{"id":3035,"date":"2014-10-21T20:32:00","date_gmt":"2014-10-21T12:32:00","guid":{"rendered":"\/\/www.gsbet888.com\/?p=3035"},"modified":"2019-08-02T18:56:09","modified_gmt":"2019-08-02T10:56:09","slug":"%e7%a7%91%e6%99%ae%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94cope-rearrangement","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94\/2014\/10\/%e7%a7%91%e6%99%ae%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94cope-rearrangement.html","title":{"rendered":"\u79d1\u666e\u91cd\u6392\u53cd\u5e94(Cope Rearrangement)"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n[3,3]-\u03c3\u91cd\u6392\u4e2d\u6700\u57fa\u672c\u7684\u53cd\u5e94\u3002<\/p>\n<p>\u8be5\u53cd\u5e94\u662f\u4e00\u4e2a<strong>\u5e73\u8861\u53cd\u5e94<\/strong>\uff0c1,4-\u5df1\u4e8c\u70ef\u8fdb\u884ccope\u91cd\u6392\u7684\u8bdd\uff0c\u9700\u8981\u8d8a\u8fc7140 kJmol<sup>-1<\/sup>\u7684\u80fd\u91cf\u5c4f\u969c\uff0c\u8fd9\u6837\u624d\u80fd\u76f8\u4e92\u53d8\u6362\u3002<\/p>\n<p>\u4ece\u5408\u6210\u5316\u5b66\u7684\u89c2\u70b9\u51fa\u53d1\uff0c\u50cf<a href=\"http:\/\/www.chem-station.com\/user-cgi-bin\/odoos\/ps_search.cgi?act=jump&amp;access=1&amp;url=http%3a%2f%2fwww%2echem%2dstation%2ecom%2fodoos%2fdata%2foxy_cope%2ehtm\">oxy-Cope\u91cd\u6392<\/a>\u90a3\u6837\uff0c\u5bfb\u627e\u5230\u80fd\u591f\u5f62\u6210\u4e0d\u53ef\u9006\u53cd\u5e94\u7684\u5e95\u7269\u624d\u5177\u6709\u66f4\u9ad8\u7684\u4ef7\u503c\u3002(\u53c2\u7167cope\u91cd\u6392\u7684\u5173\u8054\u53cd\u5e94)<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>\u30fbCope, A. C.; Hardy, E. M. <em>J. Am. Chem. Soc.<\/em> <strong>1940<\/strong>, <em>62<\/em>, 441. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ja01859a055\">10.1021\/ja01859a055<\/a><br \/>\n\u30fbRhoads, S. A.; Raulins, N. R. <em>Org. React.<\/em> <strong>1975<\/strong>, <em>22<\/em>, 1.<br \/>\n\u30fbHill, R. K.<em> Comprehensive Organic Synthesis<\/em> <strong>1991<\/strong>, <em>5<\/em>, 785.<br \/>\n\u30fbWilson, S. R. <em>Org. React.<\/em> <strong>1993<\/strong>, <em>43<\/em>, 93.<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u4e0e\u5176\u4ed6[3,3]-sigmatropic\u91cd\u6392\u7c7b\u4f3c\u3001\u53cd\u5e94\u4e2d\u5f62\u6210\u4e86\u534f\u540c\u76846\u5706\u73af\u8fc7\u6e21\u6001(\u4e00\u822c\u5448\u6905\u5f0f\u7ed3\u6784)\u8fdb\u884c\u7684\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/10\/copear2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-3037\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/10\/copear2.gif\" alt=\"copear2\" width=\"311\" height=\"73\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<p>&nbsp; <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 [3,3]-\u03c3\u91cd\u6392\u4e2d\u6700\u57fa\u672c\u7684\u53cd\u5e94\u3002 \u8be5\u53cd\u5e94\u662f\u4e00\u4e2a\u5e73\u8861\u53cd\u5e94\uff0c1,4-\u5df1\u4e8c\u70ef\u8fdb\u884ccope\u91cd\u6392\u7684\u8bdd\uff0c\u9700\u8981\u8d8a\u8fc7140 kJmol-1\u7684\u80fd\u91cf\u5c4f\u969c\uff0c\u8fd9\u6837\u624d\u80fd\u76f8\u4e92\u53d8\u6362\u3002 \u4ece\u5408\u6210\u5316\u5b66\u7684\u89c2\u70b9\u51fa\u53d1\uff0c\u50cfoxy-Cope\u91cd\u6392\u90a3\u6837\uff0c\u5bfb\u627e\u5230\u80fd\u591f\u5f62\u6210\u4e0d\u53ef\u9006\u53cd\u5e94\u7684\u5e95\u7269\u624d\u5177\u6709\u66f4\u9ad8\u7684\u4ef7\u503c\u3002(\u53c2\u7167cope\u91cd\u6392\u7684\u5173\u8054\u53cd\u5e94) &nbsp; \u57fa\u672c\u6587\u732e \u30fbCope, A. C.; Hardy, E. M. J. Am. Chem. Soc. 1940, 62, 441. DOI: 10.1021\/ja01859a055 \u30fbRhoads, S. A.; Raulins, N. R. Org. React. 1975, 22, 1. \u30fbHill, R. K. Comprehensive Organic Synthesis 1991, 5, 785. \u30fbWilson, S. R. Org. React. 1993, 43, 93. &nbsp; \u53cd\u5e94\u673a\u7406 \u4e0e\u5176\u4ed6[3,3]-sigmatropic\u91cd\u6392\u7c7b\u4f3c\u3001\u53cd\u5e94\u4e2d\u5f62\u6210\u4e86\u534f\u540c\u76846\u5706\u73af\u8fc7\u6e21\u6001(\u4e00\u822c\u5448\u6905\u5f0f\u7ed3\u6784)\u8fdb\u884c\u7684\u53cd\u5e94\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e &nbsp;","protected":false},"author":5,"featured_media":3036,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[12],"tags":[387,572],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/10\/copear1.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-MX","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3035"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=3035"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3035\/revisions"}],"predecessor-version":[{"id":28053,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3035\/revisions\/28053"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/3036"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=3035"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=3035"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=3035"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}