{"id":31718,"date":"2020-05-06T08:10:25","date_gmt":"2020-05-06T00:10:25","guid":{"rendered":"\/\/www.gsbet888.com\/?p=31718"},"modified":"2020-05-02T23:22:15","modified_gmt":"2020-05-02T15:22:15","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e9%9b%b7%e7%88%b1%e6%96%87%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84nat-catal-%ef%bc%9a%e7%94%b5%e5%8c%96%e5%ad%a6%e6%b0%a7%e5%8c%96%e6%9c%ab%e7%ab%af%e7%82%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2020\/05\/%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e9%9b%b7%e7%88%b1%e6%96%87%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84nat-catal-%ef%bc%9a%e7%94%b5%e5%8c%96%e5%ad%a6%e6%b0%a7%e5%8c%96%e6%9c%ab%e7%ab%af%e7%82%94.html","title":{"rendered":"\u6b66\u6c49\u5927\u5b66\u96f7\u7231\u6587\u6559\u6388\u8bfe\u9898\u7ec4Nat.Catal.\uff1a\u7535\u5316\u5b66\u6c27\u5316\u672b\u7aef\u7094\u70c3\u7684\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94"},"content":{"rendered":"

\u672c\u6587\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n

\u5bfc\u8bfb<\/h4>\n

\u94af\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u6c27\u6c14\u4f5c\u4e3a\u6c27\u5316\u5242\uff0c\u662f\u6c27\u5316\u7fb0\u57fa\u5316\u53cd\u5e94\u4e2d\u4e00\u79cd\u7ecf\u6d4e\u7684\u65b9\u5f0f\u3002\u7136\u800c\uff0c\u4e00\u6c27\u5316\u78b3\u548c\u7a7a\u6c14\u7684\u6df7\u5408\u6c14\u7206\u70b8\u6781\u9650\u4e3a12.5-74.0\uff05\uff0c\u4ece\u800c\u9650\u5236\u4e86\u8be5\u5de5\u827a\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u96f7\u7231\u6587\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u81ea\u7136\u50ac\u5316\u6742\u5fd7\uff08Nature Catalysis\uff09\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u65e0\u9700\u4f7f\u7528\u5916\u90e8\u6c27\u5316\u5242\uff0c\u53ef\u5728\u65e0\u9694\u819c\u7535\u89e3\u69fd\u4e2d\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u6c27\u5316\u5b9e\u73b0\u672b\u7aef\u7094\u70c3\u7684\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u5177\u6709\u5e7f\u6cdb\u7684\u5e95\u7269\u8303\u56f4\uff0883\u4e2a\u5b9e\u4f8b\uff09\uff0c\u6d89\u53ca\u4f2f\u80fa\u3001\u94f5\u76d0\u7b49\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08cyclic voltammetry\uff09\u3001\u539f\u4f4d\u7ea2\u5916\uff08in situ infrared\uff09\u548c\u5feb\u901f\u626b\u63cfX-\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\u7684\u76f8\u5173\u7814\u7a76\u4e0e\u5206\u6790\uff0c\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u7535\u5316\u5b66\u6c27\u5316\u672b\u7aef\u7094\u70c3\u7684\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u7684\u673a\u7406\u3002<\/p>\n

Electrochemical Oxidative Aminocarbonylationof Terminal Alkynes<\/p>\n

Li Zeng, Haoran Li, Jingcheng Hu, Dongchao Zhang, Jiayu Hu, Pan Peng, Shenchun Wang,Renyi Shi, Jiaqi Peng, Chih-Wen Pao, Jeng-Lung Chen, Jyh-Fu Lee, Heng Zhang,Yi-Hung Chen and Aiwen Lei<\/p>\n

Nat. Catal.<\/em> ASAP DOI: 10.1038\/s41929-020-0443-z<\/a><\/p><\/blockquote>\n

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\u6b63\u6587<\/h4>\n

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\"\"<\/a><\/p>\n

\u5728\u83b7\u5f97\u4e0a\u8ff0\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u540e\uff0c\u4f5c\u8005\u5f00\u59cb\u5bf9\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u7684\u5e95\u7269\u8303\u56f4\u8fdb\u884c\u4e86\u7814\u7a76\uff08Fig. 6\uff09\u3002\u8be5\u53cd\u5e94\u4e0d\u53d7\u5b9a\u4f4d\u6548\u5e94\u548c\u7535\u5b50\u6548\u5e94\u7684\u5f71\u54cd\uff0c\u5747\u53ef\u83b7\u5f97\u76f8\u5e94\u7684\u4ea7\u72692<\/strong>–27<\/strong>\uff0c\u6536\u738717-77\uff05\u3002\u5f53\u5e26\u6709\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u57fa\u56e2\u7684\u4e59\u7094\uff08\u5982\u4e09\u6c1f\u7532\u57fa\u3001\u6c30\u57fa\u6216\u7532\u6c27\u57fa\uff09\u65f6\uff0c\u53ef\u6709\u6548\u5730\u8fdb\u884c\u8f6c\u5316\uff0c\u4ece\u800c\u4ee551-54\uff05\u7684\u6536\u7387\u83b7\u5f97\u7094\u57fa\u9170\u80fa\u4ea7\u72693<\/strong>–5<\/strong>\u3002\u540c\u65f6\uff0c\u4ea7\u72692<\/strong>\u7684\u653e\u5927\u5b9e\u9a8c\uff0c\u4e5f\u53d6\u5f97\u8f83\u597d\u7684\u7ed3\u679c\u3002\u6b64\u5916\uff0c\u5177\u6709\u591a\u79cd\u5b98\u80fd\u56e2\uff08\u5305\u62ec\u6742\u82b3\u65cf\u73af\uff09\u7684\u591a\u79cd\u80fa\uff08\u5373\u8102\u80aa\u80fa\u3001\u82c4\u57fa\u80fa\u548c\u5747\u82c4\u57fa\u80fa\uff09\uff0c\u5747\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u5206\u522b\u83b7\u5f97\u76f8\u5e94\u7684\u4ea7\u72696<\/strong>–22<\/strong>\uff0c\u4f46\u4f7f\u7528\u53d4\u4e01\u80fa\u65f6\uff0c\u4ea7\u7269\u7684\u6536\u7387\u4f4e\uff0810\uff05\u300123\uff05\uff09\u3002\u540c\u65f6\uff0c\u8be5\u7b56\u7565\u540c\u6837\u9002\u7528\u4e8e\u9002\u4e00\u4e9b\u5177\u6709\u751f\u7269\u6d3b\u6027\u7684\u4f2f\u80fa\uff08\u53cc\u73af[2.2.1]\u5e9a-5-\u70ef-2-\u57fa\u7532\u80fa\u3001\u8272\u80fa\u548c\u8131\u6c22\u677e\u9999\u80fa\uff09\u548c\u4e19\u9170\u80fa\uff0c\u53ef\u5728\u5ba4\u6e29\u4e0b\u83b7\u5f97\u4e2d\u7b49\u6536\u7387\u7684\u4ea7\u726923<\/strong>\u300125<\/strong>\u300126<\/strong>\u548c27<\/strong>\u3002\u7531\u4e8e\u91d1\u521a\u70f7\u57fa\u5177\u6709\u5b63\u78b3\u4e2d\u5fc3\uff0c\u4ece\u800c\u5bfc\u81f4\u91d1\u521a\u70f7\u80fa\u4ea7\u726924<\/strong>\u7684\u6536\u7387\u8f83\u4f4e\uff0817\uff05\uff09\u3002<\/p>\n

\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5927\u5230\u5404\u79cd\u73af\u80fa\uff08\u5982\u5417\u5549\u3001\u56db\u6c22\u5f02\u55b9\u5549\u3001\u54cc\u5576\u3001\u5421\u54af\u70f7\u3001\u54cc\u55ea\u3001\u6c2e\u6742\u73af\u5e9a\u70f7\u7b49\uff09\u6216\u65e0\u73af\u80fa\u884d\u751f\u7269\uff0c\u5747\u53ef\u83b7\u5f9734-92\uff05\u6536\u7387\u5f97\u76ee\u6807\u7684\u4ea7\u726928<\/strong>–63<\/strong>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5e26\u6709\u6e38\u79bb\u7f9f\u57fa\uff0848<\/strong>\u300159<\/strong>\uff09\u7684\u7094\u80fa\uff0c\u4e5f\u53ef\u83b7\u5f97\u4ee4\u4eba\u6ee1\u610f\u7684\u6536\u7387\uff0848\uff05\u300168\uff05\uff09\uff0c\u4ee5\u524d\u7684\u6587\u732e\u4e0d\u6613\u5408\u6210\u3002\u6b64\u5916\uff0c\u5305\u62ec\u5730\u6c2f\u96f7\u4ed6\u5b9a\uff08desloratadine\uff09\u3001\u53bb\u82c4\u57fa\u591a\u5948\u54cc\u9f50\uff08desbenzyl donepezil\uff09\u548c\u6c1f\u897f\u6c40\uff08fluoxetine\uff09\u5728\u5185\u7684\u56db\u4e2a\u91cd\u8981\u836f\u7269\u5206\u5b50\uff0c\u5747\u53ef\u4ee531-87\uff05\u7684\u6536\u7387\uff0c\u83b7\u5f97\u6240\u9700\u7684\u4ea7\u726964<\/strong>–68<\/strong>\uff0c\u8fd9\u4e5f\u4e3a\u65b0\u836f\u7684\u53d1\u73b0\u63d0\u4f9b\u591a\u79cd\u53ef\u80fd\u3002<\/p>\n

\"\"<\/a><\/p>\n

\"\"<\/a><\/p>\n

\"\"<\/a><\/p>\n

\u5728\u5bf9\u4e8e\u4e0a\u8ff0\u8102\u65cf\u80fa\u5e95\u7269\u6269\u5c55\u4e4b\u540e\uff0c\u4f5c\u8005\u5f00\u59cb\u5c1d\u8bd5\u662f\u5426\u4f7f\u7528\u94f5\u76d0\u8fdb\u884c\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u3002\u7ecf\u8fc7\u5927\u91cf\u6761\u4ef6\u7684\u7b5b\u9009\uff0c\u4f5c\u8005\u53d1\u73b0\uff0c\u5f53\u4f7f\u7528Pd(OAc)2<\/sub>\uff088-15 mol\uff05\uff09\u548c(\u00b1)-BINAP\uff0810-15 mol\uff05\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\u548c\u914d\u4f53\u65f6\uff0c\u53ef\u5b9e\u73b0\u94f5\u76d0\u4e0e\u7094\u70c3\u7684\u53cd\u5e94\uff0c\u4ece\u800c\u4ee5\u5408\u7406\u7684\u6536\u7387\u83b7\u5f97\u4e86\u7094\u57fa\u9170\u80fa\u884d\u751f\u7269\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u4e0d\u540c\u94f5\u76d0\u5747\u53ef\u4e0eCO\u548c\u82ef\u4e59\u7094\u8fdb\u884c\u53cd\u5e94\uff0c\u83b7\u5f97\u76f8\u5e94\u7684\u7094\u57fa\u9170\u80fa\u4ea7\u726969-84<\/strong>\uff0c\u6536\u7387\u4e3a24-71\uff05\uff08Fig. 7\uff09\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6c28\u751f\u6210\u7684\u901f\u5ea6\u6162\uff0c\u9664NH4<\/sub>NO3<\/sub>\u4ee5\u5916\uff0c\u5176\u4ed6\u94f5\u76d0\u5747\u5bfc\u81f4\u8f83\u5dee\u7684\u53cd\u5e94\u7ed3\u679c\u3002\u540c\u65f6\uff0c\u5728\u7535\u5316\u5b66\u6761\u4ef6\u4e0b\uff0c\u5404\u79cd\u5b98\u80fd\u5316\u7094\u70c3\u5747\u5177\u6709\u826f\u597d\u7684\u8010\u53d7\u6027\uff0c\u4ee573-49\uff05\u7684\u6536\u7387\u63d0\u4f9b\u4e86\u6240\u9700\u768470<\/strong>–80<\/strong>\u7684\u4ea7\u7269\u3002\u4e00\u4e9b\u8102\u80aa\u65cf\u7094\u70c3\u884d\u751f\u7269\u4e5f\u4ee5\u4e2d\u7b49\u6536\u7387\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u4ea7\u726981<\/strong>–84<\/strong>\u3002<\/p>\n

\"\"<\/a><\/p>\n

\"\"<\/a><\/p>\n

\u603b\u7ed3<\/h4>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u6749\u6749 \u5bfc\u8bfb \u94af\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u6c27\u6c14\u4f5c\u4e3a\u6c27\u5316\u5242\uff0c\u662f\u6c27\u5316\u7fb0\u57fa\u5316\u53cd\u5e94\u4e2d\u4e00\u79cd\u7ecf\u6d4e\u7684\u65b9\u5f0f\u3002\u7136\u800c\uff0c\u4e00\u6c27\u5316\u78b3\u548c\u7a7a\u6c14\u7684\u6df7\u5408\u6c14\u7206\u70b8\u6781\u9650\u4e3a12.5-74.0\uff05\uff0c\u4ece\u800c\u9650\u5236\u4e86\u8be5\u5de5\u827a\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u96f7\u7231\u6587\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u81ea\u7136\u50ac\u5316\u6742\u5fd7\uff08Nature Catalysis\uff09\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u65e0\u9700\u4f7f\u7528\u5916\u90e8\u6c27\u5316\u5242\uff0c\u53ef\u5728\u65e0\u9694\u819c\u7535\u89e3\u69fd\u4e2d\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u6c27\u5316\u5b9e\u73b0\u672b\u7aef\u7094\u70c3\u7684\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u5177\u6709\u5e7f\u6cdb\u7684\u5e95\u7269\u8303\u56f4\uff0883\u4e2a\u5b9e\u4f8b\uff09\uff0c\u6d89\u53ca\u4f2f\u80fa\u3001\u94f5\u76d0\u7b49\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08cyclic voltammetry\uff09\u3001\u539f\u4f4d\u7ea2\u5916\uff08in situ infrared\uff09\u548c\u5feb\u901f\u626b\u63cfX-\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\u7684\u76f8\u5173\u7814\u7a76\u4e0e\u5206\u6790\uff0c\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u7535\u5316\u5b66\u6c27\u5316\u672b\u7aef\u7094\u70c3\u7684\u6c28\u57fa\u7fb0\u57fa\u5316\u53cd\u5e94\u7684\u673a\u7406\u3002 Electrochemical Oxidative Aminocarbonylationof Terminal Alkynes Li Zeng, Haoran Li, Jingcheng Hu, Dongchao Zhang, Jiayu Hu, Pan Peng, Shenchun Wang,Renyi Shi, Jiaqi Peng, Chih-Wen Pao, Jeng-Lung Chen, Jyh-Fu Lee, Heng Zhang,Yi-Hung Chen and Aiwen Lei Nat. Catal. 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