{"id":24797,"date":"2019-04-24T19:39:41","date_gmt":"2019-04-24T11:39:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=24797"},"modified":"2019-04-29T10:43:26","modified_gmt":"2019-04-29T02:43:26","slug":"erik-john-alexanian","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemists\/2019\/04\/erik-john-alexanian.html","title":{"rendered":"Erik John Alexanian"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005 <strong>alberto-caeiro<\/strong><\/p>\n<p>Erik John Alexanian\uff0c\u7f8e\u56fd\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u7f8e\u56fd\u5317\u5361\u7f57\u83b1\u5927\u5b66\u6559\u5802\u5c71\u5206\u6821\u6559\u6388(University of North Carolina, Chapel Hill)\u3002\uff08\u5c01\u9762\u56fe\u4e3a<a href=\"http:\/\/alexanian.chem.unc.edu\/index.html\">\u8bfe\u9898\u7ec4<\/a>\uff0c\u53f31\uff09<\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u7ecf\u5386<\/strong><\/h4>\n<ul>\n<li>2001Harvard University A.B.; Research under Professor Amir Hoveyda at Boston College.<\/li>\n<li>2006Princeton UniversityPh.D.,Erik J. Sorensen.<\/li>\n<li>2006-2008Yale University and University of Illinois Urbana-ChampaignPostdoctoral FellowJohn F. Hartwig.<\/li>\n<li>2008-2014University of North Carolina, Chapel Hill Assistant Professor.<\/li>\n<li>2014-\u73b0\u5728 University of North Carolina, Chapel Hill AssociateProfessor.<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4><strong>\u83b7\u5956\u7ecf\u5386<\/strong><\/h4>\n<ul>\n<li>Harvard College Scholarship 1998 \u2013 2001.<\/li>\n<li>James H. and Louise S. Hekimian Scholarship 1999 \u2013 2001.<\/li>\n<li>Skaggs Postdoctoral Fellowship 2002 \u2013 2003.<\/li>\n<li>Hugh Stott Taylor Fellowship 2003.<\/li>\n<li>Bristol &#8211; Myers Squibb Graduate Fellowship 2004 \u2013 2005.<\/li>\n<li>ACS Division of Organic Chemistry Fellowship 2004 \u2013 2005.<\/li>\n<li>National Institutes of Health Postdoctoral Fellowship 2006 \u2013 2008.<\/li>\n<li>Thieme Chemistry Journal Award 2011.<\/li>\n<li>NSF CAREER Award 2011 \u2013 2016.<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4><strong>\u5de5\u4f5c\u4ecb\u7ecd<\/strong><\/h4>\n<p><strong><em>1.<\/em><\/strong><strong><em>\u7ecf\u70f7\u57fa\u4eb2\u7535\u8bd5\u5242\u7684C-C\u952e\u751f\u6210\u53cd\u5e94<\/em><\/strong><\/p>\n<p>\u91d1\u5c5e\u50ac\u5316\u7684C-C\u5076\u8054\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5f62\u6210C-C\u952e\u7684\u4e00\u79cd\u4e3b\u8981\u65b9\u6cd5\uff0c\u4f46\u4f20\u7edf\u7684\u5076\u8054\u53cd\u5e94\u4e3b\u8981\u4f7f\u7528\u82b3\u57fa\u6216\u70ef\u57fa\u5364\u4ee3\u7269\/\u78fa\u9178\u916f\uff0c\u5bf9\u4e8e\u70f7\u57fa\u4eb2\u7535\u8bd5\u5242\u4f1a\u53d1\u751f\u4e25\u91cd\u7684\u03b2-H\u6d88\u9664\u53cd\u5e94\u3002\u5728\u8fd9\u91cc\uff0cAlexanian\u6559\u6388\u5f00\u53d1\u4e86\u4e00\u7c7b\u65b0\u578b\u7684\u7ecf\u70f7\u57fa\u5364\u4ee3\u7269\u7684C-C\u952e\u5f62\u6210\u53cd\u5e94\uff0c\u901a\u8fc7\u4e0e\u70ef\u70c3\u3001CO\u7b49\u7684\u4e32\u8054\u53cd\u5e94\uff0c\u6709\u6548\u7684\u5408\u6210\u4e00\u7cfb\u5217\u5c0f\u5206\u5b50\u5316\u5408\u7269<sup>\u30101-3\u3011<\/sup>\u3002\u8fd9\u91cc\u4e3b\u8981\u5229\u7528\u7684\u662f\u81ea\u7531\u57fa\u5bf9\u70ef\u70c3\u6216CO\u7684\u52a0\u6210<sup>\u30104\u3011<\/sup>\uff0c\u968f\u540e\u4e0e\u5f15\u53d1\u81ea\u7531\u57fa\u7684Pd(I)\u7ed3\u5408\uff0c\u5f62\u6210Pd(II)\u7ee7\u7eed\u50ac\u5316\u5faa\u73af\uff0c\u8be5\u6a21\u5f0f\u4e3aHeck\u53cd\u5e94\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u6a21\u5f0f\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24799 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12-680x126.png\" alt=\"\" width=\"680\" height=\"126\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12-680x126.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12-300x56.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12-768x142.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2-12.png 1041w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/a> <a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24800 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13-680x249.png\" alt=\"\" width=\"680\" height=\"249\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13-680x249.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13-300x110.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13-768x281.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/3-13.png 1088w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/a><\/p>\n<ol start=\"2\">\n<li><strong><em>\u4f4d\u70b9\u9009\u62e9\u7684\u70f7\u70c3\u8102\u80aaC-H\u952e\u5b98\u80fd\u56e2\u5316<\/em><\/strong><\/li>\n<\/ol>\n<p>\u8102\u80aaC-H\u952e\u7684\u9009\u62e9\u6027\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u5728\u5206\u5b50\u5408\u6210\u4e2d\u6709\u91cd\u8981\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u4f46\u662f\u76ee\u524d\u6709\u5b9e\u9645\u5e94\u7528\u4ef7\u503c\u7684\u6b64\u7c7b\u53cd\u5e94\u8fd8\u662f\u5f88\u5c11\u3002Alexanian\u6559\u6388\u5f00\u53d1\u4e86\u4e00\u79cd\u4ee5\u6742\u539f\u5b50\u4e3a\u4e2d\u5fc3\u7684\u81ea\u7531\u57fa\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86\u6b64\u7c7b\u53cd\u5e94\u4f4d\u70b9\u9009\u62e9\u4e14\u53ef\u9884\u6d4b\uff0c\u4ea7\u7387\u548c\u5e95\u7269\u8303\u56f4\u90fd\u662f\u6709\u5b9e\u9645\u5e94\u7528\u4ef7\u503c\u7684\u53cd\u5e94<sup>\u30105\u3011<\/sup>\u3002\u901a\u8fc7\u5149\u7167\u6b64\u7c7bN-\u6742\u539f\u5b50\u53d6\u4ee3\u7684\u9170\u80fa\uff0c\u9009\u62e9\u6027\u7684\u8102\u80aaC-H\u952eBr\u4ee3<sup>\u30105d\u3011<\/sup>\uff0cCl\u4ee3<sup>\u30105c\u3011<\/sup>\uff0c\u9ec4\u539f\u9178\u916f<sup>\u30105b\u3011<\/sup>\u53d6\u4ee3\u53cd\u5e94\u90fd\u53ef\u5b9e\u73b0\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u6709\u673a\u5149\u50ac\u5316\u5242\u5416\u5576\u7684\u50ac\u5316\uff0c\u8fd8\u53ef\u5b9e\u73b0\u9009\u62e9\u6027\u7684\u8102\u80aaC-H\u952e\u7684\u53e0\u6c2e\u53d6\u4ee3\u3002\u6b64\u5916\uff0cAlexanian\u6559\u6388\u8fd8\u5c06\u6b64\u7c7b\u65b9\u6cd5\u7528\u5230\u4e86\u9ad8\u5206\u5b50\u94fe\u6bb5\u7684\u6539\u6027\u4e2d<sup>\u30105e\u3011<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/4-11.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24801 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/4-11.png\" alt=\"\" width=\"519\" height=\"600\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/4-11.png 519w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/4-11-260x300.png 260w\" sizes=\"(max-width: 519px) 100vw, 519px\" \/><\/a><\/p>\n<p><strong><em>3.<\/em><\/strong><strong><em>\u7ecf\u5f02\u7f9f\u809f\u9178\u7684\u70ef\u70c3\u53cc\u5b98\u80fd\u56e2\u5316<\/em><\/strong><\/p>\n<p>\u901a\u8fc7\u5f02\u7f9f\u809f\u9178\u6d3b\u6cfc\u7684O-H\u952e\uff0cAlexanian\u6559\u6388\u5b9e\u73b0\u4e86\u65e0\u9700\u91d1\u5c5e\u7684\u70ef\u70c3\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94<sup>\u30106\u3011<\/sup>\uff0c\u5176\u4e2d\u5373\u53ef\u901a\u8fc7\u4eb2\u6838\u52a0\u6210\u9014\u5f84\uff0c\u4e5f\u53ef\u901a\u8fc7\u81ea\u7531\u57fa\u9014\u5f84\uff0c\u70ef\u70c3\u5b98\u80fd\u56e2\u5316\u540e\u4ea7\u7269\u53ef\u4ee5\u662f\u53cc\u7f9f\u5316\u3001\u7f9f\u80fa\u5316\u3001\u03b1-\u7f9f\u57fa\u916e\u7b49\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/5-11.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24802 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/5-11.png\" alt=\"\" width=\"445\" height=\"590\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/5-11.png 445w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/5-11-226x300.png 226w\" sizes=\"(max-width: 445px) 100vw, 445px\" \/><\/a><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ol>\n<li>Brendon T. Sargent.; Erik J. Alexanian, <em>J. Am. Chem. Soc.<\/em><strong>2017<\/strong>, <em>139<\/em>, 12438. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b07983\">DOI: 10.1021\/jacs.7b07983<\/a>;<\/li>\n<li>Alexander R. O. Venning,; Megan R. Kwiatkowski.; Joan E. Roque Pena.; Brendan C. Lainhart.; Akil A. Guruparan.; Erik J. Alexanian.<em>J. Am. Chem. Soc.<\/em><strong>2017<\/strong>, <em>139<\/em>, 11595. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b06794\">DOI: 10.1021\/jacs.7b06794<\/a>;<\/li>\n<li>Brendon T. Sargent.; Erik J. Alexanian.<em>J. Am. Chem. Soc.<\/em><strong>2016<\/strong>, <em>138<\/em>, 7520. <a href=\"https:\/\/pubsdc3.acs.org\/doi\/full\/10.1021\/jacs.6b04610\">DOI: 10.1021\/jacs.6b04610<\/a>;<\/li>\n<li>a: Kayla S. Bloome.; Rebecca L. McMahen.; Erik J. Alexanian.<em>J. Am. Chem. Soc.<\/em><strong>2011<\/strong>, <em>133<\/em>, 20146. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja2091883\">DOI: 10.1021\/ja2091883<\/a>; b: Kayla S. Bloome.; Erik J. Alexanian.<em>J. Am. Chem. Soc. <\/em><strong>2010<\/strong>, <em>132<\/em>, 12823. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja1053913\">DOI: 10.1021\/ja1053913<\/a>;<\/li>\n<li>a: Kaila A. Margrey.; William L. Czaplyski.; David A. Nicewicz.; Erik J. Alexanian.<em>J. Am. Chem. Soc. <\/em><strong>2018<\/strong>, <em>140<\/em>, 4213. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b00592\">DOI: 10.1021\/jacs.8b00592<\/a>; b: William L. Czaplyski.; Christina G. Na.; Erik J. Alexanian.<em>J. Am. Chem. Soc. <\/em><strong>2016<\/strong>, <em>138<\/em>, 13854. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b09414\">DOI: 10.1021\/jacs.6b09414<\/a>; c: Ryan Quinn.; Zef K\u00f6nst.; Sharon Michalak.; Yvonne Schmidt.; Anne Szklarski.; Alex Flores.; Sangkil Nam.; David Horne.; Christopher Vanderwal.; Erik Alexanian.<em>J. Am. Chem. Soc.<\/em><strong>2016<\/strong>, <em>138<\/em>, 696. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5b12308\">DOI: 10.1021\/jacs.5b12308<\/a>; d: Valerie A. Schmidt.; Ryan K. Quinn.; Andrew T. Brusoe.; Erik J. Alexanian. J. Am. Chem. Soc. 2014, 136, 14389.<a href=\"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja508469u\">DOI: 10.1021\/ja508469u<\/a>; e: Jill B. Williamson.; William L. Czaplyski.; Erik J. Alexanian.; Frank A. Leibfarth.<em>Angew. Chem. Int. Ed.<\/em><strong>2018<\/strong>, <em>57<\/em>, 6261. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201803020\">doi.org\/10.1002\/anie.201803020<\/a>;<\/li>\n<li>a: Valerie A. Schmidt.; Erik J. Alexanian.<em>Angew. Chem. Int. Ed.<\/em><strong>2010<\/strong>, <em>49<\/em>, 4491. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201000843\">doi.org\/10.1002\/anie.201000843<\/a>; b: Valerie A. Schmidt.; Erik J. Alexanian.<em>J. Am. Chem. Soc.<\/em><strong>2011<\/strong>, <em>133<\/em>, 11402. <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja204255e\">DOI: 10.1021\/ja204255e<\/a>; c: Valerie A. Schmidt.; Erik J. Alexanian.<em>Chem. Sci.<\/em><strong>2012<\/strong>, <em>3<\/em>, 1672. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2012\/sc\/c2sc01042a#!divAbstract\">DOI: 10.1039\/C2SC01042A<\/a>; d: Ryan K. Quinn.; Valerie A. Schmidt.; Erik J. Alexanian.<em>Chem. Sci.<\/em><strong>2013<\/strong>, <em>4<\/em>, 4030. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2013\/sc\/c3sc51466h#!divAbstract\">DOI: 10.1039\/C3SC51466H<\/a>.<\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005 alberto-caeiro Erik John Alexanian\uff0c\u7f8e\u56fd\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u7f8e\u56fd\u5317\u5361\u7f57\u83b1\u5927\u5b66\u6559\u5802\u5c71\u5206\u6821\u6559\u6388(University of North Carolina, Chapel Hill)\u3002\uff08\u5c01\u9762\u56fe\u4e3a\u8bfe\u9898\u7ec4\uff0c\u53f31\uff09 &nbsp; \u7ecf\u5386 2001Harvard University A.B.; Research under Professor Amir Hoveyda at Boston College. 2006Princeton UniversityPh.D.,Erik J. Sorensen. 2006-2008Yale University and University of Illinois Urbana-ChampaignPostdoctoral FellowJohn F. Hartwig. 2008-2014University of North Carolina, Chapel Hill Assistant Professor. 2014-\u73b0\u5728 University of North Carolina, Chapel Hill AssociateProfessor. &nbsp; \u83b7\u5956\u7ecf\u5386 Harvard College Scholarship 1998 \u2013 2001. James H. and Louise S. Hekimian Scholarship 1999 \u2013 2001. Skaggs Postdoctoral Fellowship 2002 \u2013 2003. Hugh Stott Taylor Fellowship 2003. Bristol &#8211; Myers Squibb Graduate Fellowship 2004 \u2013 2005. ACS Division of Organic Chemistry Fellowship 2004 \u2013 2005. National Institutes of Health Postdoctoral Fellowship 2006 \u2013 2008. Thieme [&hellip;]","protected":false},"author":8,"featured_media":25154,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[212],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/04\/Erik.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-6rX","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24797"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=24797"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24797\/revisions"}],"predecessor-version":[{"id":51367,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24797\/revisions\/51367"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/25154"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=24797"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=24797"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=24797"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}