{"id":28868,"date":"2019-10-08T10:09:41","date_gmt":"2019-10-08T02:09:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=28868"},"modified":"2019-10-10T14:58:16","modified_gmt":"2019-10-10T06:58:16","slug":"%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e4%b8%89%e8%82%a1%e9%9d%9e%e5%b8%b8%e8%a7%84%e5%8a%9b%e9%87%8f%ef%bc%88%e4%b8%8a%ef%bc%89-%e5%85%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/2019\/10\/%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e4%b8%89%e8%82%a1%e9%9d%9e%e5%b8%b8%e8%a7%84%e5%8a%9b%e9%87%8f%ef%bc%88%e4%b8%8a%ef%bc%89-%e5%85%89.html","title":{"rendered":"\u6709\u673a\u5408\u6210\u4e2d\u7684\u4e09\u80a1\u975e\u5e38\u89c4\u529b\u91cf\uff08\u4e0a\uff09-\u5149"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005\uff1a\u8283\u6d0b\u96ea<\/p>\n<p>\u6709\u673a\u5408\u6210\u7684\u6838\u5fc3\u662f\u5c06\u7b80\u5355\u7684\u53cd\u5e94\u7269\u6216\u8bd5\u5242\u7ec4\u5408\uff0c\u7ecf\u8fc7\u9009\u62e9\u6027\u53cd\u5e94\u6210\u4e3a\u66f4\u590d\u6742\u7684\u5206\u5b50\uff0c\u53cd\u5e94\u6210\u529f\u7684\u5173\u952e\u662f\u514b\u670d\u53cd\u5e94\u80fd\u5792\uff0c\u8fd9\u9700\u8981\u5411\u53cd\u5e94\u4f53\u7cfb\u63d0\u4f9b\u80fd\u91cf\uff0c\u901a\u5e38\u7684\u505a\u6cd5\u662f\u52a0\u70ed\uff0c\u56e0\u6b64\uff0c\u5728\u6709\u673a\u5b9e\u9a8c\u5ba4\u4e2d\u6700\u5e38\u89c1\u7684\u60c5\u5f62\u662f\u53cd\u5e94\u6cb9\u6d74\u4e2d\u653e\u4e2a\u70e7\u74f6\u3002\u4f46\u8fd1\u51e0\u5e74\u6765\uff0c\u5176\u4ed6\u4f9b\u80fd\u65b9\u5f0f\u5f00\u59cb\u51fa\u73b0\uff0c\u5c24\u5176\u662f\u5149\u3001\u7535\u548c\u673a\u68b0\u4e09\u79cd\u529b\u91cf\u3002\u6700\u8fd1\u6765\u81ea\u6fb3\u5927\u5229\u4e9a\u56fd\u7acb\u5927\u5b66Australian National University\u7684<strong>Michelle Coote<\/strong>\u6559\u6388\u548cUniversity of Tasmania\u5854\u65af\u9a6c\u5c3c\u4e9a\u5927\u5b66<strong> Alex Bissember<\/strong>\u535a\u58eb\u4ecb\u7ecd\u4e86\u5176\u4e2d\u7684\u5178\u578b\u4ee3\u8868\u53cd\u5e94\uff0c<\/p>\n<blockquote><p>Synthetic applications of light, electricity, mechanical force and flow<\/p>\n<p>Johnathon C. Robertson, Michelle L. Coote &amp; Alex C. Bissember<\/p>\n<p><em>\u00a0Nature Reviews Chemistry<\/em>, 2019, 3, 290\u2013304 , <a href=\"https:\/\/doi.org\/10.1038\/s41570-019-0094-2\">DOI: org\/10.1038\/s41570-019-0094-2<\/a>.<\/p><\/blockquote>\n<h3>\uff08\u4e0a\uff09\u53ef\u89c1\u5149<\/h3>\n<p>\u8fd1\u51e0\u5e74\u6765\uff0c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u662f\u6d3b\u8dc3\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u53ef\u4ee5\u7528\u4f4e\u5f3a\u5ea6\u7684\u53ef\u89c1\u5149\u80fd\u91cf\uff0c\u7528\u4e8e\u8fdb\u884c\u6709\u4ef7\u503c\u7684\u5408\u6210\u53cd\u5e94\u3002\u6d41\u52a8\u5316\u5b66\u88c5\u7f6e\u7684\u53d1\u5c55\u4fc3\u8fdb\u4e86\u5149\u5316\u5b66\u53cd\u5e94\uff0c\u8fd9\u79cd\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u800c\u4e14\u5927\u90e8\u5206\u7269\u8d28\u5bf9\u53ef\u89c1\u5149\u4e0d\u654f\u611f\u3002\u867d\u7136\u53cd\u5e94\u7269\u4f1a\u5438\u6536\u7d2b\u5916\u5149\uff0c\u4f46\u4e0d\u5438\u6536\u53ef\u89c1\u5149\uff0c\u53ef\u4ee5\u51cf\u5c11\u4e0d\u5fc5\u8981\u7684\u526f\u53cd\u5e94\uff0c\u4e0b\u9762\u4ecb\u7ecd\u51e0\u4f8b\u5149\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n<h4>\u5149\u50ac\u5316\u4e0d\u5bf9\u79f0\u53cd\u5e94<\/h4>\n<p>\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u5149\u5316\u5b66\u8fdb\u884c\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u9700\u8981\u4e24\u90e8\u5206\uff0c\u9664\u5149\u50ac\u5316\u5242\u5916\uff0c\u8fd8\u9700\u8981\u624b\u6027\u5171\u50ac\u5316\u5242\u6216\u989d\u5916\u7684\u6dfb\u52a0\u7269\u6765\u63a7\u5236\u624b\u6027\u3002\u7136\u800c\u76f4\u63a5\u63a7\u5236\u624b\u6027\u7684\u4e5f\u6709\u62a5\u9053\uff0c\u5982\u56fe1a\u6240\u793a\u7684\u94f1\u50ac\u5316\u5242Ir\u7528\u4e8e\u4e0d\u5bf9\u79f0\u03b1-\u70f7\u57fa\u5316\u53cd\u5e94\u3002\u5e95\u7269\u916e<strong>2<\/strong>\u548c\u94f1\u50ac\u5316\u5242<strong>3<\/strong>\u7ed3\u5408\u5f62\u6210\u4e2d\u95f4\u4f53<strong>4<\/strong>\uff0c\u5728\u5149\u7167\u4e0b\u6d3b\u5316\uff0cIr\u590d\u5408\u7269\u8fd8\u539f\u6eb4\u5316\u7269<strong>2<\/strong>\uff0c\u751f\u6210\u7684\u81ea\u7531\u57fa\u88ab<strong>4<\/strong>\u7684\u624b\u6027\u73af\u5883\u63a7\u5236\uff0c\u53ea\u80fd\u901a\u8fc7\u70ef\u9187\u5e73\u9762\u7ed3\u6784\u7684\u4e00\u9762\u53cd\u5e94\uff0c\u4ece\u800c\u5f97\u5230\u5149\u5b66\u7eaf\u5ea6\u7684\u4ea7\u7269<strong>5<\/strong>,\u5982\u56fe1a\u6240\u793a\u3002\u8fd9\u4e2a\u53cd\u5e94\u7684\u5173\u952e\u662f\u5149\u6d3b\u6027\u7684\u624b\u6027Ir\u590d\u5408\u7269\u7684\u7edd\u5bf9\u7acb\u4f53\u7ed3\u6784\u4e00\u76f4\u4fdd\u6301<sup>[1]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28869 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1.png\" alt=\"\" width=\"822\" height=\"166\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1.png 1591w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-300x61.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-768x155.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-680x137.png 680w\" sizes=\"(max-width: 822px) 100vw, 822px\" \/><\/a><\/p>\n<p style=\"text-align: center\">\u56fe1a. \u624b\u6027Ir\u590d\u5408\u7269\u50ac\u5316\u4e0d\u5bf9\u79f0\u03b1-\u70f7\u57fa\u5316\u53cd\u5e94. \u56fe\u7247\u6765\u6e90\uff1a<em>Nature Reviews Chemistry<\/em><\/p>\n<p>\u518d\u4e00\u4e2a\u53cd\u5e94\u4f8b\u662fCu<sup>\u2160<\/sup>\u548c\u5546\u4e1a\u5316\u624b\u6027\u81a6\uff08S\uff09-8\u4ecb\u5bfc\u7684\u624b\u6027\u5408\u6210C-N\u952e\u5076\u8054\u53cd\u5e94\u3002\u539f\u4f4d\u751f\u6210\u7684\u624b\u6027\u5149\u6d3b\u6027\u8bd5\u5242\u662f\u7acb\u4f53\u9009\u62e9\u6027\u8f6c\u5316\u53cd\u5e94\u7684\u5173\u952e\uff0c\u5728\u8fd9\u4e2a\u53cd\u5e94\u6848\u4f8b\u4e2d\uff0c\u7535\u5b50\u4ece\u5149\u6d3b\u5316\u7684Cu<sup>\u2160<\/sup>\u5494\u5511\u76d0\u4e0a\u8f6c\u79fb\uff0c\u5c066\u8fd8\u539f\u4e3aCl<sup>&#8211;<\/sup>\u548c\u70f7\u57fa\u81ea\u7531\u57fa\uff0c\u7136\u540e\u548cCu<sup>\u2161<\/sup>\u5494\u5511\u76d0\u5076\u8054\uff0c\u518d\u901a\u8fc7\u5bf9\u6620\u4f53\u6536\u655b\u8f6c\u5316\u7684\u5f62\u5f0f\u8f6c\u5316\u4e3a10\uff0c\u5982\u56fe1b\u6240\u793a<sup>[2]<\/sup>\u3002\u8fd9\u662f\u9996\u6b21\u7528\u5149\u6d3b\u6027\u7684Cu<sup>\u2160<\/sup>\u5494\u5511\u76d0\u50ac\u5316C-N\u5076\u8054\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28870 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2.png\" alt=\"\" width=\"865\" height=\"179\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2.png 1511w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-300x62.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-768x159.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-680x140.png 680w\" sizes=\"(max-width: 865px) 100vw, 865px\" \/><\/a><\/p>\n<p style=\"text-align: center\">\u56fe1b. Cu<sup>\u2160<\/sup>\u548c\u624b\u6027\u81a6\u4ecb\u5bfc\u7684\u4e0d\u5bf9\u79f0\u6d88\u65cb\u70f7\u57fa\u5364\u5316\u7269\u548c\u5432\u54da\/\u5494\u5511\u7684C-N\u952e\u5076\u8054\u53cd\u5e94.<\/p>\n<p style=\"text-align: center\">\u56fe\u7247\u6765\u6e90\uff1a<em>Nature Reviews Chemistry<\/em><\/p>\n<h4>\u8fde\u7eed\u5149\u4ecb\u5bfc\u7684\u7535\u5b50\u8f6c\u79fb<\/h4>\n<p>\u5177\u6709\u8f83\u5927\u8fd8\u539f\u7535\u4f4d\u7684\u5e95\u7269\uff0c\u9700\u8981\u5149\u50ac\u5316\u5242\u5177\u6709\u8db3\u591f\u5f3a\u7684\u5149\u8fd8\u539f\u80fd\u529b\uff08E&lt;-2.0V vs\u9971\u548c\u7518\u6c5e\u7535\u6781SCE\uff09\uff0c\u8fd9\u9700\u8981\u5f00\u53d1\u5229\u7528\u9ad8\u5ea6\u8fd8\u539f\u6027\u7684\u5149\u4ecb\u5bfc\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u4f8b\u5982\u6c22\u5316\u8131\u5364\u53cd\u5e94\u3001\u82b3\u57fa\u5316\u53cd\u5e94\u3001\u73af\u5408\u53cd\u5e94\uff0c\u6d3b\u5316\u7684\u82b3\u57fa\u5364\u5316\u7269<strong>11<\/strong>\u53ef\u4ee5\u901a\u8fc7\u82dd\u4e8c\u9170\u4e9a\u80fa<strong>12\u00a0<\/strong>perylene diimide\uff08PDI\uff09\u4f5c\u4e3a\u5149\u6d3b\u5316\u7684\u6c27\u5316\u8fd8\u539f\u8bd5\u5242\u3002\u4e0e\u53cd\u5e94\u76f8\u6bd4\uff0c\u673a\u7406\u66f4\u5438\u5f15\u4eba\u3002\u6fc0\u53d1\u6001\u7684PDI12<sup>*<\/sup>\u548c\u9634\u79bb\u5b50\u81ea\u7531\u57fa12<sup>.-<\/sup>\u8bf4\u660e\u8fd9\u4e9b\u5316\u5408\u7269\u4e0d\u80fd\u8fd8\u539f\u82b3\u57fa\u5364\u5316\u726911\uff0c\u7136\u800c12\u80fd\u591f\u6700\u7ec8\u83b7\u5f97\u4e24\u4e2a\u5149\u5b50\u5f62\u6210\u5f3a\u8fd8\u539f\u8bd5\u5242\u6fc0\u53d1\u7684\u81ea\u7531\u57fa\u9634\u79bb\u5b5012<sup>.-*<\/sup>\uff0c\u5b83\u53ef\u4ee5\u8fd8\u539f11\uff0c\u5982\u56fe1c\u6240\u793a<sup>[3]<\/sup>\u3002\u4f46\u8fd9\u4e5f\u6709\u4e89\u8bae\u8ba4\u4e3a\u5373\u4f7f\u662f12<sup>.-*<\/sup>\u8fd8\u4e0d\u80fd\u8db3\u4ee5\u8fd8\u539f11\u5b8c\u6210\u8f6c\u5316\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28871 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3.png\" alt=\"\" width=\"903\" height=\"244\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3.png 1681w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-300x81.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-768x207.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-680x184.png 680w\" sizes=\"(max-width: 903px) 100vw, 903px\" \/><\/a><\/p>\n<p style=\"text-align: center\">\u56fe1c.\u5149\u50ac\u5316\u82dd\u4e8c\u9170\u4e9a\u80faPDI\u901a\u8fc7\u53cc\u5149\u5b50\u9014\u5f84\u8fdb\u884c\u6c22\u5316\u8131\u5364\u53cd\u5e94\u548c\u82b3\u57fa\u5316\u53cd\u5e94\uff0c12<sup>.-*<\/sup>\u662f\u91cd\u8981\u7684\u5f3a\u8fd8\u539f\u5242. \u56fe\u7247\u6765\u6e90\uff1a<em>Nature Reviews Chemistry<\/em><\/p>\n<h4>\u5149\u5f15\u53d1\u4ea7\u751f\u6c34\u5408\u7535\u5b50<\/h4>\n<p>\u6c34\u5408\u7535\u5b50\u662f\u6781\u5f3a\u7684\u8fd8\u539f\u5242\uff0c<em>E<\/em><sub>red<\/sub>=-2.6V vs SCE\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u5408\u6210\u3002Ru\u7edc\u5408\u7269<strong>16\u00a0<\/strong>[Ru(bpy)<sub>3<\/sub>]Cl<sub>2<\/sub>\u4f5c\u4e3a\u5149\u654f\u5242\uff0c\u53ef\u4ee5\u53d1\u751f\u53cc\u5149\u5b50\u7684\u5149\u53cd\u5e94\u4ea7\u751f\u6c34\u5408\u7535\u5b50\uff0c\u5c06\u6c2f\u4e59\u9178\u916f\u8fd8\u539f\uff0c\u671f\u95f4\u6297\u574f\u8840\u9178\u94a0NaHAsc\u4f5c\u4e3a\u8f85\u52a9\u8fd8\u539f\u5242\uff0c\u5c06\u5149\u6fc0\u53d1\u6001\u7684[16]<sup>2+*<\/sup>\u8fd8\u539f\u4e3a[16]<sup>+<\/sup>\uff0c\u7eff\u8272\u6fc0\u5149\u6fc0\u53d1[16]<sup>+<\/sup>\u5438\u6536\u7b2c\u4e8c\u4e2a\u5149\u5b50\uff0c\u4ea7\u751f\u6c34\u5408\u7535\u5b50<sup>[4]<\/sup>\u3002\u8fd9\u4e2a\u53cd\u5e94\u6761\u4ef6\u8fd8\u53ef\u4ee5\u8fdb\u884c\u5176\u4ed6\u8fd8\u539f\u53cd\u5e94\uff0c\u5982\u6c22\u5316\u8131\u6c1f\u53cd\u5e94\uff0c\u7fb0\u57fa\u8fd8\u539f\uff0c\u4ee5\u53ca\u5176\u4ed6\u8fd8\u539f\u7535\u52bf\u4f4e\u4e8e-2.0V vs SCE\u7684\u5e95\u7269\u6c22\u5316\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28872 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4.png\" alt=\"\" width=\"893\" height=\"193\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4.png 1469w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4-300x65.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4-768x166.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/4-680x147.png 680w\" sizes=\"(max-width: 893px) 100vw, 893px\" \/><\/a><\/p>\n<p style=\"text-align: center\">\u56fe1d. \u6e29\u548c\u6761\u4ef6\u4e0bRu\u7edc\u5408\u7269\u751f\u6210\u6c34\u5408\u7535\u5b50\u8fd8\u539f\u6c2f\u4e59\u9178\u916f. \u56fe\u7247\u6765\u6e90\uff1a<em>Nature Reviews Chemistry<\/em><\/p>\n<h4>\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u4e2d\u7684\u8109\u51b2\u5f0f\u8f90\u5c04<\/h4>\n<p>\u5728\u5149\u50ac\u5316\u9886\u57df\uff0c\u5927\u91cf\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u3001\u5171\u50ac\u5316\u5242\u6216\u8005\u6dfb\u52a0\u7269\u589e\u5f3a\u53cd\u5e94\u6d3b\u6027\uff0c\u6269\u5927\u53cd\u5e94\u5e94\u7528\u8303\u56f4\u7b49\u3002\u8fd9\u4e9b\u52aa\u529b\u90fd\u7528\u5230\u4e86\u9ad8\u529f\u7387\u7684\u5149\u6e90\u6216\u53d1\u5149\u4e8c\u6781\u7ba1LEDs\uff0c\u4ee5\u6301\u7eed\u53d1\u51faUV\u6216\u8005\u56fa\u5b9a\u6ce2\u957f\u7684\u53ef\u89c1\u5149\u3002\u800cLED\u8109\u51b2\u8f90\u5c04\uff0c\u589e\u5f3a\u4e86\u5149\u5408\u6210\u7684\u6d3b\u6027\uff0c\u4fc3\u8fdb\u4e86\u5149\u5316\u5b66\u7684\u4ea7\u751f\u548c\u6210\u957f\u3002\u4f8b\u5982\u5728\u4e00\u9879\u81ea\u5b9a\u4e49\u591a\u76f8\u7535\u8def\u7814\u7a76\uff0c\u5206\u522b\u7528100KHz,10KHz\u548c1Hz\u7684\u53ef\u89c1\u5149\u8f90\u5c04\u8fdb\u884c25%\u7684\u5faa\u73af\uff0c\u5148\u5f0025%\u65f6\u95f4\uff0c\u7136\u540e\u518d\u517375%\u65f6\u95f4\u3002\u8109\u51b2\u8f90\u5c04\u8fdb\u884c\u03b1-\u6c28\u57fa\u7684C-H\/C-F\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u6fc0\u53d1\u9891\u7387\u8d8a\u4f4e\uff0c\u53cd\u5e94\u901f\u7387\u8d8a\u4f4e\uff0c\u751a\u81f3\u4e0d\u80fd\u5b8c\u5168\u8f6c\u5316\u3002\u5e38\u89c4\u7684\u84dd\u8272LED\u5149\u6301\u7eed\u7167\u5c04\uff0c\u4e5f\u4e0d\u80fd\u5b8c\u5168\u8f6c\u5316\uff0c\u589e\u52a0\u53cd\u5e94\u65f6\u95f4\u81f365h\u7684\u6536\u7387\u4e3a61%\u3002\u968f\u540e\u7684\u6269\u5927\u5316\u7814\u7a76\u4e2d\u53d1\u73b0\uff0c\u8109\u51b2LED\u8f90\u5c04\u5728\u5927\u591a\u6570\u53cd\u5e94\u4e2d\u90fd\u80fd\u589e\u5f3a\u6548\u7387\uff0c\u76ee\u524d\u5177\u4f53\u539f\u56e0\u73b0\u5728\u8fd8\u672a\u77e5\uff0c\u53ef\u80fd\u548c\u6fc0\u53d1\u6001\u4e2d\u95f4\u4f53\u76f8\u5173<sup>[5]<\/sup>\u3002\u4e0e\u4e4b\u7c7b\u4f3c\u7684\u662f\u8109\u51b2IR\u7ea2\u5916\u8f90\u5c04\u53ef\u4ee5\u9009\u62e9\u6027\u6fc0\u53d1\u9187\u7684\u03bd<sub>OH<\/sub>,\u52a0\u901f\u8f6c\u5316\u4e3a\u6c28\u57fa\u7532\u9178\u4e59\u8102\u548c\u805a\u6c28\u916f\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28873 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5.png\" alt=\"\" width=\"919\" height=\"559\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5.png 1413w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5-300x182.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5-768x467.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5-680x413.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/5-660x400.png 660w\" sizes=\"(max-width: 919px) 100vw, 919px\" \/><\/a><\/p>\n<p style=\"text-align: center\">\u56fe2a. \u8109\u51b2\u84dd\u5149LED\u8f90\u5c04\u4e0b\u94dc\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u50ac\u5316\u7684\u03b1-\u6c28\u57fa\u7684C-H\/C-F\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94.<\/p>\n<p style=\"text-align: center\">\u56fe\u7247\u6765\u6e90\uff1a<em>Nature Reviews Chemistry<\/em><\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li>Huo, H. et al. Asymmetric photoredox transition-metal catalysis activated by visible light. <em>Nature 515<\/em>, 100\u2013103 (<strong>2014<\/strong>).<\/li>\n<li>Kainz, Q. M. et al. Asymmetric copper-catalyzed C\u2013N cross-couplings induced by visible light. <em>Science<\/em> <em>351<\/em>, 681\u2013684 (<strong>2016<\/strong>).<\/li>\n<li>Ghosh, I., Ghosh, T., Bardagi, J. I. &amp; K\u00f6nig, B. Reduction of aryl halides by consecutive visible light-induced electron transfer processes. <em>Science<\/em> <em>346<\/em>, 725\u2013728 (<strong>2014<\/strong>).<\/li>\n<li>Naumann, R., Kerzig, C. &amp; Goez, M. Laboratory-scale photoredox catalysis using hydrated electrons sustainably generated with a single green laser. <em>Chem. Sci.<\/em> <em>8<\/em>, 7510\u20137520 (<strong>2017<\/strong>).<\/li>\n<li>Nicholls, T. P., Robertson, J. C., Gardiner, M. G. &amp; Bissember, A. C. Identifying the potential of pulsed LED irradiation in synthesis: copper-photocatalyzed C\u2013F functionalisation. <em>Chem. Commun<\/em>.<em> 54<\/em>, 4589\u20134592 (<strong>2018<\/strong>).<\/li>\n<\/ol>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u8283\u6d0b\u96ea \u6709\u673a\u5408\u6210\u7684\u6838\u5fc3\u662f\u5c06\u7b80\u5355\u7684\u53cd\u5e94\u7269\u6216\u8bd5\u5242\u7ec4\u5408\uff0c\u7ecf\u8fc7\u9009\u62e9\u6027\u53cd\u5e94\u6210\u4e3a\u66f4\u590d\u6742\u7684\u5206\u5b50\uff0c\u53cd\u5e94\u6210\u529f\u7684\u5173\u952e\u662f\u514b\u670d\u53cd\u5e94\u80fd\u5792\uff0c\u8fd9\u9700\u8981\u5411\u53cd\u5e94\u4f53\u7cfb\u63d0\u4f9b\u80fd\u91cf\uff0c\u901a\u5e38\u7684\u505a\u6cd5\u662f\u52a0\u70ed\uff0c\u56e0\u6b64\uff0c\u5728\u6709\u673a\u5b9e\u9a8c\u5ba4\u4e2d\u6700\u5e38\u89c1\u7684\u60c5\u5f62\u662f\u53cd\u5e94\u6cb9\u6d74\u4e2d\u653e\u4e2a\u70e7\u74f6\u3002\u4f46\u8fd1\u51e0\u5e74\u6765\uff0c\u5176\u4ed6\u4f9b\u80fd\u65b9\u5f0f\u5f00\u59cb\u51fa\u73b0\uff0c\u5c24\u5176\u662f\u5149\u3001\u7535\u548c\u673a\u68b0\u4e09\u79cd\u529b\u91cf\u3002\u6700\u8fd1\u6765\u81ea\u6fb3\u5927\u5229\u4e9a\u56fd\u7acb\u5927\u5b66Australian National University\u7684Michelle Coote\u6559\u6388\u548cUniversity of Tasmania\u5854\u65af\u9a6c\u5c3c\u4e9a\u5927\u5b66 Alex Bissember\u535a\u58eb\u4ecb\u7ecd\u4e86\u5176\u4e2d\u7684\u5178\u578b\u4ee3\u8868\u53cd\u5e94\uff0c Synthetic applications of light, electricity, mechanical force and flow Johnathon C. Robertson, Michelle L. Coote &amp; Alex C. 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\u56fe2a. \u8109\u51b2\u84dd\u5149LED\u8f90\u5c04\u4e0b\u94dc\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u50ac\u5316\u7684\u03b1-\u6c28\u57fa\u7684C-H\/C-F\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94. \u56fe\u7247\u6765\u6e90\uff1aNature Reviews Chemistry \u53c2\u8003\u6587\u732e Huo, H. et al. 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