{"id":29006,"date":"2019-10-18T07:50:26","date_gmt":"2019-10-17T23:50:26","guid":{"rendered":"\/\/www.gsbet888.com\/?p=29006"},"modified":"2019-10-15T15:25:45","modified_gmt":"2019-10-15T07:25:45","slug":"organotellurium-mediated-living-radical-polymerization-terp","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2019\/10\/organotellurium-mediated-living-radical-polymerization-terp.html","title":{"rendered":"Organotellurium-mediated Living Radical Polymerization (TERP)"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>TERP (Organotellurium-Mediated Living Radical Polymerization)\u662f\u53ef\u9006\u7684\u60f0\u6027\u81ea\u7531\u57fa\u805a\u5408\uff08\u2248living radical polymerization\uff09\u7684\u4e00\u79cd\u3002<\/p>\n<p>\u81ea\u7531\u57fa\u805a\u5408\u53cd\u5e94\u4e2d\u7531\u4e8e\u81ea\u7531\u57fa\u672b\u7aef\u7684\u4e92\u76f8\u7ed3\u5408\u4e0e\u62d4\u6c22\u540e\u7684\u6216\u8005\u62d4\u6c22\u540e\u7684\u6b67\u5316\u53cd\u5e94\u5bfc\u81f4\u53cd\u5e94\u7ec8\u6b62\u7b49\u95ee\u9898\uff0c\u6240\u4ee5\u751f\u6210\u7684\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u7684\u8c03\u63a7\u5c31\u53d8\u5f97\u5f88\u56f0\u96be\u3002TERP\u901a\u8fc7\u4f7f\u7528\u6709\u673a\u78b2\u5316\u5408\u7269\u4f5c\u4e3a\u94fe\u8f6c\u79fb\u5242\u548c\u81ea\u7531\u57fa\u5f15\u53d1\u5242\uff0c\u53ef\u4ee5\u5728\u6240\u6709\u805a\u5408\u7269\u94fe\u5747\u7b49\u6269\u6563\u7684\u4f4e\u6d3b\u6027\u7269\u79cd\u6d53\u5ea6\u4e0b\u805a\u5408\uff0c\u4ece\u800c\u5b9e\u73b0\u7cbe\u786e\u53ef\u63a7\u805a\u5408\u3002<\/p>\n<p>\u5b83\u662f\u7ee7NMP\uff0c<a href=\"\/\/www.gsbet888.com\/reactions\/%e8%87%aa%e7%94%b1%e5%9f%ba%e5%8f%8d%e5%ba%94\/2015\/02\/%e5%8e%9f%e5%ad%90%e8%bd%ac%e7%a7%bb%e8%87%aa%e7%94%b1%e5%9f%ba%e8%81%9a%e5%90%88atom-transfer-radical-polymerization.html\">ATRP<\/a> \uff0c<a href=\"https:\/\/www.chem-station.com\/odos\/2014\/09\/--raft-polymerization.html\">RAFT<\/a>\u7b49\u4e4b\u540e\u7684\u4e00\u79cd\u65b0\u7684\u53ef\u9006\u7684\u60f0\u6027\u81ea\u7531\u57fa\u805a\u5408\u4f53\u7cfb\uff0c\u4e0e\u5176\u4ed6\u4f53\u7cfb\u76f8\u6bd4\uff0c\u53ef\u901a\u8fc7\u5355\u79cd\u8f6c\u79fb\u5242\u63a7\u5236\u591a\u79cd\u591a\u5b98\u80fd\u4e59\u70ef\u57fa\u5355\u4f53\u7684\u805a\u5408\uff0c\u901a\u7528\u6027\u6bd4\u8f83\u5f3a\uff0c\u53e6\u5916\u5728\u5d4c\u6bb5\u5171\u805a\u7269\u5408\u6210\u65b9\u9762\u4e5f\u8868\u73b0\u51fa\u8272<em><sup>1<\/sup><\/em>\u3002<\/p>\n<p>\u8be5\u805a\u5408\u6cd5\u5df2\u7ecf\u7531\u65e5\u672c<a href=\"https:\/\/www.otsukac.co.jp\/\">\u5927\u585a\u5316\u5b66\uff08\u682a\uff09<\/a>\u5b9e\u73b0\u4e86\u5de5\u4e1a\u5316\u5e94\u7528\u3002<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ol>\n<li>Yamago, S. <em>Chem. Rev.\u00a0<\/em><strong>2009<\/strong>, <em>109<\/em>, 5051\u20135068. DOI:10.1021\/cr9001269\u2028 (Review)<\/li>\n<li>Yamago, S.; Iida, K.; Yoshida, J. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2002<\/strong>, <em>124<\/em>, 2874-2875.DOI:10.1021\/ja025554b<\/li>\n<\/ol>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<div id=\"attachment_65926\" class=\"wp-caption aligncenter\">\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-29008 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2357db2ca81eda4ad01719afe3a54f70-680x378.jpg\" alt=\"\" width=\"680\" height=\"378\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2357db2ca81eda4ad01719afe3a54f70-680x378.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2357db2ca81eda4ad01719afe3a54f70-300x167.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/2357db2ca81eda4ad01719afe3a54f70.jpg 768w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p class=\"wp-caption-text\">\u56fe1. TERP\u7684\u805a\u5408\u673a\u7406 (a) RAFT\u805a\u5408\u3001TERP\u7684\u81ea\u7531\u57fa\u4ea4\u6362\u8fde\u9501\u673a\u7406\u7684\u52bf\u80fd\u56fe (b)\u3002\u56fe\u4e2dP\u4e3aPolymer, M\u4e3aMonomer\u3002<\/p>\n<\/div>\n<p>\u6d3b\u5316\u673a\u7406\u6709\u4e24\u6b65\uff1a\u9996\u5148\u662f\u901a\u8fc7\u6709\u673a\u78b2\u5316\u5408\u7269\u53ef\u9006\u7684\u88c2\u89e3\u78b3\u81ea\u7531\u57fa\u7684\u673a\u7406\uff0c\u53e6\u5916\u4e00\u6b65\u662f\u751f\u6210\u7684\u78b3\u81ea\u7531\u57fa\u4e0e\u53e6\u4e00\u5206\u5b50\u7684\u6709\u673a\u78b2\u5316\u5408\u7269\u53cd\u5e94\u53d1\u751f\u4ea4\u6362\u8fde\u9501\u673a\u7406\u3002\u57fa\u672c\u4e0a\u53ef\u9006\u7684\u88c2\u89e3\u673a\u5236\u4ec5\u53d1\u751f\u4e8e\u5f15\u53d1\u53cd\u5e94\u3001\u805a\u5408\u4e2d\u662f\u901a\u8fc7\u4ea4\u6362\u8fde\u9501\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u3002\u4f4e\u6d3b\u6027\u79cd\u6d53\u5ea6\u4e0b\u7684\u805a\u5408\u4e5f\u662f\u53ef\u4ee5\u8fdb\u884c\u7684\uff0c\u5e76\u4e14\u53ef\u4ee5\u51e0\u5927\u9650\u5ea6\u7684\u6291\u5236\u505c\u6b62\u53cd\u5e94\u3002\u5c3d\u7ba1\u901a\u8fc7\u4ea4\u6362\u8fde\u9501\u673a\u7406\u4ee5\u7c7b\u4f3c\u4e8eRAFT\u805a\u5408\u7684\u65b9\u5f0f\u63a7\u5236\u805a\u5408\uff0c\u4f46\u662f\u673a\u7406\u672c\u8eab\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u4e0d\u540c\u7684\uff0c\u5728TERP\u4e2d\uff0c\u5728\u4ea4\u6362\u8fde\u9501\uff08\u94fe\uff09\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u57fa\u672c\u4e0a\u6ca1\u6709\u4e2d\u95f4\u4f53\u3002<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>\u6839\u636e\u53cd\u5e94\u5f62\u5f0f\uff0c\u5206\u4e3a\u7b2c\u4e00\u4ee3\uff0c\u7b2c\u4e8c\u4ee3\u548c\u7b2c\u4e09\u4ee3\u3002<\/p>\n<h5>\u7b2c1\u4ee3<\/h5>\n<p>\u4f7f\u7528\u6709\u673a\u78b2\u5316\u5408\u7269\u7684\u70ed\u89e3\u4f5c\u4e3a\u81ea\u7531\u57fa\u6e90\u3002\u56e0\u6b64\uff0c\u9700\u898180\u81f3110\u2103\u7684\u9ad8\u6e29\u6761\u4ef6\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-29009 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/b6ce4a7d78c5252b8b557674388110b7-680x231.jpg\" alt=\"\" width=\"559\" height=\"190\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/b6ce4a7d78c5252b8b557674388110b7-680x231.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/b6ce4a7d78c5252b8b557674388110b7-300x102.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/b6ce4a7d78c5252b8b557674388110b7.jpg 768w\" sizes=\"(max-width: 559px) 100vw, 559px\" \/><\/p>\n<p>Styrene\u7684\u805a\u5408\u3002\u5728\u6c2e\u6c14\u4e2d\uff0c\u5c06\u5355\u4f53\uff0cAIBN\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6df7\u5408\uff0c\u5e76\u5c06\u6e29\u5ea6\u5347\u9ad8\u81f3105\u2103\u3002\u6709\u673a\u78b2\u5316\u5408\u7269\u5206\u89e3\uff0c\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u5e76\u8fdb\u884c\u805a\u5408\u3002<\/p>\n<h5>\u7b2c2\u4ee3<\/h5>\n<p>\u81ea\u7531\u57fa\u5f15\u53d1\u5242\uff0c\u7279\u522b\u662f\u5076\u6c2e\u5f15\u53d1\u5242\u7684\u70ed\u5206\u89e3\u7528\u4f5c\u81ea\u7531\u57fa\u6e90\u3002 \u6709\u673a\u78b2\u5316\u5408\u7269\u4ec5\u7528\u4f5c\u94fe\u8f6c\u79fb\u5242\u3002 \u53ef\u4ee5\u5728\u6bd4\u7b2c\u4e00\u4ee3\u66f4\u4f4e\u7684\u6e29\u5ea6\uff0840-80\u2103\uff09\u4e0b\u8fdb\u884c\u53cd\u5e94\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-29010 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/04d750cc2f8b0c7a7b6b39d5580c60ce-680x231.jpg\" alt=\"\" width=\"680\" height=\"231\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/04d750cc2f8b0c7a7b6b39d5580c60ce-680x231.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/04d750cc2f8b0c7a7b6b39d5580c60ce-300x102.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/04d750cc2f8b0c7a7b6b39d5580c60ce.jpg 768w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>Styrene\u7684\u805a\u5408\uff0c\u5728\u6c2e\u6c14\u6c1b\u4e0b\uff0c\u5c06\u5355\u4f53\uff0cAIBN\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6df7\u5408\uff0c\u5e76\u5c06\u6e29\u5ea6\u5347\u81f360\u00b0C\uff0cAIBN\u5206\u89e3\u5e76\u4ea7\u751f\u81ea\u7531\u57fa\u4ee5\u4fc3\u8fdb\u805a\u5408\u53cd\u5e94<em><sup>3<\/sup><\/em>\u3002<\/p>\n<h5>\u7b2c\uff13\u4ee3<\/h5>\n<p>\u6709\u673a\u78b2\u5316\u5408\u7269\u7684\u5149\u89e3\u88ab\u7528\u4f5c\u81ea\u7531\u57fa\u6e90\u3002 \u5373\u4f7f\u5728\u4f4e\u6e29\uff080\u00b0C\u81f3\u5ba4\u6e29\uff09\u4e0b\u4e5f\u53ef\u4ee5\u805a\u5408\u3002 \u805a\u5408ON \/ OFF\u53ef\u4ee5\u901a\u8fc7\u5149\u7167\u5c04\u6765\u63a7\u5236\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-29011 size-large\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/a489b61a14d77b8d7b182a3ba43f2479-680x229.jpg\" alt=\"\" width=\"680\" height=\"229\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/a489b61a14d77b8d7b182a3ba43f2479-680x229.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/a489b61a14d77b8d7b182a3ba43f2479-300x101.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/a489b61a14d77b8d7b182a3ba43f2479.jpg 768w\" sizes=\"(max-width: 680px) 100vw, 680px\" \/><\/p>\n<p>N-isopropyl acrylamide (NIPAM)\u7684\u5149\u805a\u5408\u3002\u5728\u6c2e\u6c14\u6c1b\u4e2d\uff0c\u5c06\u5355\u4f53\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6eb6\u89e3\u5728\u6eb6\u5242\u4e2d\uff0c\u5e76\u7528\u5149\u7167\u5c04\u5206\u89e3\u6709\u673a\u78b2\u5316\u5408\u7269\u4ee5\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u5e76\u8fdb\u884c\u805a\u5408<em><sup>4<\/sup><\/em>\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<ul>\n<li>\u7531\u4e8e\u6709\u673a\u78b2\u5316\u5408\u7269\u5728\u6c27\u6c14\u5b58\u5728\u4e0b\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u53cd\u5e94\u5e94\u5728\u5145\u5206\u8131\u6c14\u548c\u6c2e\u53d6\u4ee3\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002<\/li>\n<\/ul>\n<h4>\u5907\u8003<\/h4>\n<ul>\n<li>\u6709\u673a\u78b2\u5316\u5408\u7269\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u53cd\u5e94\u4ee5\u514b\u89c4\u6a21\u5408\u6210\uff0c\u4e3b\u8981\u662f\u901a\u8fc7\u51cf\u538b\u84b8\u998f\u7eaf\u5316\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-29012 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/6729842ebb4755bd8de20a5dcde00c3f-680x140.jpg\" alt=\"\" width=\"500\" height=\"103\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/6729842ebb4755bd8de20a5dcde00c3f-680x140.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/6729842ebb4755bd8de20a5dcde00c3f-300x62.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2019\/10\/6729842ebb4755bd8de20a5dcde00c3f.jpg 768w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<ul>\n<li>\u52a0\u5165\u4e8c\u78b2\u5316\u7269\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u53ef\u6539\u5584\u805a\u5408\u63a7\u5236\u5ea6<em><sup>5<\/sup><\/em>\u3002<\/li>\n<li>\u4f7f\u7528\u5177\u6709\u76f8\u540c\u673a\u7406\u7684\u6709\u673a\u9511\u5316\u5408\u7269\u4f5c\u4e3a\u805a\u5408\u4f53\u7cfbOrganostibine-mediated Living Radical Polymerization (SBRP)<em><sup>7<\/sup><\/em>\u6216\u4f7f\u7528\u6709\u673a\u94cb\u5316\u5408\u7269\u7684Organobismuthine-mediated Living Radical Polymerization (BIRP)<em><sup>6<\/sup><\/em>\u4e5f\u88ab\u76f8\u7ee7\u62a5\u9053\u3002<\/li>\n<li>\u5c3d\u7ba1\u8fd9\u662f\u4e00\u79cd\u51fa\u8272\u7684\u805a\u5408\u4f53\u7cfb\uff0c\u4f46\u5e02\u573a\u4e0a\u51e0\u4e4e\u6ca1\u6709\u5e02\u552e\u7684\u5f15\u53d1\u5242\u548c\u94fe\u8f6c\u79fb\u5242\uff0c\u56e0\u6b64\u5f88\u96be\u4f5c\u4e3a\u805a\u5408\u6761\u4ef6\u5bf9\u7167\u7b5b\u9009\u7684\u9996\u9009\u3002<\/li>\n<\/ul>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li>Yamago, S. <em>Chem. Rev.\u00a0<\/em><strong>2009<\/strong>, <em>109<\/em>, 5051\u20135068. DOI:10.1021\/cr9001269<\/li>\n<li>Yamago, S.; Iida, K.; Yoshida, J. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2002<\/strong>, <em>124<\/em>, 2874-2875.DOI:10.1021\/ja025554b<\/li>\n<li>Goto, A.; Kwak, Y.; Fukuda, T.; Yamago, S.; Iida, K.; Nakajima, M.; Yoshida, J. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2003<\/strong>, <em>125<\/em>, 8720-8721. DOI:10.1021\/ja035464m<\/li>\n<li>Yamago, S.; Ukai, Y.; Matsumoto, A.; Nakamura, Y. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2009<\/strong>, <em>131<\/em>, 2100-2101. DOI:10.1021\/ja8099689<\/li>\n<li>Kwak, Y.; Tezuka, M.; Goto, A.; Fukuda, T.; Yamago, S.; <em>Macromolecules <\/em><strong>2007, <\/strong><em>40,<\/em>1881-1885. DOI:10.1021\/ma0623385<\/li>\n<li>Yamago, S.; Kayahara, E.; Kotani, M.; Ray, B.; Kwak, Y.; Goto, A.; Fukuda, T. <em>Angew. Chem. Int. Ed.\u00a0<\/em><strong>2007<\/strong>, <em>46<\/em>, 1304 \u20131306. DOI: 10.1002\/anie.200604473<\/li>\n<li>Yamago, S.; Ray, B.; Iida, K.; Yoshida, J.; Tada, T.; Yoshizaki, K.; Kwak, Y.; Goto, A.; Fukuda, T. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2004<\/strong>,<em>126<\/em>, 13908-13909. DOI:10.1021\/ja044787v<\/li>\n<\/ol>\n<h4>\u5916\u90e8\u94fe\u63a5<\/h4>\n<ul>\n<li><a href=\"https:\/\/www.otsukac.co.jp\/advanced\/living\/terp\/\">\u5927\u585a\u5316\u5b66(\u682a) TERP\u8bb2\u89e3<\/a><\/li>\n<li><a href=\"http:\/\/os.kuicr.kyoto-u.ac.jp\/\">\u4eac\u90fd\u5927\u5b66\u5c71\u5b50\u7814\u7a76\u5ba4<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 TERP (Organotellurium-Mediated Living Radical Polymerization)\u662f\u53ef\u9006\u7684\u60f0\u6027\u81ea\u7531\u57fa\u805a\u5408\uff08\u2248living radical polymerization\uff09\u7684\u4e00\u79cd\u3002 \u81ea\u7531\u57fa\u805a\u5408\u53cd\u5e94\u4e2d\u7531\u4e8e\u81ea\u7531\u57fa\u672b\u7aef\u7684\u4e92\u76f8\u7ed3\u5408\u4e0e\u62d4\u6c22\u540e\u7684\u6216\u8005\u62d4\u6c22\u540e\u7684\u6b67\u5316\u53cd\u5e94\u5bfc\u81f4\u53cd\u5e94\u7ec8\u6b62\u7b49\u95ee\u9898\uff0c\u6240\u4ee5\u751f\u6210\u7684\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u7684\u8c03\u63a7\u5c31\u53d8\u5f97\u5f88\u56f0\u96be\u3002TERP\u901a\u8fc7\u4f7f\u7528\u6709\u673a\u78b2\u5316\u5408\u7269\u4f5c\u4e3a\u94fe\u8f6c\u79fb\u5242\u548c\u81ea\u7531\u57fa\u5f15\u53d1\u5242\uff0c\u53ef\u4ee5\u5728\u6240\u6709\u805a\u5408\u7269\u94fe\u5747\u7b49\u6269\u6563\u7684\u4f4e\u6d3b\u6027\u7269\u79cd\u6d53\u5ea6\u4e0b\u805a\u5408\uff0c\u4ece\u800c\u5b9e\u73b0\u7cbe\u786e\u53ef\u63a7\u805a\u5408\u3002 \u5b83\u662f\u7ee7NMP\uff0cATRP \uff0cRAFT\u7b49\u4e4b\u540e\u7684\u4e00\u79cd\u65b0\u7684\u53ef\u9006\u7684\u60f0\u6027\u81ea\u7531\u57fa\u805a\u5408\u4f53\u7cfb\uff0c\u4e0e\u5176\u4ed6\u4f53\u7cfb\u76f8\u6bd4\uff0c\u53ef\u901a\u8fc7\u5355\u79cd\u8f6c\u79fb\u5242\u63a7\u5236\u591a\u79cd\u591a\u5b98\u80fd\u4e59\u70ef\u57fa\u5355\u4f53\u7684\u805a\u5408\uff0c\u901a\u7528\u6027\u6bd4\u8f83\u5f3a\uff0c\u53e6\u5916\u5728\u5d4c\u6bb5\u5171\u805a\u7269\u5408\u6210\u65b9\u9762\u4e5f\u8868\u73b0\u51fa\u82721\u3002 \u8be5\u805a\u5408\u6cd5\u5df2\u7ecf\u7531\u65e5\u672c\u5927\u585a\u5316\u5b66\uff08\u682a\uff09\u5b9e\u73b0\u4e86\u5de5\u4e1a\u5316\u5e94\u7528\u3002 \u57fa\u672c\u6587\u732e Yamago, S. Chem. Rev.\u00a02009, 109, 5051\u20135068. DOI:10.1021\/cr9001269\u2028 (Review) Yamago, S.; Iida, K.; Yoshida, J. J. Am. Chem. Soc.\u00a02002, 124, 2874-2875.DOI:10.1021\/ja025554b \u53cd\u5e94\u673a\u7406 \u56fe1. TERP\u7684\u805a\u5408\u673a\u7406 (a) RAFT\u805a\u5408\u3001TERP\u7684\u81ea\u7531\u57fa\u4ea4\u6362\u8fde\u9501\u673a\u7406\u7684\u52bf\u80fd\u56fe (b)\u3002\u56fe\u4e2dP\u4e3aPolymer, M\u4e3aMonomer\u3002 \u6d3b\u5316\u673a\u7406\u6709\u4e24\u6b65\uff1a\u9996\u5148\u662f\u901a\u8fc7\u6709\u673a\u78b2\u5316\u5408\u7269\u53ef\u9006\u7684\u88c2\u89e3\u78b3\u81ea\u7531\u57fa\u7684\u673a\u7406\uff0c\u53e6\u5916\u4e00\u6b65\u662f\u751f\u6210\u7684\u78b3\u81ea\u7531\u57fa\u4e0e\u53e6\u4e00\u5206\u5b50\u7684\u6709\u673a\u78b2\u5316\u5408\u7269\u53cd\u5e94\u53d1\u751f\u4ea4\u6362\u8fde\u9501\u673a\u7406\u3002\u57fa\u672c\u4e0a\u53ef\u9006\u7684\u88c2\u89e3\u673a\u5236\u4ec5\u53d1\u751f\u4e8e\u5f15\u53d1\u53cd\u5e94\u3001\u805a\u5408\u4e2d\u662f\u901a\u8fc7\u4ea4\u6362\u8fde\u9501\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u3002\u4f4e\u6d3b\u6027\u79cd\u6d53\u5ea6\u4e0b\u7684\u805a\u5408\u4e5f\u662f\u53ef\u4ee5\u8fdb\u884c\u7684\uff0c\u5e76\u4e14\u53ef\u4ee5\u51e0\u5927\u9650\u5ea6\u7684\u6291\u5236\u505c\u6b62\u53cd\u5e94\u3002\u5c3d\u7ba1\u901a\u8fc7\u4ea4\u6362\u8fde\u9501\u673a\u7406\u4ee5\u7c7b\u4f3c\u4e8eRAFT\u805a\u5408\u7684\u65b9\u5f0f\u63a7\u5236\u805a\u5408\uff0c\u4f46\u662f\u673a\u7406\u672c\u8eab\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u4e0d\u540c\u7684\uff0c\u5728TERP\u4e2d\uff0c\u5728\u4ea4\u6362\u8fde\u9501\uff08\u94fe\uff09\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u57fa\u672c\u4e0a\u6ca1\u6709\u4e2d\u95f4\u4f53\u3002 \u53cd\u5e94\u5b9e\u4f8b \u6839\u636e\u53cd\u5e94\u5f62\u5f0f\uff0c\u5206\u4e3a\u7b2c\u4e00\u4ee3\uff0c\u7b2c\u4e8c\u4ee3\u548c\u7b2c\u4e09\u4ee3\u3002 \u7b2c1\u4ee3 \u4f7f\u7528\u6709\u673a\u78b2\u5316\u5408\u7269\u7684\u70ed\u89e3\u4f5c\u4e3a\u81ea\u7531\u57fa\u6e90\u3002\u56e0\u6b64\uff0c\u9700\u898180\u81f3110\u2103\u7684\u9ad8\u6e29\u6761\u4ef6\u3002 Styrene\u7684\u805a\u5408\u3002\u5728\u6c2e\u6c14\u4e2d\uff0c\u5c06\u5355\u4f53\uff0cAIBN\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6df7\u5408\uff0c\u5e76\u5c06\u6e29\u5ea6\u5347\u9ad8\u81f3105\u2103\u3002\u6709\u673a\u78b2\u5316\u5408\u7269\u5206\u89e3\uff0c\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u5e76\u8fdb\u884c\u805a\u5408\u3002 \u7b2c2\u4ee3 \u81ea\u7531\u57fa\u5f15\u53d1\u5242\uff0c\u7279\u522b\u662f\u5076\u6c2e\u5f15\u53d1\u5242\u7684\u70ed\u5206\u89e3\u7528\u4f5c\u81ea\u7531\u57fa\u6e90\u3002 \u6709\u673a\u78b2\u5316\u5408\u7269\u4ec5\u7528\u4f5c\u94fe\u8f6c\u79fb\u5242\u3002 \u53ef\u4ee5\u5728\u6bd4\u7b2c\u4e00\u4ee3\u66f4\u4f4e\u7684\u6e29\u5ea6\uff0840-80\u2103\uff09\u4e0b\u8fdb\u884c\u53cd\u5e94\u3002 Styrene\u7684\u805a\u5408\uff0c\u5728\u6c2e\u6c14\u6c1b\u4e0b\uff0c\u5c06\u5355\u4f53\uff0cAIBN\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6df7\u5408\uff0c\u5e76\u5c06\u6e29\u5ea6\u5347\u81f360\u00b0C\uff0cAIBN\u5206\u89e3\u5e76\u4ea7\u751f\u81ea\u7531\u57fa\u4ee5\u4fc3\u8fdb\u805a\u5408\u53cd\u5e943\u3002 \u7b2c\uff13\u4ee3 \u6709\u673a\u78b2\u5316\u5408\u7269\u7684\u5149\u89e3\u88ab\u7528\u4f5c\u81ea\u7531\u57fa\u6e90\u3002 \u5373\u4f7f\u5728\u4f4e\u6e29\uff080\u00b0C\u81f3\u5ba4\u6e29\uff09\u4e0b\u4e5f\u53ef\u4ee5\u805a\u5408\u3002 \u805a\u5408ON \/ OFF\u53ef\u4ee5\u901a\u8fc7\u5149\u7167\u5c04\u6765\u63a7\u5236\u3002 N-isopropyl acrylamide (NIPAM)\u7684\u5149\u805a\u5408\u3002\u5728\u6c2e\u6c14\u6c1b\u4e2d\uff0c\u5c06\u5355\u4f53\u548c\u6709\u673a\u78b2\u5316\u5408\u7269\u6eb6\u89e3\u5728\u6eb6\u5242\u4e2d\uff0c\u5e76\u7528\u5149\u7167\u5c04\u5206\u89e3\u6709\u673a\u78b2\u5316\u5408\u7269\u4ee5\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u5e76\u8fdb\u884c\u805a\u54084\u3002 &nbsp; \u5b9e\u9a8c\u6280\u5de7 \u7531\u4e8e\u6709\u673a\u78b2\u5316\u5408\u7269\u5728\u6c27\u6c14\u5b58\u5728\u4e0b\u4e0d\u7a33\u5b9a\uff0c\u56e0\u6b64\u53cd\u5e94\u5e94\u5728\u5145\u5206\u8131\u6c14\u548c\u6c2e\u53d6\u4ee3\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002 \u5907\u8003 \u6709\u673a\u78b2\u5316\u5408\u7269\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u53cd\u5e94\u4ee5\u514b\u89c4\u6a21\u5408\u6210\uff0c\u4e3b\u8981\u662f\u901a\u8fc7\u51cf\u538b\u84b8\u998f\u7eaf\u5316\u3002 \u52a0\u5165\u4e8c\u78b2\u5316\u7269\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u53ef\u6539\u5584\u805a\u5408\u63a7\u5236\u5ea65\u3002 \u4f7f\u7528\u5177\u6709\u76f8\u540c\u673a\u7406\u7684\u6709\u673a\u9511\u5316\u5408\u7269\u4f5c\u4e3a\u805a\u5408\u4f53\u7cfbOrganostibine-mediated Living Radical Polymerization (SBRP)7\u6216\u4f7f\u7528\u6709\u673a\u94cb\u5316\u5408\u7269\u7684Organobismuthine-mediated Living Radical Polymerization (BIRP)6\u4e5f\u88ab\u76f8\u7ee7\u62a5\u9053\u3002 \u5c3d\u7ba1\u8fd9\u662f\u4e00\u79cd\u51fa\u8272\u7684\u805a\u5408\u4f53\u7cfb\uff0c\u4f46\u5e02\u573a\u4e0a\u51e0\u4e4e\u6ca1\u6709\u5e02\u552e\u7684\u5f15\u53d1\u5242\u548c\u94fe\u8f6c\u79fb\u5242\uff0c\u56e0\u6b64\u5f88\u96be\u4f5c\u4e3a\u805a\u5408\u6761\u4ef6\u5bf9\u7167\u7b5b\u9009\u7684\u9996\u9009\u3002 \u53c2\u8003\u6587\u732e Yamago, S. Chem. Rev.\u00a02009, 109, 5051\u20135068. DOI:10.1021\/cr9001269 Yamago, S.; Iida, K.; Yoshida, J. J. Am. Chem. Soc.\u00a02002, 124, 2874-2875.DOI:10.1021\/ja025554b Goto, A.; Kwak, Y.; Fukuda, T.; Yamago, S.; Iida, K.; Nakajima, M.; Yoshida, J. 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