered":"\/\/www.gsbet888.com\/?p=19172"},"modified":"2019-08-02T18:51:35","modified_gmt":"2019-08-02T10:51:35","slug":"%e5%8f%af%e4%bb%a5%e6%97%a0%e9%99%90%e7%8e%a9%e8%8a%b1%e7%9a%84aldol%e7%bc%a9%e5%90%88-%e7%ac%ac%e4%b8%89%e9%83%a8%e5%88%86%ef%bc%9a%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%9a%84%e9%85%b0%e8%83%ba%e5%92%8c","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2018\/06\/%e5%8f%af%e4%bb%a5%e6%97%a0%e9%99%90%e7%8e%a9%e8%8a%b1%e7%9a%84aldol%e7%bc%a9%e5%90%88-%e7%ac%ac%e4%b8%89%e9%83%a8%e5%88%86%ef%bc%9a%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%9a%84%e9%85%b0%e8%83%ba%e5%92%8c.html","title":{"rendered":"\u53ef\u4ee5\u65e0\u9650\u73a9\u82b1\u7684Aldol\u7f29\u5408 \u7b2c\u4e09\u90e8\u5206\uff1a\u4e0d\u5bf9\u79f0\u7684\u9170\u80fa\u548c\u916f\u7684\u53cd\u5e94\uff081\uff09"},"content":{"rendered":"
\u672c\u6587\u63a5\u4e0a\u671f\u00a0\u53ef\u4ee5\u65e0\u9650\u73a9\u82b1\u7684Aldol\u7f29\u5408 \u7b2c\u4e8c\u90e8\u5206<\/a><\/p>\n <\/p>\n \u78b3\u78b3\u952e\u6784\u7b51\u7684\u738b\u9053\u53cd\u5e94\uff1a\u7f9f\u919b\u7f29\u5408\u53cd\u5e94(Aldol reaction)\u7b2c\u4e09\u5f39 <\/a><\/p>\n Crimmins\u53d1\u73b0\u4e86\u53ef\u4ee5\u5f97\u5230Evans-syn<\/em>-aldol\u4ea7\u7269\u548c\u975eEvans-syn<\/em>-aldol\u4ea7\u7269\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u53cd\u5e94\u4e2d\u9700\u8981\u7528\u5230\u949b\u4f5c\u4e3a\u914d\u5408\u8bd5\u5242\uff0c\u8fd9\u4e2a\u65b9\u6cd5\u7684\u53d1\u660e\u5927\u5927\u589e\u52a0\u4e86\u949b\u70ef\u9187\u5728aldol\u53cd\u5e94\u4e2d\u7684\u4f7f\u7528\u8303\u56f4\u3002Ref. 3<\/p>\n \uff081\uff09\u4f7f\u75281 equiv.\u949b\u8bd5\u5242<\/p>\n \uff082\uff09\u4f7f\u75282 equiv.\u949b\u8bd5\u5242<\/p>\n \u8fd9\u91cc\u662f\u4e00\u4e2a\u03b1-\u70f7\u6c27\u57fa\u7fb0\u57fa\u5316\u5408\u7269\u7684\u4f8b\u5b50\uff1aref. 4<\/p>\n \u8fd8\u6709\u4e00\u4e9b\u7528\u4e8e\u4e0d\u5bf9\u79f0\u9170\u80fa\u548c\u916faldol\u7684\u624b\u6027\u52a9\u5242<\/p>\n 1).ref. 5<\/p>\n 2).ref. 6<\/p>\n \u5176\u4ed6\u4e00\u4e9b\u4f8b\u5b50\uff1a<\/p>\n 1) ref. 7, 8<\/p>\n 2) ref 9<\/p>\n 3) ref 10<\/p>\n 4) ref 11, 12<\/p>\n 5) ref 13<\/p>\n 6) ref 14<\/p>\n 7) ref 15<\/p>\n \u5173\u4e8eMukaiyama aldol\u7f29\u5408\u53cd\u5e94\u7684\u57fa\u672c\u5185\u5bb9\uff0c\u5728\u8fd9\u91cc\u6709\u4e00\u4e9b\u76f8\u5173\u7684\u4ecb\u7ecd\uff1a<\/p>\n \/\/www.gsbet888.com\/%E5%8C%96%E5%AD%A6%E6%9D%82%E8%AE%B0\/2015\/10\/post-6781.html<\/a>\uff0c\u8fd9\u91cc\u8865\u5145\u7684\u662f\u51e0\u7c7b\u624b\u6027\u50ac\u5316\u5242\u7684\u5f00\u53d1\u548c\u4f7f\u7528\u3002<\/p>\n\n
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