{"id":24876,"date":"2019-03-21T18:44:54","date_gmt":"2019-03-21T10:44:54","guid":{"rendered":"\/\/www.gsbet888.com\/?p=24876"},"modified":"2019-03-21T18:44:54","modified_gmt":"2019-03-21T10:44:54","slug":"aromatic-meta-photocycloaddition","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2019\/03\/aromatic-meta-photocycloaddition.html","title":{"rendered":"Aromatic meta-photocycloaddition"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>\u82b3\u9999\u65cf\u5316\u5408\u7269\u4e0e\u70ef\u70c3\u5728\u5149\u7167\u5c04\u4e0b\u53d1\u751f[3+2]\u52a0\u6210\u73af\u5316\u4ed8\u3002\u901a\u8fc7\u5e38\u89c4\u5408\u6210\u65b9\u6cd5\u4e0d\u80fd\u83b7\u5f97\u7684\u9aa8\u67b6\u53ef\u4ee5\u901a\u8fc7\u8be5\u53cd\u5e94\u5728\u77ed\u6b65\u9aa4\u5185\u83b7\u5f97\u3002\u5bf9\u4e8e\u5bb9\u6613\u4ea7\u751f\u4f4d\u7f6e\u9009\u62e9\u6027\u7684\u5206\u5b50\u5185\u53cd\u5e94\u6765\u8bf4\uff0c\u8be5\u65b9\u6cd5\u7684\u6709\u7528\u6027\u6bd4\u8f83\u9ad8\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Cornelisse, J.<em> Chem. Rev.<\/em> <strong>1993<\/strong>, <em>93<\/em>, 615. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/cr00018a002\">10.1021\/cr00018a002<\/a><\/li>\n<li>Hoffmann, N. <em>Synthesis\u00a0<\/em><strong>2004<\/strong>, 481. DOI: <a href=\"http:\/\/dx.doi.org\/10.1055\/s-2004-815973\">10.1055\/s-2004-815973<\/a><\/li>\n<li>Chappell, D.; Russell, A. T. <em>Org. Biomol. Chem.<\/em><strong>2006<\/strong>, <em>4<\/em>, 4409. DOI: <a href=\"http:\/\/dx.doi.org\/10.1039\/B614011B\">10.1039\/B614011B<\/a><\/li>\n<li>Streit, U.; Bochet, C. G. <em>Beilstein J. Org. Chem. <\/em><strong>2011<\/strong>, <em>7<\/em>, 525. doi:<a href=\"http:\/\/dx.doi.org\/10.3762\/bjoc.7.61\">10.3762\/bjoc.7.61<\/a><\/li>\n<\/ul>\n<p>&lt;photochemical reaction in total synthesis&gt;<\/p>\n<ul>\n<li>Hoffmann, N. <em>Chem. Rev.<\/em> <strong>2008<\/strong>, <em>108<\/em>, 1052. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/cr0680336\">10.1021\/cr0680336<\/a><\/li>\n<li>Bach, T.; Hehn, J. P. <em>Angew. Chem. Int. Ed.<\/em><strong>2011<\/strong>, <em>50<\/em>, 1000. DOI: <a href=\"http:\/\/dx.doi.org\/10.1002\/anie.201002845\">10.1002\/anie.201002845<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u8be5\u53cd\u5e94\u88ab\u8ba4\u4e3a\u662f\u7ecf\u7531zwitterionic\u6216\u8005biradical\u4e2d\u95f4\u4f53\u8fdb\u884c\u7684\u3002\u03c3\u952e\u5f62\u6210\u7684\u8fc7\u7a0b\u662f\u901f\u7387\u63a7\u5236\u6b65\u9aa4\u3002\u867d\u7136\u4e0e[2+2]\u53cd\u5e94\u5f62\u6210\u7ade\u4e89\uff0c\u4f46\u662f\u5f88\u591a\u60c5\u51b5\u4e0b[2+2]\u53cd\u5e94\u751f\u6210\u7269\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u4f18\u5148\u4ea7\u751f[3+2]\u52a0\u6210\u4ea7\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24879 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/meta_cycloadd_2.gif\" alt=\"\" width=\"523\" height=\"206\" \/><\/p>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>Retigeranic acid\u7684\u5408\u6210[1]\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-24880 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/meta_cycloadd_3.gif\" alt=\"\" width=\"362\" height=\"86\" \/><\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] Wender, P. A.; Singh, S. K. <em>Tetrahedron Lett.<\/em> <strong>1990<\/strong>, <em>31<\/em>, 2517. doi:<a href=\"http:\/\/dx.doi.org\/10.1016\/0040-4039(90)80114-2\">10.1016\/0040-4039(90)80114-2<\/a><\/p>\n<h4><\/h4>\n<h4>\u5173\u8054\u94fe\u63a5<\/h4>\n<ul>\n<li><a href=\"https:\/\/zh.wikipedia.org\/wiki\/\u5149\u5316\u5b66\u5408\u6210\">\u5149\u53cd\u5e94 \u2013 Wikipedia<\/a><\/li>\n<\/ul>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u82b3\u9999\u65cf\u5316\u5408\u7269\u4e0e\u70ef\u70c3\u5728\u5149\u7167\u5c04\u4e0b\u53d1\u751f[3+2]\u52a0\u6210\u73af\u5316\u4ed8\u3002\u901a\u8fc7\u5e38\u89c4\u5408\u6210\u65b9\u6cd5\u4e0d\u80fd\u83b7\u5f97\u7684\u9aa8\u67b6\u53ef\u4ee5\u901a\u8fc7\u8be5\u53cd\u5e94\u5728\u77ed\u6b65\u9aa4\u5185\u83b7\u5f97\u3002\u5bf9\u4e8e\u5bb9\u6613\u4ea7\u751f\u4f4d\u7f6e\u9009\u62e9\u6027\u7684\u5206\u5b50\u5185\u53cd\u5e94\u6765\u8bf4\uff0c\u8be5\u65b9\u6cd5\u7684\u6709\u7528\u6027\u6bd4\u8f83\u9ad8\u3002 &nbsp; \u57fa\u672c\u6587\u732e Cornelisse, J. Chem. Rev. 1993, 93, 615. DOI: 10.1021\/cr00018a002 Hoffmann, N. Synthesis\u00a02004, 481. DOI: 10.1055\/s-2004-815973 Chappell, D.; Russell, A. T. Org. Biomol. Chem.2006, 4, 4409. DOI: 10.1039\/B614011B Streit, U.; Bochet, C. G. Beilstein J. Org. Chem. 2011, 7, 525. doi:10.3762\/bjoc.7.61 &lt;photochemical reaction in total synthesis&gt; Hoffmann, N. Chem. Rev. 2008, 108, 1052. DOI: 10.1021\/cr0680336 Bach, T.; Hehn, J. P. Angew. Chem. Int. Ed.2011, 50, 1000. DOI: 10.1002\/anie.201002845 &nbsp; \u53cd\u5e94\u673a\u7406 \u8be5\u53cd\u5e94\u88ab\u8ba4\u4e3a\u662f\u7ecf\u7531zwitterionic\u6216\u8005biradical\u4e2d\u95f4\u4f53\u8fdb\u884c\u7684\u3002\u03c3\u952e\u5f62\u6210\u7684\u8fc7\u7a0b\u662f\u901f\u7387\u63a7\u5236\u6b65\u9aa4\u3002\u867d\u7136\u4e0e[2+2]\u53cd\u5e94\u5f62\u6210\u7ade\u4e89\uff0c\u4f46\u662f\u5f88\u591a\u60c5\u51b5\u4e0b[2+2]\u53cd\u5e94\u751f\u6210\u7269\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u4f18\u5148\u4ea7\u751f[3+2]\u52a0\u6210\u4ea7\u7269\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b Retigeranic acid\u7684\u5408\u6210[1] \u5b9e\u9a8c\u6b65\u9aa4 \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1] Wender, P. A.; Singh, S. K. Tetrahedron Lett. 1990, 31, 2517. doi:10.1016\/0040-4039(90)80114-2 \u5173\u8054\u94fe\u63a5 \u5149\u53cd\u5e94 \u2013 Wikipedia \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01","protected":false},"author":5,"featured_media":24878,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[2388,2387],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2014-08-21_23-06-53.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-6te","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24876"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=24876"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24876\/revisions"}],"predecessor-version":[{"id":24882,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24876\/revisions\/24882"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/24878"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=24876"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=24876"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=24876"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}