{"id":2267,"date":"2014-07-15T08:39:11","date_gmt":"2014-07-15T00:39:11","guid":{"rendered":"\/\/www.gsbet888.com\/?p=2267"},"modified":"2019-08-02T18:56:29","modified_gmt":"2019-08-02T10:56:29","slug":"castro-stephens%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94castro-stephens-coupling","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94\/2014\/07\/castro-stephens%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94castro-stephens-coupling.html","title":{"rendered":"Castro\u2013Stephens\u5076\u8054\u53cd\u5e94(Castro-Stephens Coupling)"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n<p>\u5316\u5b66\u8ba1\u91cf\u4e00\u5f53\u91cf\u7684\u4e00\u4ef7\u94dc\u4e0e\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u5408\u6210\u7094\u82ef\u7684\u53cd\u5e94\u3002<\/p>\n<p>\u52a0\u5165\u50ac\u5316\u91cf\u7684Pd(0)\u7684\u8bdd\uff0c\u53ef\u4ee5\u628a\u94dc\u7684\u91cf\u51cf\u5c11\u5230\u50ac\u5316\u91cf\u8fdb\u884c\u8be5\u53cd\u5e94(<strong style=\"color: #ff6600\">Sonogashira\u5076\u8054)<\/strong>\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>\u30fbCastro, C.E.; Stephens, R. D.\u00a0<em>J. Org. Chem<\/em>.\u00a0<strong style=\"color: #ff6600\">1963<\/strong>,\u00a0<em>28<\/em>, 2163.<br \/>\n\u30fbStephens, R. D.; Castro, C. E.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong style=\"color: #ff6600\">1963<\/strong>,\u00a0<em>28<\/em>, 3313. DOI:\u00a0<a style=\"color: #669900\" href=\"http:\/\/dx.doi.org\/10.1021\/jo01047a008\">10.1021\/jo01047a008<\/a><br \/>\n\u30fbPosner, G. H.\u00a0<em>Org. React.<\/em>\u00a0<strong style=\"color: #ff6600\">1975<\/strong>,\u00a0<em>22<\/em>, 253.<br \/>\n\u30fbSladkov, A. M.; Gol&#8217;ding, I. R.\u00a0<em>Russ. Chem. Rev.<\/em>\u00a0<strong style=\"color: #ff6600\">1979<\/strong>,\u00a0<em>48<\/em>, 868.<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u5982\u56fe\u6240\u793a\u3001\u4e59\u7094\u94dc\u2192\u7ecf\u7531\u56db\u5143\u73af\u4e2d\u95f4\u6001\u8fdb\u884c\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/yne-yn6.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-2269\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/yne-yn6.gif\" alt=\"yne-yn6\" width=\"528\" height=\"63\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>&nbsp; <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u5316\u5b66\u8ba1\u91cf\u4e00\u5f53\u91cf\u7684\u4e00\u4ef7\u94dc\u4e0e\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u5408\u6210\u7094\u82ef\u7684\u53cd\u5e94\u3002 \u52a0\u5165\u50ac\u5316\u91cf\u7684Pd(0)\u7684\u8bdd\uff0c\u53ef\u4ee5\u628a\u94dc\u7684\u91cf\u51cf\u5c11\u5230\u50ac\u5316\u91cf\u8fdb\u884c\u8be5\u53cd\u5e94(Sonogashira\u5076\u8054)\u3002 &nbsp; \u57fa\u672c\u6587\u732e \u30fbCastro, C.E.; Stephens, R. D.\u00a0J. Org. Chem.\u00a01963,\u00a028, 2163. \u30fbStephens, R. D.; Castro, C. E.\u00a0J. Org. Chem.\u00a01963,\u00a028, 3313. DOI:\u00a010.1021\/jo01047a008 \u30fbPosner, G. H.\u00a0Org. React.\u00a01975,\u00a022, 253. \u30fbSladkov, A. M.; Gol&#8217;ding, I. R.\u00a0Russ. Chem. Rev.\u00a01979,\u00a048, 868. &nbsp; \u53cd\u5e94\u673a\u7406 \u5982\u56fe\u6240\u793a\u3001\u4e59\u7094\u94dc\u2192\u7ecf\u7531\u56db\u5143\u73af\u4e2d\u95f4\u6001\u8fdb\u884c\u53cd\u5e94\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e &nbsp;","protected":false},"author":5,"featured_media":2268,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[3],"tags":[357,356,141],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/06\/yne-yne11.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-Az","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2267"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=2267"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2267\/revisions"}],"predecessor-version":[{"id":28124,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2267\/revisions\/28124"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/2268"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=2267"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=2267"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=2267"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}