{"id":2850,"date":"2014-10-16T23:58:41","date_gmt":"2014-10-16T15:58:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=2850"},"modified":"2019-08-02T18:56:15","modified_gmt":"2019-08-02T10:56:15","slug":"post-2850","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94\/2014\/10\/post-2850.html","title":{"rendered":"Kochi-F\u00fcrstner\u5076\u8054\u53cd\u5e94(Kochi-F\u00fcrstner Cross Coupling)"},"content":{"rendered":"

\u6982\u8981<\/strong><\/li>\n<\/ul>\n
\u5364\u5316\u82b3\u70c3\u30fb\u82b3\u57fa\u4e09\u6c1f\u7532\u78fa\u9178\u30fb\u82b3\u57fa\u78fa\u9178\u76d0\u4e0eGrignard\u8bd5\u5242\u5728\u94c1\u50ac\u5316\u5242<\/strong>\u7684\u4f5c\u7528\u4e0b\u8fdb\u884c\u7684\u5076\u8054\u53cd\u5e94\u3002\u6c2f\u5316\u82b3\u70c3\u662f\u8be5\u53cd\u5e94\u6700\u597d\u7684\u5e95\u7269\u3002\u800c\u6eb4\u5316\u82b3\u70c3\u4e0e\u7898\u5316\u82b3\u70c3\u5728\u8be5\u6761\u4ef6\u4e0b\u4f18\u5148\u53d1\u751f\u8131\u5364\u7d20\u5316\u53cd\u5e94\u3002<\/p>\n
\u6700\u521dJ. K. Kochi<\/a>\u7b49\u4eba\u53ea\u62a5\u9053\u4e86\u4ee5\u5364\u4ee3\u70ef\u70c3\u4f5c\u4e3a\u5e95\u7269\u7684\u53cd\u5e94\u5b9e\u4f8b\uff0c\u8fd1\u5e74\u6765 A.<\/a>F\u00fcrstner<\/a>\u5b9e\u9a8c\u5ba4\u53d1\u73b0\u5728\u8be5\u7c7b\u53cd\u5e94\u4e2d\u6dfb\u52a0NMP(N-methylpyrrolidone)\u53ef\u4ee5\u5b9e\u73b0\u5e95\u7269\u7684\u4e00\u822c\u6027\u6269\u5c55\uff0c\u4f7f\u5f97\u8be5\u53cd\u5e94\u53d8\u5f97\u66f4\u52a0\u5b9e\u7528\u3002<\/p>\n
\u8be5\u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u90fd\u662f\u5ec9\u4ef7\u7684\u6c2f\u4ee3\u82b3\u70c3\uff0c\u5ec9\u4ef7\u4f4e\u6bd2\u6027\u4e14\u79f0\u53d6\u65b9\u4fbf\u7684\u94c1(III)\uff0c\u800c\u53cd\u5e94\u6761\u4ef6\u4e5f\u662f\u5341\u5206\u6e29\u548c\u76840\u5ea6\uff5e\u5ba4\u6e29\u7684Practical\u6761\u4ef6\uff0c\u53cd\u5e94\u65f6\u95f4\u4e5f\u5341\u5206\u77ed\u6682(\u901a\u5e385\uff5e10\u5206)\uff0c\u5e76\u4e14\u5177\u6709\u5f88\u9ad8\u7684\u5b98\u80fd\u56e2\u9009\u62e9\u6027\uff0c\u662f\u4e00\u4e2a\u6781\u5176\u5177\u6709\u5f00\u53d1\u6f5c\u529b\u7684\u53cd\u5e94\u3002<\/strong>\u671f\u5f85\u53cd\u5e94\u672a\u6765\u7684\u53d1\u5c55\u3002<\/p>\n
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\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n\u30fb Tamura, M.; Kochi, J. K. J. Am. Chem. Soc.<\/em> 1971<\/strong>, 93<\/em>, 1487. DOI: 10.1021\/ja00735a030<\/a>
\n\u30fb F\u00fcrstner, A.; Leitner, A. Angew. Chem. Int. Ed.<\/em> 2002<\/strong>, 41<\/em>, 609. [abstract]<\/a>
\n\u30fb F\u00fcrstner, A.; Leitner, A.; Mendez, M.; Krause, H. J. Am. Chem. Soc.<\/em> 2002<\/strong>, 124<\/em>, 13856. DOI:10.1021\/ja027190t<\/a>
\n\u30fb Review\uff1a F\u00fcrstner, A.; Martin, R. Chem. Lett.<\/em> 2005<\/strong>, 34<\/em>, 624. doi:10.1246\/cl.2005.624<\/a><\/p>\n
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\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n\u5728\u53cd\u5e94\u4e2d\uff0c\u9ad8\u4ef7\u94c1\u50ac\u5316\u5242\u4e0eGrignard\u8bd5\u5242\u53cd\u5e94\uff0c\u751f\u6210\u4f4e\u4ef7\u6001\u7684\u590d\u6742\u7684\u914d\u4f53Fe(-II)<\/strong>\u4e2d\u95f4\u4f53\uff0c\u4e5f\u662f\u8be5\u4e2d\u95f4\u4f53\u51b3\u5b9a\u4e86\u53cd\u5e94\u7684\u9ad8\u5b98\u80fd\u56e2\u9009\u62e9\u6027\u3002(\u53c2\u8003\uff1aAngew. Chem. Int. Ed.<\/a><\/em>2000<\/strong>, 39<\/em>, 4610.<\/a>)\u3002\u7531\u4e8e\u5364\u4ee3\u03b1\u4f4d\u78b3\u539f\u5b50\u4e0a\u7684\u7acb\u4f53\u7ed3\u6784\u7684\u6d88\u5931\uff0c\u6240\u4ee5\u8fd9\u4e5f\u8bf4\u660e\u6c27\u5316\u52a0\u6210\u662f\u6309\u7167\u81ea\u7531\u57fa\u673a\u7406<\/strong>\u8fdb\u884c\u7684\u3002<\/p>\n
$\"kochi_furstner_2\"$ <\/a><\/p>\n
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\n
\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n
\u8fd1\u5e74\u6765\uff0c\u94c1\u50ac\u5316\u7684\u7814\u7a76\u4e0d\u65ad\u53d6\u5f97\u8fdb\u5c55\uff0c\u901a\u5e38\u5bf9\u4e8e\u4e0d\u5bb9\u6613\u53d1\u751f\u5076\u8054\u53cd\u5e94\u76842\u7ea7sp^{3<\/sup>-\u70f7\u57fa\u5364\u4ee3\u7269\u7684\u5076\u8054\u53cd\u5e94\u4e5f\u540c\u6837\u88ab\u5f00\u53d1\u5e94\u7528\u3002\u7279\u522b\u662fF\u00fcrstner\u7b49\u4eba\u5f00\u53d1\u7684[Li_{2<\/sub>(tmeda)][Fe(ethylene)_{4<\/sub>]\u87af\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\u7684\u8bdd[1]\uff0c\u5373\u4f7f\u5e95\u7269\u4e2d\u6709\u5f02\u6c30\u9178\u916f\u8fd9\u7c7b\u9ad8\u53cd\u5e94\u6027\u7684\u57fa\u56e2\u5b58\u5728\u4e5f\u4e0d\u53d7\u5f71\u54cd\uff0c\u5364\u4ee3\u4f4d\u7f6e\u76f4\u63a5\u4e0eGrignard\u5b9e\u9645\u8fc5\u901f\u7684\u5076\u8054\u53cd\u5e94\u3002<\/p>\n}}}
\u8fd1\u5e74\u6765\uff0c\u4e2d\u6751\u7b49\u4eba\u4f7f\u7528\u94c3\u6728\u5076\u8054\u53cd\u5e94\u7684\u6761\u4ef6\u987a\u5229\u8fdb\u884c\u4e86\u8be5\u53cd\u5e94[2]\u3002<\/p>\n
$\"kochi_furstner_3\"$ <\/a><\/p>\n
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\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n
\u5b9e\u9a8c\u5b9e\u4f8b[3]\n
$\"kochi_furstner_4\"$ <\/a><\/p>\n
\u5728\u88c5\u5907\u6709\u6405\u62cc\u5b50\u76842L\u7684\u4e8c\u9888\u5706\u5e95\u70e7\u74f6\u4e2d\uff0c\u5728Ar\u4fdd\u62a4\u4e0b\uff0c\u52a0\u51654-chlorobenzoic acid methyl ester (13.0 g, 76.2 mmol)\u3001 Fe(acac)_{3<\/sub> (1.35 g, 3.82 mmol, 0.05 eq)\u3001THF\uff08450mL\uff09\u3001N<\/em>-methylpyrrolidinone (25mL)\u3002\u5728\u51b0\u6d74\u4e0b\uff0c\u7528\u805a\u4e59\u70ef\u5957\u7ba11\u5206\u949f\u5185\u8fc5\u901f\u52a0\u5165\u8c03\u914d\u597d\u7684nonylmagnesium bromide \uff0897.0 mmol in THF, 1.25eq\uff09\u3002\u6eb6\u6db2\u7684\u989c\u8272\u8fc5\u901f\u4ece\u7ea2\u8272\u5411\u6d53\u6697\u7d2b\u8272\u53d8\u5316\u3002\u7136\u540e\u79fb\u9664\u51b0\u6d74\uff0c\u6eb6\u6db2\u5728\u5ba4\u6e29\u4e0b\u6405\u62cc7\uff5e10\u5206\u949f\u3002\u7528\u4e59\u919a\uff08200mL\uff09\u7a00\u91ca\u540e\uff0c\u7f13\u6162\u52a0\u51651M\u76d0\u9178\uff08300mL\uff09\u731d\u706d\u53cd\u5e94\u3002\u8403\u53d6\uff0c\u6c34\u76f8\u7528\u4e59\u919a\uff08200mL\uff09\u518d\u6b21\u8403\u53d6\u3002\u5408\u5e76\u6709\u51e0\u5c42\u540e\u7528\u9971\u548c\u78b3\u9178\u6c22\u94a0\u6c34\u6eb6\u6db2\uff08300mL\uff09\u8403\u53d6\u6d17\u51c0\uff0c\u7528\u65e0\u6c34\u786b\u9178\u94a0\u5e72\u71e5\u3002\u6ee4\u8fc7\u540e\uff0c\u65cb\u8f6c\u84b8\u53d1\u6d53\u7f29\u3002\u5f97\u5230\u7684\u6a59\u7ea2\u8272\u7684\u7c97\u4ea7\u7269\u7528\u51cf\u538b\u84b8\u998f(1×10^{-4<\/sup> torr, bp 103-105\u2103)\u63d0\u7eaf\uff0c\u5f97\u5230\u65e0\u8272\u6cb9\u72b6\u76ee\u6807\u4ea7\u7269\uff0815.81-16.85 g, \u53ce\u738779-84%\uff09\u3002<\/p>\n}}
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\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n\n
\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n[1]\n[2] Hatakeyama,T.; Hashimoto, T.; Kondo, Y.; Fujiwara, Y.; Seike,H.; Takaya, H.; Tamada, Y.; Ono, T.; Nakamura, M. J. Am. Chem. Soc.<\/em> 2010<\/strong>, ASAP. doi:10.1021\/ja103973a<\/a>
\n[3] Furstner, A.; Leitner, A.; Seidel, G. Org. Synth.<\/em> 2005<\/strong>, 81<\/em>, 33. [PDF]<\/a><\/p>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u5364\u5316\u82b3\u70c3\u30fb\u82b3\u57fa\u4e09\u6c1f\u7532\u78fa\u9178\u30fb\u82b3\u57fa\u78fa\u9178\u76d0\u4e0eGrignard\u8bd5\u5242\u5728\u94c1\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\u8fdb\u884c\u7684\u5076\u8054\u53cd\u5e94\u3002\u6c2f\u5316\u82b3\u70c3\u662f\u8be5\u53cd\u5e94\u6700\u597d\u7684\u5e95\u7269\u3002\u800c\u6eb4\u5316\u82b3\u70c3\u4e0e\u7898\u5316\u82b3\u70c3\u5728\u8be5\u6761\u4ef6\u4e0b\u4f18\u5148\u53d1\u751f\u8131\u5364\u7d20\u5316\u53cd\u5e94\u3002 \u6700\u521dJ. K. Kochi\u7b49\u4eba\u53ea\u62a5\u9053\u4e86\u4ee5\u5364\u4ee3\u70ef\u70c3\u4f5c\u4e3a\u5e95\u7269\u7684\u53cd\u5e94\u5b9e\u4f8b\uff0c\u8fd1\u5e74\u6765A.F\u00fcrstner\u5b9e\u9a8c\u5ba4\u53d1\u73b0\u5728\u8be5\u7c7b\u53cd\u5e94\u4e2d\u6dfb\u52a0NMP(N-methylpyrrolidone)\u53ef\u4ee5\u5b9e\u73b0\u5e95\u7269\u7684\u4e00\u822c\u6027\u6269\u5c55\uff0c\u4f7f\u5f97\u8be5\u53cd\u5e94\u53d8\u5f97\u66f4\u52a0\u5b9e\u7528\u3002 \u8be5\u53cd\u5e94\u4e2d\u4f7f\u7528\u7684\u90fd\u662f\u5ec9\u4ef7\u7684\u6c2f\u4ee3\u82b3\u70c3\uff0c\u5ec9\u4ef7\u4f4e\u6bd2\u6027\u4e14\u79f0\u53d6\u65b9\u4fbf\u7684\u94c1(III)\uff0c\u800c\u53cd\u5e94\u6761\u4ef6\u4e5f\u662f\u5341\u5206\u6e29\u548c\u76840\u5ea6\uff5e\u5ba4\u6e29\u7684Practical\u6761\u4ef6\uff0c\u53cd\u5e94\u65f6\u95f4\u4e5f\u5341\u5206\u77ed\u6682(\u901a\u5e385\uff5e10\u5206)\uff0c\u5e76\u4e14\u5177\u6709\u5f88\u9ad8\u7684\u5b98\u80fd\u56e2\u9009\u62e9\u6027\uff0c\u662f\u4e00\u4e2a\u6781\u5176\u5177\u6709\u5f00\u53d1\u6f5c\u529b\u7684\u53cd\u5e94\u3002\u671f\u5f85\u53cd\u5e94\u672a\u6765\u7684\u53d1\u5c55\u3002 \u57fa\u672c\u6587\u732e \u30fb Tamura, M.; Kochi, J. K. J. Am. Chem. Soc. 1971, 93, 1487. DOI: 10.1021\/ja00735a030 \u30fb F\u00fcrstner, A.; Leitner, A. Angew. Chem. Int. Ed. 2002, 41, 609. [abstract] \u30fb F\u00fcrstner, A.; Leitner, A.; Mendez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. DOI:10.1021\/ja027190t \u30fb Review\uff1a F\u00fcrstner, A.; Martin, R. Chem. Lett. 2005, 34, 624. doi:10.1246\/cl.2005.624 \u53cd\u5e94\u673a\u7406 \u5728\u53cd\u5e94\u4e2d\uff0c\u9ad8\u4ef7\u94c1\u50ac\u5316\u5242\u4e0eGrignard\u8bd5\u5242\u53cd\u5e94\uff0c\u751f\u6210\u4f4e\u4ef7\u6001\u7684\u590d\u6742\u7684\u914d\u4f53Fe(-II)\u4e2d\u95f4\u4f53\uff0c\u4e5f\u662f\u8be5\u4e2d\u95f4\u4f53\u51b3\u5b9a\u4e86\u53cd\u5e94\u7684\u9ad8\u5b98\u80fd\u56e2\u9009\u62e9\u6027\u3002(\u53c2\u8003\uff1aAngew. Chem. Int. Ed.2000, 39, 4610.)\u3002\u7531\u4e8e\u5364\u4ee3\u03b1\u4f4d\u78b3\u539f\u5b50\u4e0a\u7684\u7acb\u4f53\u7ed3\u6784\u7684\u6d88\u5931\uff0c\u6240\u4ee5\u8fd9\u4e5f\u8bf4\u660e\u6c27\u5316\u52a0\u6210\u662f\u6309\u7167\u81ea\u7531\u57fa\u673a\u7406\u8fdb\u884c\u7684\u3002 \u53cd\u5e94\u5b9e\u4f8b \u8fd1\u5e74\u6765\uff0c\u94c1\u50ac\u5316\u7684\u7814\u7a76\u4e0d\u65ad\u53d6\u5f97\u8fdb\u5c55\uff0c\u901a\u5e38\u5bf9\u4e8e\u4e0d\u5bb9\u6613\u53d1\u751f\u5076\u8054\u53cd\u5e94\u76842\u7ea7sp3-\u70f7\u57fa\u5364\u4ee3\u7269\u7684\u5076\u8054\u53cd\u5e94\u4e5f\u540c\u6837\u88ab\u5f00\u53d1\u5e94\u7528\u3002\u7279\u522b\u662fF\u00fcrstner\u7b49\u4eba\u5f00\u53d1\u7684[Li2(tmeda)][Fe(ethylene)4]\u87af\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\u7684\u8bdd[1]\uff0c\u5373\u4f7f\u5e95\u7269\u4e2d\u6709\u5f02\u6c30\u9178\u916f\u8fd9\u7c7b\u9ad8\u53cd\u5e94\u6027\u7684\u57fa\u56e2\u5b58\u5728\u4e5f\u4e0d\u53d7\u5f71\u54cd\uff0c\u5364\u4ee3\u4f4d\u7f6e\u76f4\u63a5\u4e0eGrignard\u5b9e\u9645\u8fc5\u901f\u7684\u5076\u8054\u53cd\u5e94\u3002 \u8fd1\u5e74\u6765\uff0c\u4e2d\u6751\u7b49\u4eba\u4f7f\u7528\u94c3\u6728\u5076\u8054\u53cd\u5e94\u7684\u6761\u4ef6\u987a\u5229\u8fdb\u884c\u4e86\u8be5\u53cd\u5e94[2]\u3002 \u5b9e\u9a8c\u6b65\u9aa4 \u5b9e\u9a8c\u5b9e\u4f8b[3] \u5728\u88c5\u5907\u6709\u6405\u62cc\u5b50\u76842L\u7684\u4e8c\u9888\u5706\u5e95\u70e7\u74f6\u4e2d\uff0c\u5728Ar\u4fdd\u62a4\u4e0b\uff0c\u52a0\u51654-chlorobenzoic acid methyl ester (13.0 g, 76.2 mmol)\u3001 Fe(acac)3 (1.35 g, 3.82 mmol, 0.05 eq)\u3001THF\uff08450mL\uff09\u3001N-methylpyrrolidinone (25mL)\u3002\u5728\u51b0\u6d74\u4e0b\uff0c\u7528\u805a\u4e59\u70ef\u5957\u7ba11\u5206\u949f\u5185\u8fc5\u901f\u52a0\u5165\u8c03\u914d\u597d\u7684nonylmagnesium bromide \uff0897.0 mmol in THF, 1.25eq\uff09\u3002\u6eb6\u6db2\u7684\u989c\u8272\u8fc5\u901f\u4ece\u7ea2\u8272\u5411\u6d53\u6697\u7d2b\u8272\u53d8\u5316\u3002\u7136\u540e\u79fb\u9664\u51b0\u6d74\uff0c\u6eb6\u6db2\u5728\u5ba4\u6e29\u4e0b\u6405\u62cc7\uff5e10\u5206\u949f\u3002\u7528\u4e59\u919a\uff08200mL\uff09\u7a00\u91ca\u540e\uff0c\u7f13\u6162\u52a0\u51651M\u76d0\u9178\uff08300mL\uff09\u731d\u706d\u53cd\u5e94\u3002\u8403\u53d6\uff0c\u6c34\u76f8\u7528\u4e59\u919a\uff08200mL\uff09\u518d\u6b21\u8403\u53d6\u3002\u5408\u5e76\u6709\u51e0\u5c42\u540e\u7528\u9971\u548c\u78b3\u9178\u6c22\u94a0\u6c34\u6eb6\u6db2\uff08300mL\uff09\u8403\u53d6\u6d17\u51c0\uff0c\u7528\u65e0\u6c34\u786b\u9178\u94a0\u5e72\u71e5\u3002\u6ee4\u8fc7\u540e\uff0c\u65cb\u8f6c\u84b8\u53d1\u6d53\u7f29\u3002\u5f97\u5230\u7684\u6a59\u7ea2\u8272\u7684\u7c97\u4ea7\u7269\u7528\u51cf\u538b\u84b8\u998f(1×10-4 torr, bp 103-105\u2103)\u63d0\u7eaf\uff0c\u5f97\u5230\u65e0\u8272\u6cb9\u72b6\u76ee\u6807\u4ea7\u7269\uff0815.81-16.85 g, \u53ce\u738779-84%\uff09\u3002 \u5b9e\u9a8c\u6280\u5de7 […]","protected":false},"author":5,"featured_media":2851,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[3],"tags":[562,552],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/09\/kochi_furstner_1.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-JY","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2850"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=2850"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2850\/revisions"}],"predecessor-version":[{"id":28074,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2850\/revisions\/28074"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/2851"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=2850"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=2850"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=2850"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}