{"id":32535,"date":"2020-07-03T08:00:36","date_gmt":"2020-07-03T00:00:36","guid":{"rendered":"\/\/www.gsbet888.com\/?p=32535"},"modified":"2020-06-29T22:49:54","modified_gmt":"2020-06-29T14:49:54","slug":"%e9%92%af%e5%82%ac%e5%8c%96%e7%82%94%e4%b8%99%e9%86%87%e8%a1%8d%e7%94%9f%e7%89%a9%e4%b8%8e%e6%9c%89%e6%9c%ba%e7%a1%bc%e9%85%b8%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2020\/07\/%e9%92%af%e5%82%ac%e5%8c%96%e7%82%94%e4%b8%99%e9%86%87%e8%a1%8d%e7%94%9f%e7%89%a9%e4%b8%8e%e6%9c%89%e6%9c%ba%e7%a1%bc%e9%85%b8%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94.html","title":{"rendered":"\u94af\u50ac\u5316\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u6709\u673a\u787c\u9178\u7684\u4e0d\u5bf9\u79f0\u5076\u8054\u53cd\u5e94\u5408\u6210\u56db\u53d6\u4ee3\u8054\u70ef"},"content":{"rendered":"<p>\u4e19\u4e8c\u70ef\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u4e0d\u9971\u548c\u70c3\uff0c\u56e0\u5176\u5177\u6709\u8f74\u624b\u6027\u800c\u53d7\u5230\u5316\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7094\u4e19\u9187\u884d\u751f\u7269\u548c\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u662f\u5408\u6210\u5916\u6d88\u65cb\u4e19\u4e8c\u70ef\u7684\u91cd\u8981\u65b9\u6cd5\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u4ee5\u5149\u5b66\u7eaf\u7684\u7094\u4e19\u9187\u884d\u751f\u7269\u548c\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\u901a\u8fc7\u624b\u6027\u8f6c\u79fb\u7b56\u7565\u5408\u6210\u624b\u6027\u4e19\u4e8c\u70ef\u7684\u7b56\u7565\u5df2\u7ecf\u6709\u4e86\u4e00\u5b9a\u7684\u53d1\u5c55\uff0c\u4f46\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u786c\u4eb2\u6838\u8bd5\u5242\u7684\u5076\u8054\u53cd\u5e94\u4e00\u822c\u662f\u5408\u6210\u624b\u6027\u7094\u7c7b\u5316\u5408\u7269\u5316\u5408\u7269[1]\uff08Scheme 1, path a\uff09\uff0c\u8fd8\u6ca1\u6709\u5173\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5408\u6210\u624b\u6027\u8054\u70ef\u5316\u5408\u7269\u7684\u62a5\u9053[2]\uff08Scheme 1, path b\uff09\u3002\u6700\u8fd1\uff0c\u5f20\u4fca\u826f\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u624b\u6027\u4e9a\u78fa\u9170\u80fa\u81a6\u914d\u4f53\uff0c\u5728\u5bf9\u6620\u9009\u62e9\u6027\u63a7\u5236\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5728\u4e0a\u8ff0\u80cc\u666f\u7684\u57fa\u7840\u4e0a\uff0c\u590d\u65e6\u5927\u5b66<a href=\"http:\/\/www.lomc.sioc.cas.cn\/yjdw\/xsdtr\/201007\/t20100702_2891823.html\">\u9ebb\u751f\u660e<\/a>\u3001<a href=\"http:\/\/www.chemistry.fudan.edu.cn\/Data\/View\/1870\">\u94b1\u8f89<\/a>\u8bfe\u9898\u7ec4\u548c<a href=\"http:\/\/www.chemistry.fudan.edu.cn\/Data\/View\/2993\">\u5f20\u4fca\u826f<\/a>\u56e2\u961f\u5171\u540c\u62a5\u9053\u4e86\u94af\u548cMing-Phos\u914d\u4f53\u50ac\u5316\u5916\u6d88\u65cb\u7684\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u6709\u673a\u787c\u9178\u53d1\u751f\u4e0d\u5bf9\u79f0\u5076\u8054\u53cd\u5e94\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u6536\u7387\u548c\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e00\u7cfb\u5217\u624b\u6027\u8054\u70ef\u5316\u5408\u7269\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e<\/p>\n<blockquote><p>\u201cPd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids\u201d<\/p>\n<p>Wang, H.; Luo, H.; Zhang, Z.-M.; Zheng, W.-F.; Yin, Y.; Qian, H.* Zhang, J.* Ma, S.* <em>J. Am. Chem. Soc.<\/em> <strong>2020<\/strong>, Early View. DOI: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.0c02876\">10.1021\/jacs.0c02876<\/a><\/p><\/blockquote>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-56.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32536 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-56.jpg\" alt=\"\" width=\"562\" height=\"242\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-56.jpg 562w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-56-300x129.jpg 300w\" sizes=\"(max-width: 562px) 100vw, 562px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Scheme 1 \u80cc\u666f\u7814\u7a76<\/p>\n<h4><strong>\u8bba\u6587\u4f5c\u8005\u4ecb\u7ecd<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-54.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32537 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-54.jpg\" alt=\"\" width=\"138\" height=\"168\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u9ebb\u751f\u660e\u9662\u58eb<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u7814\u7a76\u7ecf\u5386<\/strong><\/span><\/p>\n<ul>\n<li>1982.09 &#8211; 1986.07\uff0c\u676d\u5dde\u5927\u5b66\u5316\u5b66\u7cfb\uff0c\u5b66\u58eb\uff1b<\/li>\n<li>1986.09 &#8211; 1990.12\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\uff0c\u535a\u58eb(\u5bfc\u5e08\uff1a\u9646\u7199\u708e\u9662\u58eb)\u3002<\/li>\n<li>1990.12 &#8211; 1992.09\u3000 \u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\uff0c\u52a9\u7406\u7814\u7a76\u5458\u3001\u526f\u7814\u7a76\u5458<\/li>\n<li>1992.09 &#8211; 1993.10\uff0c\u745e\u58eb\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5927\u5b66(ETH)\uff0c\u535a\u58eb\u540e\uff1b<\/li>\n<li>1993.10 &#8211; 1997.03\uff0c\u7f8e\u56fd\u666e\u6e21\u5927\u5b66(Purdue University)\uff0c\u535a\u58eb\u540e\uff1b<\/li>\n<li>1997.03 &#8211; 1997.09\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\uff0c\u526f\u7814\u7a76\u5458\uff1b<\/li>\n<li>1997.09 &#8211; 2003.02\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\uff0c\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c\u7814\u7a76\u5458\uff1b<\/li>\n<li>2007.10\uff0c\u4efb\u534e\u4e1c\u5e08\u8303\u5927\u5b66\uff0c\u6559\u6388\uff1b\u4e2d\u79d1\u9662\u4e0a\u6d77\u6709\u673a\u6240\u7279\u8058\u7814\u7a76\u5458\uff0c\u6d59\u6c5f\u5927\u5b66\u548c\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u517c\u804c\u6559\u6388\uff1b<\/li>\n<li>2008.09\uff0c\u5f53\u9009\u4e3a\u7b2c\u4e09\u4e16\u754c\u79d1\u5b66\u9662\u9662\u58eb\uff1b<\/li>\n<li>2009.11\uff0c\u62c5\u4efb\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5b66\u672f\u59d4\u5458\u4f1a\u4e3b\u4efb\uff1b<\/li>\n<li>2014.1\uff0c\u51fa\u4efb\u6d59\u6c5f\u5927\u5b66\u7406\u5b66\u90e8\u4e3b\u4efb\uff0c\u540c\u5e74\u5168\u804c\u52a0\u5165\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb \u3002<\/li>\n<\/ul>\n<p><span style=\"color: #0000ff;\"><strong>\u83b7\u5956\u53ca\u8363\u8a89<\/strong><\/span><\/p>\n<ul>\n<li>1991\u5e74\uff0c\u83b7\u4e2d\u79d1\u9662\u9662\u957f\u5956\u5b66\u91d1\u7279\u522b\u5956<\/li>\n<li>1994\u5e74\uff0c\u83b7Research Accomplishments Award<\/li>\n<li>1997\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956(\u6392\u540d\u7b2c\u4e8c)<\/li>\n<li>1999\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5e74\u79d1\u5b66\u5bb6\u5956\u4e00\u7b49\u5956<\/li>\n<li>1999\u5e74\uff0c\u83b7\u6c42\u662f\u57fa\u91d1\u6770\u51fa\u9752\u5e74\u5b66\u8005\u5956<\/li>\n<li>1999\u5e74\uff0c\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956 (\u6392\u540d\u7b2c\u4e8c)<\/li>\n<li>1999\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u5341\u5927\u6770\u51fa\u9752\u5e74<\/li>\n<li>1999\u5e74\uff0c\u83b7\u4e2d\u56fd\u5316\u5b66\u4f1a\u9752\u5e74\u5316\u5b66\u5956<\/li>\n<li>2000\u5e74\uff0c\u83b7Young Scholar Travel Grant Award for the 2000 International Chemical Congress of Pacific Basin Societies, American Chemistry Society 2003\u5e74\uff0c\u83b7\u5168\u56fd\u7559\u5b66\u56de\u56fd\u4eba\u5458\u6210\u5c31\u5956<\/li>\n<li>2003\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u4f18\u79c0\u7814\u7a76\u751f\u5bfc\u5e08\u5956<\/li>\n<li>2004\u5e74\uff0c\u83b7\u4e0a\u6d77\u4f18\u79c0\u7559\u5b66\u56de\u56fd\u4eba\u624d<\/li>\n<li>2004\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u4f18\u79c0\u7814\u7a76\u751f\u6307\u5bfc\u6559\u5e08<\/li>\n<li>2004\u5e74\uff0c\u83b7Mr. and Mrs. Sun Chan Memorial Award in Organic Chemistry<\/li>\n<li>2004\u5e74\uff0c\u83b7\u4e2d\u56fd\u5316\u5b66\u4f1a\u6709\u673a\u5316\u5b66\u4e13\u4e1a\u59d4\u5458\u4f1a\u201c\u6709\u673a\u5408\u6210\u521b\u9020\u5956\u201d<\/li>\n<li>2004\u5e74\uff0c\u83b7\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u8ba1\u5212\u5148\u8fdb\u4e2a\u4eba<\/li>\n<li>2004\u5e74\uff0c\u83b7\u4e0a\u6d77\u5e02\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u5956(\u6392\u540d\u7b2c\u4e00)<\/li>\n<li>2004\u5e74\uff0c\u83b7\u7b2c\u4e94\u5c4a\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u7261\u4e39\u5956<\/li>\n<li>2005\u5e74\uff0c\u83b7OMCOS-Springer\u00a0 Award<\/li>\n<li>2006\u5e74\uff0c\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956(\u6392\u540d\u7b2c\u4e00)<\/li>\n<li>2006\u5e74\uff0c\u83b7\u4e2d\u79d1\u9662\u7814\u7a76\u751f\u9662\u4f18\u79c0\u6559\u80b2\u5de5\u4f5c\u8005<\/li>\n<li>2007\u5e74\uff0c\u83b72004-2006\u5e74\u5ea6\u4e0a\u6d77\u5e02\u52b3\u52a8\u6a21\u8303\u79f0\u53f7<\/li>\n<li>2008\u5e74\uff0c\u83b7\u7b2c\u4e09\u5c4a\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ec4\u8000\u66fe\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u5956<\/li>\n<li>2008\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u4f18\u79c0\u7814\u7a76\u751f\u6307\u5bfc\u6559\u5e08\u5956<\/li>\n<li>2009\u5e74\uff0c\u83b7\u4e2d\u56fd\u79d1\u5b66\u9662\u4f18\u79c0\u7814\u7a76\u751f\u6307\u5bfc\u6559\u5e08\u5956<\/li>\n<li>2010\u5e74\uff0c\u83b7\u4e0a\u6d77\u5e02\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956<\/li>\n<\/ul>\n<p><span style=\"color: #0000ff;\"><strong>\u7814\u7a76\u9886\u57df<\/strong><\/span><\/p>\n<ol>\n<li>\u91d1\u5c5e\u6709\u673a\u5316\u5b66<\/li>\n<li>\u81ea\u7531\u57fa\u5316\u5b66<\/li>\n<li>\u591a\u6b65\u5408\u6210<\/li>\n<\/ol>\n<h4><strong>\u8bba\u6587\u6982\u8981<\/strong><\/h4>\n<p>\u4ee51-\u82ef\u57fa\u5e9a-2-\u7094\u57fa\u78b3\u9178\u7532\u916f\uff08<strong>1a-A<\/strong>\uff09\u548c\u82ef\u787c\u9178<strong>2a<\/strong>\u4e3a\u6a21\u677f\u5e95\u7269\uff0c\u4f5c\u8005\u5bf91-\u82ef\u57fa\u5e9a-2-\u7094\u57fa\u78b3\u9178\u7532\u916f\u7684\u79bb\u53bb\u57fa\u56e2\u3001\u94af\u50ac\u5316\u5242\u3001\u624b\u6027\u914d\u4f53\u4ee5\u53ca\u6eb6\u5242\u7b49\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u53cd\u590d\u7b5b\u9009\uff0c\u786e\u5b9a\u6700\u4f18\u53cd\u5e94\u6761\u4ef6\uff1a\u6c2e\u6c14\u4fdd\u62a4\u6761\u4ef6\u4e0b\uff0c\u4ee5\u79bb\u53bb\u57fa\u56e2\u4e3aBz\u7684\u6d88\u65cb<strong>1a<\/strong>\u548c\u82ef\u787c\u9178<strong>2a<\/strong>\u4e3a\u6a21\u677f\u5e95\u7269\uff0c5 mol% Pd(dmdba)<sub>2<\/sub>\u548c12 mol% Ming-Phos\u914d\u4f53<strong>L46<\/strong>\u4e3a\u50ac\u5316\u5242\uff0c2.0 equiv H<sub>2<\/sub>O\u4e3a\u6dfb\u52a0\u7269\uff0cc-Hex\/MTBE\u4e3a\u6eb6\u5242\uff0c\u572823\u2103\u6761\u4ef6\u4e0b\u53cd\u5e9424\u5c0f\u65f6\uff0c\u80fd\u4ee574%\u7684\u6536\u7387\u548c93%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u624b\u6027\u8054\u70ef<strong>3aa<\/strong>\u3002<\/p>\n<p>\u5728\u6700\u4f18\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u82ef\u787c\u9178\u7684\u5e95\u7269\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\uff08Scheme 2\uff09\u3002\u5404\u79cd\u90bb\u3001\u95f4\u3001\u5bf9\u4f4d\u82b3\u57fa\u53d6\u4ee3\u3001\u5404\u79cd\u82b3\u6742\u73af\u53d6\u4ee3\u3001\u70ef\u4e19\u57fa\u53d6\u4ee3\u4ee5\u53ca\u73af\u70ef\u57fa\u53d6\u4ee3\u7684\u82ef\u787c\u9178\u5c31\u5747\u80fd\u8f83\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u6536\u7387\u548c\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u4f46\u7532\u57fa\u53d6\u4ee3\u6216\u73af\u4e19\u70ef\u53d6\u4ee3\u7684\u82ef\u787c\u9178\u4e0d\u80fd\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u4e0d\u80fd\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-43.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32538 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-43.jpg\" alt=\"\" width=\"517\" height=\"585\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-43.jpg 517w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-43-265x300.jpg 265w\" sizes=\"(max-width: 517px) 100vw, 517px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Scheme 2 \u5e95\u7269\u6269\u5c55<\/p>\n<p>\u7d27\u63a5\u7740\uff0c\u4f5c\u8005\u8003\u5bdf\u4e86\u7094\u4e19\u9187\u7684\u5e95\u7269\u8303\u56f4\uff08Scheme 3\uff09\u3002R<sup>1<\/sup>\u53d6\u4ee3\u57fa\u4e3a\u5404\u79cd\u53d6\u4ee3\u7684\u82b3\u57fa\u6216R<sup>1<\/sup>\u53d6\u4ee3\u57fa\u4e3a\u5404\u79cd\u94fe\u72b6\u70f7\u70c3\u4ee5\u53ca\u70ef\u4e19\u57fa\u7684\u7094\u4e19\u9187\u5747\u80fd\u8f83\u597d\u7684\u9002\u5e94\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u4ee5\u826f\u597d\u81f3\u4f18\u79c0\u7684\u6536\u7387\u548c\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u76f8\u5e94\u4ea7\u7269\u3002\u4f46\u5f53R<sup>1<\/sup>\u53d6\u4ee3\u57fa\u4e3a\u975e\u82b3\u57fa\u6216R<sup>3<\/sup>\u53d6\u4ee3\u57fa\u4e3a\u7532\u57fa\u65f6\uff0c\u53cd\u5e94\u4e0d\u80fd\u6b63\u5e38\u8fdb\u884c\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-35.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32539 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-35.jpg\" alt=\"\" width=\"573\" height=\"608\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-35.jpg 573w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-35-283x300.jpg 283w\" sizes=\"(max-width: 573px) 100vw, 573px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Scheme 3 \u5e95\u7269\u6269\u5c55<\/p>\n<p>\u4e3a\u4e86\u8bc1\u660e\u53cd\u5e94\u7684\u5e94\u7528\u6f5c\u529b\uff0c\u4f5c\u8005\u8fd8\u8fdb\u884c\u4e86\u884d\u751f\u5316\u53cd\u5e94\uff08Scheme 4\uff09\u3002\u70ef\u57fa\u4e19\u4e8c\u70ef\uff08<em>R<\/em>,<em>E<\/em>\uff09-<strong>3al<\/strong>\u548c<strong>3ao<\/strong>\u53ef\u8fdb\u4e00\u6b65\u4e0e<em>N<\/em>-\u7532\u57fa\u9a6c\u6765\u9170\u4e9a\u80fa\u548c\u987a\u4e01\u70ef\u4e8c\u9178\u9150\u53d1\u751fDA\u53cd\u5e94\uff0c\u80fd\u4ee5\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u548c\u975e\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u5177\u6709\u8fde\u7eed\u4e09\u4e2a\u624b\u6027\u4e2d\u5fc3\u7684\u53cc\u73af\u4ea7\u7269<strong>4<\/strong>\u3001<strong>5<\/strong>\u548c<strong>6<\/strong>\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u4e00\u9505\u6cd5\u4e5f\u53ef\u4ee5\u4f18\u5f02\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e09\u73af\u5316\u5408\u7269<strong>7<\/strong>\u548c<strong>8<\/strong>\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u4e86\u8ba1\u7b97\uff0c\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u8be5\u53cd\u5e94\u540c\u65f6\u5b58\u5728\u52a8\u6001\u52a8\u529b\u5b66\u62c6\u5206\u548c\u52a8\u529b\u5b66\u62c6\u5206\u4e24\u79cd\u8fc7\u7a0b\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-24.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32540 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-24.jpg\" alt=\"\" width=\"494\" height=\"632\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-24.jpg 494w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-24-234x300.jpg 234w\" sizes=\"(max-width: 494px) 100vw, 494px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Scheme 4 \u884d\u751f\u53cd\u5e94<\/p>\n<h4><strong>\u8bba\u6587\u603b\u7ed3\u8bc4\u4ef7<\/strong><\/h4>\n<p>\u590d\u65e6\u5927\u5b66\u9ebb\u751f\u660e\u3001\u94b1\u8f89\u8bfe\u9898\u7ec4\u548c\u5f20\u4fca\u826f\u56e2\u961f\u5171\u540c\u62a5\u9053\u4e86\u94af\u548cMing-Phos\u914d\u4f53\u50ac\u5316\u5916\u6d88\u65cb\u7684\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u6709\u673a\u787c\u9178\u53d1\u751f\u4e0d\u5bf9\u79f0\u5076\u8054\u53cd\u5e94\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u6536\u7387\u548c\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e00\u7cfb\u5217\u624b\u6027\u8054\u70ef\u5316\u5408\u7269\u3002\u540c\u65f6\uff0c\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u8be5\u53cd\u5e94\u540c\u65f6\u5b58\u5728\u52a8\u6001\u52a8\u529b\u5b66\u62c6\u5206\u548c\u52a8\u529b\u5b66\u62c6\u5206\u4e24\u79cd\u8fc7\u7a0b\uff0c\u4f46\u6c34\u5728\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\u8fd8\u6709\u5f85\u8fdb\u4e00\u6b65\u7814\u7a76\u3002<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] Oelke, A. J.; Sun, J.; Fu, G. C. <em> Am. Chem. Soc.<\/em> <strong>2012<\/strong>, <em>134<\/em>, 2966-2969. DOI: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja300031w\">10.1021\/ja300031w<\/a><\/li>\n<li>[2] (a) Wang, Y.; Zhang, W.; Ma, S. <em> Am. Chem. Soc. <\/em><strong>2013<\/strong>, <em>135<\/em>, 11517-11520; DOI: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja406135t\">10.1021\/ja406135t<\/a> (b) Liu, Z.-L.; Yang, C.; Xue, Q.-Y.; Zhao, M.; Shan, C.-C.; Xu, Y.-H.; Loh, T.-P. <em>Angew. Chem., Int. Ed.<\/em> <strong>2019<\/strong>, <em>58<\/em>, 16538-16542. DOI: <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201908343\">10.1002\/anie.201908343<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u4e19\u4e8c\u70ef\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u4e0d\u9971\u548c\u70c3\uff0c\u56e0\u5176\u5177\u6709\u8f74\u624b\u6027\u800c\u53d7\u5230\u5316\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7094\u4e19\u9187\u884d\u751f\u7269\u548c\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u662f\u5408\u6210\u5916\u6d88\u65cb\u4e19\u4e8c\u70ef\u7684\u91cd\u8981\u65b9\u6cd5\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u4ee5\u5149\u5b66\u7eaf\u7684\u7094\u4e19\u9187\u884d\u751f\u7269\u548c\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\u901a\u8fc7\u624b\u6027\u8f6c\u79fb\u7b56\u7565\u5408\u6210\u624b\u6027\u4e19\u4e8c\u70ef\u7684\u7b56\u7565\u5df2\u7ecf\u6709\u4e86\u4e00\u5b9a\u7684\u53d1\u5c55\uff0c\u4f46\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u786c\u4eb2\u6838\u8bd5\u5242\u7684\u5076\u8054\u53cd\u5e94\u4e00\u822c\u662f\u5408\u6210\u624b\u6027\u7094\u7c7b\u5316\u5408\u7269\u5316\u5408\u7269[1]\uff08Scheme 1, path a\uff09\uff0c\u8fd8\u6ca1\u6709\u5173\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5408\u6210\u624b\u6027\u8054\u70ef\u5316\u5408\u7269\u7684\u62a5\u9053[2]\uff08Scheme 1, path b\uff09\u3002\u6700\u8fd1\uff0c\u5f20\u4fca\u826f\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u624b\u6027\u4e9a\u78fa\u9170\u80fa\u81a6\u914d\u4f53\uff0c\u5728\u5bf9\u6620\u9009\u62e9\u6027\u63a7\u5236\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5728\u4e0a\u8ff0\u80cc\u666f\u7684\u57fa\u7840\u4e0a\uff0c\u590d\u65e6\u5927\u5b66\u9ebb\u751f\u660e\u3001\u94b1\u8f89\u8bfe\u9898\u7ec4\u548c\u5f20\u4fca\u826f\u56e2\u961f\u5171\u540c\u62a5\u9053\u4e86\u94af\u548cMing-Phos\u914d\u4f53\u50ac\u5316\u5916\u6d88\u65cb\u7684\u7094\u4e19\u9187\u884d\u751f\u7269\u4e0e\u6709\u673a\u787c\u9178\u53d1\u751f\u4e0d\u5bf9\u79f0\u5076\u8054\u53cd\u5e94\uff0c\u80fd\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u6536\u7387\u548c\u4f18\u79c0\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e00\u7cfb\u5217\u624b\u6027\u8054\u70ef\u5316\u5408\u7269\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u4e8e \u201cPd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids\u201d Wang, H.; Luo, H.; Zhang, Z.-M.; Zheng, W.-F.; Yin, Y.; Qian, H.* Zhang, J.* Ma, S.* J. Am. Chem. Soc. 2020, Early View. 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