{"id":28899,"date":"2019-10-09T12:40:24","date_gmt":"2019-10-09T04:40:24","guid":{"rendered":"\/\/www.gsbet888.com\/?p=28899"},"modified":"2019-10-09T12:40:24","modified_gmt":"2019-10-09T04:40:24","slug":"%e4%b8%96%e7%95%8c%e8%91%97%e5%90%8d%e5%8c%96%e5%ad%a6%e5%ae%b6-%e6%9d%91%e4%b8%8a-%e6%ad%a3%e6%b5%a9-masahiro-murakami","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemists\/2019\/10\/%e4%b8%96%e7%95%8c%e8%91%97%e5%90%8d%e5%8c%96%e5%ad%a6%e5%ae%b6-%e6%9d%91%e4%b8%8a-%e6%ad%a3%e6%b5%a9-masahiro-murakami.html","title":{"rendered":"\u4e16\u754c\u8457\u540d\u5316\u5b66\u5bb6\u2014\u2014\u6751\u4e0a \u6b63\u6d69 (Masahiro Murakami)"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005\uff1aalberto-caeiro<\/p>\n<p>\u6751\u4e0a \u6b63\u6d69<sup>[1]<\/sup> (Masahiro Murakami)\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u5927\u5b66\u9662\u6559\u6388\uff0c\u4e3b\u8981\u4ece\u4e8b\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u548c\u6709\u673a\u5408\u6210\u5316\u5b66\u7814\u7a76\u3002\u56fe\u7247\uff1a<a href=\"https:\/\/www.icomc2018.com\/masahiro-murakami\/\">ICOMC2018<\/a>\uff0c\u4e2a\u4eba\u7b80\u5386\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201108679\">ACIE, 2012, 2808<\/a> &amp; <a href=\"http:\/\/www.sbchem.kyoto-u.ac.jp\/murakami-lab\/index.html\">Homepage<\/a>\u3002<\/p>\n<h4>\u7ecf\u5386<\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>1979, The University of Tokyo, B. Sc.;<\/li>\n<li>1981, The University of Tokyo, M. Sc.;<\/li>\n<li>1984, The University of Tokyo D. Sc. Advisor: Prof. Mukaiyama;<\/li>\n<li>1984-1987, The University of Tokyo, Assistant Researcher;<\/li>\n<li>1987-1993, Kyoto University, Assistant Researcher;<\/li>\n<li>1991-1992, ETH Z\u00fcrich, Switzerland Postdoctoral Fellow, Advisor: Prof. Eschenmoser;<\/li>\n<li>1993-2001, Kyoto University Associate Professor;<\/li>\n<li>2002-now, Kyoto University, Professor.<\/li>\n<\/ul>\n<h4>\u83b7\u5956\u7ecf\u5386<\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>The Chemical Society of Japan Award for Young Chemists, 1989;<\/li>\n<li>The Chemical Society of Japan Award for Creative Work, 2004;<\/li>\n<li>Nagoya Silver Medal, 2008;<\/li>\n<li>Synthetic Organic Chemistry Award, Japan, 2013.<\/li>\n<\/ul>\n<h4>\u5de5\u4f5c\u4ecb\u7ecd<\/h4>\n<ol>\n<li><strong>\u4ee5\u5149\u4f5c\u4e3a\u80fd\u6e90\u7684\u5316\u5b66\u8f6c\u5316<sup>[2]<\/sup><\/strong><\/li>\n<\/ol>\n<p>\u81ea\u7136\u754c\u4eceCO<sub>2<\/sub>\u548cH<sub>2<\/sub>O\u51fa\u53d1\uff0c\u4ee5\u5149\u4f5c\u4e3a\u80fd\u6e90\u5408\u6210\u78b3\u6c34\u5316\u5408\u7269\u7684\u5149\u5408\u4f5c\u7528\u8fc7\u7a0b\u53ef\u4ee5\u88ab\u5206\u4e3a\u4e24\u4e2a\u9636\u6bb5\u2014\u2014\u5149\u53cd\u5e94\u9636\u6bb5\u548c\u6697\u53cd\u5e94\u9636\u6bb5\u3002\u5728\u5149\u53cd\u5e94\u9636\u6bb5\u4e2d\uff0c\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u5bcc\u80fd\u7269\u79cd\uff0c\u6697\u53cd\u5e94\u9636\u6bb5\u4e2d\uff0c\u5bcc\u80fd\u7269\u79cd\u901a\u8fc7\u70ed\u53cd\u5e94\u91ca\u653e\u80fd\u91cf\u5f62\u6210\u78b3\u6c34\u5316\u5408\u7269\u3002<\/p>\n<p>\u6751\u4e0a\u6559\u6388\u4ee5\u6b64\u4e24\u6b65\u673a\u7406\u4e3a\u57fa\u7840\uff0c\u8bbe\u8ba1\u4e86\u901a\u8fc7\u5149\u53cd\u5e94\u4ea7\u751f\u5bcc\u80fd\u7269\u79cd\uff0c\u5e76\u5728\u968f\u540e\u7684\u70ed\u53cd\u5e94\u4e2d\u91ca\u653e\u80fd\u91cf\u7684\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86\u975e\u6d3b\u5316\u7269\u8d28\u5982CO<sub>2<\/sub>\u7684\u5316\u5b66\u8f6c\u5316\u3002\u5728a\u4e2d\uff0c\u901a\u8fc7Norrish I\u578b\u5149\u53cd\u5e94\u751f\u6210\u7684N-\u6742\u73af\u4e01\u9187\u5728\u78b1\u7684\u4f5c\u7528\u4e0b\u53ef\u5b9e\u73b0CO<sub>2<\/sub>\u7684\u56fa\u5b9a<sup>[2a]<\/sup>\uff1b\u5728b\u4e2d\u5219\u662f\u5149\u7167\u540e\u5f62\u6210\u9ad8\u80fd\u53cc\u70ef\u4e2d\u95f4\u4f53\u4e0eCO<sub>2<\/sub>\u53d1\u751fD-A\u53cd\u5e94\uff0c\u5e95\u7269\u53d7\u6fc0\u53d1\u83b7\u5f97\u7684\u80fd\u91cf\u7684\u8fc7\u7a0b\u662f\u53cd\u5e94\u7684\u5185\u5728\u9a71\u52a8\u529b<sup>[2d]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28900 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2.png\" alt=\"\" width=\"685\" height=\"572\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2.png 831w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2-300x250.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2-768x640.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/1-2-680x567.png 680w\" sizes=\"(max-width: 685px) 100vw, 685px\" \/><\/a><\/p>\n<ol start=\"2\">\n<li><strong>\u975e\u6d3b\u5316\u952e\u7684\u5316\u5b66\u8f6c\u5316<sup>[3]<\/sup><\/strong><\/li>\n<\/ol>\n<p>\u4f20\u7edf\u6709\u673a\u5316\u5b66\u4e2d\uff0c\u5316\u5408\u7269\u7684\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u901a\u5e38\u4f4d\u4e8e\u03c0\u952e\uff0c\u5982C=C\u548cC=O\uff0c\u6781\u6027\u03c3\u952e\uff0c\u5982C-X\u952e\uff0cC-M\u952e\u3002\u800c\u4f4e\u6781\u6027\u03c3\u952eC-H\u952e\u548c\u975e\u6781\u6027\u952eC\u2013C\u952e\u7684\u53cd\u5e94\u6d3b\u6027\u5219\u8f83\u4f4e\u3002\u56e0\u6b64\uff0c\u5982\u679c\u975e\u6d3b\u6027\u952e\u80fd\u591f\u7528\u4e8e\u5316\u5b66\u8f6c\u5316\uff0c\u5316\u5b66\u5408\u6210\u7684\u6f5c\u529b\u5c06\u4f1a\u6781\u5927\u7684\u62d3\u5c55\u3002<\/p>\n<p>\u84ec\u52c3\u53d1\u5c55\u7684\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u53ef\u4ee5\u5f88\u597d\u7684\u9002\u7528\u4e8e\u975e\u6d3b\u6027\u952e\u7684\u6d3b\u5316\u53ca\u8f6c\u5316\u8fc7\u7a0b\u3002\u6751\u4e0a\u6559\u6388\u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u954d\u548c\u94d1\uff0c\u5b9e\u73b0\u4e86\u73af\u4e01\u916e\u975e\u6d3b\u6027C-C\u952e\u7684\u5207\u65ad\uff0c\u5e76\u4ee5\u6b64\u4e3a\u57fa\u7840\uff0c\u5b9e\u73b0\u4e86\u591a\u79cdC-C\u952e\u7684\u6784\u5efa\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28901 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2.png\" alt=\"\" width=\"625\" height=\"392\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2.png 844w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2-300x188.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2-768x481.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2-2-680x426.png 680w\" sizes=\"(max-width: 625px) 100vw, 625px\" \/><\/a><\/p>\n<ol start=\"3\">\n<li><strong>\u7aef\u7094\u7684\u4e00\u9505\u591a\u5b98\u80fd\u56e2\u5316<sup>[4,5]<\/sup><\/strong><\/li>\n<\/ol>\n<p>\u7aef\u7094\u662f\u4e00\u79cd\u5927\u5b97\u7684\u5316\u5de5\u539f\u6599\uff0c\u5e76\u4e14\u5177\u6709\u597d\u7684\u7a33\u5b9a\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u3002\u56e0\u6b64\u7094\u70c3\u5e38\u88ab\u7528\u505a\u5316\u5b66\u5408\u6210\u7684\u8d77\u59cb\u539f\u6599\u3002\u6751\u4e0a\u6559\u6388\u81f4\u529b\u4e8e\u4e00\u9505\u6cd5\u5b9e\u73b0\u7094\u70c3\u7684\u591a\u91cd\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u5b9e\u73b0\u590d\u6742\u5206\u5b50\u7684\u5408\u6210\u3002\u5982\u5728a\u4e2d\uff0c\u53e0\u6c2e\u5316\u5408\u7269\u4e0e\u7094\u70c3\u53d1\u751f[3+2]\u73af\u52a0\u6210\u53cd\u5e94(Huisgen reaction)\u5f62\u6210\u7684\u4e09\u5511\uff0c\u968f\u540e\u5728\u94d1\u7684\u50ac\u5316\u4e0b\u8131N<sub>2<\/sub>\uff0c\u5f97\u5230\u542b\u6c2e\u7684\u591a\u73af\u5316\u5408\u7269\u3002\u5728b\u4e2d\u5219\u662f\u6c22\u787c\u5316\u540e\u53cc\u952e\u79fb\u4f4d\u5f62\u6210\u70ef\u4e19\u57fa\u787c\uff0c\u968f\u540e\u53d1\u751f\u70f7\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-28902 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2.png\" alt=\"\" width=\"724\" height=\"471\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2.png 1016w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2-300x195.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2-768x500.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2-680x442.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/3-2-260x170.png 260w\" sizes=\"(max-width: 724px) 100vw, 724px\" \/><\/a><\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>[1] Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2012<\/strong>, <em>51<\/em>, 2808, <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201108679\">doi.org\/10.1002\/anie.201108679<\/a>;<\/li>\n<li>[2] a. Naoki Ishida, Yasuhiro Shimamoto, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2012<\/strong>, <em>51<\/em>, 11750. <a href=\"dx.doi.org\/10.1002\/anie.201206166\">DOI: 10.1002\/anie.201206166<\/a>; b. Naoki Ishida, Shota Sawano, Masahiro Murakami, <em>Nat. Commun.<\/em>, <strong>2014<\/strong>, <em>5<\/em>, 3111. <a href=\"https:\/\/www.nature.com\/articles\/ncomms4111.pdf\">DOI: 10.1038\/ncomms4111<\/a>; c. Naoki Ishida, David Ne\u010das, Yusuke Masuda, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2015<\/strong>, <em>54<\/em>, 7418. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201502584\">DOI: 10.1002\/anie.201502584<\/a>; d. Yusuke Masuda, Naoki Ishida, Masahiro Murakami, <em>J. Am. Chem. Soc.<\/em>, <strong>2015<\/strong>, <em>137<\/em>, 14063. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5b10032\">DOI: 10.1021\/jacs.5b10032<\/a>; e.<\/li>\n<li>[3] a. Masahiro Murakami, Hideki Amii, Yoshihiko Ito, <em>Nature<\/em>, <strong>1994<\/strong>, <em>370<\/em>, 540. <a href=\"https:\/\/www.nature.com\/articles\/370540a0\">doi.org\/10.1038\/370540a0<\/a>; b. Masahiro Murakami, Tamon Itahashi, Yoshihiko Ito, <em>J. Am. Chem. Soc<\/em>., <strong>2002<\/strong>, <em>124<\/em>, 13976. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja021062n\">DOI: 10.1021\/ja021062n<\/a>; c. Akira Yada, Shoichiro Fujita, Masahiro Murakami, <em>J. Am. Chem. Soc.<\/em>, <strong>2014<\/strong>, <em>136<\/em>, 7217. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja502229c\">DOI: 10.1021\/ja502229c<\/a>; d. Naoki Ishida, Shintaro Okumura, Tairin Kawasaki, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2018<\/strong>, <em>57<\/em>, 11399. <a href=\"dx.doi.org\/10.1002\/anie.201805333\">DOI: 10.1002\/anie.201805333<\/a>;<\/li>\n<li>[4] a. Tomoya Miura, Tsuneaki Biyajima, Tetsuji Fujii, Masahiro Murakami, <em>J. Am. Chem. Soc.<\/em>, <strong>2012<\/strong>, <em>134<\/em>, 194. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja2104203\">DOI: 10.1021\/ja2104203<\/a>; b. Tomoya Miura, Takamasa Tanaka, Kentaro Hiraga, Scott G. Stewart, Masahiro Murakami, <em>J. Am. Chem. Soc.<\/em>, <strong>2013<\/strong>, <em>135<\/em>, 13652. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja407166r\">DOI: 10.1021\/ja407166r<\/a>; c. Tomoya Miura, Yoshikazu Fujimoto, Yuuta Funakoshi, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2015<\/strong>, <em>54<\/em>, 9967. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201504013\">DOI: 10.1002\/anie.201504013<\/a>;<\/li>\n<li>[5] a. Hiroshi Shimizu, Tomohiro Igarashi, Tomoya Miura, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2011<\/strong>, <em>50<\/em>, 11465. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201105148\">DOI: 10.1002\/anie.201105148<\/a>; b. Tomoya Miura, Yui Nishida, Masahiro Murakami, <em>J. Am. Chem. Soc.<\/em>, <strong>2014<\/strong>, <em>136<\/em>, 6223. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja502169d\">DOI: 10.1021\/ja502169d<\/a>; c. Tomoya Miura, Junki Nakahashi, Takanori Sasatsu, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2019<\/strong>, <em>58<\/em>, 1138. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201811205\">DOI: 10.1002\/anie.201811205<\/a>; d. Tomoya Miura, Naoki Oku, Masahiro Murakami, <em>Angew. Chem., Int. Ed.<\/em>, <strong>2019<\/strong>, <em>in press<\/em>, <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201908299\">DOI: 10.1002\/anie.201908299<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1aalberto-caeiro \u6751\u4e0a \u6b63\u6d69[1] (Masahiro Murakami)\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u5927\u5b66\u9662\u6559\u6388\uff0c\u4e3b\u8981\u4ece\u4e8b\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u548c\u6709\u673a\u5408\u6210\u5316\u5b66\u7814\u7a76\u3002\u56fe\u7247\uff1aICOMC2018\uff0c\u4e2a\u4eba\u7b80\u5386\uff1aACIE, 2012, 2808 &amp; Homepage\u3002 \u7ecf\u5386 1979, The University of Tokyo, B. Sc.; 1981, The University of Tokyo, M. Sc.; 1984, The University of Tokyo D. Sc. Advisor: Prof. Mukaiyama; 1984-1987, The University of Tokyo, Assistant Researcher; 1987-1993, Kyoto University, Assistant Researcher; 1991-1992, ETH Z\u00fcrich, Switzerland Postdoctoral Fellow, Advisor: Prof. Eschenmoser; 1993-2001, Kyoto University Associate Professor; 2002-now, Kyoto University, Professor. \u83b7\u5956\u7ecf\u5386 The Chemical Society of Japan Award for Young Chemists, 1989; The Chemical Society of Japan Award for Creative Work, 2004; Nagoya Silver Medal, 2008; Synthetic Organic Chemistry Award, Japan, 2013. \u5de5\u4f5c\u4ecb\u7ecd \u4ee5\u5149\u4f5c\u4e3a\u80fd\u6e90\u7684\u5316\u5b66\u8f6c\u5316[2] \u81ea\u7136\u754c\u4eceCO2\u548cH2O\u51fa\u53d1\uff0c\u4ee5\u5149\u4f5c\u4e3a\u80fd\u6e90\u5408\u6210\u78b3\u6c34\u5316\u5408\u7269\u7684\u5149\u5408\u4f5c\u7528\u8fc7\u7a0b\u53ef\u4ee5\u88ab\u5206\u4e3a\u4e24\u4e2a\u9636\u6bb5\u2014\u2014\u5149\u53cd\u5e94\u9636\u6bb5\u548c\u6697\u53cd\u5e94\u9636\u6bb5\u3002\u5728\u5149\u53cd\u5e94\u9636\u6bb5\u4e2d\uff0c\u5149\u6fc0\u53d1\u540e\u4ea7\u751f\u5bcc\u80fd\u7269\u79cd\uff0c\u6697\u53cd\u5e94\u9636\u6bb5\u4e2d\uff0c\u5bcc\u80fd\u7269\u79cd\u901a\u8fc7\u70ed\u53cd\u5e94\u91ca\u653e\u80fd\u91cf\u5f62\u6210\u78b3\u6c34\u5316\u5408\u7269\u3002 \u6751\u4e0a\u6559\u6388\u4ee5\u6b64\u4e24\u6b65\u673a\u7406\u4e3a\u57fa\u7840\uff0c\u8bbe\u8ba1\u4e86\u901a\u8fc7\u5149\u53cd\u5e94\u4ea7\u751f\u5bcc\u80fd\u7269\u79cd\uff0c\u5e76\u5728\u968f\u540e\u7684\u70ed\u53cd\u5e94\u4e2d\u91ca\u653e\u80fd\u91cf\u7684\u8fc7\u7a0b\uff0c\u5b9e\u73b0\u4e86\u975e\u6d3b\u5316\u7269\u8d28\u5982CO2\u7684\u5316\u5b66\u8f6c\u5316\u3002\u5728a\u4e2d\uff0c\u901a\u8fc7Norrish I\u578b\u5149\u53cd\u5e94\u751f\u6210\u7684N-\u6742\u73af\u4e01\u9187\u5728\u78b1\u7684\u4f5c\u7528\u4e0b\u53ef\u5b9e\u73b0CO2\u7684\u56fa\u5b9a[2a]\uff1b\u5728b\u4e2d\u5219\u662f\u5149\u7167\u540e\u5f62\u6210\u9ad8\u80fd\u53cc\u70ef\u4e2d\u95f4\u4f53\u4e0eCO2\u53d1\u751fD-A\u53cd\u5e94\uff0c\u5e95\u7269\u53d7\u6fc0\u53d1\u83b7\u5f97\u7684\u80fd\u91cf\u7684\u8fc7\u7a0b\u662f\u53cd\u5e94\u7684\u5185\u5728\u9a71\u52a8\u529b[2d]\u3002 \u975e\u6d3b\u5316\u952e\u7684\u5316\u5b66\u8f6c\u5316[3] \u4f20\u7edf\u6709\u673a\u5316\u5b66\u4e2d\uff0c\u5316\u5408\u7269\u7684\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\u901a\u5e38\u4f4d\u4e8e\u03c0\u952e\uff0c\u5982C=C\u548cC=O\uff0c\u6781\u6027\u03c3\u952e\uff0c\u5982C-X\u952e\uff0cC-M\u952e\u3002\u800c\u4f4e\u6781\u6027\u03c3\u952eC-H\u952e\u548c\u975e\u6781\u6027\u952eC\u2013C\u952e\u7684\u53cd\u5e94\u6d3b\u6027\u5219\u8f83\u4f4e\u3002\u56e0\u6b64\uff0c\u5982\u679c\u975e\u6d3b\u6027\u952e\u80fd\u591f\u7528\u4e8e\u5316\u5b66\u8f6c\u5316\uff0c\u5316\u5b66\u5408\u6210\u7684\u6f5c\u529b\u5c06\u4f1a\u6781\u5927\u7684\u62d3\u5c55\u3002 \u84ec\u52c3\u53d1\u5c55\u7684\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u53ef\u4ee5\u5f88\u597d\u7684\u9002\u7528\u4e8e\u975e\u6d3b\u6027\u952e\u7684\u6d3b\u5316\u53ca\u8f6c\u5316\u8fc7\u7a0b\u3002\u6751\u4e0a\u6559\u6388\u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u954d\u548c\u94d1\uff0c\u5b9e\u73b0\u4e86\u73af\u4e01\u916e\u975e\u6d3b\u6027C-C\u952e\u7684\u5207\u65ad\uff0c\u5e76\u4ee5\u6b64\u4e3a\u57fa\u7840\uff0c\u5b9e\u73b0\u4e86\u591a\u79cdC-C\u952e\u7684\u6784\u5efa\u3002 \u7aef\u7094\u7684\u4e00\u9505\u591a\u5b98\u80fd\u56e2\u5316[4,5] \u7aef\u7094\u662f\u4e00\u79cd\u5927\u5b97\u7684\u5316\u5de5\u539f\u6599\uff0c\u5e76\u4e14\u5177\u6709\u597d\u7684\u7a33\u5b9a\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u3002\u56e0\u6b64\u7094\u70c3\u5e38\u88ab\u7528\u505a\u5316\u5b66\u5408\u6210\u7684\u8d77\u59cb\u539f\u6599\u3002\u6751\u4e0a\u6559\u6388\u81f4\u529b\u4e8e\u4e00\u9505\u6cd5\u5b9e\u73b0\u7094\u70c3\u7684\u591a\u91cd\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u5b9e\u73b0\u590d\u6742\u5206\u5b50\u7684\u5408\u6210\u3002\u5982\u5728a\u4e2d\uff0c\u53e0\u6c2e\u5316\u5408\u7269\u4e0e\u7094\u70c3\u53d1\u751f[3+2]\u73af\u52a0\u6210\u53cd\u5e94(Huisgen reaction)\u5f62\u6210\u7684\u4e09\u5511\uff0c\u968f\u540e\u5728\u94d1\u7684\u50ac\u5316\u4e0b\u8131N2\uff0c\u5f97\u5230\u542b\u6c2e\u7684\u591a\u73af\u5316\u5408\u7269\u3002\u5728b\u4e2d\u5219\u662f\u6c22\u787c\u5316\u540e\u53cc\u952e\u79fb\u4f4d\u5f62\u6210\u70ef\u4e19\u57fa\u787c\uff0c\u968f\u540e\u53d1\u751f\u70f7\u57fa\u5316\u53cd\u5e94\u3002 \u53c2\u8003\u6587\u732e [1] Masahiro Murakami, [&hellip;]","protected":false},"author":26,"featured_media":28903,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[212],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/84c5424ef5af9b201b1c8f8c3aaed16b.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-7w7","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/28899"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=28899"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/28899\/revisions"}],"predecessor-version":[{"id":28907,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/28899\/revisions\/28907"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/28903"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=28899"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=28899"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=28899"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}