{"id":25167,"date":"2019-05-13T17:40:44","date_gmt":"2019-05-13T09:40:44","guid":{"rendered":"\/\/www.gsbet888.com\/?p=25167"},"modified":"2019-05-13T17:30:27","modified_gmt":"2019-05-13T09:30:27","slug":"x-peter-zhang","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemists\/2019\/05\/x-peter-zhang.html","title":{"rendered":"X. Peter Zhang"},"content":{"rendered":"
Peter Zhang(\u5f20\u5c0f\u7965)\uff0c\u5b89\u5fbd\u5e08\u8303\u5927\u5b66\u6821\u53cb\uff0c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u7f8e\u56fdBoston College(\u6ce2\u58eb\u987f\u5b66\u9662)\u6559\u6388\u3002\uff08\u5b9e\u9a8c\u5ba4\u4e3b\u9875<\/a>)\u3002<\/p>\n <\/p>\n <\/p>\n <\/p>\n \u9664\u4e86\u81ea\u7531\u57fa\u53d6\u4ee3\u548c\u52a0\u6210\u53cd\u5e94\u5916\uff0c\u81ea\u6709\u673a\u5316\u5b66\u8fd8\u5177\u6709\u79bb\u5b50\u5316\u5b66\u4e0d\u5177\u6709\u7684\u53cd\u5e94\uff0c\u5982\u81ea\u7531\u57fa\u652b\u53d6\u53cd\u5e94\u548c\u81ea\u7531\u57fa\u03b2-\u88c2\u89e3\uff0c\u56e0\u6b64\u8d8a\u6765\u8d8a\u53d7\u5230\u5408\u6210\u5316\u5b66\u5bb6\u4eec\u7684\u5173\u6ce8\u3002\u5b9e\u9645\u4e0a\uff0c\u81ea\u7531\u57fa\u5316\u5b66\u5728\u590d\u6742\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u5e94\u7528\uff08\u6709\u673a\u6240\u674e\u6602\u2014\u2014\u81ea\u7531\u57fa\u8bfe\u4ef6<\/a>\uff09\u3002\u81ea\u7531\u57fa\u76f8\u8f83\u4e0e\u79bb\u5b50\u5316\u5b66\uff0c\u6709\u4ee5\u4e0b\u4f18\u70b9\uff1a\u5728\u6e29\u548c\u6761\u4ef6\u548c\u4e2d\u6027\u73af\u5883\u4e0b\u53ef\u4ee5\u8f83\u9ad8\u901f\u7387\u53d1\u751f\u53cd\u5e94\uff0c\u5e76\u4e14\u6709\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\uff1b\u81ea\u7531\u57fa\u94fe\u5f0f\u53cd\u5e94\u76f8\u8f83\u5bb9\u6613\u53d1\u751f\u548c\u53ef\u63a7\uff0c\u53ef\u7528\u4e8e\u9ad8\u6548\u6784\u5efa\u5177\u6709\u591a\u624b\u6027\u4e2d\u5fc3\u7684\u590d\u6742\u5206\u5b50\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u81ea\u7531\u57fa\u5316\u5b66\u4e5f\u6709\u81ea\u8eab\u7684\u7f3a\u70b9\uff1a\u81ea\u7531\u57fa\u7684\u4ea7\u751f\uff1b\u53cd\u5e94\u6027\u7684\u8c03\u63a7\uff0c\u5305\u62ec\u53cd\u5e94\u6027\uff0c\u533a\u57df\u9009\u62e9\u6027\u3001\u5bf9\u6620\u9009\u62e9\u6027\u7b49\u3002<\/p>\n \u56fe1\uff1a\u81ea\u7531\u57fa\u53cd\u5e94\u7c7b\u578b\u53ca\u6311\u6218<\/em><\/p>\n \u5f20\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u5de5\u4f5c\u81f4\u529b\u4e8e\u53d1\u5c55\u4e00\u79cd\u65b0\u7684\u53cd\u5e94\u9014\u5f84\uff0c\u5b9e\u73b0\u81ea\u7531\u57fa\u7684\u9009\u62e9\u6027\u53cd\u5e94\uff0c\u7279\u522b\u662f\u5bf9\u6620\u9009\u62e9\u6027\u7684\u53cd\u5e94\uff0c\u6b64\u81ea\u7531\u57fa\u5316\u5b66\u4e2d\u7684\u96be\u70b9\u3002<\/p>\n \u5177\u6709open-shell\u7684\u987a\u78c1\u91d1\u5c5e\u590d\u5408\u7269\uff0c\u5176d\u8f68\u9053\u4e0a\u5177\u6709\u672a\u6210\u5bf9\u7535\u5b50\uff0c\u56e0\u6b64\u53ef\u4ee5\u79f0\u4e3a\u91d1\u5c5e\u81ea\u7531\u57fa\u7269\u79cd\u3002\u8003\u8651\u5230\u8fd9\u4ee5\u672a\u6210\u5bf9\u7535\u5b50\u7684\u72ec\u7279\u53cd\u5e94\u6027\uff0c\u5f20\u6559\u6388\u5e0c\u671b\u627e\u5230\u4e00\u7c7b\u53ef\u88ab\u6b64\u91d1\u5c5e\u81ea\u7531\u57fa\u7269\u8d28\u5f15\u53d1\u4ea7\u751f\u76f8\u5e94C-, N-, O-\u81ea\u7531\u57fa\u7684\u5e95\u7269\uff0c\u901a\u8fc7\u8c03\u6574\u914d\u4f53\uff0c\u5b9e\u73b0\u53ef\u8c03\u63a7\u7684\u50ac\u5316\u53cd\u5e94\u3002\u4e0e\u4f20\u7edf\u7684\u81ea\u7531\u57fa\u53cd\u5e94\u76f8\u6bd4\uff0c\u6b64\u81ea\u7531\u57fa\u4e0d\u518d\u662f\u201c\u81ea\u7531\u201c\u7684\uff0c\u5b83\u4e0e\u91d1\u5c5e\u590d\u5408\u7269\u76f8\u8fde\uff0c\u56e0\u6b64\u4e0e\u91d1\u5c5e\u914d\u4f4d\u7684\u914d\u4f53\u53ef\u4ee5\u8c03\u8282\u7535\u6027\u548c\u4f4d\u963b\u4ece\u800c\u8c03\u63a7\u53cd\u5e94\u9009\u62e9\u6027\uff0c\u800c\u5f31\u7684M-C, M-N, M-O\u952e\u53ef\u4ee5\u4e0e\u81ea\u7531\u57fa\u53d1\u751f\u81ea\u7531\u57fa\u53d6\u4ee3\u53cd\u5e94\uff0c\u518d\u751f\u91d1\u5c5e\u81ea\u7531\u57fa\uff0c\u5b9e\u73b0\u9009\u62e9\u6027\u7684\u50ac\u5316\u5faa\u73af\u53cd\u5e94\u3002<\/p>\n \u535f\u5549\u94b4\u662f\u4e00\u7c7b\u9002\u7528\u4e8e\u6b64\u4f53\u7cfb\u7684\u91d1\u5c5e\u81ea\u7531\u57fa\u50ac\u5316\u5242\uff0c\u91d1\u5c5eCo\u4e3a\u7b2c\u56db\u5468\u671f\u7684d7<\/sup>\u91d1\u5c5e\uff0c\u535f\u5549\u914d\u4f53\u5728\u751f\u547d\u4f53\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\u6709\u5e7f\u6cdb\u5e94\u7528\uff0c\u800c\u5361\u5bbe\u662f\u4e00\u7c7b\u53ef\u770b\u4f5c\u53cc\u81ea\u7531\u57fa\u7684\u5e95\u7269\uff0c\u53ef\u4ee5\u4e0e\u91d1\u5c5e\u81ea\u7531\u57fa\u53cd\u5e94\u5f97\u5230\u81ea\u7531\u57fa\u7269\u79cd\u3002\u5f20\u6559\u6388\u5bf9\u535f\u5549\u94b4\u50ac\u5316\u5242\u4e0e\u5361\u5bbe\u524d\u4f53\u7684\u53cd\u5e94\u6709\u6df1\u5165\u7814\u7a76\uff0c\u76ee\u524d\u53ef\u884c\u7684\u53cd\u5e94\u6709\u70ef\u70c3\u7684\u73af\u4e19\u70f7\u5316[1]<\/sup>\uff0c\u6c2e\u6742\u73af\u4e19\u70f7\u5316\u53cd\u5e94[3]<\/sup>\uff1bC-H\u952e\u7684\u70f7\u57fa\u5316\u53cd\u5e94[2]<\/sup>\uff0c\u80fa\u5316\u53cd\u5e94[4]<\/sup>\u7b49\u3002<\/p>\n \u56fe2\uff1a\u535f\u5549\u94b4\u50ac\u5316\u5242\u4e0e\u5361\u5bbe\u524d\u4f53\u7684\u53cd\u5e94\u7c7b\u578b<\/em><\/p>\n <\/p>\n\u7ecf\u5386<\/strong><\/h4>\n
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