{"id":29570,"date":"2019-11-27T08:00:22","date_gmt":"2019-11-27T00:00:22","guid":{"rendered":"\/\/www.gsbet888.com\/?p=29570"},"modified":"2019-11-25T19:45:12","modified_gmt":"2019-11-25T11:45:12","slug":"%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e6%a2%85%e5%a4%a9%e8%83%9c%e8%af%be%e9%a2%98%e7%bb%84jacs%ef%bc%9a%e7%94%b5%e5%8c%96%e5%ad%a6%e4%bf%83%e4%bd%bfir%e5%82%ac%e5%8c%96%e5%ae%9e%e7%8e%b0","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2019\/11\/%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e6%a2%85%e5%a4%a9%e8%83%9c%e8%af%be%e9%a2%98%e7%bb%84jacs%ef%bc%9a%e7%94%b5%e5%8c%96%e5%ad%a6%e4%bf%83%e4%bd%bfir%e5%82%ac%e5%8c%96%e5%ae%9e%e7%8e%b0.html","title":{"rendered":"\u4e0a\u6d77\u6709\u673a\u6240\u6885\u5929\u80dc\u8bfe\u9898\u7ec4JACS\uff1a\u7535\u5316\u5b66\u4fc3\u4f7fIr\u50ac\u5316\u5b9e\u73b0\u4e59\u70ef\u57faC-H\u5b98\u80fd\u5316"},"content":{"rendered":"

\u672c\u6587\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n

\u5bfc\u8bfb<\/h4>\n

\u7535\u5316\u5b66\u4e0e\u91d1\u5c5e\u50ac\u5316\u534f\u540c\u4f5c\u7528\u5df2\u6210\u4e3aC-H\u5b98\u80fd\u5316\u7684\u5f3a\u5927\u5de5\u5177\uff0c\u7136\u800c\u8be5\u53cd\u5e94\u4e3b\u8981\u9650\u4e8e\u82b3\u70c3C-H\u5b98\u80fd\u5316\u3002\u8fd1\u65e5\uff0c\u4e0a\u6d77\u6709\u673a\u6240\u6885\u5929\u80dc\u8bfe\u9898\u7ec4\u5728<\/strong>JACS<\/em><\/strong>\u53d1\u8868\u8bba\u6587<\/strong>\uff0c\u62a5\u544aIr\u50ac\u5316\u4e0b\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u4e59\u70ef\u57faC-H\u5b98\u80fd\u5316\uff0c\u5b9e\u73b0\u4e19\u70ef\u9178\u4e0e\u7094\u70c3\u7684\u5076\u8054\u3002\u5728\u8be5\u53cd\u5e94\u4e2d\uff0c\u94f1\u50ac\u5316\u5242\u53ef\u5b9e\u73b0C-H\/O-H\u7094\u70c3\u7684\u73af\u5316\uff0c\u83b7\u5f97\u4f18\u5f02\u6536\u7387\u7684\u03b1<\/em>-\u5421\u5583\u916e\u3002\u521d\u6b65\u673a\u7406\u8868\u660e\uff0c\u9633\u6781\u6c27\u5316\u4e8c\u70ef-\u94f1\uff08I<\/strong>\uff09\u914d\u5408\u7269\uff08\u914d\u4f4d\u9971\u548c\u768418\u7535\u5b50\u914d\u5408\u7269\uff09\u5bf9\u4e8e\u91ca\u653e\u4ea7\u7269\u548c\u518d\u5faa\u73afIr\uff08III<\/strong>\uff09\u4e2d\u95f4\u4f53\u81f3\u5173\u91cd\u8981\u3002\u91cd\u8981\u7684\u662f\uff0c\u53cd\u5e94\u6761\u4ef6\u4e00\u81f4\uff08\u4e0d\u5b58\u5728\u7535\u6d41\uff09\uff0c\u5e38\u89c1\u7684\u5316\u5b66\u6c27\u5316\u5242\uff08\u5982Ag(I)\u6216Cu(II)\uff09\u4e0d\u4f1a\u83b7\u5f97\u76f8\u5e94\u7684\u4ea7\u7269\u3002<\/p>\n

Electrochemistry-Enabled Ir-Catalyzed Vinylic C\u2013H Functionalization<\/p>\n

Qi-Liang YangYi-Kang XingXiang-Yang WangHong-Xing MaXin-Jun WengXiang YangHai-Ming GuoTian-Sheng Mei*<\/p>\n

JACS, APSP,\u00a0DOI\uff1a10.1021\/jacs.9b11915<\/a><\/p><\/blockquote>\n

\"\"<\/a><\/p>\n

\u6b63\u6587<\/h4>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\u968f\u540e\uff0c\u901a\u8fc7\u4f7fIrCp*(OAc)2<\/sub>\uff08DMSO\uff09\u7edc\u5408\u72699<\/strong>\u4e0e\u5e95\u72691a<\/strong>\u572860\u2103\u4e0b\u53cd\u5e942h\u5408\u6210\u7edc\u5408\u726910<\/strong>\uff0c\u518d\u4e0e\u70942a<\/strong>\u53cd\u5e94\u5f97\u5230\u914d\u5408\u72698a<\/strong>\uff08Scheme 5A\uff09\uff0c\u94f1\u914d\u5408\u72698a<\/strong>\u4f5c\u4e3a\u7535\u5316\u5b66\u4e59\u70efC-H\u73af\u5316\u53cd\u5e94\u7684\u6709\u6548\u4e2d\u95f4\u4f53\u548c\u50ac\u5316\u5242\uff08Scheme 5B\uff09\u3002\u6709\u8da3\u7684\u662f\uff0c\u572860\u2103\u6216120\u2103\u4e0b\u7528\u4ee3\u8868\u6027\u7684\u5316\u5b66\u6c27\u5316\u5242Ag2<\/sub>CO3<\/sub>\u548cCu(OAc)2<\/sub><\/strong>\u4e0e8a<\/strong>\u53cd\u5e94\u83b7\u5f97\u6781\u4f4e\u6536\u7387\u76843a<\/strong>\uff0c\u4f46\u5f53\u901a\u5165\u7535\u6d41\u540e\u4ea7\u7387\u63d0\u9ad8\u81f384\uff05\uff08Scheme 5C\uff09\u3002<\/p>\n

\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\u603b\u7ed3<\/h4>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u6749\u6749 \u5bfc\u8bfb 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Electrochemistry-Enabled Ir-Catalyzed Vinylic C\u2013H Functionalization Qi-Liang YangYi-Kang XingXiang-Yang WangHong-Xing MaXin-Jun WengXiang YangHai-Ming GuoTian-Sheng Mei* JACS, APSP,\u00a0DOI\uff1a10.1021\/jacs.9b11915 \u6b63\u6587 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