{"id":22135,"date":"2018-12-29T17:31:56","date_gmt":"2018-12-29T09:31:56","guid":{"rendered":"\/\/www.gsbet888.com\/?p=22135"},"modified":"2019-08-02T18:50:56","modified_gmt":"2019-08-02T10:50:56","slug":"%e5%8c%96%e5%ad%a6%e7%a9%ba%e9%97%b42018%e5%b9%b4%e4%ba%ba%e6%b0%94%e8%ae%b0%e4%ba%8b%e6%8e%92%e8%a1%8c%e6%a6%9c","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemnews\/2018\/12\/%e5%8c%96%e5%ad%a6%e7%a9%ba%e9%97%b42018%e5%b9%b4%e4%ba%ba%e6%b0%94%e8%ae%b0%e4%ba%8b%e6%8e%92%e8%a1%8c%e6%a6%9c.html","title":{"rendered":"\u5316\u5b66\u7a7a\u95f42018\u5e74\u4eba\u6c14\u8bb0\u4e8b\u6392\u884c\u699c"},"content":{"rendered":"

2018\u5e74\u4e0d\u77e5\u4e0d\u89c9\u5df2\u7ecf\u53c8\u8981\u7ed3\u675f\u4e86\uff0c\u5316\u5b66\u7a7a\u95f4\u4e5f\u8d70\u5b8c\u4e86\u7b2c\u4e94<\/strong>\u4e2a\u5e74\u5934\u30022018\u5e74\u5316\u5b66\u7a7a\u95f4\u603b\u5171\u520a\u767b\u8bb0\u4e8b256\u7bc7<\/strong>\uff0c\u57fa\u672c\u4e0a\u9664\u4e86\u5468\u672b\u8282\u5047\u65e5\uff0c\u6bcf\u5929\u575a\u6301\u4fdd\u6301\u81f3\u5c11\u4e00\u7bc7<\/strong>\u66f4\u65b0\uff0c\u8fd9\u4e94\u5e74\u6765\uff0c\u5230\u4eca\u5929\u4e3a\u6b62\uff0c\u603b\u5171\u64b0\u5199\u520a\u767b\u8bb0\u4e8b1365\u7bc7<\/strong>\uff0c\u5404\u4f4d\u70ed\u7231\u5316\u5b66\u7684\u5c0f\u7f16\u4eec\u8f9b\u82e6\u4e86\uff01\u540c\u65f6\u611f\u8c22\u4e00\u76f4\u4ee5\u6765\u5173\u6ce8\u6211\u4eec\u7684\u8bfb\u8005\u670b\u53cb\u4eec\uff0c\u4f60\u4eec\u7684\u652f\u6301\u662f\u6211\u4eec\u7684\u52a8\u529b\u3002\u5e0c\u671b\u4f60\u4eec\u7ee7\u7eed\u5173\u6ce8\u5316\u5b66\u7a7a\u95f4\uff0c\u540c\u65f6\u7ee7\u7eed\u63d0\u51fa\u4f60\u4eec\u5b9d\u8d35\u7684\u610f\u89c1\u548c\u5efa\u8bae\uff0c\u8ba9\u6211\u4eec\u7684\u5185\u5bb9\u66f4\u52a0\u4e25\u8c28\uff0c\u51c6\u786e\u30022019\u5e74\uff0c\u5e0c\u671b\u4e5f\u80fd\u6709\u66f4\u591a\u7684\u5bf9\u5316\u5b66\u611f\u5174\u8da3\u7684\u4eba\u52a0\u5165\u6211\u4eec\uff0c\u4e00\u8d77\u4ea4\u6d41\uff0c\u4e00\u8d77\u5ba3\u4f20\u5316\u5b66\uff01<\/p>\n

\u5728\u65b0\u5e74\u5f00\u59cb\u4e4b\u524d\uff0c\u6211\u4eec\u5c31\u5bf9\u8fc7\u53bb\u4e00\u5e74\u7684\u4eba\u6c14\u8bb0\u4e8b\u505a\u4e00\u4e2a\u56de\u987e\u5427\uff1a<\/p>\n

\u4eba\u6c14\u53cd\u5e94\u6392\u884c\u699cTOP3\uff1a<\/h4>\n

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Passerini \u53cd\u5e94<\/a>\u00a0\u00a04,142 views<\/span><\/p>\n

\u5f02\u8148\u662f\u4e00\u7c7b\u72ec\u7279\u7684\u6709\u673a\u7269\uff0c\u53ef\u4ee5\u540c\u65f6\u4e0e\u4eb2\u7535\u8bd5\u5242\u3001\u4eb2\u6838\u8bd5\u5242\u53cd\u5e94\u3002\u5f02\u8148\u5728\u5408\u6210\u4e0a\u6709\u7528\u9014\u7684\u7b2c\u4e00\u4e2a\u53cd\u5e94\u662f\u7531M.Passerini\u62a5\u9053\u7684\uff0c\u4ed6\u63d0\u51fa\u5f02\u8148\u548c\u7fa7\u9178\u8fd8\u6709\u7fb0\u57fa\u5316\u5408\u7269(\u919b\u6216\u916e)\u4e00\u6b65\u53cd\u5e94\u53ef\u5f97\u5230-\u9170\u6c27\u57fa\u9170\u80fa\uff0c\u4e5f\u5c31\u662f\u73b0\u5728\u6240\u719f\u77e5\u7684Passerini multicomponent reaction(MCR)\u3002<\/p>\n

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\u5b89\u606f\u9999\u7f29\u5408\u53cd\u5e94(Benzoin Condensation)<\/a><\/p>\n

\u4e8c\u5f53\u91cf\u7684\u82b3\u919b\uff0c\u5728\u6c30\u57fa\u6e90\u4eb2\u6838\u50ac\u5316\u5242\u7684\u5b58\u5728\u4e0b\uff0c\u81ea\u8eab\u8fdb\u884c\u7f29\u5408\u53cd\u5e94\uff0c\u5f62\u6210\u5b89\u606f\u9999\u4ea7\u7269\u7684\u53cd\u5e94\u3002<\/p>\n

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PCC\/PDC\u6c27\u5316\u53cd\u5e94 PCC\/PDC Oxidation<\/a> <\/span>\u00a0<\/span><\/p>\n

\u4f7f\u7528\u6c2f\u94ec\u9178\u5421\u5576\u76d0 (Pyridinium Chlorochromate; PCC)<\/strong>\u6216\u662f\u4e8c\u6c2f\u94ec\u9178\u5421\u5576\u76d0 <\/strong>(Pyridinium\u00a0 Dichromate; PDC)<\/strong>\u5bf9\u9187\u8fdb\u884c\u6c27\u5316\u53cd\u5e94\u80fd\u591f\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3001\u5bf9\u542b\u6709\u4e0d\u7a33\u5b9a\u53d6\u4ee3\u57fa\u56e2\u7684\u5e95\u7269\u4e5f\u9002\u7528\u3002\u76f8\u5bf9\u5e94Jones\u6c27\u5316<\/a>\u6216Sarett-Collins\u6c27\u5316<\/a>\u53ef\u4ee5\u5f97\u5230\u916e\u3001\u8fd9\u7c7b\u8bd5\u5242\u3001\u5c24\u5176\u4f7f\u7528PCC\u53ef\u4ee5\u5f97\u5230\u919b\u3002<\/p>\n

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\u5176\u4ed6\u4eba\u6c14\u5e16\u5b50\uff08TOP4-10\uff09<\/p>\n