{"id":30101,"date":"2020-02-14T08:00:41","date_gmt":"2020-02-14T00:00:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=30101"},"modified":"2020-03-15T23:33:38","modified_gmt":"2020-03-15T15:33:38","slug":"lopez-ortiz-%e7%83%af%e5%9f%ba%e5%8c%96","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/02\/lopez-ortiz-%e7%83%af%e5%9f%ba%e5%8c%96.html","title":{"rendered":"L\u00f3pez Ortiz \u70ef\u57fa\u5316"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>2000\u5e74\uff0c\u897f\u73ed\u7259Almer\u00eda\u5927\u5b66 (Universidad de Almer\u00eda)\u7684L\u00f3pez Ortiz\u7b49\u62a5\u9053\u4e86\u9996\u4f8b\u901a\u8fc7\u5728\u5f3a\u78b1\u6027\u6761\u4ef6 (\u6b63\u4e01\u57fa\u9502) \u4e0b\uff0cP-\u4e8c\u82ef\u57fa (\u70f7\u57fa) (N-\u7532\u6c27\u7fb0\u57fa)\u78f7\u8148 (P-diphenyl (alkyl) (N-carboxymethyl)phosphazenes)\u4e0e\u919b\u6216\u916e\u4f5c\u7528\uff0c\u5b8c\u6210\u4e86\u4e8c\u53d6\u4ee3\u3001\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\uff0c\u6587\u732e\u4e2d\u5c06\u8be5\u65b9\u6cd5\u5b66\u79f0\u4e3aL\u00f3pez Ortiz\u70ef\u57fa\u5316 (L\u00f3pez Ortiz olefination)<sup> [1]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30102 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4.png\" alt=\"\" width=\"871\" height=\"189\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4.png 1320w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4-300x65.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4-768x167.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/1-4-680x148.png 680w\" sizes=\"(max-width: 871px) 100vw, 871px\" \/><\/a><\/p>\n<p>2003\u5e74\uff0cL\u00f3pez Ortiz\u91c7\u7528\u78b1\u6027\u66f4\u5f3a\u7684\u53d4\u4e01\u57fa\u9502\u539f\u4f4d\u5f62\u6210\u7684\u53cc\u9502\u4ee3\u78f7\u8148\uff0c\u968f\u540e\u4e0e\u919b\u6216\u916e\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u73af\u7f29\u5408\u53cd\u5e94\uff0c\u540c\u65f6\u5206\u79bb\u51fabicyclic 1,2-oxaphosphetanes\uff0c\u901a\u8fc7\u5bf9bicyclic 1,2-oxaphosphetanes\u7684\u7acb\u4f53\u4e13\u4e00\u6027\u70ed\u89e3\u53cd\u5e94\uff0c\u6210\u529f\u5b8c\u6210\u4e86\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210<sup>[2]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30103 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6.png\" alt=\"\" width=\"824\" height=\"188\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6.png 1461w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6-300x69.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6-768x176.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/2-6-680x155.png 680w\" sizes=\"(max-width: 824px) 100vw, 824px\" \/><\/a><\/p>\n<p>L\u00f3pez Ortiz\u70ef\u57fa\u5316\u53cd\u5e94\u4e3a\u4e8c\u53d6\u4ee3\u3001\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u5f00\u8f9f\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>[1] E. Peralta P\u00e9rez, F. L\u00f3pez Ortiz, <em>Chem. Commun.<\/em><strong> 2000<\/strong>, 2029. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2000\/CC\/b006413k#!divAbstract\">10.1039\/B006413K<\/a>.<\/li>\n<li>[2] J. Garc\u00eda-L\u00f3pez, E. Peralta-P\u00e9rez, A. Forc\u00e9n-Acebal, S. Garc\u00eda-Grandab,\u00a0F. L\u00f3pez Ortiz,<em> Chem. Comun<\/em>. <strong>2003<\/strong>, 856. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2003\/CC\/B212708C#!divAbstract\">10.1039\/B212708C. <\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30104 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7.png\" alt=\"\" width=\"828\" height=\"466\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7.png 1466w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7-300x169.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7-768x432.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/3-7-680x383.png 680w\" sizes=\"(max-width: 828px) 100vw, 828px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30105 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6.png\" alt=\"\" width=\"790\" height=\"328\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6.png 1456w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6-300x124.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6-768x319.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/4-6-680x282.png 680w\" sizes=\"(max-width: 790px) 100vw, 790px\" \/><\/a><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>[1] F. L\u00f3pez-Ortiz, E. Pel\u00e1ez-Arango, B. Tejerina, E. P\u00e9rez-Carre\u00f1o, S. Garc\u00eda-Granda, <em>J. Am. Chem. Soc<\/em>. <strong>1995<\/strong>, <em>117<\/em>, 9972. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00145a006\">10.1021\/ja00145a006.<\/a><\/li>\n<li>[2] K. Utvary, R. Hagenauer, Monatsh. <em>Chem<\/em>.,<strong> 1963<\/strong>, <em>94<\/em>, 797. doi: <a href=\"http:\/\/link.springer.com\/10.1007\/BF00913085\">10.1007\/BF00913085.<\/a><\/li>\n<li>[3] K. Utvary, E. Freundlinger, V. Gutmann, Monatsh. <em>Chem<\/em>., <strong>1966<\/strong>, <em>97<\/em>, 348. doi: <a href=\"http:\/\/link.springer.com\/10.1007\/BF00905251\">10.1007\/BF00905251.<\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u4e8c\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210<sup>[1]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30106 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1.png\" alt=\"\" width=\"902\" height=\"165\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1.png 979w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1-300x55.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1-768x140.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/a-1-680x124.png 680w\" sizes=\"(max-width: 902px) 100vw, 902px\" \/><\/a><\/p>\n<p>\u4e09\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210<sup>[2]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30107 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1.png\" alt=\"\" width=\"821\" height=\"231\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1.png 1119w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1-300x84.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1-768x216.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/b-1-680x191.png 680w\" sizes=\"(max-width: 821px) 100vw, 821px\" \/><\/a><\/p>\n<p>\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210<sup>[2]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30108 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c.png\" alt=\"\" width=\"836\" height=\"188\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c.png 1423w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c-300x67.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c-768x173.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/01\/c-680x153.png 680w\" sizes=\"(max-width: 836px) 100vw, 836px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p>-35 \u00baC\u4e0b\uff0c\u5411\u78f7\u8148\u7684\u56db\u6c22\u544b\u5583\u6eb6\u6db2(1 eq. \u5e95\u7269\u6d53\u5ea60.04 M)\u4e2d\u52a0\u5165\u53d4\u4e01\u57fa\u9502 (2.2 eq. 1.7 M \u73af\u5df1\u70f7\u6eb6\u6db2)\uff0c30 min\u540e\uff0c\u52a0\u5165\u919b\u6216\u916e\u5e95\u7269 (1 eq.)\u3002\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u5728-95 \u00baC\u4e0b\u6405\u62cc2 h 30 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#ff0000;\"><strong>\u53d4\u4e01\u57fa\u9502\u9047\u7a7a\u6c14\u6781\u6613\u81ea\u71c3\uff0c\u8fdb\u800c\u9020\u6210\u4e25\u91cd\u5b9e\u9a8c\u4e8b\u6545\uff0c\u53d6\u7528\u8fd9\u7c7b\u8bd5\u5242\u65f6\uff0c\u5747\u9700\u8981\u4e25\u683c\u7684\u65e0\u6c34\u65e0\u6c27\u64cd\u4f5c\u3002\u5fc5\u8981\u65f6\u5efa\u8bae\u5728\u6c29\u6c14\u624b\u5957\u7bb1\u4e2d\u5c0f\u5fc3\u64cd\u4f5c<\/strong><strong> (<\/strong><strong>\u64cd\u4f5c\u65f6\uff0c\u5b9e\u9a8c\u53f0\u9762\u52a1\u5fc5\u6574\u6d01\uff0c\u540c\u65f6\u79fb\u9664\u53f0\u9762\u4e0a\u5168\u90e8\u7684\u53ef\u71c3\u6027\u7684\u7269\u54c1\uff0c\u5982\u68c9\u82b1\u3001\u6ee4\u7eb8\u3001\u6709\u673a\u6eb6\u5242\u53ca\u5404\u7c7b\u5851\u6599\u5bb9\u5668\u7b49<\/strong><strong>)<\/strong><strong>\u3002\u7528\u6ce8\u5c04\u5668<\/strong><strong> (<\/strong><strong>\u6700\u597d\u91c7\u7528\u5e26\u6709<\/strong><strong>Luer Lock<\/strong><strong>\u7684\u6ce8\u5c04\u5668<\/strong><strong>)<\/strong><strong>\u64cd\u4f5c\u65f6\uff0c\u53ef\u5c06\u9488\u5934\u63d2\u5165\u80f6\u585e\u4e2d\u9694\u7edd\u7a7a\u6c14\uff0c\u540c\u65f6\u52a1\u5fc5\u786e\u4fdd\u5176\u5bc6\u5c01\u6027\u4f18\u826f\uff0c\u6700\u597d\u91c7\u7528\u62bd\u53d6\u6c29\u6c14<\/strong><strong> (<\/strong><strong>\u6c29\u6c14\u4e0e\u7a7a\u6c14\u6709\u8f83\u5927\u7684\u5bc6\u5ea6\u5dee\u5f02\uff0c\u6bd4\u6c2e\u6c14\u80fd\u591f\u66f4\u597d\u5730\u6392\u9664\u6ce8\u5c04\u5668\u5185\u7684\u7a7a\u6c14<\/strong><strong>)<\/strong><strong>\u7684\u65b9\u6cd5\uff0c\u6392\u9664\u6ce8\u5c04\u5668\u5185\u7684\u7a7a\u6c14\uff0c\u5e76\u4e25\u683c\u6309\u89c4\u8303\u64cd\u4f5c<\/strong><strong> (<\/strong><strong>\u5b89\u5168\u7684\u64cd\u4f5c\u65b9\u6cd5\u8be6\u89c1<\/strong><\/span><a href=\"https:\/\/pubs.acs.org\/author\/Johansen,+Martin+B\">M. B. Johansen<\/a>,\u00a0<a href=\"https:\/\/pubs.acs.org\/author\/Kondrup,+Jens+C\">J. C. Kondrup<\/a>,\u00a0<a href=\"https:\/\/pubs.acs.org\/author\/Hinge,+Mogens\">M. Hinge<\/a>, <a href=\"https:\/\/pubs.acs.org\/author\/Lindhardt,+Anders+T\">A. T. Lindhardt<\/a><strong>, <\/strong><em>Org. Process Res. Dev<\/em>.,\u00a0<strong>2018<\/strong>,\u00a0<em>22<\/em>, 903. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.oprd.8b00151\">10.1021\/acs.oprd.8b00151<\/a><strong>)<\/strong><strong>\uff0c<span style=\"color: #ff0000;\">\u5e76\u7a7f\u6234\u9632\u706b\u5b9e\u9a8c\u9632\u670d\u3002\u53d6\u7528\u7ed3\u675f\uff0c\u62d4\u51fa\u6ce8\u5c04\u5668\u65f6\uff0c\u8981\u4e25\u683c\u9632\u6b62\u6e85\u51fa\u3002\u5b9e\u9a8c\u7ed3\u675f\u540e\uff0c\u52a1\u5fc5\u8981\u7528\u9187\u7c7b\u6eb6\u5242\u5c0f\u5fc3\u6dec\u706d\u6b8b\u7559\u5728\u6ce8\u5c04\u5668\u5185\u7684\u53d4\u4e01\u57fa\u9502\u8bd5\u5242\u3002\u53cd\u5e94\u7684\u6dec\u706d\u8fc7\u7a0b\u540c\u6837\u9700\u8981\u5c0f\u5fc3\uff0c\u53ef\u7528\u6b63\u5df1\u70f7\u7c7b\u60f0\u6027\u6eb6\u5242\u5148\u7a00\u91ca\uff0c\u518d\u7528\u9187\u6dec\u706d\uff0c\u4ed4\u7ec6\u64cd\u4f5c\u3002<\/span><\/strong><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: disc;\">\n<li>[1] E. Peralta P\u00e9rez, F. L\u00f3pez Ortiz,<em> Chem. Commun.<\/em> <strong>2000<\/strong>, 2029. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2000\/CC\/b006413k#!divAbstract\">10.1039\/B006413K<\/a>.<\/li>\n<li>[2] J. Garc\u00eda-L\u00f3pez, E. Peralta-P\u00e9rez, A. Forc\u00e9n-Acebal, S. Garc\u00eda-Grandab,\u00a0F. L\u00f3pez-Ortiz,<em> Chem. Comun<\/em>. <strong>2003<\/strong>, 856. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2003\/CC\/B212708C#!divAbstract\">10.1039\/B212708C.<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 2000\u5e74\uff0c\u897f\u73ed\u7259Almer\u00eda\u5927\u5b66 (Universidad de Almer\u00eda)\u7684L\u00f3pez Ortiz\u7b49\u62a5\u9053\u4e86\u9996\u4f8b\u901a\u8fc7\u5728\u5f3a\u78b1\u6027\u6761\u4ef6 (\u6b63\u4e01\u57fa\u9502) \u4e0b\uff0cP-\u4e8c\u82ef\u57fa (\u70f7\u57fa) (N-\u7532\u6c27\u7fb0\u57fa)\u78f7\u8148 (P-diphenyl (alkyl) (N-carboxymethyl)phosphazenes)\u4e0e\u919b\u6216\u916e\u4f5c\u7528\uff0c\u5b8c\u6210\u4e86\u4e8c\u53d6\u4ee3\u3001\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\uff0c\u6587\u732e\u4e2d\u5c06\u8be5\u65b9\u6cd5\u5b66\u79f0\u4e3aL\u00f3pez Ortiz\u70ef\u57fa\u5316 (L\u00f3pez Ortiz olefination) [1]\u3002 2003\u5e74\uff0cL\u00f3pez Ortiz\u91c7\u7528\u78b1\u6027\u66f4\u5f3a\u7684\u53d4\u4e01\u57fa\u9502\u539f\u4f4d\u5f62\u6210\u7684\u53cc\u9502\u4ee3\u78f7\u8148\uff0c\u968f\u540e\u4e0e\u919b\u6216\u916e\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u73af\u7f29\u5408\u53cd\u5e94\uff0c\u540c\u65f6\u5206\u79bb\u51fabicyclic 1,2-oxaphosphetanes\uff0c\u901a\u8fc7\u5bf9bicyclic 1,2-oxaphosphetanes\u7684\u7acb\u4f53\u4e13\u4e00\u6027\u70ed\u89e3\u53cd\u5e94\uff0c\u6210\u529f\u5b8c\u6210\u4e86\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210[2]\u3002 L\u00f3pez Ortiz\u70ef\u57fa\u5316\u53cd\u5e94\u4e3a\u4e8c\u53d6\u4ee3\u3001\u4e09\u53d6\u4ee3\u53ca\u56db\u53d6\u4ee3\u70ef\u70c3\u7684\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u5f00\u8f9f\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u65b9\u6cd5\u3002 \u57fa\u672c\u6587\u732e [1] E. Peralta P\u00e9rez, F. L\u00f3pez Ortiz, Chem. Commun. 2000, 2029. doi: 10.1039\/B006413K. [2] J. Garc\u00eda-L\u00f3pez, E. Peralta-P\u00e9rez, A. Forc\u00e9n-Acebal, S. Garc\u00eda-Grandab,\u00a0F. L\u00f3pez Ortiz, Chem. Comun. 2003, 856. doi: 10.1039\/B212708C. \u53cd\u5e94\u673a\u7406 \u53c2\u8003\u6587\u732e [1] F. L\u00f3pez-Ortiz, E. Pel\u00e1ez-Arango, B. Tejerina, E. P\u00e9rez-Carre\u00f1o, S. Garc\u00eda-Granda, J. Am. Chem. Soc. 1995, 117, 9972. doi: 10.1021\/ja00145a006. [2] K. Utvary, R. Hagenauer, Monatsh. Chem., 1963, 94, 797. doi: 10.1007\/BF00913085. [3] K. Utvary, E. Freundlinger, V. Gutmann, Monatsh. 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