{"id":25632,"date":"2019-06-17T08:20:27","date_gmt":"2019-06-17T00:20:27","guid":{"rendered":"\/\/www.gsbet888.com\/?p=25632"},"modified":"2019-06-15T15:22:48","modified_gmt":"2019-06-15T07:22:48","slug":"ni%e5%82%ac%e5%8c%96%e4%bc%af%e9%86%87%e7%9a%84%e4%ba%a4%e5%8f%89%e8%84%b1%e6%b0%a2%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2019\/06\/ni%e5%82%ac%e5%8c%96%e4%bc%af%e9%86%87%e7%9a%84%e4%ba%a4%e5%8f%89%e8%84%b1%e6%b0%a2%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Ni\u50ac\u5316\u4f2f\u9187\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"<p>\u683c\u6c0f\u8bd5\u5242\u4e0e\u919b\u7684\u53cd\u5e94\u662fC-C\u952e\u5f62\u6210\u6700\u91cd\u8981\u7b56\u7565\u4e4b\u4e00\u3002\u5176\u4e2d\uff0c\u919b\u662f\u901a\u8fc7\u9187\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u5f97\u5230\u7684\uff0c\u800c\u683c\u5f0f\u8bd5\u5242\u662f\u7531\u7b49\u5f53\u91cf\u7684\u6709\u673a\u5364\u5316\u7269\u4e0e\u91d1\u5c5eMg\u53d1\u751f\u8fd8\u539f\u53cd\u5e94\u5236\u5f97\uff0c\u6700\u540e\u683c\u6c0f\u8bd5\u5242\u518d\u4e0e\u919b\u53cd\u5e94\u5f97\u5230\u4ea7\u7269\u916e\u4e5f\u9700\u8981\u6c27\u5316\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5408\u6210\u4ea7\u7269\u916e\u76f8\u5f53\u4e8e\u7ecf\u5386\u4e863\u6b21\u6c27\u5316\u8fd8\u539f\u6b65\u9aa4\u3002\u8fd9\u79cd\u4f20\u7edf\u7684\u5236\u5907\u916e\u7684\u53cd\u5e94\u539f\u5b50\u5229\u7528\u7387\u8f83\u4f4e\uff0c\u9020\u6210\u4e86\u4e25\u91cd\u7684\u7ecf\u6d4e\u6d6a\u8d39(Scheme 1a)\u3002\u6700\u8fd1\uff0cKrische\u8bfe\u9898\u7ec4\u62a5\u9053\u7684Rh\u50ac\u5316\u9187\u4e0e\u4e8c\u70ef\u76f4\u63a5\u53d1\u751f\u7fb0\u57fa\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u7b56\u7565\u5c06\u591a\u91cd\u6c27\u5316\u53cd\u5e94\u4e0e\u6784\u5efa\u590d\u6742\u4ea7\u7269\u8f6c\u5316\u4e3a\u7b80\u5355\u7684\u50ac\u5316\u6b65\u9aa4\uff0c\u514b\u670d\u4e86\u4f20\u7edf\u65b9\u6cd5\u4e2d\u539f\u5b50\u5229\u7528\u7387\u4f4e\u7684\u95ee\u9898(Scheme 1b)\u3002\u53d7\u5230\u8be5\u62a5\u9053\u7684\u542f\u53d1\u4ee5\u53ca\u4e4b\u524d\u7684\u5de5\u4f5c\uff0c\u52a0\u62ff\u5927\u6e25\u592a\u534e\u5927\u5b66<a href=\"https:\/\/www.newmanlab.ca\/steve\">Stephen G. Newman\u56e2\u961f<\/a>\u62a5\u9053\u4e86Ni\u50ac\u5316\u4f2f\u9187\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e<\/p>\n<blockquote><p>Ketone Synthesis by a Nickel-Catalyzed Dehydrogenative Cross-Coupling of Primary Alcohols<\/p>\n<p>Verheyen, T.; van Turnhout, L.; Vandavasi, J. K.; Isbrandt, E. S.; Borggraeve, W. M. D.; Newman, S. G.* <em>J. Am. Chem. Soc.<\/em> 2019, Just Accepted Manuscript<\/p>\n<p>DOI: 10.1021\/jacs.9b03280<\/p><\/blockquote>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/2-13.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25634 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/2-13.png\" alt=\"\" width=\"443\" height=\"586\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/2-13.png 443w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/2-13-227x300.png 227w\" sizes=\"(max-width: 443px) 100vw, 443px\" \/><\/a><\/p>\n<h4><strong>\u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd\uff1a<\/strong><\/h4>\n<h2><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25635 size-medium\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10-300x203.png\" alt=\"\" width=\"300\" height=\"203\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10-300x203.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10-768x520.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10-680x460.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/3-10.png 889w\" sizes=\"(max-width: 300px) 100vw, 300px\" \/><\/a><\/h2>\n<p>\u8bba\u6587\u4f5c\u8005\uff1aStephen G. Newman \u52a9\u7406\u6559\u6388<\/p>\n<h4><strong>\u6559\u80b2\u80cc\u666f\uff1a<\/strong><\/h4>\n<ul>\n<li>BSc, Dalhousie University<\/li>\n<li>PhD, University of Toronto<\/li>\n<li>NSERC Postdoctoral Fellow,\u00a0MIT<\/li>\n<\/ul>\n<h4><strong>\u83b7\u5956\u60c5\u51b5\uff1a<\/strong><\/h4>\n<ul>\n<li>2007, CSC Silver Medal<\/li>\n<li>2008, University Medal in Chemistry<\/li>\n<li>2008, Dalhousie University Silver Medal<\/li>\n<li>\u200b2011, Boehringer Ingelheim Prize<\/li>\n<li>2013, UofT Chair&#8217;s Doctoral Medal<\/li>\n<li>2015, Thieme Chemistry Journal Awardee<\/li>\n<li>2016, Visiting Professor &#8211; KU Leuven<\/li>\n<li>\u200b2016, John Charles Polanyi Prize<\/li>\n<li>2018, Ontario Early Researcher Award<\/li>\n<li>2019, CNC-IUPAC Travel Award<\/li>\n<li>2014-2019, Tier 2 Canada Research Chair<\/li>\n<\/ul>\n<p>\u7814\u7a76\u65b9\u5411\uff1aTransition metal catalysis, flow chemistry, green chemistry strategies<\/p>\n<h4><strong>\u8bba\u6587\u6982\u8981\uff1a<\/strong><\/h4>\n<p>\u4ee5\u82c4\u9187<strong>1<\/strong>\u548c\u4e09\u6c1f\u7532\u78fa\u9178\u82ef\u916f<strong>2<\/strong>\u4e3a\u6a21\u677f\u5e95\u7269\uff0c\u4f5c\u8005\u5bf9\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u53cd\u590d\u7b5b\u9009\uff0c\u786e\u5b9a\u6700\u4f18\u6761\u4ef6(Table 1)\uff1a10 mol% Ni(cod)<sub>2<\/sub>\u548c12 mol% Triphos\u4e3a\u50ac\u5316\u5242\uff0cTMP\u4e3a\u78b1\uff0c5 equiv\u4e19\u916e\u4e3a\u6c22\u53d7\u4f53\uff0c\u7532\u82ef\u4e3a\u6eb6\u5242\uff0c\u5728130 \u2103\u6761\u4ef6\u4e0b\u53cd\u5e9420 h\uff0c\u80fd\u4ee593%\u7684\u6536\u7387\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/4-10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25636 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/4-10.png\" alt=\"\" width=\"444\" height=\"590\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/4-10.png 444w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/4-10-226x300.png 226w\" sizes=\"(max-width: 444px) 100vw, 444px\" \/><\/a>\u5728\u6700\u4f18\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u5e95\u7269\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\uff08Scheme 2\uff09\u3002\u5404\u79cd\u82b3\u57fa\u53d6\u4ee3\u7684\u9187\u3001\u542b\u82b3\u57fa\u6c2f\u3001\u9170\u80fa\u3001\u96cc\u916e\u9aa8\u67b6\u7684\u9187\u3001\u5404\u79cd\u6742\u73af\u9187\u3001\u5404\u79cd\u8102\u80aa\u9187\u5982\u73af\u5df1\u57fa\u9187\u3001\u73af\u4e19\u57fa\u9187\u3001\u73af\u4e01\u57fa\u9187\u4ee5\u53ca1-\u91d1\u521a\u70f7\u7532\u9187\u5747\u80fd\u8f83\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u826f\u597d\u7684\u6536\u7387\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u5404\u79cd\u82b3\u57fa\u53d6\u4ee3\u3001\u6742\u73af\u53d6\u4ee3\u7684\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u4e5f\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u80fd\u4ee5\u8f83\u9ad8\u7684\u6536\u7387\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u901a\u8fc7\u7b80\u5355\u7684\u884d\u751f\u53cd\u5e94\uff0c\u4f5c\u8005\u53ef\u4ee5\u5408\u6210\u5177\u6709\u5149\u5b66\u6d3b\u6027\u7684\u916a\u6c28\u9178\u884d\u751f\u7269<strong>38<\/strong>\u548c\u542b\u916e\u6297\u7cbe\u795e\u75c5\u836f<strong>41<\/strong>\u548c<strong>44<\/strong>\u3002\u540c\u65f6\uff0c\u963f\u5c14\u8328\u6d77\u9ed8\u6c0f\u75c7\u6cbb\u7597\u836f\u827e\u5730\u82ef\u918c\u548c\u6297\u83cc\u836f\u53ef\u8f6c\u5316\u4e3a\u65b0\u578b\u916e<strong>39<\/strong>\u548c<strong>40<\/strong>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25637 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7.png\" alt=\"\" width=\"941\" height=\"601\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7.png 941w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7-300x192.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7-768x491.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/5-7-680x434.png 680w\" sizes=\"(max-width: 941px) 100vw, 941px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25638 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4.png\" alt=\"\" width=\"940\" height=\"300\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4.png 940w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4-300x96.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4-768x245.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/6-4-680x217.png 680w\" sizes=\"(max-width: 940px) 100vw, 940px\" \/><\/a><\/p>\n<p>\u7d27\u63a5\u7740\uff0c\u4f5c\u8005\u505a\u4e86\u4e00\u7cfb\u5217\u5bf9\u7167\u8bd5\u9a8c\u3002\u901a\u8fc7\u5bf9\u7167\u5b9e\u9a8c\u7684\u673a\u7406\uff0c\u4f5c\u8005\u63a8\u6d4b\u53ef\u80fd\u7684\u673a\u7406\uff1a\u9996\u5148\uff0cNi(0)\u50ac\u5316\u5242<strong>I<\/strong>\u4e0e\u6709\u673a\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u53cd\u5e94\u751f\u6210\u6c27\u5316\u52a0\u6210\u4e2d\u95f4\u4f53<strong>II<\/strong>\u3002<strong>II<\/strong>\u4e0e\u9187\u53cd\u5e94\u53ef\u5f62\u6210\u9187\u76d0<strong>III<\/strong>\uff08\u6c27\u5316\u5faa\u73af1\uff09\u3002<strong>III<\/strong>\u53d1\u751f\u03b2-\u6c22\u6d88\u9664\u53cd\u5e94\u53ef\u5f97\u5230\u919b\u548cNi-\u6c22\u5316\u7269<strong>IV<\/strong>,<strong> IV<\/strong>\u53d1\u751f\u8fd8\u539f\u6d88\u9664\u53ef\u751f\u6210<strong>I<\/strong>\u548c\u8fd8\u539f\u7684\u6709\u673a\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u82b3\u57fa\u954d<strong>II<\/strong>\u53ef\u4e0e\u919b\u53d1\u751f\u63d2\u5165\u53cd\u5e94\u751f\u6210\u9187\u76d0<strong>V<\/strong>\u3002<strong>V<\/strong>\u53d1\u751f\u8fd8\u539f\u6d88\u9664\u53ef\u751f\u6210\u4ea7\u7269\u916e\u548cNi-\u6c22\u5316\u7269<strong>IV\u3002<\/strong>Ni-\u6c22\u5316\u7269<strong>IV<\/strong>\u53ef\u8fd8\u539f\u4e19\u916e\u6dfb\u52a0\u5242\u751f\u6210\u9187\u548c\u7edc\u5408\u7269<strong>VII<\/strong>\uff0c\u751f\u6210\u7684\u9187\u53ef\u4ee5\u7ee7\u7eed\u4e0e\u8d77\u59cb\u539f\u6599\u7684\u9187\u7ed3\u5408\u751f\u6210<strong>VIII<\/strong>\u3002<strong>VIII<\/strong>\u7ecf\u5386\u03b2-\u6c22\u6d88\u9664\u8fc7\u7a0b\u751f\u6210\u919b\uff0c\u540c\u65f6\u91d1\u5c5e\u6c22\u5316\u7269<strong>VI<\/strong>\u518d\u751f\uff08\u6c27\u5316\u5faa\u73af2\uff09\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/7-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-25639 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/7-4.png\" alt=\"\" width=\"436\" height=\"587\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/7-4.png 436w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/7-4-223x300.png 223w\" sizes=\"(max-width: 436px) 100vw, 436px\" \/><\/a><\/p>\n<h4><strong>\u8bba\u6587\u603b\u7ed3\u8bc4\u4ef7\uff1a<\/strong><\/h4>\n<p>\u52a0\u62ff\u5927\u6e25\u592a\u534e\u5927\u5b66<a href=\"https:\/\/www.newmanlab.ca\/steve\">Stephen G. Newman\u56e2\u961f<\/a>\u62a5\u9053\u4e86Ni\u50ac\u5316\u4f2f\u9187\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94\uff0c\u80fd\u4ee5\u9ad8\u6536\u7387\u5f97\u5230\u4e00\u7cfb\u5217\u916e\u3002\u8be5\u53cd\u5e94\u539f\u5b50\u5229\u7528\u7387\u9ad8\uff0c\u4e3a\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u9014\u5f84\u3002<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n<ol>\n<li>Anastas, P.; Eghbali, N.\u00a0<em>\u00a0Chem. Soc. Rev. <\/em><strong>2010<\/strong>, <em>39<\/em>, 301. DOI: <a href=\"https:\/\/doi.org\/10.1039\/B918763B\">10.1039\/B918763B<\/a><\/li>\n<li>Ketcham, J. M.; Shin, I.; Montgomery, T. P.; Krische, M. J.<em> Angew<\/em>.\u00a0<em>Chem.,<\/em> <em>Int. Ed. <\/em><strong>2014<\/strong>, <em>53<\/em>, 9142. DOI: <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201403873\">10.1002\/anie.201403873<\/a><\/li>\n<\/ol>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u683c\u6c0f\u8bd5\u5242\u4e0e\u919b\u7684\u53cd\u5e94\u662fC-C\u952e\u5f62\u6210\u6700\u91cd\u8981\u7b56\u7565\u4e4b\u4e00\u3002\u5176\u4e2d\uff0c\u919b\u662f\u901a\u8fc7\u9187\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u5f97\u5230\u7684\uff0c\u800c\u683c\u5f0f\u8bd5\u5242\u662f\u7531\u7b49\u5f53\u91cf\u7684\u6709\u673a\u5364\u5316\u7269\u4e0e\u91d1\u5c5eMg\u53d1\u751f\u8fd8\u539f\u53cd\u5e94\u5236\u5f97\uff0c\u6700\u540e\u683c\u6c0f\u8bd5\u5242\u518d\u4e0e\u919b\u53cd\u5e94\u5f97\u5230\u4ea7\u7269\u916e\u4e5f\u9700\u8981\u6c27\u5316\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u5408\u6210\u4ea7\u7269\u916e\u76f8\u5f53\u4e8e\u7ecf\u5386\u4e863\u6b21\u6c27\u5316\u8fd8\u539f\u6b65\u9aa4\u3002\u8fd9\u79cd\u4f20\u7edf\u7684\u5236\u5907\u916e\u7684\u53cd\u5e94\u539f\u5b50\u5229\u7528\u7387\u8f83\u4f4e\uff0c\u9020\u6210\u4e86\u4e25\u91cd\u7684\u7ecf\u6d4e\u6d6a\u8d39(Scheme 1a)\u3002\u6700\u8fd1\uff0cKrische\u8bfe\u9898\u7ec4\u62a5\u9053\u7684Rh\u50ac\u5316\u9187\u4e0e\u4e8c\u70ef\u76f4\u63a5\u53d1\u751f\u7fb0\u57fa\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u7b56\u7565\u5c06\u591a\u91cd\u6c27\u5316\u53cd\u5e94\u4e0e\u6784\u5efa\u590d\u6742\u4ea7\u7269\u8f6c\u5316\u4e3a\u7b80\u5355\u7684\u50ac\u5316\u6b65\u9aa4\uff0c\u514b\u670d\u4e86\u4f20\u7edf\u65b9\u6cd5\u4e2d\u539f\u5b50\u5229\u7528\u7387\u4f4e\u7684\u95ee\u9898(Scheme 1b)\u3002\u53d7\u5230\u8be5\u62a5\u9053\u7684\u542f\u53d1\u4ee5\u53ca\u4e4b\u524d\u7684\u5de5\u4f5c\uff0c\u52a0\u62ff\u5927\u6e25\u592a\u534e\u5927\u5b66Stephen G. Newman\u56e2\u961f\u62a5\u9053\u4e86Ni\u50ac\u5316\u4f2f\u9187\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e Ketone Synthesis by a Nickel-Catalyzed Dehydrogenative Cross-Coupling of Primary Alcohols Verheyen, T.; van Turnhout, L.; Vandavasi, J. K.; Isbrandt, E. S.; Borggraeve, W. M. D.; Newman, S. G.* J. Am. Chem. Soc. 2019, Just Accepted Manuscript DOI: 10.1021\/jacs.9b03280 \u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd\uff1a \u8bba\u6587\u4f5c\u8005\uff1aStephen G. Newman \u52a9\u7406\u6559\u6388 \u6559\u80b2\u80cc\u666f\uff1a BSc, Dalhousie University PhD, University of Toronto NSERC Postdoctoral Fellow,\u00a0MIT \u83b7\u5956\u60c5\u51b5\uff1a 2007, CSC Silver Medal 2008, University Medal in Chemistry 2008, Dalhousie University Silver Medal \u200b2011, Boehringer Ingelheim Prize 2013, UofT Chair&#8217;s Doctoral Medal 2015, Thieme Chemistry Journal Awardee 2016, Visiting Professor &#8211; KU Leuven \u200b2016, John Charles Polanyi Prize 2018, Ontario Early Researcher Award 2019, CNC-IUPAC Travel Award 2014-2019, Tier [&hellip;]","protected":false},"author":24,"featured_media":25633,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/06\/1-13.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-6Fq","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/25632"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/24"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=25632"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/25632\/revisions"}],"predecessor-version":[{"id":25659,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/25632\/revisions\/25659"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/25633"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=25632"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=25632"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=25632"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}