{"id":2213,"date":"2014-07-22T22:31:34","date_gmt":"2014-07-22T14:31:34","guid":{"rendered":"\/\/www.gsbet888.com\/?p=2213"},"modified":"2019-08-02T18:56:31","modified_gmt":"2019-08-02T10:56:31","slug":"%e9%9c%8d%e5%a4%ab%e6%9b%bc%e6%b6%88%e9%99%a4-hofmann-elimination","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e6%b6%88%e9%99%a4%e5%8f%8d%e5%ba%94\/2014\/07\/%e9%9c%8d%e5%a4%ab%e6%9b%bc%e6%b6%88%e9%99%a4-hofmann-elimination.html","title":{"rendered":"\u970d\u592b\u66fc\u6d88\u9664 Hofmann Elimination"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n<p>\u56db\u7ea7\u80fa\u76d0\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7E1cB\u6d88\u9664\u53cd\u5e94\uff0c\u4f18\u5148\u751f\u6210\u53d6\u4ee3\u57fa\u5c11\u7684\u70ef\u70c3\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u4e0d\u4f1a\u53d1\u751f\u78b3\u9aa8\u67b6\u91cd\u6392\uff0c\u6240\u4ee5\u8be5\u53cd\u5e94\u5e38\u5e38\u7528\u6765\u9a8c\u8bc1\u751f\u7269\u78b1\u7684\u9aa8\u67b6\u6784\u9020\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>\u30fbHofmann, A.W.\u00a0<em>Ann.<\/em>\u00a0<strong style=\"color: #ff6600\">1851<\/strong>,\u00a0<em>78<\/em>, 253.<br \/>\n\u30fbHofmann, A.W.\u00a0<em>Ann.<\/em><strong style=\"color: #ff6600\">\u00a01851<\/strong>,\u00a0<em>79<\/em>, 2203.<br \/>\n\u30fbHofmann, A.W.\u00a0<em>Ber.<\/em>\u00a0<strong style=\"color: #ff6600\">1881<\/strong>,\u00a0<em>14<\/em>, 659.<br \/>\n\u30fbCope, A.C.; Trumbull, E.R.\u00a0<em>Org. React.<\/em>\u00a0<strong style=\"color: #ff6600\">1960<\/strong>,\u00a0<em>11<\/em>, 317.<br \/>\n\u30fbDePuy, C.H.; King, R.W.\u00a0<em>Chem. Rev.\u00a0<\/em><strong style=\"color: #ff6600\">1960<\/strong>,\u00a0<em>60<\/em>, 431. DOI:\u00a0<a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1021\/cr60207a001\">10.1021\/cr60207a001<\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u56db\u7ea7\u80fa\u6216\u8005\u950d\u7684\u79bb\u53bb\u80fd\u6bd4\u8f83\u4f4e\uff0c\u8be5\u53cd\u5e94\u662f\u7ecf\u7531<strong style=\"color: #ff6600\">E1cB\u6216E2\u673a\u7406<\/strong>\u8fdb\u884c\u7684\u6d88\u9664\u53cd\u5e94\u3002\u78b3\u8d1f\u79bb\u5b50\u5bb9\u6613\u4ea7\u751f\u5728\u7ea7\u4f4e\u7684\u78b3\u539f\u5b50\u4e0a\uff0c\u6240\u4ee5\u8be5\u53cd\u5e94\u5177\u6709\u4e0eZaitsev\u6cd5\u5219\u76f8\u53cd\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/n-ene-6.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-2215\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/n-ene-6.gif\" alt=\"n-ene-6\" width=\"360\" height=\"80\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>\u901a\u5e38\u751f\u6210\u53d6\u4ee3\u57fa\u5c11\u7684\u70ef\u70c3\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/hofmann_elim_3.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-2216\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/hofmann_elim_3.gif\" alt=\"hofmann_elim_3\" width=\"346\" height=\"96\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>&nbsp; <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u56db\u7ea7\u80fa\u76d0\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7E1cB\u6d88\u9664\u53cd\u5e94\uff0c\u4f18\u5148\u751f\u6210\u53d6\u4ee3\u57fa\u5c11\u7684\u70ef\u70c3\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u4e0d\u4f1a\u53d1\u751f\u78b3\u9aa8\u67b6\u91cd\u6392\uff0c\u6240\u4ee5\u8be5\u53cd\u5e94\u5e38\u5e38\u7528\u6765\u9a8c\u8bc1\u751f\u7269\u78b1\u7684\u9aa8\u67b6\u6784\u9020\u3002 &nbsp; \u57fa\u672c\u6587\u732e \u30fbHofmann, A.W.\u00a0Ann.\u00a01851,\u00a078, 253. \u30fbHofmann, A.W.\u00a0Ann.\u00a01851,\u00a079, 2203. \u30fbHofmann, A.W.\u00a0Ber.\u00a01881,\u00a014, 659. \u30fbCope, A.C.; Trumbull, E.R.\u00a0Org. React.\u00a01960,\u00a011, 317. \u30fbDePuy, C.H.; King, R.W.\u00a0Chem. Rev.\u00a01960,\u00a060, 431. DOI:\u00a010.1021\/cr60207a001 &nbsp; \u53cd\u5e94\u673a\u7406 \u56db\u7ea7\u80fa\u6216\u8005\u950d\u7684\u79bb\u53bb\u80fd\u6bd4\u8f83\u4f4e\uff0c\u8be5\u53cd\u5e94\u662f\u7ecf\u7531E1cB\u6216E2\u673a\u7406\u8fdb\u884c\u7684\u6d88\u9664\u53cd\u5e94\u3002\u78b3\u8d1f\u79bb\u5b50\u5bb9\u6613\u4ea7\u751f\u5728\u7ea7\u4f4e\u7684\u78b3\u539f\u5b50\u4e0a\uff0c\u6240\u4ee5\u8be5\u53cd\u5e94\u5177\u6709\u4e0eZaitsev\u6cd5\u5219\u76f8\u53cd\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u3002 &nbsp; &nbsp; \u53cd\u5e94\u5b9e\u4f8b \u901a\u5e38\u751f\u6210\u53d6\u4ee3\u57fa\u5c11\u7684\u70ef\u70c3\u3002 &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e &nbsp;","protected":false},"author":5,"featured_media":2214,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[315],"tags":[363,362],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/n-ene-8.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-zH","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2213"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=2213"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2213\/revisions"}],"predecessor-version":[{"id":28129,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2213\/revisions\/28129"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/2214"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=2213"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=2213"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=2213"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}