{"id":20372,"date":"2018-09-10T06:30:21","date_gmt":"2018-09-09T22:30:21","guid":{"rendered":"\/\/www.gsbet888.com\/?p=20372"},"modified":"2019-08-02T18:51:17","modified_gmt":"2019-08-02T10:51:17","slug":"iminocarbenoids-derived-from-triazoles-for-transannulations-13-insertions","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2018\/09\/iminocarbenoids-derived-from-triazoles-for-transannulations-13-insertions.html","title":{"rendered":"Iminocarbenoids Derived from Triazoles for Transannulations\/1,3-Insertions"},"content":{"rendered":"<p><strong>N-\u78fa\u9170\u57fa-1,2,3-\u4e09\u5511\u5728\u7fa7\u9178\u94d1\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u3001\u80fd\u591f\u4ea7\u751f\u542b\u6709\u4eb2\u6838\u6027\u7684imine\u57fa\u56e2\u7684\u5361\u5bbe\u4e2d\u95f4\u4f53\u3002\u8be5imina-carbenoid\u4e2d\u95f4\u4f53\u53ef\u4ee5\u8fdb\u800c\u53d1\u751f\u8de8\u73af\u6216\u80051,3-\u63d2\u5165\u53cd\u5e94\u3002<\/strong><\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<p><strong>Review<\/strong><\/p>\n<ul>\n<li>Davies, H. M. L.; Alford, J. S. <i>Chem. Soc. Rev.<\/i> <b>2014<\/b>, <i>43<\/i>, 5151. DOI:<a href=\"http:\/\/dx.doi.org\/10.1039\/C4CS00072B\">10.1039\/C4CS00072B<\/a><\/li>\n<li>Chattopadhyay, B.; Gevorgyan, V. <i>Angew. Chem.<\/i>,<i> Int. Ed.<\/i> <b>2012<\/b>, <i>51<\/i>, 862. DOI:<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.201104807\">10.1002\/anie.201104807<\/a><\/li>\n<\/ul>\n<h4>\u80cc\u666f: \u4ece<strong>\u4e09\u5511\u8f6c\u5316\u4e3a\u5361\u5bbe\u6d3b\u6027\u4e2d\u95f4\u4f53<\/strong><\/h4>\n<p>1,2,3-\u4e09\u5511\u53ef\u4ee5\u901a\u8fc7\u53e0\u6c2e\u4e0e\u7094\u70c3\u7684<a href=\"\/\/www.gsbet888.com\/reactions\/2016\/04\/post-9339.html\">click\u53cd\u5e94<\/a>\u8fdb\u884c\u5408\u6210\u3001\u662f\u4e00\u79cd\u82b3\u9999\u65cf\u5316\u5408\u7269<sup>[3]<\/sup>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-medium wp-image-20374\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/d790665566f014a9ec88d4f5ce24d7a6-300x110.png\" alt=\"\" width=\"300\" height=\"110\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/d790665566f014a9ec88d4f5ce24d7a6-300x110.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/d790665566f014a9ec88d4f5ce24d7a6.png 400w\" sizes=\"(max-width: 300px) 100vw, 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Rearrangement via A Conjugated 1,3-Dipole<\/a><\/li>\n<li><a href=\"\/\/www.gsbet888.com\/reactions\/2014\/11\/%e9%87%91%e5%b1%9e%e5%8d%a1%e5%ae%be%e7%9a%84c-h%e6%8f%92%e5%85%a5%e5%8f%8d%e5%ba%94c-h-insertion-of-metal-carbenoid.html\">C\u2014H Insertion of Metal Carbenoid<\/a><\/li>\n<\/ul>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li>Davies, H. M. L.; Alford, J. S. <i>Chem. Soc. Rev.<\/i> <b>2014<\/b>, <i>43<\/i>, 5151. DOI:<a href=\"http:\/\/dx.doi.org\/10.1039\/C4CS00072B\">10.1039\/C4CS00072B<\/a><\/li>\n<li>Chattopadhyay, B.; Gevorgyan, V. <i>Angew. Chem.<\/i>,<i> Int. Ed.<\/i> <b>2012<\/b>, <i>51<\/i>, 862. DOI:<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.201104807\">10.1002\/anie.201104807<\/a><\/li>\n<li>\u00a0Raushel, J.; Fokin, V. V. <em>Org. Lett.<\/em> <strong>2010<\/strong>, <em>12<\/em>, 4952. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ol102087r\">10.1021\/ol102087r<\/a><\/li>\n<li>[a] Harmon, R. E.; Stanley, F. Jr.; Gupta, S. K.; Johnson, J.\u00a0<em>J. Org. Chem.\u00a0<\/em><strong>1970<\/strong>,\u00a0<em>35<\/em>, 3444. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo00835a057\">10.1021\/jo00835a057 <\/a>[b]\u00a0L\u2019abb\u00e9, G.\u00a0<em>Bull. Soc. Chim. Belg.\u00a0<\/em><strong>1990<\/strong><em>,\u00a0<\/em><em>99<\/em>, 281\u2013290. DOI: <a class=\"epub-doi\" href=\"https:\/\/doi.org\/10.1002\/bscb.19900990410\">10.1002\/bscb.19900990410<\/a><\/li>\n<li>Nakamura, E.; Yoshikai, N.; Yamanaka, M.\u00a0<em>J. Am. Chem. Soc.<\/em>\u00a0<strong>2002<\/strong>,\u00a0<em>124<\/em>, 7181.DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja017823o\">10.1021\/ja017823o<\/a><\/li>\n<li>\u8de8\u73af\u662fTransannulation\u7684\u4e2d\u8bd1<\/li>\n<li>Chattopadhyay, B.; Gevorgyan, V.\u00a0<em>Org. Lett.<\/em>\u00a0<strong>2011<\/strong>,<em>13<\/em>, 3746. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ol2014347\">10.1021\/ol2014347<\/a><\/li>\n<li>Kwok, S. W.; Zhang, L.; Grimster, N. P.; Fokin, V. V. <em>Angew. Chem., Int. Ed<\/em>. <strong>2014<\/strong>, <em>53<\/em>, 3452. DOI: <a class=\"epub-doi\" href=\"https:\/\/doi.org\/10.1002\/anie.201306706\">10.1002\/anie.201306706<\/a><\/li>\n<li>\u4ece\u70ef\u70c3\u5f97\u5230\u4e8c\u6c22\u5421\u54af\u7684\u53cd\u5e94\uff0c\u8be6\u7ec6\u53c2\u8003\u6587\u732e[8].<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-20381 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/8b78596f173c119f742f7d023617ab86.png\" alt=\"\" width=\"668\" height=\"138\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/8b78596f173c119f742f7d023617ab86.png 668w, https:\/\/assets.www.gsbet888.com\/uploads\/2018\/09\/8b78596f173c119f742f7d023617ab86-300x62.png 300w\" sizes=\"(max-width: 668px) 100vw, 668px\" \/><\/li>\n<li>Zibinsky, M.; Fokin, V. V. <em>Angew. Chem., Int. Ed.<\/em> <strong>2013<\/strong>, <em>52<\/em>, 1507. DOI:\u00a0<a class=\"epub-doi\" href=\"https:\/\/doi.org\/10.1002\/anie.201206388\">10.1002\/anie.201206388<\/a><\/li>\n<li>Horneff, T.; Chuprakov, S.; Chernyak, N.; Gevorgyan, V.; Fokin, V. V.\u00a0<em>J. Am. Chem. Soc.<\/em>\u00a0<strong>2008,\u00a0<\/strong><em>130<\/em>, 14972. DOI;\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja805079v\">10.1021\/ja805079v<\/a><\/li>\n<li>\u00a0Chuprakov, S.; Worrell, B. T.; Selander, N.; Sit, R. K.; Fokin, V. V. <em>J. Am. Chem. Soc.<\/em> <strong>2014<\/strong>, <em>136<\/em>, 195. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja408185c\">10.1021\/ja408185c<\/a><\/li>\n<li>Kubiak, R. W. II; Mighion, J. D.; Wilkerson-Hill, S. M.; Alford, J. S.; Yoshidomi, T.; Davies, H. M. L. <em>Org. Lett. <\/em><strong>2016<\/strong>, <em>18<\/em>, 3118. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/acs.orglett.6b01298\">10.1021\/acs.orglett.6b01298<\/a><\/li>\n<li>Miura, T.; Biyajima, T.; Fujii, T.; Murakami, M. <em>J. Am. Chem. Soc. <\/em><strong>2012<\/strong>, <em>134<\/em>, 194. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/ja308285r\">\u00a010.1021\/ja308285r<\/a><\/li>\n<\/ol>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n<p>&nbsp; <\/p>\n","protected":false},"excerpt":{"rendered":"N-\u78fa\u9170\u57fa-1,2,3-\u4e09\u5511\u5728\u7fa7\u9178\u94d1\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u3001\u80fd\u591f\u4ea7\u751f\u542b\u6709\u4eb2\u6838\u6027\u7684imine\u57fa\u56e2\u7684\u5361\u5bbe\u4e2d\u95f4\u4f53\u3002\u8be5imina-carbenoid\u4e2d\u95f4\u4f53\u53ef\u4ee5\u8fdb\u800c\u53d1\u751f\u8de8\u73af\u6216\u80051,3-\u63d2\u5165\u53cd\u5e94\u3002 \u57fa\u672c\u6587\u732e Review Davies, H. M. L.; Alford, J. S. Chem. Soc. Rev. 2014, 43, 5151. DOI:10.1039\/C4CS00072B Chattopadhyay, B.; Gevorgyan, V. Angew. Chem., Int. Ed. 2012, 51, 862. 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M. L.; Alford, J. S. Chem. Soc. Rev. 2014, 43, 5151. DOI:10.1039\/C4CS00072B Chattopadhyay, B.; Gevorgyan, V. Angew. Chem., Int. Ed. 2012, 51, 862. DOI:10.1002\/anie.201104807 \u00a0Raushel, J.; Fokin, V. V. 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