{"id":2909,"date":"2014-10-16T13:49:27","date_gmt":"2014-10-16T05:49:27","guid":{"rendered":"\/\/www.gsbet888.com\/?p=2909"},"modified":"2019-08-02T18:56:14","modified_gmt":"2019-08-02T10:56:14","slug":"post-2909","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2014\/10\/post-2909.html","title":{"rendered":"Soai\u4e0d\u5bf9\u79f0\u81ea\u6211\u50ac\u5316(Soai Asymmetric Autocatalysis)"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n<p>\u6c28\u57fa\u9187\u50ac\u5316\u5242\u7684\u6709\u673a\u950c\u4e0d\u5bf9\u79f01,2-\u52a0\u6210\u53cd\u5e94\u7684\u4e00\u79cd\u3002\u4ece\u53cd\u5e94\u5f62\u5f0f\u6216\u8005\u5bf9\u5408\u6210\u5316\u5b66\u7684\u6709\u7528\u6027\u4e0a\u6765\u770b\uff0c\u6ca1\u6709\u4ec0\u4e48\u7279\u522b\u503c\u5f97\u5173\u6ce8\u7684\u3002<\/p>\n<p>\u4f46\u662f\uff0c\u8fd9\u4e2a\u53cd\u5e94\u975e\u5e38\u7f55\u89c1\u7684\u662f<strong>\u81ea\u8eab\u4e0d\u5bf9\u79f0<span style=\"color: #ff0000\">\u50ac\u5316\u53cd\u5fdc\uff08aymmetric autocatalysis\uff09\u3002<\/span><\/strong>\u8981\u8bf4\u5230\u5e95\u6709\u591a\u7f55\u89c1\uff0c\u4ece\u6700\u521d\u8fd9\u4e2a\u53cd\u5e94\u88ab\u62a5\u9053\u5230\u73b0\u5728\u7ecf\u5386\u4e8615\u5e74\u4ee5\u4e0a\uff0c\u8fd9\u6837\u7684\u53cd\u5e94\u8fd8\u5c31\u53ea\u6709\u8fd9\u4e00\u4f8b\u3002<\/p>\n<p>\u8be5\u53cd\u5e94\u4e2d\u53ea\u9700\u8981\u7528\u5f88\u5fae\u91cf(0.00005%\u5de6\u53f3)\u4f4e\u624b\u6027\u7684\u5bf9\u6620\u5f02\u6784\u4f53\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\u7684\u8bdd\uff0c\u53ef\u4ee5\u5f97\u5230\u624b\u6027\u503c\u5927\u5927\u63d0\u9ad8\u7684\u4ea7\u7269\u3002\u5728\u8fd9\u4e4b\u540e\uff0c\u4e0d\u5bf9\u79f0\u589e\u591a\u7684\u4ea7\u7269\u518d\u4f5c\u4e3a\u50ac\u5316\u5242\u53cd\u5e94\uff0c\u5728\u51e0\u4e2a\u5faa\u73af\u540e\uff0c\u5c31\u80fd\u5f97\u523099%ee\u4ee5\u4e0a\u7684\u5149\u5b66\u6d3b\u6027\u5f88\u7eaf\u7684\u4ea7\u7269\u3002<\/p>\n<p>\u8fd9\u4e2a\u53cd\u5e94\u7ed9\u51fa\u4e86\u4e00\u4e2a\u4e8b\u5b9e\uff0c\u5c31\u662f\u300c\u8981\u5f97\u5230\u5149\u5b66\u6d3b\u6027\u7684\u5316\u5408\u7269\uff0c\u4e0d\u4e00\u5b9a\u9700\u8981\u4f7f\u7528ee\u9ad8\u7684\u5316\u5408\u7269\u4f5c\u4e3a\u5e95\u7269\u300d\u3002\u8fd9\u662f\u4e00\u4e2a<strong>\u300c\u7a0d\u5fae\u6709\u4e00\u70b9\u70b9ee\u7684\u5bf9\u6620\u5f02\u6784\u6df7\u5408\u7269\uff0c\u5229\u7528\u8be5\u65b9\u6cd5\u53ef\u4ee5\u5f97\u5230\u7eaf\u7684\u5177\u6709\u5149\u5b66\u6d3b\u6027\u7684\u4ea7\u7269\u300d<\/strong>\u6700\u6709\u529b\u7684\u5b9e\u4f8b\u3002\u4e0d\u5f97\u4e0d\u8bf4\u8fd9\u662f\u4e00\u4e2a\u5212\u65f6\u4ee3\u7684\u53d1\u73b0\u3002<\/p>\n<p>\u7531\u4e8e\u6b64\u7279\u5f81\uff0c<strong>\u300c\u81ea\u7136\u754c\u4e2d\u5929\u7136\u5b58\u5728\u7684\u6c28\u57fa\u9178\u4e0e\u7cd6\u3001\u4e3a\u4ec0\u4e48\u4e3b\u8981\u4ee5\u4e00\u79cd\u5bf9\u6620\u5f02\u6784\u4f53\u7684\u5f62\u5f0f\u5b58\u5728\u300d<\/strong>\u8fd9\u4e2a\u95ee\u9898\u4e5f\u81ea\u7136\u800c\u7136\u80fd\u591f\u7406\u89e3\u4e86\u3002<\/p>\n<p>\u8be5\u53cd\u5e94\u53ef\u4ee5\u8bf4\u5df2\u7ecf\u8d85\u51fa\u4e86\u6709\u673a\u5408\u6210\u53cd\u5e94\u7684\u6846\u67b6\u8303\u56f4\uff0c\u5bf9\u79d1\u5b66\u754c\u5177\u6709\u6781\u5927\u5f71\u54cd\u7684\u4e3a\u6570\u4e0d\u591a\u7684\u53cd\u5e94\u4e4b\u4e00\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>\u30fbSoai, K.; Shibata, T.; Morioka H.; Choji, K. <em>Nature<\/em> <strong>1995<\/strong>, <em>378<\/em>, 767. doi:<a href=\"http:\/\/dx.doi.org\/10.1038\/378767a0\">10.1038\/378767a0<\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u6b63\u5982\u8be5\u53cd\u5e94\u6240\u793a\uff0c\u751f\u6210\u7269\u4e0e\u50ac\u5316\u5242\u662f\u540c\u4e00\u4e2a\u7269\u8d28\uff0c\u800c\u751f\u6210\u7269\u4e5f\u81ea\u7136\u800c\u7136\u6210\u4e3a\u4e86\u50ac\u5316\u5242\u81ea\u884c\u8fdb\u884c\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u4e0d\u5bf9\u79f0\u653e\u5927\u73b0\u8c61\u5728\u4e8e\u4e0d\u5bf9\u79f0\u53cd\u5e94\u53ca\u5176\u6f5c\u5728\u7684\u975e\u7ebf\u6027\u73b0\u8c61\u3002<\/p>\n<p align=\"left\">\u8fd9\u662f\u4e00\u4e2a\u5341\u5206\u6709\u8da3\u7684\u53cd\u5e94\uff0c\u6240\u4ee5\u8fd9\u5f3a\u70c8\u5438\u5f15\u7740\u7406\u8bba\u5316\u5b66\u5bb6\u5bf9\u4e8e\u5b83\u7684\u5174\u8da3\u3002<\/p>\n<p align=\"left\">\u6700\u8fd1Blackmond\u7b49\u4eba\u3001\u5bf9\u4e8e\u8fd9\u4e2a\u53cd\u5e94\u63d0\u51fa\u4e86\u4e8c\u805a\u4f53\u8fc7\u6e21\u6001\u53cd\u5e94\u673a\u7406\u7684\u5047\u8bbe(\u53c2\u8003\uff1a<a href=\"http:\/\/dx.doi.org\/10.1021\/ja034705n\"><em>J. Am. Chem. Soc.<\/em> <strong>2003<\/strong>,<em>125<\/em>, 8978.<\/a>)\u3002<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>\u624b\u6027\u5f15\u53d1\u5242\u5e76\u4e0d\u9650\u5b9a\u4e8e\u8be5\u6709\u673a\u5149\u5b66\u6d3b\u6027\u7684\u5316\u5408\u7269\u3002\u4f8b\u5982\u5706\u504f\u632f\u5149\u548c\u624b\u6027\u6db2\u6676\u4e4b\u95f4\u7684\u63a5\u89e6\uff0c\u4e5f\u53ef\u80fd\u662f\u7269\u7406\u56e0\u7d20\u7684\u7f18\u6545\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong><a href=\"\/\/www.gsbet888.com\/\"><strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a><strong>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u6c28\u57fa\u9187\u50ac\u5316\u5242\u7684\u6709\u673a\u950c\u4e0d\u5bf9\u79f01,2-\u52a0\u6210\u53cd\u5e94\u7684\u4e00\u79cd\u3002\u4ece\u53cd\u5e94\u5f62\u5f0f\u6216\u8005\u5bf9\u5408\u6210\u5316\u5b66\u7684\u6709\u7528\u6027\u4e0a\u6765\u770b\uff0c\u6ca1\u6709\u4ec0\u4e48\u7279\u522b\u503c\u5f97\u5173\u6ce8\u7684\u3002 \u4f46\u662f\uff0c\u8fd9\u4e2a\u53cd\u5e94\u975e\u5e38\u7f55\u89c1\u7684\u662f\u81ea\u8eab\u4e0d\u5bf9\u79f0\u50ac\u5316\u53cd\u5fdc\uff08aymmetric autocatalysis\uff09\u3002\u8981\u8bf4\u5230\u5e95\u6709\u591a\u7f55\u89c1\uff0c\u4ece\u6700\u521d\u8fd9\u4e2a\u53cd\u5e94\u88ab\u62a5\u9053\u5230\u73b0\u5728\u7ecf\u5386\u4e8615\u5e74\u4ee5\u4e0a\uff0c\u8fd9\u6837\u7684\u53cd\u5e94\u8fd8\u5c31\u53ea\u6709\u8fd9\u4e00\u4f8b\u3002 \u8be5\u53cd\u5e94\u4e2d\u53ea\u9700\u8981\u7528\u5f88\u5fae\u91cf(0.00005%\u5de6\u53f3)\u4f4e\u624b\u6027\u7684\u5bf9\u6620\u5f02\u6784\u4f53\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\u7684\u8bdd\uff0c\u53ef\u4ee5\u5f97\u5230\u624b\u6027\u503c\u5927\u5927\u63d0\u9ad8\u7684\u4ea7\u7269\u3002\u5728\u8fd9\u4e4b\u540e\uff0c\u4e0d\u5bf9\u79f0\u589e\u591a\u7684\u4ea7\u7269\u518d\u4f5c\u4e3a\u50ac\u5316\u5242\u53cd\u5e94\uff0c\u5728\u51e0\u4e2a\u5faa\u73af\u540e\uff0c\u5c31\u80fd\u5f97\u523099%ee\u4ee5\u4e0a\u7684\u5149\u5b66\u6d3b\u6027\u5f88\u7eaf\u7684\u4ea7\u7269\u3002 \u8fd9\u4e2a\u53cd\u5e94\u7ed9\u51fa\u4e86\u4e00\u4e2a\u4e8b\u5b9e\uff0c\u5c31\u662f\u300c\u8981\u5f97\u5230\u5149\u5b66\u6d3b\u6027\u7684\u5316\u5408\u7269\uff0c\u4e0d\u4e00\u5b9a\u9700\u8981\u4f7f\u7528ee\u9ad8\u7684\u5316\u5408\u7269\u4f5c\u4e3a\u5e95\u7269\u300d\u3002\u8fd9\u662f\u4e00\u4e2a\u300c\u7a0d\u5fae\u6709\u4e00\u70b9\u70b9ee\u7684\u5bf9\u6620\u5f02\u6784\u6df7\u5408\u7269\uff0c\u5229\u7528\u8be5\u65b9\u6cd5\u53ef\u4ee5\u5f97\u5230\u7eaf\u7684\u5177\u6709\u5149\u5b66\u6d3b\u6027\u7684\u4ea7\u7269\u300d\u6700\u6709\u529b\u7684\u5b9e\u4f8b\u3002\u4e0d\u5f97\u4e0d\u8bf4\u8fd9\u662f\u4e00\u4e2a\u5212\u65f6\u4ee3\u7684\u53d1\u73b0\u3002 \u7531\u4e8e\u6b64\u7279\u5f81\uff0c\u300c\u81ea\u7136\u754c\u4e2d\u5929\u7136\u5b58\u5728\u7684\u6c28\u57fa\u9178\u4e0e\u7cd6\u3001\u4e3a\u4ec0\u4e48\u4e3b\u8981\u4ee5\u4e00\u79cd\u5bf9\u6620\u5f02\u6784\u4f53\u7684\u5f62\u5f0f\u5b58\u5728\u300d\u8fd9\u4e2a\u95ee\u9898\u4e5f\u81ea\u7136\u800c\u7136\u80fd\u591f\u7406\u89e3\u4e86\u3002 \u8be5\u53cd\u5e94\u53ef\u4ee5\u8bf4\u5df2\u7ecf\u8d85\u51fa\u4e86\u6709\u673a\u5408\u6210\u53cd\u5e94\u7684\u6846\u67b6\u8303\u56f4\uff0c\u5bf9\u79d1\u5b66\u754c\u5177\u6709\u6781\u5927\u5f71\u54cd\u7684\u4e3a\u6570\u4e0d\u591a\u7684\u53cd\u5e94\u4e4b\u4e00\u3002 &nbsp; \u57fa\u672c\u6587\u732e \u30fbSoai, K.; Shibata, T.; Morioka H.; Choji, K. Nature 1995, 378, 767. doi:10.1038\/378767a0 &nbsp; \u53cd\u5e94\u673a\u7406 \u6b63\u5982\u8be5\u53cd\u5e94\u6240\u793a\uff0c\u751f\u6210\u7269\u4e0e\u50ac\u5316\u5242\u662f\u540c\u4e00\u4e2a\u7269\u8d28\uff0c\u800c\u751f\u6210\u7269\u4e5f\u81ea\u7136\u800c\u7136\u6210\u4e3a\u4e86\u50ac\u5316\u5242\u81ea\u884c\u8fdb\u884c\u50ac\u5316\u53cd\u5e94\u3002 \u4e0d\u5bf9\u79f0\u653e\u5927\u73b0\u8c61\u5728\u4e8e\u4e0d\u5bf9\u79f0\u53cd\u5e94\u53ca\u5176\u6f5c\u5728\u7684\u975e\u7ebf\u6027\u73b0\u8c61\u3002 \u8fd9\u662f\u4e00\u4e2a\u5341\u5206\u6709\u8da3\u7684\u53cd\u5e94\uff0c\u6240\u4ee5\u8fd9\u5f3a\u70c8\u5438\u5f15\u7740\u7406\u8bba\u5316\u5b66\u5bb6\u5bf9\u4e8e\u5b83\u7684\u5174\u8da3\u3002 \u6700\u8fd1Blackmond\u7b49\u4eba\u3001\u5bf9\u4e8e\u8fd9\u4e2a\u53cd\u5e94\u63d0\u51fa\u4e86\u4e8c\u805a\u4f53\u8fc7\u6e21\u6001\u53cd\u5e94\u673a\u7406\u7684\u5047\u8bbe(\u53c2\u8003\uff1aJ. Am. Chem. Soc. 2003,125, 8978.)\u3002 \u53cd\u5e94\u5b9e\u4f8b \u624b\u6027\u5f15\u53d1\u5242\u5e76\u4e0d\u9650\u5b9a\u4e8e\u8be5\u6709\u673a\u5149\u5b66\u6d3b\u6027\u7684\u5316\u5408\u7269\u3002\u4f8b\u5982\u5706\u504f\u632f\u5149\u548c\u624b\u6027\u6db2\u6676\u4e4b\u95f4\u7684\u63a5\u89e6\uff0c\u4e5f\u53ef\u80fd\u662f\u7269\u7406\u56e0\u7d20\u7684\u7f18\u6545\u3002 &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d","protected":false},"author":5,"featured_media":2910,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[561],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/09\/soai_1.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-KV","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2909"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=2909"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2909\/revisions"}],"predecessor-version":[{"id":28068,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/2909\/revisions\/28068"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/2910"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=2909"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=2909"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=2909"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}