{"id":19733,"date":"2018-08-21T05:57:33","date_gmt":"2018-08-20T21:57:33","guid":{"rendered":"\/\/www.gsbet888.com\/?p=19733"},"modified":"2019-08-02T18:51:24","modified_gmt":"2019-08-02T10:51:24","slug":"%e4%b8%89%e9%94%ae%e7%9a%84%e5%bd%a2%e6%88%90%e5%92%8c%e4%b8%89%e9%94%ae%e5%88%b0%e5%8f%8c%e9%94%ae%e7%9a%84%e8%bd%ac%e5%8c%96-%e7%ac%ac%e4%b8%80%e9%83%a8%e5%88%86%ef%bc%9acorey-fuchs%e5%8f%8d","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2018\/08\/%e4%b8%89%e9%94%ae%e7%9a%84%e5%bd%a2%e6%88%90%e5%92%8c%e4%b8%89%e9%94%ae%e5%88%b0%e5%8f%8c%e9%94%ae%e7%9a%84%e8%bd%ac%e5%8c%96-%e7%ac%ac%e4%b8%80%e9%83%a8%e5%88%86%ef%bc%9acorey-fuchs%e5%8f%8d.html","title":{"rendered":"\u4e09\u952e\u7684\u5f62\u6210\u548c\u4e09\u952e\u5230\u53cc\u952e\u7684\u8f6c\u5316 \u7b2c\u4e00\u90e8\u5206\uff1aCorey-Fuchs\u53cd\u5e94\uff0cSeyferth-Gilbert\u53cd\u5e94\u548c\u7094\u70c3\u590d\u5206\u89e3"},"content":{"rendered":"

\u4f5c\u8005 \u5b59\u82cf\u8d5f<\/p>\n

\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u70ef\u70c3\u548c\u7094\u70c3\u5177\u6709\u5f88\u597d\u7684\u6d3b\u6027\uff0c\u4ed6\u4eec\u4e5f\u53ef\u80fd\u662f\u5929\u7136\u4ea7\u7269\u5f53\u4e2d\u7684\u6d3b\u6027\u90e8\u4f4d\uff0c\u5728\u4e4b\u524d\u5c0f\u7f16\u4e5f\u6709\u4ecb\u7ecd\u4e86\u51e0\u79cd\u53cc\u952e\u5f62\u6210\u7684\u65b9\u6cd5\uff0c\u5305\u62ec\u6bd4\u8f83\u5e38\u7528\u7684Wittig\u53cd\u5e94\uff0cHEW\u53cd\u5e94\uff0c\u70ef\u70c3\u590d\u5206\u89e3\uff0cTakai\u53cd\u5e94\uff0c\u7b49\u7b49\u3002<\/p>\n

\u4f17\u6240\u5468\u77e5\uff0c\u70ef\u70c3\u53ef\u4ee5\u901a\u8fc7\u7094\u7684\u8fd8\u539f\u5f97\u5230\uff0c\u5e76\u4e14\u53ef\u4ee5\u901a\u8fc7\u4e0d\u540c\u7684\u53cd\u5e94\u6761\u4ef6\u5f97\u5230\u4e0d\u540c\u6784\u5f62\u7684\u53cc\u952e\uff0c\u4e0b\u8fb9\u662f\u5176\u4e2d\u7684\u4e24\u79cd\u65b9\u6cd5\uff1a<\/p>\n

\"\"<\/a><\/p>\n

\u6362\u53e5\u8bdd\u8bf4\uff0c\u70ef\u548c\u7094\u53ef\u4ee5\u76f8\u4e92\u8f6c\u5316\uff0c\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u7094\u53ef\u4ee5\u88ab\u8fd8\u539f\u6210\u70ef\uff0c\u800c\u70ef\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u70ef\u4e5f\u53ef\u4ee5\u8131\u6c22\u6c27\u5316\u6210\u7094\u3002<\/p>\n

\u4e00\u3001\u76f4\u63a5\u6cd5\u751f\u6210\u7094\u70c3<\/p>\n

\"\"<\/a><\/p>\n

    \n
  1. \u5229\u7528\u7fb0\u57fa\u548c\u78f7\u8bd5\u5242\u7684\u65b9\u6cd5<\/li>\n<\/ol>\n

    (i) Corey-Fuchs\u53cd\u5e94 ref. 1<\/p>\n

    \"\"<\/a><\/p>\n

    \u8fd9\u662f\u4e00\u4e2a\u975e\u5e38\u6709\u7528\u7684\u7528\u4e8e\u751f\u6210\u7094\u70c3\u7684\u4e24\u90e8\u53cd\u5e94\uff0c\u8fd9\u4e2a\u53cd\u5e94\u53ef\u7528\u4e8e\u4ece\u919b\u4e3a\u53cd\u5e94\u5e95\u7269\u5408\u6210\u7aef\u4f4d\u7094\u70c3\u548c\u4e09\u53d6\u4ee3\u7684\u7094\uff1b\u53cd\u5e94\u7684\u7b2c\u4e00\u90e8\u5176\u5b9e\u548cWittig\u53cd\u5e94\u975e\u5e38\u7c7b\u4f3c\u3002<\/p>\n

    \u53cd\u5e94\u673a\u7406\uff1a<\/p>\n

    \"\"<\/a><\/p>\n

    \u4e00\u4e2a\u5b9e\u4f8b\uff1aref. 2<\/p>\n

    \"\"<\/a><\/p>\n

    (ii) Seyferth-Gilbert\u53cd\u5e94 ref. 3<\/p>\n

    \"\"<\/a><\/p>\n

    Seyferth-Gilbert\u53cd\u5e94\u53ef\u4ee5\u5f53\u4f5cSeyferth-Gilbert\u53cd\u5e94\u7528\u4e8e\u5408\u6210\u7aef\u4f4d\u7094\u70c3\u7684\u4e00\u4e2a\u66ff\u4ee3\u53cd\u5e94\u3002\u4ece\u673a\u7406\u4e0a\u6765\u770b\uff0cSeyferth-Gilbert\u53cd\u5e94\u548cHEW\u53cd\u5e94\u7684\u673a\u7406\u975e\u5e38\u76f8\u4f3c\uff0c\u90fd\u751f\u6210\u4e86\u6709\u6742\u539f\u5b50\u7684\u56db\u5143\u73af\u4e2d\u95f4\u4f53\uff1a<\/p>\n

    \"\"<\/a><\/p>\n

    \u4e00\u4e2a\u5b9e\u4f8b\uff1aref. 4<\/p>\n

    \"\"<\/a><\/p>\n

    (iii) Seyferth-Gilbert\u53cd\u5e94Ohira-Bestmann\u7684\u6539\u8fdb\uff1a<\/p>\n

    (1) \u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u662fOhira-Bestmann\u8bd5\u5242 (ref. 5):<\/p>\n

    \"\"<\/a><\/p>\n

    (2) ref. 6<\/p>\n

    \"\"<\/a><\/p>\n

    \u53cd\u5e94\u673a\u7406\uff1a<\/p>\n

    \"\"<\/a><\/p>\n

    \u5728Ohira-Bestmann\u7684\u6539\u8fdb\u4e2d\uff0c\u91cd\u6c2e\u78f7\u8bd5\u5242\u662f\u7531\u53cd\u5e94\u4e2d\u7684\u4e59\u9170\u5316\u5408\u7269\u76f4\u63a5\u751f\u6210\u7684\uff0c\u56e0\u6b64\u53cd\u5e94\u4e2d\u7684\u78b1\u53ef\u4ee5\u4f7f\u7528\u78b1\u6027\u8f83\u5f31\u7684\u78b1\u3002<\/p>\n

      \n
    1. \u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u65b9\u6cd5<\/li>\n<\/ol>\n

      (i) \u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94<\/p>\n

      \"\"<\/a><\/p>\n

      \u56e0\u4e3a\u4ea4\u53c9\u590d\u5206\u89e3\u53cd\u5e94\u7684\u6027\u8d28\u6240\u51b3\u5b9a\uff0c\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u901a\u5e38\u662f\u53d1\u751f\u5728\u5206\u5b50\u5185\u7684\u53cd\u5e94\u6216\u8005\u662f\u540c\u79cd\u5206\u5b50\u4e4b\u95f4\u7684\u590d\u5206\u89e3\u53cd\u5e94\u3002\u53e6\u4e00\u4e2a\u53ef\u4ee5\u89e3\u51b3\u7684\u95ee\u9898\u662f\uff0c\u5bf9\u4e8e\u5927\u73af\u5316\u5408\u7269\u4e2d\u53cc\u952e\u7684\u5408\u6210\uff0c\u70ef\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u5e38\u662f\u4e00\u4e2a\u6709\u7528\u7684\u7b56\u7565\uff0c\u4f46\u662f\u9009\u62e9\u6027\u5f80\u5f80\u4e0d\u597d\uff0c\u800c\u901a\u8fc7\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u53ef\u4ee5\u5f97\u5230\u4e09\u952e\uff0c\u518d\u901a\u8fc7\u4f7f\u7528\u9009\u62e9\u6027\u7684\u8fd8\u539f\u8bd5\u5242\uff0c\u5c31\u53ef\u4ee5\u751f\u6210\u7acb\u4f53\u8f6c\u79fb\u7684Z<\/em>\u6216\u662fE<\/em>\u6784\u5f62\u7684\u53cc\u952e\u4e86\u3002<\/p>\n

      \u53cd\u5e94\u50ac\u5316\u5242\uff1aref. 7, 8<\/p>\n

      \"\"<\/a><\/p>\n

      \u6b64\u5916\u8fd8\u6709\u4e00\u79cd\u66f4\u52a0\u7a33\u5b9a\u4e14\u6613\u64cd\u4f5c\u7684\u50ac\u5316\u5242\uff1aref. 9, 10<\/p>\n

      \"\"<\/a><\/p>\n

      \u53cd\u5e94\u673a\u7406\u548c\u70ef\u70c3\u590d\u5206\u89e3\u5341\u5206\u7c7b\u4f3c\uff1a<\/p>\n

      \"\"<\/a><\/p>\n

      \u5173\u73af\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\uff1aref. 11, 12<\/p>\n

      \"\"<\/a><\/p>\n

      \u5728\u590d\u5206\u89e3\u53cd\u5e94\u4e4b\u540e\u52a0\u5165\u8fd8\u539f\u5242\uff0c\u901a\u8fc7\u63a7\u5236\u8fd8\u539f\u8fc7\u7a0b\u7684\u9009\u62e9\u6027\u53ef\u4ee5\u5f97\u5230\u4e24\u79cd\u4e0d\u540c\u6784\u5f62\u7684\u5927\u73af\u53cc\u952e\u5316\u5408\u7269\u3002\u4f8b\u5982\uff1aref. 13<\/p>\n

      \"\"<\/a><\/p>\n

      \u8fd9\u4e2a\u6b65\u9aa4\u662f\u5408\u6210epothilone C\u4e2d\u7684\u5173\u952e\u6b65\u9aa4\uff0c\u867d\u7136\u53cd\u5e94\u4ea7\u7269\u4e2d\u7684\u53cc\u952e\u53ef\u4ee5\u901a\u8fc7\u70ef\u70c3\u590d\u5206\u89e3\u5f97\u5230\uff0c\u4f46\u662f\u70ef\u70c3\u590d\u5206\u89e3\u53ea\u80fd\u5f97\u5230\u4e24\u79cd\u53cc\u952e\u5f02\u6784\u4f53\u7684\u6df7\u5408\u7269\uff0c\u9009\u62e9\u6027\u4e0d\u597d\u3002<\/p>\n

       <\/p>\n

      REFERENCES<\/strong><\/h4>\n
        \n
      1. Tetrahedron Lett., <\/em>1972, 3769, DOI: 1016\/S0040-4039(01)94157-7<\/a><\/li>\n
      2. Tetrahedron Lett., <\/em>1986, 27, 3059, DOI: 1016\/S0040-4039(00)84716-4<\/a><\/li>\n
      3. J. Org. Chem.<\/em>, 1982<\/strong>, 47<\/em> (22), pp 4181\u20134188, DOI: <\/strong>10.1021\/jo00143a002<\/a><\/li>\n
      4. Angew. Chem. Int. Ed., <\/em>1999, 38, 1652, DOI: 10.1002\/(SICI)1521-3773(19990601)38:11<1652::AID-ANIE1652>3.0.CO;2-K<\/a><\/li>\n
      5. J. Am. Chem. Soc.<\/em>, 2000<\/strong>, 122<\/em> (16), pp 3830\u20133838, DOI: <\/strong>10.1021\/ja994285v<\/a><\/li>\n
      6. J. Am. Chem. Soc.<\/em>, 2002<\/strong>, 124<\/em> (18), pp 4956\u20134957, DOI: <\/strong>10.1021\/ja0258428<\/a><\/li>\n
      7. Organometallics<\/em>, 1985<\/strong>, 4<\/em> (1), pp 74\u201383, DOI: <\/strong>1021\/om00120a014<\/a><\/li>\n
      8. Chem. Eur. J.<\/em>, 2001, 7, 5299, DOI: 10.1002\/1521-3765(20011217)7:24<5299::AID-CHEM5299>3.0.CO;2-X<\/a><\/li>\n
      9. J. Am. Chem. Soc.<\/em>, 2010<\/strong>, 132<\/em> (40), pp 14064\u201314066, DOI: <\/strong>10.1021\/ja107141p<\/a><\/li>\n
      10. J. Am. Chem. Soc.<\/em>, 2010<\/strong>, 132<\/em> (32), pp 11045\u201311057, DOI: <\/strong>10.1021\/ja104800w<\/a><\/li>\n
      11. J. Am. Chem. Soc.<\/em>, 2002<\/strong>, 124<\/em> (27), pp 7922\u20137923, DOI: <\/strong>10.1021\/ja026457l<\/a><\/li>\n
      12. Chem. Commun.<\/em>, 2002<\/strong>, 2182-2183, DOI: 10.1039\/B207169J<\/a><\/li>\n
      13. Chem. Eur. J.<\/em>, 2001, 7, 5299, 10.1002\/1521-3765(20011217)7:24<5299::AID-CHEM5299>3.0.CO;2-X<\/a>S<\/li>\n<\/ol>\n

        \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005 \u5b59\u82cf\u8d5f \u5728\u6709\u673a\u5408\u6210\u4e2d\uff0c\u70ef\u70c3\u548c\u7094\u70c3\u5177\u6709\u5f88\u597d\u7684\u6d3b\u6027\uff0c\u4ed6\u4eec\u4e5f\u53ef\u80fd\u662f\u5929\u7136\u4ea7\u7269\u5f53\u4e2d\u7684\u6d3b\u6027\u90e8\u4f4d\uff0c\u5728\u4e4b\u524d\u5c0f\u7f16\u4e5f\u6709\u4ecb\u7ecd\u4e86\u51e0\u79cd\u53cc\u952e\u5f62\u6210\u7684\u65b9\u6cd5\uff0c\u5305\u62ec\u6bd4\u8f83\u5e38\u7528\u7684Wittig\u53cd\u5e94\uff0cHEW\u53cd\u5e94\uff0c\u70ef\u70c3\u590d\u5206\u89e3\uff0cTakai\u53cd\u5e94\uff0c\u7b49\u7b49\u3002 \u4f17\u6240\u5468\u77e5\uff0c\u70ef\u70c3\u53ef\u4ee5\u901a\u8fc7\u7094\u7684\u8fd8\u539f\u5f97\u5230\uff0c\u5e76\u4e14\u53ef\u4ee5\u901a\u8fc7\u4e0d\u540c\u7684\u53cd\u5e94\u6761\u4ef6\u5f97\u5230\u4e0d\u540c\u6784\u5f62\u7684\u53cc\u952e\uff0c\u4e0b\u8fb9\u662f\u5176\u4e2d\u7684\u4e24\u79cd\u65b9\u6cd5\uff1a \u6362\u53e5\u8bdd\u8bf4\uff0c\u70ef\u548c\u7094\u53ef\u4ee5\u76f8\u4e92\u8f6c\u5316\uff0c\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u7094\u53ef\u4ee5\u88ab\u8fd8\u539f\u6210\u70ef\uff0c\u800c\u70ef\u5728\u4e00\u5b9a\u6761\u4ef6\u4e0b\u70ef\u4e5f\u53ef\u4ee5\u8131\u6c22\u6c27\u5316\u6210\u7094\u3002 \u4e00\u3001\u76f4\u63a5\u6cd5\u751f\u6210\u7094\u70c3 \u5229\u7528\u7fb0\u57fa\u548c\u78f7\u8bd5\u5242\u7684\u65b9\u6cd5 (i) Corey-Fuchs\u53cd\u5e94 ref. 1 \u8fd9\u662f\u4e00\u4e2a\u975e\u5e38\u6709\u7528\u7684\u7528\u4e8e\u751f\u6210\u7094\u70c3\u7684\u4e24\u90e8\u53cd\u5e94\uff0c\u8fd9\u4e2a\u53cd\u5e94\u53ef\u7528\u4e8e\u4ece\u919b\u4e3a\u53cd\u5e94\u5e95\u7269\u5408\u6210\u7aef\u4f4d\u7094\u70c3\u548c\u4e09\u53d6\u4ee3\u7684\u7094\uff1b\u53cd\u5e94\u7684\u7b2c\u4e00\u90e8\u5176\u5b9e\u548cWittig\u53cd\u5e94\u975e\u5e38\u7c7b\u4f3c\u3002 \u53cd\u5e94\u673a\u7406\uff1a \u4e00\u4e2a\u5b9e\u4f8b\uff1aref. 2 (ii) Seyferth-Gilbert\u53cd\u5e94 ref. 3 Seyferth-Gilbert\u53cd\u5e94\u53ef\u4ee5\u5f53\u4f5cSeyferth-Gilbert\u53cd\u5e94\u7528\u4e8e\u5408\u6210\u7aef\u4f4d\u7094\u70c3\u7684\u4e00\u4e2a\u66ff\u4ee3\u53cd\u5e94\u3002\u4ece\u673a\u7406\u4e0a\u6765\u770b\uff0cSeyferth-Gilbert\u53cd\u5e94\u548cHEW\u53cd\u5e94\u7684\u673a\u7406\u975e\u5e38\u76f8\u4f3c\uff0c\u90fd\u751f\u6210\u4e86\u6709\u6742\u539f\u5b50\u7684\u56db\u5143\u73af\u4e2d\u95f4\u4f53\uff1a \u4e00\u4e2a\u5b9e\u4f8b\uff1aref. 4 (iii) Seyferth-Gilbert\u53cd\u5e94Ohira-Bestmann\u7684\u6539\u8fdb\uff1a (1) \u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u662fOhira-Bestmann\u8bd5\u5242 (ref. 5): (2) ref. 6 \u53cd\u5e94\u673a\u7406\uff1a \u5728Ohira-Bestmann\u7684\u6539\u8fdb\u4e2d\uff0c\u91cd\u6c2e\u78f7\u8bd5\u5242\u662f\u7531\u53cd\u5e94\u4e2d\u7684\u4e59\u9170\u5316\u5408\u7269\u76f4\u63a5\u751f\u6210\u7684\uff0c\u56e0\u6b64\u53cd\u5e94\u4e2d\u7684\u78b1\u53ef\u4ee5\u4f7f\u7528\u78b1\u6027\u8f83\u5f31\u7684\u78b1\u3002 \u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u65b9\u6cd5 (i) \u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94 \u56e0\u4e3a\u4ea4\u53c9\u590d\u5206\u89e3\u53cd\u5e94\u7684\u6027\u8d28\u6240\u51b3\u5b9a\uff0c\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u901a\u5e38\u662f\u53d1\u751f\u5728\u5206\u5b50\u5185\u7684\u53cd\u5e94\u6216\u8005\u662f\u540c\u79cd\u5206\u5b50\u4e4b\u95f4\u7684\u590d\u5206\u89e3\u53cd\u5e94\u3002\u53e6\u4e00\u4e2a\u53ef\u4ee5\u89e3\u51b3\u7684\u95ee\u9898\u662f\uff0c\u5bf9\u4e8e\u5927\u73af\u5316\u5408\u7269\u4e2d\u53cc\u952e\u7684\u5408\u6210\uff0c\u70ef\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u5e38\u662f\u4e00\u4e2a\u6709\u7528\u7684\u7b56\u7565\uff0c\u4f46\u662f\u9009\u62e9\u6027\u5f80\u5f80\u4e0d\u597d\uff0c\u800c\u901a\u8fc7\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u53ef\u4ee5\u5f97\u5230\u4e09\u952e\uff0c\u518d\u901a\u8fc7\u4f7f\u7528\u9009\u62e9\u6027\u7684\u8fd8\u539f\u8bd5\u5242\uff0c\u5c31\u53ef\u4ee5\u751f\u6210\u7acb\u4f53\u8f6c\u79fb\u7684Z\u6216\u662fE\u6784\u5f62\u7684\u53cc\u952e\u4e86\u3002 \u53cd\u5e94\u50ac\u5316\u5242\uff1aref. 7, 8 \u6b64\u5916\u8fd8\u6709\u4e00\u79cd\u66f4\u52a0\u7a33\u5b9a\u4e14\u6613\u64cd\u4f5c\u7684\u50ac\u5316\u5242\uff1aref. 9, 10 \u53cd\u5e94\u673a\u7406\u548c\u70ef\u70c3\u590d\u5206\u89e3\u5341\u5206\u7c7b\u4f3c\uff1a \u5173\u73af\u7094\u70c3\u590d\u5206\u89e3\u53cd\u5e94\uff1aref. 11, 12 \u5728\u590d\u5206\u89e3\u53cd\u5e94\u4e4b\u540e\u52a0\u5165\u8fd8\u539f\u5242\uff0c\u901a\u8fc7\u63a7\u5236\u8fd8\u539f\u8fc7\u7a0b\u7684\u9009\u62e9\u6027\u53ef\u4ee5\u5f97\u5230\u4e24\u79cd\u4e0d\u540c\u6784\u5f62\u7684\u5927\u73af\u53cc\u952e\u5316\u5408\u7269\u3002\u4f8b\u5982\uff1aref. 13 \u8fd9\u4e2a\u6b65\u9aa4\u662f\u5408\u6210epothilone C\u4e2d\u7684\u5173\u952e\u6b65\u9aa4\uff0c\u867d\u7136\u53cd\u5e94\u4ea7\u7269\u4e2d\u7684\u53cc\u952e\u53ef\u4ee5\u901a\u8fc7\u70ef\u70c3\u590d\u5206\u89e3\u5f97\u5230\uff0c\u4f46\u662f\u70ef\u70c3\u590d\u5206\u89e3\u53ea\u80fd\u5f97\u5230\u4e24\u79cd\u53cc\u952e\u5f02\u6784\u4f53\u7684\u6df7\u5408\u7269\uff0c\u9009\u62e9\u6027\u4e0d\u597d\u3002   REFERENCES Tetrahedron Lett., 1972, 3769, DOI: 1016\/S0040-4039(01)94157-7 Tetrahedron Lett., 1986, 27, 3059, DOI: 1016\/S0040-4039(00)84716-4 J. Org. Chem., 1982, 47 (22), pp 4181\u20134188, DOI: 10.1021\/jo00143a002 Angew. Chem. Int. Ed., 1999, 38, 1652, DOI: 10.1002\/(SICI)1521-3773(19990601)38:11<1652::AID-ANIE1652>3.0.CO;2-K J. Am. Chem. Soc., 2000, 122 (16), pp 3830\u20133838, DOI: 10.1021\/ja994285v J. Am. Chem. Soc., 2002, 124 (18), pp 4956\u20134957, DOI: 10.1021\/ja0258428 Organometallics, 1985, 4 […]","protected":false},"author":8,"featured_media":19963,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[414],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/07\/1167b765267b0f9fabaae1fe0e8b76c6.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-58h","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/19733"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=19733"}],"version-history":[{"count":6,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/19733\/revisions"}],"predecessor-version":[{"id":27047,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/19733\/revisions\/27047"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/19963"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=19733"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=19733"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=19733"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}