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\u672c\u6587\u4f5c\u8005\uff1a\u9648\u5341\u4e94<\/p>\n

\u5bfc\u8bfb<\/h4>\n

\u8fd1\u65e5\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66Yoshikai\u8bfe\u9898\u7ec4\uff08Yoshikai\u6559\u6388\u548c\u5434\u4fca\u826f\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\uff08Journal of the American Chemical Society\uff09\u62a5\u9053\u4e86\u901a\u8fc7\u73af\u72b6\u4e09\u4ef7\u7898\u4eb2\u7535\u8bd5\u5242\u548c\u9187\u5bf9\u7094\u7684\u53cd\u5f0f1,2-\u53cc\u5b98\u80fd\u5316\u53cd\u5e94\uff0c\u8be5\u53cd\u5e94\u80fd\u4ee5\u5f88\u9ad8\u7684\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u591a\u53d6\u4ee3\u7684\u4e59\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269,\u8fd8\u53ef\u4ee5\u517c\u5bb9\u5404\u79cd\u5185\u7094\u548c\u7aef\u7094\uff0c\u4ee5\u53ca\u5404\u79cd\u9187\u3002\u4ea7\u7269\u4e2d1,2-\u82ef\u5e76\u7898\u6c27\u6742\u8302\u73af\u90e8\u5206\u53ef\u4ee5\u4f5c\u4e3a\u901a\u7528\u7684\u5408\u6210\u524d\u4f53\uff0c\u7528\u4e8e\u5408\u6210\u7ed3\u6784\u591a\u6837\u4e14\u96be\u4ee5\u901a\u8fc7\u5176\u4ed6\u65b9\u5f0f\u5408\u6210\u7684\u4e59\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269\u3002\u9187\u7684C-O\u952e\u6d3b\u5316\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u7531\u4e8e\u5b58\u5728\u8f83\u9ad8\u7684\u952e\u80fd\u4ece\u800c\u5bfc\u81f4\u5408\u6210\u4e0a\u5177\u6709\u4e00\u5b9a\u7684\u96be\u5ea6\u3002<\/p>\n

Stereoselective Access to Highly Substituted Vinyl Ethers via trans- Difunctionalization of Alkynes with Alcohols and Iodine(III) Electrophile<\/p>\n

Wei Ding, Jinkui Chai, Chen Wang, Junliang Wu,* and Naohiko Yoshikai* J. Am. Chem. Soc.<\/em> ASAP DOI: 10.1021\/jacs.0c04140<\/a><\/p><\/blockquote>\n

\"\"<\/a><\/p>\n

\u6b63\u6587<\/h4>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

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\u7ed3\u8bed<\/h4>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u9648\u5341\u4e94 \u5bfc\u8bfb \u8fd1\u65e5\uff0c\u5357\u6d0b\u7406\u5de5\u5927\u5b66Yoshikai\u8bfe\u9898\u7ec4\uff08Yoshikai\u6559\u6388\u548c\u5434\u4fca\u826f\u6559\u6388\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\uff08Journal of the American Chemical Society\uff09\u62a5\u9053\u4e86\u901a\u8fc7\u73af\u72b6\u4e09\u4ef7\u7898\u4eb2\u7535\u8bd5\u5242\u548c\u9187\u5bf9\u7094\u7684\u53cd\u5f0f1,2-\u53cc\u5b98\u80fd\u5316\u53cd\u5e94\uff0c\u8be5\u53cd\u5e94\u80fd\u4ee5\u5f88\u9ad8\u7684\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u5408\u6210\u591a\u53d6\u4ee3\u7684\u4e59\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269,\u8fd8\u53ef\u4ee5\u517c\u5bb9\u5404\u79cd\u5185\u7094\u548c\u7aef\u7094\uff0c\u4ee5\u53ca\u5404\u79cd\u9187\u3002\u4ea7\u7269\u4e2d1,2-\u82ef\u5e76\u7898\u6c27\u6742\u8302\u73af\u90e8\u5206\u53ef\u4ee5\u4f5c\u4e3a\u901a\u7528\u7684\u5408\u6210\u524d\u4f53\uff0c\u7528\u4e8e\u5408\u6210\u7ed3\u6784\u591a\u6837\u4e14\u96be\u4ee5\u901a\u8fc7\u5176\u4ed6\u65b9\u5f0f\u5408\u6210\u7684\u4e59\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269\u3002\u9187\u7684C-O\u952e\u6d3b\u5316\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u7531\u4e8e\u5b58\u5728\u8f83\u9ad8\u7684\u952e\u80fd\u4ece\u800c\u5bfc\u81f4\u5408\u6210\u4e0a\u5177\u6709\u4e00\u5b9a\u7684\u96be\u5ea6\u3002 Stereoselective Access to Highly Substituted Vinyl Ethers via trans- Difunctionalization of Alkynes with Alcohols and Iodine(III) Electrophile Wei Ding, Jinkui Chai, Chen Wang, Junliang Wu,* and Naohiko Yoshikai* J. Am. Chem. Soc. ASAP DOI: 10.1021\/jacs.0c04140 \u6b63\u6587 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