{"id":31419,"date":"2020-04-24T08:00:19","date_gmt":"2020-04-24T00:00:19","guid":{"rendered":"\/\/www.gsbet888.com\/?p=31419"},"modified":"2020-04-19T18:38:16","modified_gmt":"2020-04-19T10:38:16","slug":"%e5%bf%8d%e4%b9%85%e4%bf%9d-%e6%b4%8b-shinokubo-hiroshi","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemists\/2020\/04\/%e5%bf%8d%e4%b9%85%e4%bf%9d-%e6%b4%8b-shinokubo-hiroshi.html","title":{"rendered":"\u5fcd\u4e45\u4fdd \u6d0b Shinokubo Hiroshi"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005\uff1aalberto-caeiro<\/p>\n<p><a href=\"http:\/\/www.chembio.nagoya-u.ac.jp\/labhp\/organic1\/member.html\">\u5fcd\u4e45\u4fdd\u3000\u6d0b Shinokubo Hiroshi<\/a>\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65e5\u672c\u540d\u53e4\u5c4b\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u6559\u6388\u3002\u56fe\u7247\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201207020\">Author Profile, Hiroshi Shinokubo<\/a>.<\/p>\n<h4><strong>\u7ecf\u5386<\/strong><\/h4>\n<ul style=\"list-style-type: disc;\">\n<li>1994\u20131995 Ph. D., Graduate School of Engineering, Kyoto University\uff08\u4eac\u90fd\u5927\u5b66\uff09<\/li>\n<li>1995\u20132003 Assistant Professor, Graduate School of Engineering, Kyoto University<\/li>\n<li>1999\u20132000 Research Fellow, Massachusetts Institute of Technology (Rick L. Danheiser Group)<\/li>\n<li>2003\u20132008 Associate Professor, Graduate School of Science, Kyoto University<\/li>\n<li>2003\u20132007 JST-PRESTO Researcher<\/li>\n<li>2008\u2013present Professor, Graduate School of Engineering, Nagoya University\uff08\u540d\u53e4\u5c4b\u5927\u5b66\uff09<\/li>\n<\/ul>\n<h4><strong>\u83b7\u5956\u7ecf\u5386<\/strong><\/h4>\n<ul>\n<li>1999 The Society of Synthetic Organic Chemistry, Japan (SSOCJ) Award for Research Proposal<\/li>\n<li>2001 Bulletin of the Chemical Society of Japan Award<\/li>\n<li>2001 The Chemical Society of Japan Lecture Award for Young Chemists<\/li>\n<li>2004 The Chemical Society of Japan Award for Young Chemists<\/li>\n<li>2008 Banyu Young Chemist Award<\/li>\n<li>2009 Ministry of Education, Culture, Sports, Science and Technology (MEXT) Award for Young Scientists\/<\/li>\n<li>2012 JSPS Prize (Japan Society for the Promotion of Science)<\/li>\n<li>2013 DIC Functional Materials Award (the Society of Synthetic Organic Chemistry, Japan)<\/li>\n<li>2018 Inoue Prize for Science<\/li>\n<li>2018 The Yazaki Academic Research Award<\/li>\n<li>2019 Les Ambassadeurs de l\u2019INC (movie)<\/li>\n<\/ul>\n<h4><strong>\u7814\u7a76\u4ecb\u7ecd<\/strong><\/h4>\n<p><span style=\"color: #0000ff;\"><strong><em>1. \u82b3\u9999\u6027\u548c\u53cd\u82b3\u9999\u6027\u5316\u5408\u7269\u7814\u7a76<\/em><\/strong><\/span><\/p>\n<p>\u6839\u636e\u7ecf\u5178\u7684H\u00fcckel\u89c4\u5219\uff0c\u5728\u73af\u72b6\u5171\u8f6d\u7269\u4e2d\u5305\u542b4n + 2\u4e2a\u03c0\u7535\u5b50\u7684\u5316\u5408\u7269\u8868\u73b0\u51fa\u82b3\u9999\u6027\uff0c\u5178\u578b\u7684\u4f8b\u5b50\u662f\u82ef\u3002\u65e0\u8bba\u6750\u6599\uff0c\u836f\u7269\u6216\u5929\u7136\u4ea7\u7269\u5982\u4f55\uff0c\u82b3\u9999\u5316\u5408\u7269\u65e0\u5904\u4e0d\u5728\u3002\u56e0\u6b64\uff0c\u9610\u660e\u82b3\u9999\u5316\u5408\u7269\u7684\u6027\u8d28\u4e00\u76f4\u662f\u91cd\u8981\u7684\u7814\u7a76\u8bfe\u9898\u3002<\/p>\n<p>\u5177\u67094n\u4e2a\u03c0\u7535\u5b50\u7684\u73af\u72b6\u03c0\u5171\u8f6d\u5206\u5b50\u5219\u8868\u73b0\u51fa\u53cd\u82b3\u9999\u6027\u3002\u5bf9\u4e8e\u53cd\u82b3\u9999\u6027\u5316\u5408\u7269\uff0c\u7269\u7406\u6709\u673a\u5316\u5b66\u5bf9\u5176\u5177\u6709\u7684\u53cd\u82b3\u9999\u6027\u6709\u8f83\u5927\u7684\u7814\u7a76\u70ed\u60c5\uff0c\u5408\u6210\u5316\u5b66\u5bb6\u5219\u56e0\u5176\u5177\u6709\u7684\u72ed\u7a84\u7684HOMO-LUMO\u95f4\u9699\uff0c\u5e0c\u671b\u53ca\u5176\u7528\u4e8e\u5316\u5b66\u5408\u6210\u53ca\u5206\u5b50\u7535\u5b50\u6750\u6599\u7b49\u5404\u79cd\u5e94\u7528\u4e2d\u3002\u4f46\u53cd\u82b3\u9999\u5316\u5408\u7269\u5219\u56e0\u5176\u4e0d\u7a33\u5b9a\u800c\u96be\u4ee5\u5408\u6210\u548c\u5206\u79bb\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31421 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6.jpg\" alt=\"\" width=\"701\" height=\"138\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6.jpg 924w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6-300x59.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6-680x134.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/2-6-768x151.jpg 768w\" sizes=\"(max-width: 701px) 100vw, 701px\" \/><\/a><\/p>\n<p style=\"text-align: center;\"><em>Aromaticity &amp; antiaromaticity<\/em><\/p>\n<p>\u5bf9\u6b64\uff0cShinokubo\u6559\u6388\u4ee5\u514b\u7ea7\u89c4\u6a21\u5408\u6210\u4e86\u53cd\u82b3\u9999\u6027\u91d1\u5c5e\u5316\u5408\u7269Norcorrole<sup>[1a]<\/sup>\u3002\u8be5\u91d1\u5c5e\u5316\u5408\u7269\u663e\u793a\u51fa\u660e\u663e\u7684\u53cd\u82b3\u9999\u6027\u6027\u8d28\u7684\u540c\u65f6\uff0c\u80fd\u591f\u5728\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u7684\u5904\u7406\uff0c\u8fd9\u5728\u4ee5\u5f80\u7684\u53cd\u82b3\u9999\u6027\u5316\u5408\u7269\u4e2d\u662f\u96be\u4ee5\u5b9e\u73b0\u7684\u3002\u6b64\u540e\uff0cShinokubo\u6559\u6388\u4e00\u76f4\u81f4\u529b\u4e8e\u5408\u6210\u5404\u79cdNorcorrole\u7c7b\u4f3c\u7269\uff0c\u4ee5\u9610\u660e\u53cd\u82b3\u9999\u5316\u5408\u7269\u6027\u8d28\u53ca\u63a2\u7d22\u4f5c\u4e3a\u6750\u6599\u5e94\u7528\u7684\u6f5c\u529b\u3002<\/p>\n<p>\u5728\u7814\u7a76\u5806\u53e0\u578bNorcorrole\u4e8c\u805a\u4f53\u65f6\uff0c\u4ed6\u4eec\u9996\u6b21\u901a\u8fc7\u5b9e\u9a8c\u8bc1\u660e\u4e86\u4e24\u79cd\u53cd\u82b3\u65cf\u5316\u5408\u7269\u5728\u5806\u53e0\u65f6\u5747\u8868\u73b0\u51fa\u82b3\u9999\u6027\u7684\u7406\u8bba\u5047\u8bbe<sup>[1b]<\/sup>\u3002\u53cd\u82b3\u9999\u6027\u91d1\u5c5e\u590d\u5408\u7269Norcorrole\u7528\u4f5c\u7535\u6781\u6d3b\u6027\u6750\u6599\u65f6\uff0c\u53ef\u5b9e\u73b0\u9ad8\u5bb9\u91cf\u548c\u7a33\u5b9a\u7684\u53ef\u5145\u7535\u7535\u6c60<sup>[1c]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31422 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6.jpg\" alt=\"\" width=\"709\" height=\"426\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6.jpg 1213w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6-300x180.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6-680x408.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/3-6-768x461.jpg 768w\" sizes=\"(max-width: 709px) 100vw, 709px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong><em>2. \uff08\u53cd\uff09\u82b3\u9999\u5316\u5408\u7269\u7684\u63ba\u6742<\/em><\/strong><\/span><\/p>\n<p>\u03c0\u5171\u8f6d\u6709\u673a\u5206\u5b50\u5177\u6709\u591a\u79cd\u5149\u5b66\u548c\u7535\u5b50\u529f\u80fd\uff0c\u6709\u671b\u6210\u4e3a\u4e0b\u4e00\u4ee3\u7684\u65b0\u578b\u6750\u6599\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u7684\u4e3b\u8981\u9aa8\u67b6\u4e00\u822c\u4e3a\u78b3\u539f\u5b50\u548c\u6c22\u539f\u5b50\u7ec4\u6210\u3002Shinokubo\u6559\u6388\u5219\u4e00\u76f4\u5c1d\u8bd5\u5411\u5176\u4e2d\u5f15\u5165\u6742\u539f\u5b50\uff08\u5982\u6c2e\u548c\u787c\uff09\uff0c\u4ee5\u63a2\u7d22\u5176\u672a\u77e5\u7684\u6027\u8d28\u3002<\/p>\n<p>\u76ee\u524d\u6742\u539f\u5b50\u63ba\u5165\u7684\u5316\u5408\u7269\u5305\u62ec\u535f\u5549porphyrin<sup>[2a]<\/sup>\uff0c\u5494\u54afcorrole<sup>[2b]<\/sup>\uff0c\u8298pyrene<sup>[2c]<\/sup>\uff0cbuckybowl<sup>[2d]<\/sup>\uff0ccirculene<sup>[2e]<\/sup>\u3002\u5728\u63ba\u5165\u6742\u539f\u5b50\u540e\uff0c\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u5149\u5438\u6536\u6027\u80fd\uff0c\u7535\u5bfc\u7387\uff0c\u53d1\u5149\u7b49\u65b9\u9762\u663e\u793a\u51fa\u4e0e\u5e38\u89c4\u5316\u5408\u7269\u4e0d\u540c\u4e14\u5438\u5f15\u4eba\u7684\u6027\u80fd\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31423 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5.jpg\" alt=\"\" width=\"676\" height=\"381\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5.jpg 940w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5-300x169.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5-680x383.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/4-5-768x433.jpg 768w\" sizes=\"(max-width: 676px) 100vw, 676px\" \/><\/a><\/p>\n<p style=\"text-align: center;\"><em>First row: porphyrin, corrole, pyrene; Second row: buckybowl, circulene<\/em><\/p>\n<p><em><span style=\"color: #0000ff;\"><strong>3. \u751f\u7269\u529f\u80fd\u5206\u5b50\u7814\u7a76<\/strong><\/span><\/em><\/p>\n<p>\u535f\u5549\u662f\u8840\u7ea2\u7d20\u548c\u53f6\u7eff\u7d20\u7684\u57fa\u672c\u9aa8\u67b6\u3002\u8fd9\u4e9b\u5929\u7136\u8272\u7d20\u5728\u751f\u7269\u4f53\u5185\u7684\u4ee3\u8c22\u548c\u80fd\u91cf\u5b58\u50a8\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002Shinokubo\u6559\u6388\u5e0c\u671b\u901a\u8fc7\u4f7f\u7528\u4ed6\u4eec\u72ec\u521b\u7684\u5206\u5b50\u8f6c\u5316\u65b9\u6cd5\uff0c\u521b\u9020\u51fa\u5177\u6709\u8d85\u8d8a\u751f\u7269\u4f53\u5e38\u89c4\u529f\u80fd\u7684\u65b0\u7279\u6027\u7684\u5206\u5b50\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/5-3.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-31424 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/5-3.jpg\" alt=\"\" width=\"701\" height=\"258\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/5-3.jpg 766w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/5-3-300x110.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/5-3-680x250.jpg 680w\" sizes=\"(max-width: 701px) 100vw, 701px\" \/><\/a><\/p>\n<p style=\"text-align: center;\"><em>Heme &amp; chlorophyll<\/em><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] a. Shinokubo H. Angew. Chem. Int. Ed. 2012, 51, 8542. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/anie.201204395\">DOI: 10.1002\/anie.201204395<\/a>; b. Shinokubo H. <em>Nat. Commun.<\/em> <strong>2019<\/strong>, <em>10<\/em>, 3576. <a href=\"https:\/\/www.nature.com\/articles\/s41467-019-11467-4\">DOI: 10.1038\/s41467-019-11467-4<\/a>; c. Shinokubo H. <em>Angew. Chem. Int. Ed.<\/em> <strong>2014<\/strong>, <em>53<\/em>, 3096. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201310374\">DOI: 10.1002\/anie.201310374<\/a>.<\/li>\n<li>[2] a. Shinokubo H. <em>J. Am. Chem. Soc.<\/em> <strong>2019<\/strong>, <em>141<\/em>, 4800. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b13169\">DOI: 10.1021\/jacs.8b13169<\/a>;<\/li>\n<li>[3] Shinokubo H. <em>Organometallics<\/em> <strong>2019<\/strong>, <em>38<\/em>, 2878. <a href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.organomet.9b00303\">DOI: 10.1021\/acs.organomet.9b00303<\/a>;<\/li>\n<li>[4] Shinokubo H. <em>Chem. Commun.<\/em> <strong>2018<\/strong>, <em>54<\/em>, 5177. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/CC\/C8CC01937A#!divAbstract\">DOI: 10.1039\/C8CC01937A<\/a>;<\/li>\n<li>[5] Shinokubo H. <em>J. Am. Chem. Soc.<\/em> <strong>2018<\/strong>, <em>140<\/em>, 4649. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b00798\">DOI: 10.1021\/jacs.8b00798<\/a>;<\/li>\n<li>[6] Shinokubo H. <em>Org. Lett.<\/em> 2017, <strong><em>19<\/em><\/strong>, 2718. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.7b01074\">DOI: 10.1021\/acs.orglett.7b01074<\/a>.<\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1aalberto-caeiro \u5fcd\u4e45\u4fdd\u3000\u6d0b Shinokubo Hiroshi\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65e5\u672c\u540d\u53e4\u5c4b\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u6559\u6388\u3002\u56fe\u7247\uff1aAuthor Profile, Hiroshi Shinokubo. \u7ecf\u5386 1994\u20131995 Ph. D., Graduate School of Engineering, Kyoto University\uff08\u4eac\u90fd\u5927\u5b66\uff09 1995\u20132003 Assistant Professor, Graduate School of Engineering, Kyoto University 1999\u20132000 Research Fellow, Massachusetts Institute of Technology (Rick L. Danheiser Group) 2003\u20132008 Associate Professor, Graduate School of Science, Kyoto University 2003\u20132007 JST-PRESTO Researcher 2008\u2013present Professor, Graduate School of Engineering, Nagoya University\uff08\u540d\u53e4\u5c4b\u5927\u5b66\uff09 \u83b7\u5956\u7ecf\u5386 1999 The Society of Synthetic Organic Chemistry, Japan (SSOCJ) Award for Research Proposal 2001 Bulletin of the Chemical Society of Japan Award 2001 The Chemical Society of Japan Lecture Award for Young Chemists 2004 The Chemical Society of Japan Award for Young Chemists 2008 Banyu Young Chemist Award 2009 Ministry of Education, [&hellip;]","protected":false},"author":26,"featured_media":31420,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[212],"tags":[2564,2565,2566],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/04\/1-8.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-8aL","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/31419"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=31419"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/31419\/revisions"}],"predecessor-version":[{"id":31641,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/31419\/revisions\/31641"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/31420"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=31419"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=31419"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=31419"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}