{"id":30601,"date":"2020-03-12T08:00:16","date_gmt":"2020-03-12T00:00:16","guid":{"rendered":"\/\/www.gsbet888.com\/?p=30601"},"modified":"2020-03-05T23:25:28","modified_gmt":"2020-03-05T15:25:28","slug":"akabori-momotani-%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/03\/akabori-momotani-%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Akabori-Momotani \u53cd\u5e94"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>Akabori-Momotani\u53cd\u5e94 (Akabori-Momotani reaction) \u662f\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\uff0c\u6c28\u57fa\u9178\u4e0e\u82b3\u9999\u919b\u4e4b\u95f4\u8fdb\u884c\u8131\u7fa7\u7f29\u5408 (decarboxylative condensation)\u8fc7\u7a0b\uff0c\u751f\u6210\u6c28\u57fa\u9187\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u7531\u65e5\u672c\u5927\u962a\u5927\u5b66 (\u5927\u962a\u5927\u5b66\uff0cOsaka university)\u7684\u8d64\u5800\u56db\u90ce (\u8d64\u5800 \u56db\u90ce, Akabori Shiro)\u4e0e\u6843\u8c37\u5609\u6a58 (\u6843\u8c37\u5609\u6a58, Momotani, Kakitsu )\u57281943\u5e74\u9996\u6b21\u62a5\u9053<sup>[1]<\/sup>\u3002\u8be5\u53cd\u5e94\u4ea7\u7387\u4f18\u826f\uff0c\u7136\u800c\uff0c\u8be5\u6761\u4ef6\u5e95\u7269\u9002\u7528\u8303\u56f4\u8f83\u7a84\uff0c\u4e0d\u9002\u7528\u4e0e\u4e09\u7ea7\u6c28\u57fa\u9178\u3002\u540c\u65f6\uff0c\u65e0\u6cd5\u83b7\u5f97\u66f4\u9ad8\u7a0b\u5ea6\u7684\u7acb\u4f53\u9009\u62e9\u6027 (Akabori-Momotani\u53cd\u5e94\u4ec5\u5177\u6709\u4e2d\u7b49\u7a0b\u5ea6\u7684\u7acb\u4f53\u9009\u62e9\u6027)\u3002\u56e0\u6b64\uff0c\u8be5\u53cd\u5e94\u5728\u5f53\u4ee3\u6709\u673a\u5408\u6210\u7814\u7a76\u4e2d\u5df2\u5c11\u6709\u5e94\u7528\u3002\u76ee\u524d\uff0c\u8be5\u53cd\u5e94\u7684\u5e94\u7528\u4e3b\u8981\u96c6\u4e2d\u4e8e\u90e8\u5206\u836f\u7269\u7684\u7814\u7a76\u65b9\u9762<sup>[2]-[4]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30602 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1.png\" alt=\"\" width=\"715\" height=\"223\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1.png 949w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1-300x94.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1-680x212.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/1-1-768x240.png 768w\" sizes=\"(max-width: 715px) 100vw, 715px\" \/><\/a><\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: disc;\">\n<li>[1] S. Akabori, K. Momotani, <em>J. Chem. Soc. Jpn<\/em>. <strong>1943<\/strong>, <em>64<\/em>, 608. doi: <a href=\"https:\/\/www.jstage.jst.go.jp\/article\/nikkashi1921\/64\/5\/64_5_608\/_article\/-char\/ja\/\">10.1246\/nikkashi1921. <\/a><\/li>\n<li>[2] D. Doughty, E. Kent, B. Painter, P. E. Pigou, M. R. Johnston, <em>Forens. Sci. Int<\/em>. <strong>2018<\/strong>, <em>287<\/em>, 207. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.forsciint.2018.01.023\">10.1016\/j.forsciint.2018.01.023<\/a>.<\/li>\n<li>[3] A. Doddridge, M. Collins, H. Salouros, <em>Drug Test. Anal<\/em>. <strong>2018<\/strong>, <em>10<\/em>, 548. doi: <a href=\"https:\/\/doi.org\/10.1002\/dta.2239\">10.1002\/dta.2239<\/a>.<\/li>\n<li>[4] B. Painter, P. Pigou, J. Clandest. <em>Lab. Investig. Chem. Assoc.<\/em> <strong>2012<\/strong>, <em>22<\/em>, 6.<\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30603 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1.png\" alt=\"\" width=\"800\" height=\"389\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1.png 1232w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1-300x146.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1-680x331.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/2-1-768x373.png 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/a><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: disc;\">\n<li>[1] D. Doughty, E. Kent, B. Painter, P. E. Pigou, M. R. Johnston, <em>Forens. Sci. Int<\/em>. <strong>2018<\/strong>, <em>287<\/em>, 207. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.forsciint.2018.01.023\">10.1016\/j.forsciint.2018.01.023<\/a>.<\/li>\n<li>[2] G. Pandey, P. Banerjee, S. R. Gadre, <em>Chem. Rev<\/em>. <strong>2006<\/strong>, <em>106<\/em>, 4484. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/cr050011g\">10.1021\/cr050011g.<\/a><\/li>\n<li>[3] O. Tsuge, S. Kanemasa, M. Ohe, S. Takenaka, <em>Bull. Chem. Soc. Jpn<\/em>. <strong>1987<\/strong>, <em>60<\/em>, 4079. doi: <a href=\"https:\/\/www.journal.csj.jp\/doi\/abs\/10.1246\/bcsj.60.4079\">10.1246\/bcsj.60.4079.<\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u6c28\u57fa\u9187\u7684\u5408\u6210<sup>[1]-[3]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-30604 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1.png\" alt=\"\" width=\"722\" height=\"309\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1.png 1031w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1-300x128.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1-680x291.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/3-1-768x329.png 768w\" sizes=\"(max-width: 722px) 100vw, 722px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p>\u5c06<em>N<\/em>-\u7532\u57fa\u4e19\u6c28\u9178(1 eq.)\u4e0e\u82ef\u7532\u919b (1.2 eq.)\u6eb6\u4e8eDMSO\uff0c\u5c06\u4e0a\u8ff0\u6df7\u5408\u7269\u5728130\u00b0C\u4e0b\u6405\u62cc\u52a0\u70ed1 h\u3002\u968f\u540e\uff0c\u52a0\u51655%\u4e59\u9178\u6eb6\u6db2\uff0c\u518d\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u8fdb\u884c\u52a0\u70ed\u56de\u6d41\u30024 h\u540e\uff0c\u5c06\u4e0a\u8ff0\u6df7\u5408\u7269\u51b7\u5374\u81f3\u5ba4\u6e29\u3002\u968f\u540e\uff0c\u52a0\u5165\u4e8c\u6c2f\u7532\u70f7\u8fdb\u884c\u8403\u53d6\u3002\u6c34\u76f8\u52a0\u516510%\u6c22\u6c27\u5316\u94a0\u6eb6\u6db2\u8c03\u8282pH\u81f310\u540e\uff0c\u7ee7\u7eed\u52a0\u5165\u4e8c\u6c2f\u7532\u70f7\u8fdb\u884c\u8403\u53d6\u3002\u5c06\u5408\u5e76\u7684\u6709\u673a\u76f8\u52a0\u5165\u65e0\u6c34\u786b\u9178\u94a0\u8fdb\u884c\u5e72\u71e5\uff0c\u5728\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u540e\uff0c\u83b7\u5f97\u76f8\u5e94\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul style=\"list-style-type: disc;\">\n<li>[1] S. Akabori, K. Momotani, <em>J. Chem. Soc. Jpn<\/em>. <strong>1943<\/strong>, <em>64<\/em>, 608. doi: <a href=\"https:\/\/www.jstage.jst.go.jp\/article\/nikkashi1921\/64\/5\/64_5_608\/_article\/-char\/ja\/\">10.1246\/nikkashi1921. <\/a><\/li>\n<li>[2] D. Doughty, E. Kent, B. Painter, P. E. Pigou, M. R. Johnston, <em>Forens. Sci. Int<\/em>. <strong>2018<\/strong>, <em>287<\/em>, 207. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.forsciint.2018.01.023\">10.1016\/j.forsciint.2018.01.023<\/a>.<\/li>\n<li>[3] A. Doddridge, M. Collins, H. Salouros, <em>Drug Test. Anal<\/em>. <strong>2018<\/strong>, <em>10<\/em>, 548. doi: <a href=\"https:\/\/doi.org\/10.1002\/dta.2239\">10.1002\/dta.2239<\/a>.<\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 Akabori-Momotani\u53cd\u5e94 (Akabori-Momotani reaction) \u662f\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\uff0c\u6c28\u57fa\u9178\u4e0e\u82b3\u9999\u919b\u4e4b\u95f4\u8fdb\u884c\u8131\u7fa7\u7f29\u5408 (decarboxylative condensation)\u8fc7\u7a0b\uff0c\u751f\u6210\u6c28\u57fa\u9187\u7684\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u7531\u65e5\u672c\u5927\u962a\u5927\u5b66 (\u5927\u962a\u5927\u5b66\uff0cOsaka university)\u7684\u8d64\u5800\u56db\u90ce (\u8d64\u5800 \u56db\u90ce, Akabori Shiro)\u4e0e\u6843\u8c37\u5609\u6a58 (\u6843\u8c37\u5609\u6a58, Momotani, Kakitsu )\u57281943\u5e74\u9996\u6b21\u62a5\u9053[1]\u3002\u8be5\u53cd\u5e94\u4ea7\u7387\u4f18\u826f\uff0c\u7136\u800c\uff0c\u8be5\u6761\u4ef6\u5e95\u7269\u9002\u7528\u8303\u56f4\u8f83\u7a84\uff0c\u4e0d\u9002\u7528\u4e0e\u4e09\u7ea7\u6c28\u57fa\u9178\u3002\u540c\u65f6\uff0c\u65e0\u6cd5\u83b7\u5f97\u66f4\u9ad8\u7a0b\u5ea6\u7684\u7acb\u4f53\u9009\u62e9\u6027 (Akabori-Momotani\u53cd\u5e94\u4ec5\u5177\u6709\u4e2d\u7b49\u7a0b\u5ea6\u7684\u7acb\u4f53\u9009\u62e9\u6027)\u3002\u56e0\u6b64\uff0c\u8be5\u53cd\u5e94\u5728\u5f53\u4ee3\u6709\u673a\u5408\u6210\u7814\u7a76\u4e2d\u5df2\u5c11\u6709\u5e94\u7528\u3002\u76ee\u524d\uff0c\u8be5\u53cd\u5e94\u7684\u5e94\u7528\u4e3b\u8981\u96c6\u4e2d\u4e8e\u90e8\u5206\u836f\u7269\u7684\u7814\u7a76\u65b9\u9762[2]-[4]\u3002 \u57fa\u672c\u6587\u732e [1] S. Akabori, K. Momotani, J. Chem. Soc. Jpn. 1943, 64, 608. doi: 10.1246\/nikkashi1921. [2] D. Doughty, E. Kent, B. Painter, P. E. Pigou, M. R. Johnston, Forens. Sci. Int. 2018, 287, 207. doi: 10.1016\/j.forsciint.2018.01.023. [3] A. Doddridge, M. Collins, H. Salouros, Drug Test. Anal. 2018, 10, 548. doi: 10.1002\/dta.2239. [4] B. Painter, P. Pigou, J. Clandest. Lab. Investig. Chem. Assoc. 2012, 22, 6. \u53cd\u5e94\u673a\u7406 \u53c2\u8003\u6587\u732e [1] D. Doughty, E. Kent, B. Painter, P. E. Pigou, M. R. Johnston, Forens. Sci. Int. 2018, 287, 207. doi: 10.1016\/j.forsciint.2018.01.023. [2] G. Pandey, P. [&hellip;]","protected":false},"author":21,"featured_media":30605,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[188,2449,2450],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/03\/e9d9881ad126c3c7ffd59541ff82bc8f.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-7Xz","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30601"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=30601"}],"version-history":[{"count":3,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30601\/revisions"}],"predecessor-version":[{"id":30709,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/30601\/revisions\/30709"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/30605"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=30601"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=30601"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=30601"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}