![\"\"](\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/2.png\")
<\/a><\/p>\n\u5229\u7528\u4e30\u5bcc\u7684\u5316\u5de5\u539f\u6599\u6765\u5408\u6210\u66f4\u6709\u4ef7\u503c\u7684\u5316\u5b66\u4ea7\u54c1\u53d7\u5230\u5316\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u7532\u82efC(sp3<\/sup>)-H\u5b98\u80fd\u56e2\u5316\u5219\u662f\u4e00\u4e2a\u5178\u578b\u7684\u4f8b\u5b50\u3002\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269C-H\u952e\u6d3b\u5316\u7684\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684C-H\u952e\u6c27\u5316\u53cd\u5e94\u3001\u6c22\u539f\u5b50\u8f6c\u79fb\u4ee5\u53ca\u5355\u7535\u5b50\u8f6c\u79fb\u6c27\u5316\u53cd\u5e94\u8fd9\u4e09\u79cd\uff0c\u4e14\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e0d\u9519\u7684\u8fdb\u5c55\uff0c\u4f46\u5173\u4e8e\u4e0d\u5bf9\u79f0\u5408\u6210\u624b\u6027\u836f\u7269\u548c\u624b\u6027\u529f\u80fd\u6750\u6599\u7684\u62a5\u9053\u8fd8\u5f88\u5c11\u3002Davies\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u624b\u6027\u4e8c\u94d1\u50ac\u5316\u5242\u50ac\u5316\u7532\u82ef\u884d\u751f\u7269\u7684\u4ef2\u78b3\u548c\u4f2f\u78b3\u53d1\u751f\u533a\u57df\u9009\u62e9\u6027\u548c\u5bf9\u6620\u9009\u62e9\u6027\u7684C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff08Fig.1a\uff09[1]\u3002\u6700\u8fd1\uff0cMelchiorre\u8bfe\u9898\u7ec4\u5145\u5206\u5229\u7528\u4e9a\u94f5\u79bb\u5b50\u4e2d\u95f4\u4f53\u9ad8\u6fc0\u53d1\u6001\u6c27\u5316\u7535\u4f4d\u7684\u4f18\u52bf\u5b9e\u73b0\u4e86\u7532\u82ef\u53ca\u5176\u5bcc\u7535\u5b50\u884d\u751f\u7269\u7684\u5355\u7535\u5b50\u8f6c\u79fb\u53cd\u5e94\uff0c\u5408\u6210\u82c4\u57fa\u81ea\u7531\u57fa\uff08Fig.1b\uff09[2]\u3002<\/p>\n
\u8fd9\u79cd\u5c06\u81ea\u7531\u57fa\u7b56\u7565\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7532\u82ef\u884d\u751f\u7269\u7684C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u6709\u52a9\u4e8e\u4ea7\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\uff0c\u800c\u4e14\u7531\u4e8e\u82c4\u57fa\u81ea\u7531\u57fa\u7684\u7a33\u5b9a\u6027\u8f83\u9ad8\uff0c\u53ef\u4ee5\u5f88\u597d\u5730\u5c06C(sp3<\/sup>)-H\u4e0eC(sp2<\/sup>)-H\u533a\u5206\u5f00\u6765\u30021909\u5e74\uff0cPatern\u00f2\u548cChieffi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5149\u50ac\u5316\u916e\u4e0e\u70ef\u70c3\u7684[2+2]\u73af\u52a0\u6210\u53cd\u5e94\u3002\u4e4b\u540e\uff0c\u8be5\u53cd\u5e94\u88ab\u8bc1\u660e\u5149\u6d3b\u5316\u72b6\u6001\u4e0b\u7684\u4e09\u91cd\u6001\u4e0e\u6d3b\u5316\u7684\u70ef\u70c3\u3001\u7094\u70c3\u548c\u70f7\u70c3\u53cd\u5e94\u662f\u901a\u8fc7SET\u6c27\u5316\u8fd8\u539f\u6216HAT\u673a\u7406\u3002\u4e8e\u662f\uff0c\u5316\u5b66\u5bb6\u731c\u60f3\u7c7b\u4f3c\u7684\u5149\u5316\u5b66\u673a\u7406\u80fd\u5426\u76f4\u63a5\u7528\u4e8e\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269\u7684C(sp3<\/sup>)-H\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u5177\u6709\u91cd\u8981\u751f\u7269\u6d3b\u6027\u76843-\u7f9f\u57fa-3-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u57fa\u5432\u54da\u4e3b\u8981\u901a\u8fc73-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u5432\u54da\u53d1\u751f\u03b1-\u6c27\u5316\u53cd\u5e94\u5f97\u5230\uff0c\u4f46\u8be5\u7c7b\u53cd\u5e94\u5b58\u5728\u8d77\u59cb\u539f\u6599\u5236\u4f5c\u7e41\u7410\u3001\u5e95\u7269\u8303\u56f4\u5c40\u9650\u7b49\u95ee\u9898\uff0c\u56e0\u6b643-\u7f9f\u57fa-3-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u57fa\u5432\u54da\u5316\u5408\u7269\u7684\u5408\u6210\u4ecd\u7136\u9762\u4e34\u5de8\u5927\u6311\u6218\u3002\u5728\u4e0a\u8ff0\u80cc\u666f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u6c5f\u667a\u52c7\u56e2\u961f<\/a>\u62a5\u9053\u4e86\u624b\u6027Br\u00f8nsted\u9178\u6216Lewis\u9178\u50ac\u5316\u5242\u50ac\u5316\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269\u4e0e\u975b\u7ea2\u6216\u82ef\u5e76\u4e59\u4e8c\u916e\u7684C(sp3<\/sup>)-H\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u5408\u6210\u624b\u6027\u53d4\u9187\u5316\u5408\u7269\uff08Fig.2\uff09\u3002\u65b0\u52a0\u5761\u79d1\u6280\u8bbe\u8ba1\u5927\u5b66Richmond Lee\u6559\u6388\u63d0\u4f9b\u4e86\u8ba1\u7b97\u5316\u5b66\u652f\u6301\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e<\/p>\n
Li, F.; Tian, D.; Fan, Y.; Lee, R.; Lu, G.; Yin, Y.; Qiao, B.; Zhao, X.; Xiao Z.; Jiang, Z.*<\/p>\n
Nat. Commun. 2019, early view\u00a0DOI: 10.1038\/s41467-019-09857-9<\/p><\/blockquote>\n
\u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd\uff1a<\/strong><\/h4>\n
\u7814\u7a76\u8005\uff1a\u6c5f\u667a\u52c7\u6559\u6388<\/p>\n
\u7814\u7a76\u8005\u7ecf\u5386\uff1a<\/strong><\/p>\n
\n
- 1992\u5e749\u6708-1996\u5e746\u6708\uff0c\u6d59\u6c5f\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u7406\u5b66\u5b66\u58eb<\/li>\n
- 1999\u5e749\u6708-2004\u5e741\u6708\uff0c\u6d59\u6c5f\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u6709\u673a\u5316\u5b66\u4e13\u4e1a\u7406\u5b66\u535a\u58eb<\/li>\n
- 2004\u5e742\u6708-2005\u5e744\u6708\uff0c\u9999\u6e2f\u6d78\u4f1a\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08\uff1aWing-Hong Chan\u6559\u6388<\/li>\n
- 2005\u5e748\u6708-2009\u5e748\u6708\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08\uff1aChoon-Hong Tan\u6559\u6388<\/li>\n
- 2013\u5e744\u6708-2013\u5e7410\u6708\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff0c\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u5b66\u9662\uff0c\u9ad8\u7ea7\u7814\u7a76\u5458<\/li>\n
- 2009\u5e748\u6708-2018\uff0c\u6cb3\u5357\u5927\u5b66\uff0c\u6cb3\u5357\u7701\u5929\u7136\u836f\u7269\u4e0e\u514d\u75ab\u5de5\u7a0b\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u5165\u9009\u8005\uff0c\u6cb3\u5357\u7701\u7279\u8058\u6559\u6388\uff08\u6709\u673a\u5316\u5b66\uff09<\/li>\n
- 2018\u5e74\u81f3\u4eca \uff0c\u6cb3\u5357\u5e08\u8303\u5927\u5b66\uff0c\u5316\u5b66\u5316\u5de5\u5b66\u9662 \u9662\u957f<\/li>\n<\/ul>\n
\u8363\u8a89\u5956\u9879\uff1a<\/strong><\/p>\n
\n
- \u6cb3\u5357\u7701\u9752\u5e74\u9aa8\u5e72\u6559\u5e08\uff082010\uff09<\/li>\n
- \u6cb3\u5357\u7701\u6559\u80b2\u5385\u5b66\u672f\u6280\u672f\u5e26\u5934\u4eba\uff082010\uff09<\/li>\n
- \u6cb3\u5357\u7701\u9752\u5c11\u5e74\u79d1\u6280\u521b\u65b0\u5956\uff08\u9752\u5e74\u7ec4\uff09\uff082012\uff09<\/li>\n
- \u6cb3\u5357\u7701\u4f18\u79c0\u9752\u5e74\u79d1\u6280\u4e13\u5bb6\u79f0\u53f7\uff082012\uff09<\/li>\n
- \u6cb3\u5357\u7701\u7b2c\u5341\u4e00\u5c4a\u9752\u5e74\u79d1\u6280\u5956\uff082012\uff09<\/li>\n
- \u6cb3\u5357\u7701\u5b66\u672f\u6280\u672f\u5e26\u5934\u4eba\uff082012\uff09<\/li>\n
- \u6cb3\u5357\u7701\u7b2c\u5341\u4e03\u5c4a\u9752\u5e74\u4e94\u56db\u5956\u7ae0\uff082013\uff09<\/li>\n
- \u6cb3\u5357\u7701\u6559\u80b2\u5385\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u5956\uff08\u6392\u540d1\uff0c2016\uff09<\/li>\n
- \u5f00\u5c01\u5e02\u4f18\u79c0\u6559\u5e08\uff082017\uff09<\/li>\n
- \u6cb3\u5357\u7701\u79d1\u6280\u8fdb\u6b65\u4e8c\u7b49\u5956\uff08\u6392\u540d1\uff0c2017\uff09<\/li>\n
- \u56fd\u5bb6\u201c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u201d\uff082017\uff09<\/li>\n<\/ul>\n
<\/p>\n
\u6761\u4ef6\u4f18\u5316<\/strong>\uff1a<\/h4>\n
\u57283 W\u84dd\u5149\u7167\u5c04\u4e0b\uff0c\u975b\u7ea21<\/strong>\u5728\u7532\u82ef\u6eb6\u5242\u4e2d\u7684\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4f18\u5316\uff0c\u4f5c\u8005\u53d1\u73b0\uff0c0.1 mmol 1e\u548c5.0 mmol \u7532\u82ef\u4e3a\u6a21\u677f\u5e95\u7269\uff0c20 mol\uff05 La(OTf)3\u548c22 mol\uff05\u624b\u6027\u7edc\u5408\u7269L1\u4e3a\u50ac\u5316\u5242\uff0c70 mg 4 \u00c5 \u5206\u5b50\u7b5b\u4e3a\u6dfb\u52a0\u7269\uff0cPhCl (4.0 mL)\u4e3a\u6700\u4f18\u6eb6\u5242\uff0c\u572825\u2103\u6761\u4ef6\u4e0b\u53cd\u5e9450 h\uff0c\u80fd\u4ee557%\u7684\u6536\u7387\u548c98%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76ee\u6807\u4ea7\u72692e<\/strong>\u3002\u82e5\u6362\u6210\u65e0\u6eb6\u5242\u6761\u4ef6\uff0c\u5219\u80fd\u4ee5\u4ee571%\u7684\u6536\u7387\u548c98%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff08Table 1\uff09\u3002<\/p>\n
\u5e95\u7269\u6269\u5c55\uff1a<\/strong><\/h4>\n
\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u8be5\u53cd\u5e94\u7684\u5e95\u7269\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf(Fig. 3)\uff0c\u62ec\u53f7\u4e2d\u7684\u6570\u636e\u4e3a\u65e0\u6eb6\u5242\u6761\u4ef6\u4e0b\u7684\u53cd\u5e94\u60c5\u51b5\u3002\u5404\u79cd\u5438\u7535\u5b50\u3001\u7ed9\u7535\u5b50\u53d6\u4ee3\u7684\u82b3\u73af\u3001\u6c18\u4ee3\u7532\u82ef\u4ee5\u53ca\u6742\u82b3\u73af\u5747\u80fd\u5f88\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u8f83\u9ad8\u7684\u6536\u7387\u548c\u4e2d\u7b49\u81f3\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u82e5\u6362\u6210\u5438\u7535\u5b50\u66f4\u5f3a\u7684\u785d\u57fa\u548c\u4e09\u6c1f\u7532\u57fa\u53d6\u4ee3\u7684\u82b3\u73af\uff0c\u5219\u53ea\u80fd\u751f\u6210\u81ea\u8eab\u5076\u8054\u526f\u4ea7\u7269\u3002\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u4ee5\u53ca\u73af\u72b6\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u80fd\u8f83\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u4e2d\u7b49\u7684\u6536\u7387\u548c\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\uff0c\u4f46\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027\u8f83\u4f4e\u3002\u5bf9\u4e8e\u4e09\u7ea7\u82b3\u73af\u4e5f\u80fd\u4ee5\u8f83\u4f4e\u7684\u6536\u7387\u548c\u8f83\u9ad8\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\uff0c\u4f46\u5bf9\u4f4d\u53d6\u4ee3\u7684\u4e09\u7ea7\u82b3\u73af\u5f97\u5230\u7684\u4ea7\u7269\u65e0\u5bf9\u6620\u9009\u62e9\u6027\u3002\u540c\u65f6\uff0c\u5404\u79cd\u82b3\u73af\u53d6\u4ee3\u7684\u975b\u7ea2\u4e5f\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\u3002<\/p>\n
\u673a\u7406\u7814\u7a76\uff1a<\/strong><\/h4>\n
\u4e3a\u4e86\u9610\u660e\u673a\u7406\uff0c\u4f5c\u8005\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u7d2b\u5916-\u53ef\u89c1\u5149\u5438\u6536\u5149\u8c31\u5206\u6790\uff0c\u53d1\u73b0\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u65e0\u53d7\u4f53-\u7ed9\u4f53\u914d\u4f4d\u5316\u5408\u7269\u751f\u6210\u3002\u7d27\u63a5\u7740\uff0c\u4f5c\u8005\u53c8\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u5bf9\u7167\u8bd5\u9a8c\u548c\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u7814\u7a76\u3002\u5bf9\u7167\u8bd5\u9a8c\u7684\u6570\u636e\u8bf4\u660eHAT\u8fc7\u7a0b\u4e2d\u786e\u5b9e\u4ea7\u751f\u4e86\u82c4\u57fa\u81ea\u7531\u57fa\uff0c\u540c\u65f6\uff0c\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u7814\u7a76\u8868\u660eC-H\u952e\u65ad\u88c2\u662f\u50ac\u5316\u5faa\u73af\u4e0d\u53ef\u9006\u7684\u7b2c\u4e00\u6b65\uff0c\u662f\u8be5\u53cd\u5e94\u7684\u51b3\u901f\u6b65\u9aa4(Fig. 4).\u3002<\/p>\n
\u5e95\u7269\u6269\u5c55<\/strong>\uff1a<\/h4>\n
\u82ef\u5e76\u4e59\u4e8c\u916e6<\/strong>\u5728\u65e0\u6eb6\u5242\u7684\u7532\u82ef\u6eb6\u6db2\u4e2d\u53cd\u5e94\uff0c20 mol% CPA-1\u4e3a\u50ac\u5316\u5242\uff0c80 mg 4 \u00c5 \u4e3a\u6dfb\u52a0\u7269\uff0c\u5728 \u22125 \u00b0C \u6761\u4ef6\u4e0b\u53cd\u5e9460 h\uff0c\u80fd\u4ee551%\u7684\u6536\u7387\u548c90%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u5728\u5f97\u5230\u7684\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u5404\u79cd\u7532\u82ef\u884d\u751f\u7269\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u80fd\u4ee5\u4e2d\u7b49\u7684\u6536\u7387\u548c\u8f83\u9ad8\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u53d4\u9187\u4ea7\u7269(Fig.5)\u3002<\/p>\n
\u8bba\u6587\u603b\u7ed3\u8bc4\u4ef7\uff1a<\/strong><\/h4>\n
\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u6c5f\u667a\u52c7\u56e2\u961f<\/a>\u62a5\u9053\u4e86\u624b\u6027Br\u00f8nsted\u9178\u6216Lewis\u9178\u50ac\u5316\u5242\u50ac\u5316\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269\u4e0e\u53ef\u89c1\u5149\u6d3b\u5316\u7684\u975b\u7ea2\u6216\u82ef\u5e76\u4e59\u4e8c\u916e\u7684C(sp3<\/sup>)-H\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u80fd\u4ee5\u4e2d\u7b49\u7684\u6536\u7387\u548c\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e00\u7cfb\u5217\u751f\u7269\u5177\u6709\u751f\u7269\u6d3b\u6027\u76843-\u7f9f\u57fa-3-\u82c4\u57fa\u53d6\u4ee3\u76842-\u7f9f\u57fa\u5432\u54da\u7ed3\u6784\u3002\u8fd9\u79cdC-H\u63d2\u5165\u53cd\u5e94\u53ca\u81ea\u7531\u57fa\u5076\u8054\u7b56\u7565\u4e5f\u540c\u6837\u9002\u7528\u4e8e\u82ef\u5e76\u4e59\u4e8c\u916e\uff0c\u4e3a\u53d4\u9187\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u9014\u5f84\u3002<\/p>\n
\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n
\n
- Qin, C.; Davies, H. M. L.\u00a0J. Am. Chem. Soc.<\/em> 2014<\/strong>, 136<\/em>, 9792. DOI: 10.1021\/ja504797x<\/a><\/li>\n
- Mazzarella, D.; Crisenza, G. E. M.; Melchiorre, P. J.\u00a0Am. Chem. Soc.<\/em> 2018<\/strong>, 140<\/em>, 8439. DOI: 10.1021\/jacs.8b05240<\/a><\/li>\n<\/ol>\n
\u76f8\u5173\u94fe\u63a5<\/h4>\n
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\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u5229\u7528\u4e30\u5bcc\u7684\u5316\u5de5\u539f\u6599\u6765\u5408\u6210\u66f4\u6709\u4ef7\u503c\u7684\u5316\u5b66\u4ea7\u54c1\u53d7\u5230\u5316\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0c\u7532\u82efC(sp3)-H\u5b98\u80fd\u56e2\u5316\u5219\u662f\u4e00\u4e2a\u5178\u578b\u7684\u4f8b\u5b50\u3002\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269C-H\u952e\u6d3b\u5316\u7684\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684C-H\u952e\u6c27\u5316\u53cd\u5e94\u3001\u6c22\u539f\u5b50\u8f6c\u79fb\u4ee5\u53ca\u5355\u7535\u5b50\u8f6c\u79fb\u6c27\u5316\u53cd\u5e94\u8fd9\u4e09\u79cd\uff0c\u4e14\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e0d\u9519\u7684\u8fdb\u5c55\uff0c\u4f46\u5173\u4e8e\u4e0d\u5bf9\u79f0\u5408\u6210\u624b\u6027\u836f\u7269\u548c\u624b\u6027\u529f\u80fd\u6750\u6599\u7684\u62a5\u9053\u8fd8\u5f88\u5c11\u3002Davies\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u624b\u6027\u4e8c\u94d1\u50ac\u5316\u5242\u50ac\u5316\u7532\u82ef\u884d\u751f\u7269\u7684\u4ef2\u78b3\u548c\u4f2f\u78b3\u53d1\u751f\u533a\u57df\u9009\u62e9\u6027\u548c\u5bf9\u6620\u9009\u62e9\u6027\u7684C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff08Fig.1a\uff09[1]\u3002\u6700\u8fd1\uff0cMelchiorre\u8bfe\u9898\u7ec4\u5145\u5206\u5229\u7528\u4e9a\u94f5\u79bb\u5b50\u4e2d\u95f4\u4f53\u9ad8\u6fc0\u53d1\u6001\u6c27\u5316\u7535\u4f4d\u7684\u4f18\u52bf\u5b9e\u73b0\u4e86\u7532\u82ef\u53ca\u5176\u5bcc\u7535\u5b50\u884d\u751f\u7269\u7684\u5355\u7535\u5b50\u8f6c\u79fb\u53cd\u5e94\uff0c\u5408\u6210\u82c4\u57fa\u81ea\u7531\u57fa\uff08Fig.1b\uff09[2]\u3002 \u8fd9\u79cd\u5c06\u81ea\u7531\u57fa\u7b56\u7565\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7532\u82ef\u884d\u751f\u7269\u7684C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u6709\u52a9\u4e8e\u4ea7\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\uff0c\u800c\u4e14\u7531\u4e8e\u82c4\u57fa\u81ea\u7531\u57fa\u7684\u7a33\u5b9a\u6027\u8f83\u9ad8\uff0c\u53ef\u4ee5\u5f88\u597d\u5730\u5c06C(sp3)-H\u4e0eC(sp2)-H\u533a\u5206\u5f00\u6765\u30021909\u5e74\uff0cPatern\u00f2\u548cChieffi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5149\u50ac\u5316\u916e\u4e0e\u70ef\u70c3\u7684[2+2]\u73af\u52a0\u6210\u53cd\u5e94\u3002\u4e4b\u540e\uff0c\u8be5\u53cd\u5e94\u88ab\u8bc1\u660e\u5149\u6d3b\u5316\u72b6\u6001\u4e0b\u7684\u4e09\u91cd\u6001\u4e0e\u6d3b\u5316\u7684\u70ef\u70c3\u3001\u7094\u70c3\u548c\u70f7\u70c3\u53cd\u5e94\u662f\u901a\u8fc7SET\u6c27\u5316\u8fd8\u539f\u6216HAT\u673a\u7406\u3002\u4e8e\u662f\uff0c\u5316\u5b66\u5bb6\u731c\u60f3\u7c7b\u4f3c\u7684\u5149\u5316\u5b66\u673a\u7406\u80fd\u5426\u76f4\u63a5\u7528\u4e8e\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269\u7684C(sp3)-H\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u5177\u6709\u91cd\u8981\u751f\u7269\u6d3b\u6027\u76843-\u7f9f\u57fa-3-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u57fa\u5432\u54da\u4e3b\u8981\u901a\u8fc73-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u5432\u54da\u53d1\u751f\u03b1-\u6c27\u5316\u53cd\u5e94\u5f97\u5230\uff0c\u4f46\u8be5\u7c7b\u53cd\u5e94\u5b58\u5728\u8d77\u59cb\u539f\u6599\u5236\u4f5c\u7e41\u7410\u3001\u5e95\u7269\u8303\u56f4\u5c40\u9650\u7b49\u95ee\u9898\uff0c\u56e0\u6b643-\u7f9f\u57fa-3-\u82c4\u57fa\u53d6\u4ee32-\u7f9f\u57fa\u5432\u54da\u5316\u5408\u7269\u7684\u5408\u6210\u4ecd\u7136\u9762\u4e34\u5de8\u5927\u6311\u6218\u3002\u5728\u4e0a\u8ff0\u80cc\u666f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6cb3\u5357\u5e08\u8303\u5927\u5b66\u6c5f\u667a\u52c7\u56e2\u961f\u62a5\u9053\u4e86\u624b\u6027Br\u00f8nsted\u9178\u6216Lewis\u9178\u50ac\u5316\u5242\u50ac\u5316\u7532\u82ef\u53ca\u5176\u884d\u751f\u7269\u4e0e\u975b\u7ea2\u6216\u82ef\u5e76\u4e59\u4e8c\u916e\u7684C(sp3)-H\u76f4\u63a5\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u5408\u6210\u624b\u6027\u53d4\u9187\u5316\u5408\u7269\uff08Fig.2\uff09\u3002\u65b0\u52a0\u5761\u79d1\u6280\u8bbe\u8ba1\u5927\u5b66Richmond Lee\u6559\u6388\u63d0\u4f9b\u4e86\u8ba1\u7b97\u5316\u5b66\u652f\u6301\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e Chiral acid-catalysed enantioselective C\u2212H functionalization of toluene and its derivatives driven by visible light Li, F.; Tian, D.; Fan, Y.; Lee, R.; Lu, G.; Yin, Y.; Qiao, B.; Zhao, X.; Xiao Z.; Jiang, Z.* Nat. Commun. 2019, early view\u00a0DOI: 10.1038\/s41467-019-09857-9 \u4f5c\u8005\u63a8\u6d4b\u53ef\u80fd\u7684\u673a\u7406\uff08Fig.2\uff09\uff1a\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\uff0c\u5bf9\u4e8e\u6fc0\u53d1\u6001\u8fd8\u539f\u7535\u52bf\u4e0e[Acr+-Mes]ClO4\u7535\u52bf\u76f8\u5f53\u7684\u975b\u7ea2\uff08\u59821d\uff09\u53ef\u8f6c\u5316\u4e3a\u5177\u6709\u9ad8\u8fd8\u539f\u7535\u52bf\u7684\u4e09\u91cd\u6fc0\u53d1\u6001I, 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\u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd\uff1a \u7814\u7a76\u8005\uff1a\u6c5f\u667a\u52c7\u6559\u6388 \u7814\u7a76\u8005\u7ecf\u5386\uff1a 1992\u5e749\u6708-1996\u5e746\u6708\uff0c\u6d59\u6c5f\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u7406\u5b66\u5b66\u58eb 1999\u5e749\u6708-2004\u5e741\u6708\uff0c\u6d59\u6c5f\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u6709\u673a\u5316\u5b66\u4e13\u4e1a\u7406\u5b66\u535a\u58eb 2004\u5e742\u6708-2005\u5e744\u6708\uff0c\u9999\u6e2f\u6d78\u4f1a\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08\uff1aWing-Hong Chan\u6559\u6388 2005\u5e748\u6708-2009\u5e748\u6708\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\uff0c\u5316\u5b66\u7cfb\uff0c\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08\uff1aChoon-Hong Tan\u6559\u6388 2013\u5e744\u6708-2013\u5e7410\u6708\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff0c\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u5b66\u9662\uff0c\u9ad8\u7ea7\u7814\u7a76\u5458 2009\u5e748\u6708-2018\uff0c\u6cb3\u5357\u5927\u5b66\uff0c\u6cb3\u5357\u7701\u5929\u7136\u836f\u7269\u4e0e\u514d\u75ab\u5de5\u7a0b\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u5165\u9009\u8005\uff0c\u6cb3\u5357\u7701\u7279\u8058\u6559\u6388\uff08\u6709\u673a\u5316\u5b66\uff09 2018\u5e74\u81f3\u4eca \uff0c\u6cb3\u5357\u5e08\u8303\u5927\u5b66\uff0c\u5316\u5b66\u5316\u5de5\u5b66\u9662 \u9662\u957f \u8363\u8a89\u5956\u9879\uff1a \u6cb3\u5357\u7701\u9752\u5e74\u9aa8\u5e72\u6559\u5e08\uff082010\uff09 \u6cb3\u5357\u7701\u6559\u80b2\u5385\u5b66\u672f\u6280\u672f\u5e26\u5934\u4eba\uff082010\uff09 \u6cb3\u5357\u7701\u9752\u5c11\u5e74\u79d1\u6280\u521b\u65b0\u5956\uff08\u9752\u5e74\u7ec4\uff09\uff082012\uff09 \u6cb3\u5357\u7701\u4f18\u79c0\u9752\u5e74\u79d1\u6280\u4e13\u5bb6\u79f0\u53f7\uff082012\uff09 \u6cb3\u5357\u7701\u7b2c\u5341\u4e00\u5c4a\u9752\u5e74\u79d1\u6280\u5956\uff082012\uff09 \u6cb3\u5357\u7701\u5b66\u672f\u6280\u672f\u5e26\u5934\u4eba\uff082012\uff09 \u6cb3\u5357\u7701\u7b2c\u5341\u4e03\u5c4a\u9752\u5e74\u4e94\u56db\u5956\u7ae0\uff082013\uff09 \u6cb3\u5357\u7701\u6559\u80b2\u5385\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u5956\uff08\u6392\u540d1\uff0c2016\uff09 \u5f00\u5c01\u5e02\u4f18\u79c0\u6559\u5e08\uff082017\uff09 \u6cb3\u5357\u7701\u79d1\u6280\u8fdb\u6b65\u4e8c\u7b49\u5956\uff08\u6392\u540d1\uff0c2017\uff09 \u56fd\u5bb6\u201c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u201d\uff082017\uff09 \u6761\u4ef6\u4f18\u5316\uff1a \u57283 W\u84dd\u5149\u7167\u5c04\u4e0b\uff0c\u975b\u7ea21\u5728\u7532\u82ef\u6eb6\u5242\u4e2d\u7684\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4f18\u5316\uff0c\u4f5c\u8005\u53d1\u73b0\uff0c0.1 mmol 1e\u548c5.0 mmol \u7532\u82ef\u4e3a\u6a21\u677f\u5e95\u7269\uff0c20 mol\uff05 La(OTf)3\u548c22 mol\uff05\u624b\u6027\u7edc\u5408\u7269L1\u4e3a\u50ac\u5316\u5242\uff0c70 mg 4 \u00c5 \u5206\u5b50\u7b5b\u4e3a\u6dfb\u52a0\u7269\uff0cPhCl (4.0 mL)\u4e3a\u6700\u4f18\u6eb6\u5242\uff0c\u572825\u2103\u6761\u4ef6\u4e0b\u53cd\u5e9450 h\uff0c\u80fd\u4ee557%\u7684\u6536\u7387\u548c98%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76ee\u6807\u4ea7\u72692e\u3002\u82e5\u6362\u6210\u65e0\u6eb6\u5242\u6761\u4ef6\uff0c\u5219\u80fd\u4ee5\u4ee571%\u7684\u6536\u7387\u548c98%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff08Table 1\uff09\u3002 \u5e95\u7269\u6269\u5c55\uff1a \u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u8be5\u53cd\u5e94\u7684\u5e95\u7269\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf(Fig. 3)\uff0c\u62ec\u53f7\u4e2d\u7684\u6570\u636e\u4e3a\u65e0\u6eb6\u5242\u6761\u4ef6\u4e0b\u7684\u53cd\u5e94\u60c5\u51b5\u3002\u5404\u79cd\u5438\u7535\u5b50\u3001\u7ed9\u7535\u5b50\u53d6\u4ee3\u7684\u82b3\u73af\u3001\u6c18\u4ee3\u7532\u82ef\u4ee5\u53ca\u6742\u82b3\u73af\u5747\u80fd\u5f88\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u8f83\u9ad8\u7684\u6536\u7387\u548c\u4e2d\u7b49\u81f3\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u82e5\u6362\u6210\u5438\u7535\u5b50\u66f4\u5f3a\u7684\u785d\u57fa\u548c\u4e09\u6c1f\u7532\u57fa\u53d6\u4ee3\u7684\u82b3\u73af\uff0c\u5219\u53ea\u80fd\u751f\u6210\u81ea\u8eab\u5076\u8054\u526f\u4ea7\u7269\u3002\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u4ee5\u53ca\u73af\u72b6\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u80fd\u8f83\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u4e2d\u7b49\u7684\u6536\u7387\u548c\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\uff0c\u4f46\u4e8c\u7ea7\u82c4\u57fa\u884d\u751f\u7269\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027\u8f83\u4f4e\u3002\u5bf9\u4e8e\u4e09\u7ea7\u82b3\u73af\u4e5f\u80fd\u4ee5\u8f83\u4f4e\u7684\u6536\u7387\u548c\u8f83\u9ad8\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\uff0c\u4f46\u5bf9\u4f4d\u53d6\u4ee3\u7684\u4e09\u7ea7\u82b3\u73af\u5f97\u5230\u7684\u4ea7\u7269\u65e0\u5bf9\u6620\u9009\u62e9\u6027\u3002\u540c\u65f6\uff0c\u5404\u79cd\u82b3\u73af\u53d6\u4ee3\u7684\u975b\u7ea2\u4e5f\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\u3002 \u673a\u7406\u7814\u7a76\uff1a \u4e3a\u4e86\u9610\u660e\u673a\u7406\uff0c\u4f5c\u8005\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u7d2b\u5916-\u53ef\u89c1\u5149\u5438\u6536\u5149\u8c31\u5206\u6790\uff0c\u53d1\u73b0\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u65e0\u53d7\u4f53-\u7ed9\u4f53\u914d\u4f4d\u5316\u5408\u7269\u751f\u6210\u3002\u7d27\u63a5\u7740\uff0c\u4f5c\u8005\u53c8\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u5bf9\u7167\u8bd5\u9a8c\u548c\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u7814\u7a76\u3002\u5bf9\u7167\u8bd5\u9a8c\u7684\u6570\u636e\u8bf4\u660eHAT\u8fc7\u7a0b\u4e2d\u786e\u5b9e\u4ea7\u751f\u4e86\u82c4\u57fa\u81ea\u7531\u57fa\uff0c\u540c\u65f6\uff0c\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u7814\u7a76\u8868\u660eC-H\u952e\u65ad\u88c2\u662f\u50ac\u5316\u5faa\u73af\u4e0d\u53ef\u9006\u7684\u7b2c\u4e00\u6b65\uff0c\u662f\u8be5\u53cd\u5e94\u7684\u51b3\u901f\u6b65\u9aa4(Fig. 4).\u3002 \u5e95\u7269\u6269\u5c55\uff1a \u82ef\u5e76\u4e59\u4e8c\u916e6\u5728\u65e0\u6eb6\u5242\u7684\u7532\u82ef\u6eb6\u6db2\u4e2d\u53cd\u5e94\uff0c20 mol% CPA-1\u4e3a\u50ac\u5316\u5242\uff0c80 mg 4 \u00c5 \u4e3a\u6dfb\u52a0\u7269\uff0c\u5728 \u22125 \u00b0C \u6761\u4ef6\u4e0b\u53cd\u5e9460 h\uff0c\u80fd\u4ee551%\u7684\u6536\u7387\u548c90%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u5728\u5f97\u5230\u7684\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u5404\u79cd\u7532\u82ef\u884d\u751f\u7269\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u80fd\u4ee5\u4e2d\u7b49\u7684\u6536\u7387\u548c\u8f83\u9ad8\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u53d4\u9187\u4ea7\u7269(Fig.5)\u3002 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