{"id":30318,"date":"2020-02-25T08:00:09","date_gmt":"2020-02-25T00:00:09","guid":{"rendered":"\/\/www.gsbet888.com\/?p=30318"},"modified":"2020-02-24T10:56:46","modified_gmt":"2020-02-24T02:56:46","slug":"%e5%ae%98%e8%83%bd%e5%9b%a2%e7%9a%84%e8%bd%ac%e5%8c%96-%e9%85%af%e5%8c%96%e5%92%8c%e9%85%b0%e8%83%ba%e5%8c%96%e5%8f%8d%e5%ba%94%ef%bc%88%e4%ba%8c%ef%bc%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/02\/%e5%ae%98%e8%83%bd%e5%9b%a2%e7%9a%84%e8%bd%ac%e5%8c%96-%e9%85%af%e5%8c%96%e5%92%8c%e9%85%b0%e8%83%ba%e5%8c%96%e5%8f%8d%e5%ba%94%ef%bc%88%e4%ba%8c%ef%bc%89.html","title":{"rendered":"\u5b98\u80fd\u56e2\u7684\u8f6c\u5316\u2014\u2014\u916f\u5316\u548c\u9170\u80fa\u5316\u53cd\u5e94\uff08\u4e8c\uff09"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005\uff1a\u5b59\u82cf\u8d5f<\/p>\n<h4><strong>\u7b2c\u4e8c\u90e8\u5206<\/strong> <strong>\u76f4\u63a5\u6cd5\u916f\u5316\u53cd\u5e94<\/strong><\/h4>\n<p>\u5728\u4e0a\u4e00\u8282\u4e2d\u6211\u4eec\u4ecb\u7ecd\u4e86\u51e0\u79cd\u95f4\u63a5\u916f\u5316\u7684\u65b9\u6cd5\uff0c\u5305\u62ec\u9170\u6c2f\u4e2d\u95f4\u4f53\u6cd5\uff0c\u9178\u9150\u4e2d\u95f4\u4f53\u6cd5\uff0c\u8fd9\u6b21\u6211\u4eec\u4ecb\u7ecd\u51e0\u79cd\u4e00\u6b65\u916f\u5316\u7684\u65b9\u6cd5\u3002<\/p>\n<p>1. Fisher-Speier\u916f\u5316<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/1-8.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30319 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/1-8.png\" alt=\"\" width=\"697\" height=\"122\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/1-8.png 766w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/1-8-300x52.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/1-8-680x119.png 680w\" sizes=\"(max-width: 697px) 100vw, 697px\" \/><\/a><\/p>\n<p>Fisher-Speier\u916f\u5316\u662f\u6700\u76f4\u63a5\u6700\u201c\u66b4\u529b\u201d\u7684\u916f\u5316\u65b9\u6cd5\uff0c\u5b83\u53ea\u9002\u7528\u4e8e\u6ca1\u6709\u5176\u4ed6\u5b98\u80fd\u56e2\u548c\u590d\u6742\u7ed3\u6784\u7684\u7b80\u5355\u5206\u5b50\u7684\u916f\u5316\u53cd\u5e94\uff0c\u901a\u5e38\u53cd\u5e94\u88c5\u7f6e\u4e2d\u4f1a\u5728\u53cd\u5e94\u5bb9\u5668\u548c\u56de\u6d41\u7f50\u95f4\u6dfb\u52a0Dean Stark\u88c5\u7f6e\uff0c\u5373\u5206\u6c34\u5668\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/2-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30320 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/2-7.png\" alt=\"\" width=\"148\" height=\"492\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/2-7.png 188w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/2-7-90x300.png 90w\" sizes=\"(max-width: 148px) 100vw, 148px\" \/><\/a><\/p>\n<p>2. Steglich\u916f\u5316\u53cd\u5e94<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30321 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8.png\" alt=\"\" width=\"755\" height=\"118\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8.png 832w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8-300x47.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8-680x106.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/3-8-768x120.png 768w\" sizes=\"(max-width: 755px) 100vw, 755px\" \/><\/a><\/p>\n<p>\u78b3\u4e8c\u4e9a\u80fa\u7c7b\u8bd5\u5242\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4e5f\u662f\u8d77\u5230\u6d3b\u5316\u53cd\u5e94\u5e95\u7269\u7684\u4f5c\u7528\uff0c\u540c\u65f6\u53d1\u751f\u8131\u6c34\u7684\u8fc7\u7a0b\u3002\u4f7f\u7528\u78b3\u4e8c\u4e9a\u80fa \u662f\u6700\u5e38\u7528\u7684\u916f\u5316\uff08\u548c\u9170\u80fa\u5316\uff09\u7684\u624b\u6bb5\u4e4b\u4e00\u3002\u53cd\u5e94\u4e2dDMAP\u4e0d\u662f\u5fc5\u987b\u7684\uff0c\u4f46\u50ac\u5316\u91cf\u7684DMAP\u53ef\u4ee5\u52a0\u901f\u53cd\u5e94\u7684\u8fdb\u7a0b\uff0c\u751a\u81f3\u53ef\u4ee5\u4f7f\u5f97\u53cd\u5e94\u53ef\u4ee5\u5728\u5e38\u6e29\u4e0b\u53d1\u751f\u3002DCC\u7684\u4e00\u4e2a\u7f3a\u70b9\u662f\u5728\u53cd\u5e94\u4e2d\u4f1a\u751f\u6210\u96be\u5bb9\u7684\u5c3f\u7d20\u884d\u751f\u7269DCU\uff0c\u6709\u65f6\u4f1a\u4f7f\u5f97\u4ea7\u7269\u8f83\u96be\u5206\u79bb\uff0c\u6b64\u5916DCC\u7684\u6bd2\u6027\u8f83\u5927\uff0c\u56e0\u6b64\u540e\u7eed\u7684\u4e5f\u5f00\u53d1\u51fa\u4e86\u51e0\u79cd\u53ef\u4ee5\u66ff\u4ee3\u8bd5\u5242\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30322 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7.png\" alt=\"\" width=\"708\" height=\"325\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7.png 1170w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7-300x138.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7-680x312.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7-768x352.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/4-7-370x170.png 370w\" sizes=\"(max-width: 708px) 100vw, 708px\" \/><\/a><\/p>\n<p>\u53cd\u5e94\u673a\u7406\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30323 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7.png\" alt=\"\" width=\"741\" height=\"336\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7.png 1241w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7-300x136.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7-680x308.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/5-7-768x348.png 768w\" sizes=\"(max-width: 741px) 100vw, 741px\" \/><\/a><\/p>\n<p>\u5f53\u53cd\u5e94\u4f53\u7cfb\u4e2d\u52a0\u5165\u50ac\u5316\u91cf\u7684DMAP\u65f6\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30324 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6.png\" alt=\"\" width=\"716\" height=\"204\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6.png 905w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6-300x86.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6-680x194.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/6-6-768x219.png 768w\" sizes=\"(max-width: 716px) 100vw, 716px\" \/><\/a><\/p>\n<p>\u8fd9\u91cc\u662f\u51e0\u4e2a\u5e94\u7528\uff1a<\/p>\n<p>a. \u957f\u94fe\u7684\u9170\u57fa\u5316\uff1a[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30325 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7.png\" alt=\"\" width=\"741\" height=\"440\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7.png 1119w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7-300x178.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7-680x404.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/7-7-768x456.png 768w\" sizes=\"(max-width: 741px) 100vw, 741px\" \/><\/a><\/p>\n<p>b. \u53cd\u5e94\u4e2d\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u5f88\u597d\uff1a[2]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30326 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5.png\" alt=\"\" width=\"758\" height=\"487\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5.png 1166w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5-300x193.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5-680x437.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/8-5-768x494.png 768w\" sizes=\"(max-width: 758px) 100vw, 758px\" \/><\/a><\/p>\n<p>c. \u5927\u4f4d\u963b\u7684\u4ef2\u9187\u7684\u53cd\u5e94<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30327 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5.png\" alt=\"\" width=\"768\" height=\"156\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5.png 1229w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5-300x61.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5-680x138.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/9-5-768x156.png 768w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/a><\/p>\n<p>3. 2-\u5421\u5576\u786b\u916f\u8bd5\u5242\uff08\u5927\u73af\u5185\u916f\u5316\uff09<\/p>\n<p>\u7fa7\u9178\u79bb\u5b50\u53ef\u4ee5\u548c2-\u6c2f\u5421\u5576\u9633\u79bb\u5b50\u6d3b\u5316\u7684\u916f\u52a0\u5408\u7269\u8bd5\u5242\u53d1\u751f\u53d6\u4ee3\u4ece\u800c\u5b9e\u73b0\u916f\u5316\u8fc7\u7a0b\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30328 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4.png\" alt=\"\" width=\"681\" height=\"174\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4.png 823w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4-300x77.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4-680x174.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/10-4-768x196.png 768w\" sizes=\"(max-width: 681px) 100vw, 681px\" \/><\/a><\/p>\n<p>\u800c\u786b\u916f\u662f\u4e00\u7c7b\u975e\u5e38\u6d3b\u6cfc\u7684\u9170\u57fa\u5316\u8bd5\u5242\uff0c\u5b83\u4eec\u975e\u5e38\u9002\u7528\u4e8e\u5927\u73af\u5185\u916f\u5316\u53cd\u5e94\u3002\u5927\u4f4d\u963b\u7684\u5185\u916f\u5316\u65f62-\u5421\u5576\u786b\u916f\u548cCu(II)\u914d\u5408\u4f7f\u7528\u6548\u679c\u4f1a\u66f4\u597d\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30329 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4.png\" alt=\"\" width=\"615\" height=\"170\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4.png 803w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4-300x83.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4-680x188.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/11-4-768x212.png 768w\" sizes=\"(max-width: 615px) 100vw, 615px\" \/><\/a><\/p>\n<p>\u5e76\u4e142-\u5421\u5576\u4e8c\u786b\u919a\u548c2-\u54aa\u5511\u4e8c\u786b\u919a\u4e5f\u53ef\u4ee5\u7528\u4e8e\u4f5c\u4e3a\u6d3b\u5316\u8bd5\u5242\uff0c\u5e76\u4e14\u5bf9\u5927\u73af\u53cd\u5e94\u7279\u522b\u6709\u6548\uff0c\u4e14\u6536\u7387\u5f88\u9ad8\u3002\u8fd9\u4e9b\u8bd5\u5242\u5728\u4f5c\u7528\u662f\u6700\u5173\u952e\u7684\u5c31\u662f\u4f1a\u5f62\u6210\u5206\u5b50\u5185\u6c22\u952e\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30330 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3.png\" alt=\"\" width=\"660\" height=\"155\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3.png 818w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3-300x70.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3-680x160.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/12-3-768x180.png 768w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/><\/a><\/p>\n<p>\u53cd\u5e94\u673a\u7406\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30331 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3.png\" alt=\"\" width=\"731\" height=\"413\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3.png 1155w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3-300x169.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3-680x384.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/13-3-768x434.png 768w\" sizes=\"(max-width: 731px) 100vw, 731px\" \/><\/a><\/p>\n<p>\u4e00\u4e2a\u4f8b\u5b50\uff1a[3]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30332 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2.png\" alt=\"\" width=\"782\" height=\"243\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2.png 1242w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2-300x93.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2-680x211.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/14-2-768x238.png 768w\" sizes=\"(max-width: 782px) 100vw, 782px\" \/><\/a><\/p>\n<h4><strong>REFERENCES<\/strong><\/h4>\n<ul style=\"list-style-type: circle;\">\n<li>[1] J.<em> Am. Chem. Soc<\/em>.<strong> 1994<\/strong>, 116, 26, 12111-12112, <a href=\"https:\/\/doi.org\/10.1021\/ja00105a085\">DOI:10.1021\/ja00105a085<\/a><\/li>\n<li>[2] <a href=\"http:\/\/dx.doi.org\/10.1073\/pnas.0401247101\">Proc.<em> Natl. Acad. Sci<\/em>. U.S.A. 2004, 101, 11955.<\/a> DOI: <a href=\"https:\/\/doi.org\/10.1073\/pnas.0401247101\">10.1073\/pnas.0401247101<\/a><\/li>\n<li>[3] J.<em> Am. Chem. Soc. <\/em><strong>1974<\/strong>, 96, 17, 5614-5616. <a href=\"https:\/\/doi.org\/10.1021\/ja00824a073\">DOI:10.1021\/ja00824a073<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u5b59\u82cf\u8d5f \u7b2c\u4e8c\u90e8\u5206 \u76f4\u63a5\u6cd5\u916f\u5316\u53cd\u5e94 \u5728\u4e0a\u4e00\u8282\u4e2d\u6211\u4eec\u4ecb\u7ecd\u4e86\u51e0\u79cd\u95f4\u63a5\u916f\u5316\u7684\u65b9\u6cd5\uff0c\u5305\u62ec\u9170\u6c2f\u4e2d\u95f4\u4f53\u6cd5\uff0c\u9178\u9150\u4e2d\u95f4\u4f53\u6cd5\uff0c\u8fd9\u6b21\u6211\u4eec\u4ecb\u7ecd\u51e0\u79cd\u4e00\u6b65\u916f\u5316\u7684\u65b9\u6cd5\u3002 1. Fisher-Speier\u916f\u5316 Fisher-Speier\u916f\u5316\u662f\u6700\u76f4\u63a5\u6700\u201c\u66b4\u529b\u201d\u7684\u916f\u5316\u65b9\u6cd5\uff0c\u5b83\u53ea\u9002\u7528\u4e8e\u6ca1\u6709\u5176\u4ed6\u5b98\u80fd\u56e2\u548c\u590d\u6742\u7ed3\u6784\u7684\u7b80\u5355\u5206\u5b50\u7684\u916f\u5316\u53cd\u5e94\uff0c\u901a\u5e38\u53cd\u5e94\u88c5\u7f6e\u4e2d\u4f1a\u5728\u53cd\u5e94\u5bb9\u5668\u548c\u56de\u6d41\u7f50\u95f4\u6dfb\u52a0Dean Stark\u88c5\u7f6e\uff0c\u5373\u5206\u6c34\u5668\uff1a 2. Steglich\u916f\u5316\u53cd\u5e94 \u78b3\u4e8c\u4e9a\u80fa\u7c7b\u8bd5\u5242\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4e5f\u662f\u8d77\u5230\u6d3b\u5316\u53cd\u5e94\u5e95\u7269\u7684\u4f5c\u7528\uff0c\u540c\u65f6\u53d1\u751f\u8131\u6c34\u7684\u8fc7\u7a0b\u3002\u4f7f\u7528\u78b3\u4e8c\u4e9a\u80fa \u662f\u6700\u5e38\u7528\u7684\u916f\u5316\uff08\u548c\u9170\u80fa\u5316\uff09\u7684\u624b\u6bb5\u4e4b\u4e00\u3002\u53cd\u5e94\u4e2dDMAP\u4e0d\u662f\u5fc5\u987b\u7684\uff0c\u4f46\u50ac\u5316\u91cf\u7684DMAP\u53ef\u4ee5\u52a0\u901f\u53cd\u5e94\u7684\u8fdb\u7a0b\uff0c\u751a\u81f3\u53ef\u4ee5\u4f7f\u5f97\u53cd\u5e94\u53ef\u4ee5\u5728\u5e38\u6e29\u4e0b\u53d1\u751f\u3002DCC\u7684\u4e00\u4e2a\u7f3a\u70b9\u662f\u5728\u53cd\u5e94\u4e2d\u4f1a\u751f\u6210\u96be\u5bb9\u7684\u5c3f\u7d20\u884d\u751f\u7269DCU\uff0c\u6709\u65f6\u4f1a\u4f7f\u5f97\u4ea7\u7269\u8f83\u96be\u5206\u79bb\uff0c\u6b64\u5916DCC\u7684\u6bd2\u6027\u8f83\u5927\uff0c\u56e0\u6b64\u540e\u7eed\u7684\u4e5f\u5f00\u53d1\u51fa\u4e86\u51e0\u79cd\u53ef\u4ee5\u66ff\u4ee3\u8bd5\u5242\uff1a \u53cd\u5e94\u673a\u7406\uff1a \u5f53\u53cd\u5e94\u4f53\u7cfb\u4e2d\u52a0\u5165\u50ac\u5316\u91cf\u7684DMAP\u65f6\uff1a \u8fd9\u91cc\u662f\u51e0\u4e2a\u5e94\u7528\uff1a a. \u957f\u94fe\u7684\u9170\u57fa\u5316\uff1a[1] b. \u53cd\u5e94\u4e2d\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u5f88\u597d\uff1a[2] c. \u5927\u4f4d\u963b\u7684\u4ef2\u9187\u7684\u53cd\u5e94 3. 2-\u5421\u5576\u786b\u916f\u8bd5\u5242\uff08\u5927\u73af\u5185\u916f\u5316\uff09 \u7fa7\u9178\u79bb\u5b50\u53ef\u4ee5\u548c2-\u6c2f\u5421\u5576\u9633\u79bb\u5b50\u6d3b\u5316\u7684\u916f\u52a0\u5408\u7269\u8bd5\u5242\u53d1\u751f\u53d6\u4ee3\u4ece\u800c\u5b9e\u73b0\u916f\u5316\u8fc7\u7a0b\uff1a \u800c\u786b\u916f\u662f\u4e00\u7c7b\u975e\u5e38\u6d3b\u6cfc\u7684\u9170\u57fa\u5316\u8bd5\u5242\uff0c\u5b83\u4eec\u975e\u5e38\u9002\u7528\u4e8e\u5927\u73af\u5185\u916f\u5316\u53cd\u5e94\u3002\u5927\u4f4d\u963b\u7684\u5185\u916f\u5316\u65f62-\u5421\u5576\u786b\u916f\u548cCu(II)\u914d\u5408\u4f7f\u7528\u6548\u679c\u4f1a\u66f4\u597d\u3002 \u5e76\u4e142-\u5421\u5576\u4e8c\u786b\u919a\u548c2-\u54aa\u5511\u4e8c\u786b\u919a\u4e5f\u53ef\u4ee5\u7528\u4e8e\u4f5c\u4e3a\u6d3b\u5316\u8bd5\u5242\uff0c\u5e76\u4e14\u5bf9\u5927\u73af\u53cd\u5e94\u7279\u522b\u6709\u6548\uff0c\u4e14\u6536\u7387\u5f88\u9ad8\u3002\u8fd9\u4e9b\u8bd5\u5242\u5728\u4f5c\u7528\u662f\u6700\u5173\u952e\u7684\u5c31\u662f\u4f1a\u5f62\u6210\u5206\u5b50\u5185\u6c22\u952e\uff1a \u53cd\u5e94\u673a\u7406\uff1a \u4e00\u4e2a\u4f8b\u5b50\uff1a[3] REFERENCES [1] J. Am. Chem. Soc. 1994, 116, 26, 12111-12112, DOI:10.1021\/ja00105a085 [2] Proc. Natl. Acad. Sci. U.S.A. 2004, 101, 11955. DOI: 10.1073\/pnas.0401247101 [3] J. Am. Chem. Soc. 1974, 96, 17, 5614-5616. DOI:10.1021\/ja00824a073 \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01","protected":false},"author":26,"featured_media":30312,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/02\/cover-Functional-Groups-Manipulation-Esterification-and-Amidation-5.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-7T0","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30318"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=30318"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30318\/revisions"}],"predecessor-version":[{"id":30553,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30318\/revisions\/30553"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/30312"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=30318"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=30318"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=30318"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}