{"id":24924,"date":"2019-03-28T10:12:48","date_gmt":"2019-03-28T02:12:48","guid":{"rendered":"\/\/www.gsbet888.com\/?p=24924"},"modified":"2019-03-28T10:12:48","modified_gmt":"2019-03-28T02:12:48","slug":"angew-chem-int-ed-%e5%b0%91%e9%87%8f%e7%a2%b1%e5%8d%b3%e5%8f%af%e8%bf%9e%e6%8e%a5%e9%86%87%e5%92%8c%e7%82%94%e7%83%83","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2019\/03\/angew-chem-int-ed-%e5%b0%91%e9%87%8f%e7%a2%b1%e5%8d%b3%e5%8f%af%e8%bf%9e%e6%8e%a5%e9%86%87%e5%92%8c%e7%82%94%e7%83%83.html","title":{"rendered":"Angew. Chem. Int. Ed. \u5c11\u91cf\u78b1\u5373\u53ef\u8fde\u63a5\u9187\u548c\u7094\u70c3"},"content":{"rendered":"

David Milstein<\/a>\u8bfe\u9898\u7ec4\u6700\u8fd1<\/strong>\u62a5\u9053\u4e86\u7531\u53d4\u4e01\u9187\u94be\u50ac\u5316\u7684\u03b1-\u70f7\u57fa\u916e\u7684\u5408\u6210\u65b9\u6cd5\u3002\u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u9ad8\u539f\u5b50\u6548\u7387\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94\u3002<\/b><\/p>\n

\u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94<\/h4>\n

\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u78b3 – \u78b3\u952e\u5f62\u6210\u662f\u6709\u673a\u5316\u5408\u7269\u7684\u6709\u529b\u5408\u6210\u624b\u6bb5\u4e4b\u4e00\u3001\u51e0\u5341\u5e74\u6765\u4e5f\u5f00\u53d1\u51fa\u4e86\u5f88\u591a\u5f88\u591a\u65b0\u5947\u7684\u53d8\u6362\u53cd\u5e94\u3002\u7136\u800c\uff0c\u8fc7\u6e21\u91d1\u5c5e\u65e0\u8bba\u662f\u5728\u6bd2\u6027\u8fd8\u662f\u6210\u672c\u6765\u8bf4\uff0c\u90fd\u4e0d\u662f\u7b2c\u4e00\u9009\u62e9\uff0c\u5982\u4f55\u80fd\u591f\u5f00\u53d1\u51fa\u4e00\u79cd\u65e0\u9700\u4f7f\u7528\u5373\u53ef\u5b9e\u73b0\u76f8\u540c\u6548\u679c\u7684\u53cd\u5e94\u5c31\u663e\u5f97\u5f88\u6709\u4ef7\u503c\u3002\u56e0\u6b64\uff0c\u8fd1\u5e74\u6765\uff0c\u4e5f\u5df2\u7ecf\u62a5\u9053\u4e86\u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u8f6c\u5316\u53cd\u5e94\u7684\u5f00\u53d1\u5e94\u7528\u5b9e\u4f8b\u3002\u5176\u4e2d\uff0c\u53d4\u4e01\u57fa\u94be\u6210\u4e3a\u4e86\u4e00\u79cd\u201c\u9b54\u6cd5\u8bd5\u5242\u201d\uff0c\u5e76\u4e14\u5f00\u53d1\u51fa\u4e86\u4e00\u4e9b\u7528\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u66ff\u4ee3\u7684\u8f6c\u6362\u53cd\u5e94[1]<\/span><\/sup>\u3002\u4f8b\u5982\u30012010<\/span>\u5e74\u62a5\u9053\u7684\u82b3\u57fa\u5364\u4e0e\u82b3\u70c3\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94[1c]<\/span><\/sup>\u3002\u672c\u53cd\u5e94\u9700\u8981\u4f7f\u7528\u5f53\u91cf\u4ee5\u4e0a\u7684\u53d4\u4e01\u57fa\u94be(\u56fe<\/span>1A)<\/span>\u3002\u6700\u8fd1\u3001\u8fd8\u62a5\u9053\u4e86\u53d4\u4e01\u9187\u94be\u50ac\u5316\u7684\u6742\u82b3\u70c3\u7684C-H\u7532\u7845\u70f7\u57fa\u5316\u53cd\u5e94(\u56fe<\/span>1B)[2] <\/sup><\/span>\u3002\u7136\u800c\uff0c\u4f7f\u7528\u53d4\u4e01\u9187\u94be\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u53cd\u5e94\u4ecd\u7136\u8fd8\u662f\u6709\u5f88\u591a\u5c40\u9650\u3002<\/p>\n

\u3000\u8fd9\u6b21\u3001\u5c0f\u7f16\u4ecb\u7ecd\u4e00\u4e0b\u7531\u9b4f\u8328\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u7684Milstein<\/span>\u6559\u6388<\/a>\u8bfe\u9898\u7ec4\u5f00\u53d1\u7684\u4e0d\u4f7f\u7528\u8fc7\u5ea6\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u03b1\u2013\u70f7\u57fa\u916e\u7684\u5408\u6210\u6cd5<\/span>(\u56fe<\/span>1C)<\/span>\u3002\u8fd9\u662f\u4f7f\u7528\u53d4\u4e01\u9187\u94be\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u65b0\u53cd\u5e94\u3002<\/p>\n

\n

\"\"<\/p>\n

\u56fe1. \u4f7f\u7528\u53d4\u4e01\u57fa\u94be\u7684\u53cd\u5e94 (A)\u5076\u8054\u53cd\u5e94 (B)\u6742\u82b3\u70c3\u7684\u7532\u7845\u70f7\u57fa\u5316 (C)\u03b1-\u70f7\u57fa\u916e\u5408\u6210<\/p>\n<\/div>\n

C<\/strong>\u2013C Bond Formation of Benzyl Alcohols and Alkynes using Catalytic Amount of KOt<\/sup><\/em>Bu: Unusual Regioselectivity via a Radical Mechanism<\/strong><\/p>\n

Kumar, A.; Janes, T.; Chakraborty, S.; Daw, P.; Wolff, N. V.; Carmieli, R.; Diskin-Posner, Y.; Milstein, D.<\/p>\n

Angew. Chem. Int. Ed. <\/em>2019<\/strong>,58<\/em>, 3373-3377.\u00a0DOI:10.1002\/anie.201812687<\/a><\/p><\/blockquote>\n

\u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd<\/h4>\n

\"\"<\/p>\n

David Milstein<\/strong><\/a><\/p>\n

\u5c65\u5386
\n1976 PhD, Hebrew University of Jerusalem (Prof. J. Blum)
\n1977-1978 Posdoc, Colorado State University (Prof. J. K. Stille)
\n1979-1982 Senior Research Chemist, Central Research and Development Department, DuPont Co.
\n1983-1986 Group Leader DuPont Co.
\n1987-1992 Associate Professor, Department of Organic Chemistry, Weizmann Institute of Science
\n1993-\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0Full Professor, Department of Organic Chemistry, Weizmann Institute of Science
\n1996-2005 Head, Department of Organic Chemistry, Weizmann Institute of Science
\n1996-\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0The Israel Matz Professorial Chair of Organic Chemistry, Weizmann Institute of Science
\n2000-2017 Founder and Head, Kimmel Center for Molecular Design, Weizmann Institute of Science<\/p>\n

\u7814\u7a76\u5185\u5bb9\uff1a\u9009\u62e9\u6027\u5b98\u80fd\u56e2\u5316\u7684\u5f00\u53d1\uff0c\u73af\u5883\u8c03\u548c\u578b\u5747\u4e00\u6027\u50ac\u5316\u5242\u7684\u5f00\u53d1\u4e0e\u5e94\u7528<\/p>\n

\u8bba\u6587\u6982\u8981<\/h4>\n

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\u3000\u4f5c\u8005\u901a\u8fc7\u5404\u79cd\u5bf9\u673a\u7406\u7814\u7a76\uff0c\u8ba4\u4e3a\u8be5\u53cd\u5e94\u901a\u8fc7\u4ee5\u4e0b\u56fe\u6240\u793a\u7684\u673a\u7406\u8fdb\u884c\u7684(\u56fe<\/span>2B)<\/span>\u3002(1)<\/span>\u53d4\u4e01\u9187\u94be\u4f7f\u82ef\u7532\u9187\u53bb\u8d28\u5b50\u5316\uff0c\u7136\u540e\u4e0e\u82ef\u4e59\u7094\uff08HAT\uff09\u6c22\u8f6c\u79fb\u5f62\u6210\u70f7\u6c27\u81ea\u7531\u57faA\u00a0<\/strong>(2)\u901a\u8fc7\u5c06A<\/strong>\u63d2\u5165\u82ef\u4e59\u7094\u4e2d\u5f62\u6210\u70f7\u6c27\u81ea\u7531\u57faB<\/strong>.<\/span>(3)B<\/b><\/span>\u53d1\u751f1,2-\u6c22\u8f6c\u79fb\u751f\u6210C<\/span><\/b>\u3001\u7136\u540eB<\/span><\/b>\u4e0eC<\/span><\/b>\u5404\u81ea\u901a\u8fc71,3-\u6c22\u8f6c\u79fb<\/span>\u30011,2-\u6c22\u8f6c\u79fb\u5f62\u6210<\/span>D<\/span><\/b>(4)D<\/b><\/span>\u7684\u5171\u632f\u7ed3\u6784\u5f0fE<\/span><\/b>\u8d28\u5b50\u5316\u751f\u6210\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53F<\/span><\/b>\u3002(5)\u82c4\u9187\u79bb\u5b50\u4e0e<\/span>F<\/span><\/b>\u53d1\u751f\u6c22\u5f02\u52a8\u5f62\u6210\u70ef\u91873\u2019<\/span><\/b>\u30023\u2019<\/span><\/b>\u7684\u5f02\u6784\u5316\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u03b1\u2013\u70f7\u57fa\u916e<\/span>3<\/span><\/b>\u3002<\/p>\n

\n

\"\"<\/p>\n

\u56fe2. (A) \u5e95\u7269\u9002\u7528\u8303\u56f4, (B) \u5047\u5b9a\u53cd\u5e94\u673a\u7406<\/p>\n<\/div>\n

\u7efc\u4e0a\u6240\u8ff0\u3001\u8fd9\u6b21\u53d4\u4e01\u57fa\u94be\u50ac\u5316\u7684\u65b0\u5947\u03b1\u2013\u70f7\u57fa\u916e\u7684\u5408\u6210\u6cd5\u88ab\u5f00\u53d1\u62a5\u9053<\/span>\u3002David<\/a> Milstein<\/a><\/strong>\u6559\u6388\u53ef\u80fd\u7531\u4e8e\u5176\u5728\u675c\u90a6\u6709\u8fc7\u5de5\u4f5c\u7ecf\u5386\uff0c\u6240\u4ee5\u4ed6\u72ec\u7acb\u540e\u7684\u5de5\u4f5c\u90fd\u5f88\u91cd\u89c6\u5b9e\u7528\u6027\u4e0e\u9ad8\u6548\u6027\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/h4>\n
    \n
  1. [a] Sun, -L.; Shi, Z.-J.; Chem. Rev. <\/em>2014<\/strong>,114<\/em>,9219. DOI; 10.1021\/cr400274j<\/a> [b] Barham,J. P.; Coulthard, G.;Emery, K. J.;Doni, E.;Cumine, F.;Nocera, G.; John,M. P.; Berlouis,L. E. A.; McGuire, T.; Tuttle,T.; Murphy,J. A. J. Am. Chem. Soc. <\/em>2016<\/strong>,138<\/em>,7402.\u00a0DOI; 10.1021\/jacs.6b03282<\/a>[c] Sun, C.-L.; Li, H.; Yu, D.-G.; Yu, M.; Zhou, X.; Lu, X.-Y.; Huang, K.; Zheng, S.-F.; Li, B.-J.; Shi, Z.-J. Nat. Chem.\u00a0<\/em>2010<\/strong>, 2<\/em>, 1044. DOI; 10.1038\/NCHEM.862<\/a><\/li>\n
  2. \u00a0[a] Toutov, A. A.; Liu, W.-B.; Betz, K. N.; Fedorov, A.; Stoltz, B. M.; Grubbs, R. H. Nature\u00a0<\/em>2015<\/strong>, 518<\/em>, 80. DOI; 10.1038\/nature14126<\/a> [b] Liu, W.-B.; Schuman, D. P.; Yang, Y.-F.; Toutov, A. A.; Liang, Y.; Klare, H. F. T.; Nesnas, N.; Oestreich, M.; Blackmond, D. G.; Virgil, S. C.; Banerjee, S.; Zare, R. N.; Grubbs, R. H.; Houk, K. N.; Stoltz, B. M. J. Am. Chem. Soc.\u00a0<\/em>2017<\/strong>, 139<\/em>, 6867. DOI; 10.1021\/jacs.6b13031<\/a>[c] Banerjee, S.; Yang, Y.-F.; Jenkins, I. D.; Liang, Y.; Toutov, A. A.; Liu, W.-B.; Schuman, D. P.; Grubbs, R. H.; Stoltz, B. M.; Krenske, E. H.; Houk, K. N.; Zare, R. N. J. Am. Chem. Soc.\u00a0<\/em>2017<\/strong>, 139<\/em>, 6880. DOI; 10.1021\/jacs.6b13032<\/a><\/li>\n<\/ol>\n

    \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong> \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"David Milstein\u8bfe\u9898\u7ec4\u6700\u8fd1\u62a5\u9053\u4e86\u7531\u53d4\u4e01\u9187\u94be\u50ac\u5316\u7684\u03b1-\u70f7\u57fa\u916e\u7684\u5408\u6210\u65b9\u6cd5\u3002\u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u9ad8\u539f\u5b50\u6548\u7387\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94\u3002 \u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94 \u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u78b3 – \u78b3\u952e\u5f62\u6210\u662f\u6709\u673a\u5316\u5408\u7269\u7684\u6709\u529b\u5408\u6210\u624b\u6bb5\u4e4b\u4e00\u3001\u51e0\u5341\u5e74\u6765\u4e5f\u5f00\u53d1\u51fa\u4e86\u5f88\u591a\u5f88\u591a\u65b0\u5947\u7684\u53d8\u6362\u53cd\u5e94\u3002\u7136\u800c\uff0c\u8fc7\u6e21\u91d1\u5c5e\u65e0\u8bba\u662f\u5728\u6bd2\u6027\u8fd8\u662f\u6210\u672c\u6765\u8bf4\uff0c\u90fd\u4e0d\u662f\u7b2c\u4e00\u9009\u62e9\uff0c\u5982\u4f55\u80fd\u591f\u5f00\u53d1\u51fa\u4e00\u79cd\u65e0\u9700\u4f7f\u7528\u5373\u53ef\u5b9e\u73b0\u76f8\u540c\u6548\u679c\u7684\u53cd\u5e94\u5c31\u663e\u5f97\u5f88\u6709\u4ef7\u503c\u3002\u56e0\u6b64\uff0c\u8fd1\u5e74\u6765\uff0c\u4e5f\u5df2\u7ecf\u62a5\u9053\u4e86\u4e0d\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u7684\u8f6c\u5316\u53cd\u5e94\u7684\u5f00\u53d1\u5e94\u7528\u5b9e\u4f8b\u3002\u5176\u4e2d\uff0c\u53d4\u4e01\u57fa\u94be\u6210\u4e3a\u4e86\u4e00\u79cd\u201c\u9b54\u6cd5\u8bd5\u5242\u201d\uff0c\u5e76\u4e14\u5f00\u53d1\u51fa\u4e86\u4e00\u4e9b\u7528\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u66ff\u4ee3\u7684\u8f6c\u6362\u53cd\u5e94[1]\u3002\u4f8b\u5982\u30012010\u5e74\u62a5\u9053\u7684\u82b3\u57fa\u5364\u4e0e\u82b3\u70c3\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94[1c]\u3002\u672c\u53cd\u5e94\u9700\u8981\u4f7f\u7528\u5f53\u91cf\u4ee5\u4e0a\u7684\u53d4\u4e01\u57fa\u94be(\u56fe1A)\u3002\u6700\u8fd1\u3001\u8fd8\u62a5\u9053\u4e86\u53d4\u4e01\u9187\u94be\u50ac\u5316\u7684\u6742\u82b3\u70c3\u7684C-H\u7532\u7845\u70f7\u57fa\u5316\u53cd\u5e94(\u56fe1B)[2] \u3002\u7136\u800c\uff0c\u4f7f\u7528\u53d4\u4e01\u9187\u94be\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u53cd\u5e94\u4ecd\u7136\u8fd8\u662f\u6709\u5f88\u591a\u5c40\u9650\u3002 \u3000\u8fd9\u6b21\u3001\u5c0f\u7f16\u4ecb\u7ecd\u4e00\u4e0b\u7531\u9b4f\u8328\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u7684Milstein\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u53d1\u7684\u4e0d\u4f7f\u7528\u8fc7\u5ea6\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u03b1\u2013\u70f7\u57fa\u916e\u7684\u5408\u6210\u6cd5(\u56fe1C)\u3002\u8fd9\u662f\u4f7f\u7528\u53d4\u4e01\u9187\u94be\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u65b0\u53cd\u5e94\u3002 \u56fe1. \u4f7f\u7528\u53d4\u4e01\u57fa\u94be\u7684\u53cd\u5e94 (A)\u5076\u8054\u53cd\u5e94 (B)\u6742\u82b3\u70c3\u7684\u7532\u7845\u70f7\u57fa\u5316 (C)\u03b1-\u70f7\u57fa\u916e\u5408\u6210 C\u2013C Bond Formation of Benzyl Alcohols and Alkynes using Catalytic Amount of KOtBu: Unusual Regioselectivity via a Radical Mechanism Kumar, A.; Janes, T.; Chakraborty, S.; Daw, P.; Wolff, N. V.; Carmieli, R.; Diskin-Posner, Y.; Milstein, D. Angew. Chem. Int. Ed. 2019,58, 3373-3377.\u00a0DOI:10.1002\/anie.201812687 \u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd David Milstein \u5c65\u5386 1976 PhD, Hebrew University of Jerusalem (Prof. J. Blum) 1977-1978 Posdoc, Colorado State University (Prof. J. K. Stille) 1979-1982 Senior Research Chemist, Central Research and Development Department, DuPont Co. 1983-1986 Group Leader DuPont Co. 1987-1992 Associate Professor, Department of Organic Chemistry, Weizmann Institute of Science 1993-\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0Full Professor, Department of Organic Chemistry, […]","protected":false},"author":5,"featured_media":24925,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[414,1271],"tags":[2397,2396,2395],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/03\/2019-03-05_14-47-07.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-6u0","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24924"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=24924"}],"version-history":[{"count":13,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24924\/revisions"}],"predecessor-version":[{"id":24972,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/24924\/revisions\/24972"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/24925"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=24924"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=24924"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=24924"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}