{"id":2218,"date":"2014-07-28T08:37:46","date_gmt":"2014-07-28T00:37:46","guid":{"rendered":"\/\/www.gsbet888.com\/?p=2218"},"modified":"2019-08-02T18:56:30","modified_gmt":"2019-08-02T10:56:30","slug":"balz-schiemann-reaction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2014\/07\/balz-schiemann-reaction.html","title":{"rendered":"Balz-Schiemann Reaction"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n<p>\u8fd9\u662f\u4e2a\u82b3\u9999\u91cd\u6c2e\u76d0\u4e0e\u6c1f\u787c\u9178\u53cd\u5e94\u751f\u6210\u7684\u6c1f\u787c\u9178\u91cd\u6c2e\u76d0\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u5206\u89e3\uff0c\u5e76\u5728\u82b3\u9999\u73af\u4e0a\u5f15\u5165\u6c1f\u7684\u53cd\u5e94\u3002\u4e00\u822c\u7684\u91cd\u6c2e\u76d0\u5e72\u71e5\u7684\u8bdd\u5bb9\u6613\u7206\u70b8\uff0c\u975e\u5e38\u5371\u9669\uff0c\u4f46\u56db\u6c1f\u787c\u9178\u76d0\u786e\u662f\u4f8b\u5916\u7684\u7a33\u5b9a\u3002\u5e72\u71e5\u540e\u7684\u56db\u6c1f\u787c\u9178\u76d0\u53ef\u4ee5\u7a33\u5b9a\u7684\u88ab\u5206\u89e3\uff0c\u751f\u6210\u82b3\u9999\u6c1f\u5316\u7269\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>\u30fbBalz, G.; Schiemann, G.\u00a0<em>Ber.<\/em>\u00a0<strong style=\"color: #ff6600\">1927<\/strong>,\u00a0<em>60<\/em>, 1186. doi:<a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1002\/cber.19270600539\">10.1002\/cber.19270600539<\/a><br \/>\n\u30fbRoe, A.\u00a0<em>Org. React.<\/em>\u00a0<strong style=\"color: #ff6600\">1949<\/strong>,\u00a0<em>5<\/em>, 193.<br \/>\n\u30fbSuschitzky, H.\u00a0<em>Adv. Fluorine Chem.<\/em>\u00a0<strong style=\"color: #ff6600\">1965<\/strong>,\u00a0<em>4<\/em>, 1.<br \/>\n\u30fbAl&#8217;sing, T. K.; Sochilin, E. G.\u00a0<em>Zh. Org. Khim.<\/em>\u00a0<strong style=\"color: #ff6600\">1970<\/strong>,\u00a0<em>7<\/em>, 530.<br \/>\n\u30fbBecker, H. G. O.; Israel, G.\u00a0<em>J. Prakt. Chem.<\/em>\u00a0<strong style=\"color: #ff6600\">1979<\/strong>,\u00a0<em>321<\/em>, 579.<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u53cd\u5e94\u673a\u7406\u88ab\u8ba4\u4e3a\u8ddf<a style=\"color: #669900\" href=\"http:\/\/www.chem-station.com\/user-cgi-bin\/odoos\/ps_search.cgi?act=jump&amp;access=1&amp;url=http%3a%2f%2fwww%2echem%2dstation%2ecom%2fodos%2f2009%2f06%2fsandmeyer%2dsandmeyer%2dreaction%2ehtml\">Sandmeyer\u53cd\u5e94<\/a>\u7c7b\u4f3c\u3001\u5177\u4f53\u8fd8\u4e0d\u660e\u786e\u3002<br \/>\n(\u53c2\u8003\uff1a<a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1021\/ja00837a019\">\u00a0<em>J. Am. Chem. Soc.<\/em>\u00a0<strong style=\"color: #ff6600\">1975<\/strong>,\u00a0<em>97<\/em>, 799.<\/a>\u3001<em><a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1021\/ja00437a084\">J. Am. Chem. Soc.<\/a><\/em>\u00a0<a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1021\/ja00437a084\"><strong style=\"color: #ff6600\">1976<\/strong>,\u00a0<em>98<\/em>, 6753.<\/a>\uff09<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/schiemann_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-2219\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/schiemann_2.gif\" alt=\"schiemann_2\" width=\"710\" height=\"109\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p style=\"text-align: center\"><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong><a href=\"\/\/www.gsbet888.com\/\"><strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a><strong>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u8fd9\u662f\u4e2a\u82b3\u9999\u91cd\u6c2e\u76d0\u4e0e\u6c1f\u787c\u9178\u53cd\u5e94\u751f\u6210\u7684\u6c1f\u787c\u9178\u91cd\u6c2e\u76d0\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u5206\u89e3\uff0c\u5e76\u5728\u82b3\u9999\u73af\u4e0a\u5f15\u5165\u6c1f\u7684\u53cd\u5e94\u3002\u4e00\u822c\u7684\u91cd\u6c2e\u76d0\u5e72\u71e5\u7684\u8bdd\u5bb9\u6613\u7206\u70b8\uff0c\u975e\u5e38\u5371\u9669\uff0c\u4f46\u56db\u6c1f\u787c\u9178\u76d0\u786e\u662f\u4f8b\u5916\u7684\u7a33\u5b9a\u3002\u5e72\u71e5\u540e\u7684\u56db\u6c1f\u787c\u9178\u76d0\u53ef\u4ee5\u7a33\u5b9a\u7684\u88ab\u5206\u89e3\uff0c\u751f\u6210\u82b3\u9999\u6c1f\u5316\u7269\u3002 &nbsp; \u57fa\u672c\u6587\u732e \u30fbBalz, G.; Schiemann, G.\u00a0Ber.\u00a01927,\u00a060, 1186. doi:10.1002\/cber.19270600539 \u30fbRoe, A.\u00a0Org. React.\u00a01949,\u00a05, 193. \u30fbSuschitzky, H.\u00a0Adv. Fluorine Chem.\u00a01965,\u00a04, 1. \u30fbAl&#8217;sing, T. K.; Sochilin, E. G.\u00a0Zh. Org. Khim.\u00a01970,\u00a07, 530. \u30fbBecker, H. G. O.; Israel, G.\u00a0J. Prakt. Chem.\u00a01979,\u00a0321, 579. &nbsp; \u53cd\u5e94\u673a\u7406 \u53cd\u5e94\u673a\u7406\u88ab\u8ba4\u4e3a\u8ddfSandmeyer\u53cd\u5e94\u7c7b\u4f3c\u3001\u5177\u4f53\u8fd8\u4e0d\u660e\u786e\u3002 (\u53c2\u8003\uff1a\u00a0J. Am. Chem. Soc.\u00a01975,\u00a097, 799.\u3001J. Am. Chem. Soc.\u00a01976,\u00a098, 6753.\uff09 &nbsp; \u53cd\u5e94\u5b9e\u4f8b &nbsp; &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d","protected":false},"author":5,"featured_media":2456,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[365,364],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/07\/n-x-2.2.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-zM","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2218"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=2218"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2218\/revisions"}],"predecessor-version":[{"id":28128,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2218\/revisions\/28128"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/2456"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=2218"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=2218"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=2218"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}