{"id":32897,"date":"2020-06-17T08:23:25","date_gmt":"2020-06-17T00:23:25","guid":{"rendered":"\/\/www.gsbet888.com\/?p=32897"},"modified":"2020-06-17T08:23:25","modified_gmt":"2020-06-17T00:23:25","slug":"%e5%a4%9a%e5%8a%9f%e8%83%bd%e6%98%be%e8%89%b2%e5%89%82-%e8%8c%9a%e4%b8%89%e9%85%ae%ef%bc%88ninhydrin%ef%bc%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/molecule\/2020\/06\/%e5%a4%9a%e5%8a%9f%e8%83%bd%e6%98%be%e8%89%b2%e5%89%82-%e8%8c%9a%e4%b8%89%e9%85%ae%ef%bc%88ninhydrin%ef%bc%89.html","title":{"rendered":"\u591a\u529f\u80fd\u663e\u8272\u5242\u2014\u2014\u831a\u4e09\u916e\uff08Ninhydrin\uff09"},"content":{"rendered":"<h4><strong>\u5f15\u8a00<\/strong><\/h4>\n<p>\u6709\u673a\u5408\u6210\u5b9e\u9a8c\u4e2d\uff0c\u8584\u5c42\u8272\u8c31\uff08Thin Layer Chromatography\uff0cTLC\uff09\u662f\u4e00\u79cd\u57fa\u7840\u4e14\u5e38\u7528\u7684\u5206\u6790\u5206\u79bb\u65b9\u6cd5\uff0c\u4e3a\u4e86\u89c2\u5bdf\u8fd9\u4e9b\u7269\u8d28\u5728\u8272\u8c31\u5e26\u4e0a\u7684\u4f4d\u7f6e\uff0c\u6211\u4eec\u6700\u5e38\u7528\u7684\u65b9\u6cd5\u662f\u5728\u7d2b\u5916\u706f\u4e0b\u89c2\u5bdf\u3002\u7136\u800c\uff0c\u5e76\u975e\u6240\u6709\u7684\u5316\u5408\u7269\u90fd\u5177\u6709\u7d2b\u5916\u5438\u6536\uff0c\u6709\u65f6\u6211\u4eec\u4e5f\u9700\u8981\u5bf9\u8272\u8c31\u5e26\u4e0a\u7684\u7269\u8d28\u8fdb\u884c\u521d\u6b65\u5224\u65ad\uff0c\u8fd9\u65f6TLC\u663e\u8272\u5242\u5c31\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u5b9e\u9a8c\u4e2d\u7ecf\u5e38\u7528\u5230\u7684\u663e\u8272\u5242\u5305\u62ec\u9ad8\u9530\u9178\u94be\u3001\u78f7\u94bc\u9178\u30012, 4-\u4e8c\u785d\u57fa\u82ef\u80bc\u3001\u9999\u8349\u919b\u3001\u7898\u5355\u8d28\u3001\u831a\u4e09\u916e\u7b49\uff0c\u8fd9\u4e9b\u663e\u8272\u5242\u5177\u6709\u5e7f\u8c31\u663e\u8272\u6027\u8d28\u6216\u53ea\u80fd\u548c\u7279\u5b9a\u79cd\u7c7b\u7684\u7269\u8d28\u53d1\u751f\u663e\u8272\u53cd\u5e94\uff0c\u5176\u4e2d\u831a\u4e09\u916e\u5c31\u662f\u4e00\u79cd\u6c28\u57fa\u5316\u5408\u7269\u7684\u7279\u5b9a\u663e\u8272\u5242\uff0c\u5b83\u4e0e\u6c28\u57fa\u4f5c\u7528\u540e\u4f1a\u663e\u793a\u51fa\u72ec\u7279\u7684\u84dd\u7d2b\u8272\u2014\u2014\u7f57\u66fc\u7d2b\uff08Ruhemann&#8217;s purple\uff09\uff0c\u51ed\u501f\u8fd9\u4e00\u6027\u8d28\u831a\u4e09\u916e\u88ab\u5e7f\u6cdb\u7528\u4e8e\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u7279\u522b\u662f\u6c28\u57fa\u9178\u548c\u591a\u80bd\u5316\u5408\u7269\u7684\u68c0\u6d4b\uff0c\u5728\u5211\u4fa6\u9886\u57df\u4e5f\u662f\u9274\u5b9a\u6307\u7eb9\u7684\u91cd\u8981\u624b\u6bb5\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-scaled.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32898 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-scaled.jpg\" alt=\"\" width=\"653\" height=\"444\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-scaled.jpg 2560w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-300x204.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-680x462.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-768x522.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-1536x1044.jpg 1536w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/1-90-2048x1392.jpg 2048w\" sizes=\"(max-width: 653px) 100vw, 653px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u7ecf\u831a\u4e09\u916e\u663e\u8272\u540e\u7684\u6c28\u57fa\u9178\u7247\u6bb5<\/p>\n<h4><strong>\u831a\u4e09\u916e\u7684\u53d1\u73b0<\/strong><\/h4>\n<p>\u7eb5\u89c2\u79d1\u5b66\u53f2\uff0c\u6709\u5f88\u591a\u91cd\u8981\u7684\u53d1\u660e\u548c\u53d1\u73b0\u5747\u662f\u6e90\u4e8e\u610f\u5916\u548c\u5076\u7136\uff0c\u831a\u4e09\u916e\u4e5f\u662f\u5982\u6b64\uff0c\u53ea\u4e0d\u8fc7\u8fd9\u6bb5\u5386\u53f2\u4ee5\u53ca\u5b83\u7684\u53d1\u73b0\u8005\u90fd\u9c9c\u4e3a\u4eba\u77e5\u7f62\u4e86\u3002\u5fb7\u88d4\u82f1\u56fd\u5316\u5b66\u5bb6Siegfried Ruhemann\u53d1\u73b0\u831a\u4e09\u916e\u5176\u5b9e\u662f\u6e90\u4e8e\u4ed6\u5bf9\u70ef\u9187\u5316\u73af\u72b6\u7fb0\u57fa\u5316\u5408\u7269\u7684\u7814\u7a76\u5174\u8da3\uff0c\u90a3\u65f6\u4ed6\u53d1\u73b0\u5316\u5408\u7269<strong>I<\/strong>\u4e3b\u8981\u4ee5\u70ef\u9187\u5f62\u5f0f\u5b58\u5728\u5e76\u4e14\u63a8\u6d4b\u73af\u5916\u7684\u4e59\u9170\u57fa\u5bf9\u70ef\u9187\u4e92\u53d8\u6709\u5f71\u54cd\u3002\u4e3a\u4e86\u9a8c\u8bc1\u8fd9\u4e00\u731c\u60f3\uff0c\u4ed6\u8bbe\u8ba1\u4e86\u5177\u6709\u76f8\u4f3c\u7ed3\u6784\u7684\u5316\u5408\u7269<strong>II<\/strong>\uff0c\u5e76\u51b3\u5b9a\u91c7\u75281-\u831a\u916e\uff081-indanone\uff09\u4e3a\u8d77\u59cb\u539f\u6599\u8fdb\u884c\u5408\u6210\u3002\u6839\u636e\u6700\u521d\u8bbe\u60f3\uff0c1-\u831a\u916e\u88ab4-\u4e9a\u785d\u57fa\u4e8c\u7532\u82ef\u80fa\uff084-nitroso dimethylaniline\uff09\u6c27\u5316\u540e\u5f97\u5230\u7684\u4e9a\u80fa\u4e2d\u95f4\u4f53\u6c34\u89e3\u5373\u53ef\u5f97\u5230\u90bb\u4e8c\u916e\u4ea7\u7269\u3002\u7136\u800c\u4e8b\u4e0e\u613f\u8fdd\uff0c\u4ed6\u4eec\u59cb\u7ec8\u6ca1\u6cd5\u5408\u6210\u671f\u5f85\u7684\u4e9a\u80fa\u4e2d\u95f4\u4f53\uff0c\u540e\u6765\u624d\u53d1\u73b01-\u831a\u916e\u7684\u4e24\u4e2a\u4e9a\u7532\u57fa\u5747\u53c2\u4e0e\u4e86\u53cd\u5e94\u2014\u2014\u5b9e\u9645\u5f97\u5230\u7684\u662f\u53cc\u4e9a\u80fa\u4e2d\u95f4\u4f53\uff0c\u6c34\u89e3\u540e\u5f97\u5230\u4e86\u4e09\u916e\u7684\u5355\u6c34\u5408\u7269\uff08monohydrate of triketone\uff09\uff0cRuhemann\u6839\u636e\u4ea7\u7269\u65e0\u8272\u7684\u6027\u8d28\u6392\u9664\u4e86\u90bb\u4e8c\u916e\u7ed3\u6784\u7684\u53ef\u80fd\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32899 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88.jpg\" alt=\"\" width=\"696\" height=\"359\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88.jpg 1348w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88-300x155.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88-680x351.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/2-88-768x396.jpg 768w\" sizes=\"(max-width: 696px) 100vw, 696px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u831a\u4e09\u916e\u7684\u53d1\u73b0\u8fc7\u7a0b<\/p>\n<h4><strong>\u831a\u4e09\u916e\u7684\u663e\u8272\u539f\u7406<\/strong><\/h4>\n<p>\u80fa\u7c7b\u5316\u5408\u7269\u4e0e\u831a\u4e09\u916e\u4f5c\u7528\u540e\u4f1a\u663e\u8272\u7684\u72ec\u7279\u73b0\u8c61\u7a76\u7adf\u662f\u5982\u4f55\u88abRuhemann\u53d1\u73b0\u7684\u6211\u4eec\u5df2\u7ecf\u4e0d\u5f97\u800c\u77e5\uff0c\u5982\u4eca\u53ea\u80fd\u7aa5\u63a2\u5230\u4ed6\u6700\u521d\u8bb0\u8f7d\u7684\u5173\u952e\u4fe1\u606f\uff1a\u201c<em>Of especial interest is the action of ammonia on the triketone. If the aqueous solution of the mixture of both substances is kept for a short time it turns a deep reddish-violet<\/em>\u2026\u201d\u3002\u800c\u8fd9\u79cd\u6709\u989c\u8272\u7684\u7269\u8d28Ruhemann\u8ba4\u4e3a\u662f\u5305\u542b\u4e24\u4e2a\u831a\u4e09\u916e\u7247\u6bb5\u7684\u67d0\u79cd\u4e9a\u80fa\uff0c\u8fd9\u4e0e\u73b0\u4ee3\u5316\u5b66\u7684\u89c2\u70b9\u4e00\u81f4\u3002\u5f53\u4ed6\u6b63\u8981\u5bf9\u831a\u4e09\u916e\u53ca\u5176\u663e\u8272\u539f\u7406\u8fdb\u884c\u66f4\u6df1\u5165\u548c\u7cfb\u7edf\u6027\u7814\u7a76\u65f6\uff0c\u6070\u9022\u4e00\u6218\u7206\u53d1\u540e\u82f1\u56fd\u56fd\u5185\u201c\u53cd\u5fb7\u201d\u60c5\u7eea\u9ad8\u6da8\uff0cRuhemann\u4e0d\u5f97\u4e0d\u8f9e\u804c\u56de\u5230\u5fb7\u56fd\u3002<\/p>\n<p>\u73b0\u5728\u4eba\u4eec\u5df2\u7ecf\u5bf9\u831a\u4e09\u916e\u4e0e\u6c28\u57fa\u9178\u4f5c\u7528\u540e\u7684\u663e\u8272\u673a\u7406\u6709\u4e86\u6e05\u695a\u8ba4\u8bc6\uff0c\u831a\u4e09\u916e\u9996\u5148\u8131\u6c34\u4e0e\u6c28\u57fa\u7f29\u5408\u5f97\u5230\u4e9a\u80fa\uff08Schiff base\uff09\uff0c\u56e0\u6b64\u53ea\u6709\u6c28\u6216\u4f2f\u80fa\u624d\u80fd\u53d1\u751f\u6b64\u6b65\u53cd\u5e94\uff0c\u968f\u540e\u4e9a\u80fa\u8131\u7fa7\u540e\u5f02\u6784\u5316\u4e3a\u53e6\u4e00\u79cd\u5f62\u5f0f\u7684\u4e9a\u80fa\uff0c\u6c34\u89e3\u540e\u91ca\u653e\u51fa\u51fa\u4e00\u5206\u5b50\u4f2f\u80fa\u548c\u4e00\u5206\u5b50\u919b\u3002\u4f2f\u80fa\u8fdb\u4e00\u6b65\u4e0e\u831a\u4e09\u916e\u53d1\u751f\u7f29\u5408\u5f97\u5230\u4e8c\u805a\u7684\u4e9a\u80fa\u884d\u751f\u7269\u4ece\u800c\u663e\u793a\u51fa\u88ab\u6211\u4eec\u79f0\u4e4b\u4e3a\u201cRuhemann&#8217;s purple\u201d\u7684\u989c\u8272\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\uff0c\u5e76\u975e\u6240\u6709\u6c28\u57fa\u9178\u53ca\u5177\u6709\u6e38\u79bba-\u6c28\u57fa\u7684\u80bd\u4e0e\u831a\u4e09\u916e\u53cd\u5e94\u90fd\u4ea7\u751f\u84dd\u7d2b\u8272\u7269\u8d28\uff0c\u4f8b\u5982\u812f\u6c28\u9178\u548c\u7f9f\u812f\u6c28\u9178\u4e0e\u831a\u4e09\u916e\u53cd\u5e94\u540e\u5219\u4f1a\u4ea7\u751f\u9ec4\u8272\u7269\u8d28\u3002\u9057\u61be\u7684\u662f\uff0c\u5c3d\u7ba1\u831a\u4e09\u916e\u4e5f\u53ef\u4ee5\u68c0\u6d4b\u4e8c\u7ea7\u80fa\uff0c\u4f46\u5bf9\u5176\u663e\u8272\u673a\u7406\u76ee\u524d\u8fd8\u6709\u5f88\u591a\u4e0d\u6e05\u695a\u7684\u5730\u65b9\uff0c\u4e5f\u5c1a\u672a\u6709\u7edf\u4e00\u7684\u8bf4\u6cd5\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32900 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74.jpg\" alt=\"\" width=\"719\" height=\"344\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74.jpg 1424w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74-300x143.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74-680x325.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/3-74-768x367.jpg 768w\" sizes=\"(max-width: 719px) 100vw, 719px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u831a\u4e09\u916e\u4e0e\u6c28\u57fa\u9178\u4f5c\u7528\u7684\u663e\u8272\u539f\u7406<\/p>\n<h4><strong>\u831a\u4e09\u916e\u7684\u5e94\u7528<\/strong><\/h4>\n<p>\u831a\u4e09\u916e\u72ec\u7279\u7684\u663e\u8272\u7279\u6027\u4f7f\u5176\u5728\u80fa\u7c7b\u5316\u5408\u7269\u7684\u68c0\u6d4b\uff0c\u7279\u522b\u662f\u6c28\u57fa\u9178\u7684\u68c0\u6d4b\u4e0a\u6709\u91cd\u8981\u5e94\u7528\uff0c\u5b83\u4e0e\u6c28\u57fa\u9178\u7684\u53cd\u5e94\u88ab\u79f0\u4e3a\u831a\u4e09\u916e\u53cd\u5e94\uff08Ninhydrin Reaction\uff09\uff0c\u8be5\u53cd\u5e94\u5341\u5206\u7075\u654f\u5e76\u4e14\u53ef\u6839\u636e\u751f\u6210\u7684\u84dd\u7d2b\u8272\u6df1\u6d45\u5728\u7279\u5b9a\u6ce2\u957f\u4e0b\u8fdb\u884c\u6bd4\u8272\u6d4b\u5b9a\u6837\u54c1\u4e2d\u6c28\u57fa\u9178\u7684\u542b\u91cf\u3002\u831a\u4e09\u916e\u8fd8\u53ef\u7528\u6765\u76d1\u6d4b\u56fa\u76f8\u80bd\u5408\u6210\u4e2d\u7684\u8131\u4fdd\u62a4\u8fc7\u7a0b\uff08Kaiser\u6d4b\u8bd5\uff09\uff1a\u80bd\u94fe\u7684\u78b3\u7aef\u4e0e\u56fa\u76f8\u57fa\u8d28\u8fde\u63a5\u540e\u5229\u7528\u6c2e\u7aef\u6269\u5c55\u80bd\u94fe\uff0c\u5f53\u8131\u53bb\u6c2e\u539f\u5b50\u4e0a\u7684\u4fdd\u62a4\u540e\uff0c\u831a\u4e09\u916e\u6d4b\u8bd5\u5448\u84dd\u8272\uff0c\u6b64\u5916\u6c28\u57fa\u9178\u6b8b\u57fa\u662f\u5728\u6c2e\u7aef\u88ab\u4fdd\u62a4\u7684\u60c5\u51b5\u4e0b\u63a5\u5165\u80bd\u94fe\u7684\uff0c\u56e0\u6b64\u5982\u679c\u4e0b\u4e00\u4e2a\u6c28\u57fa\u9178\u6b8b\u57fa\u6210\u529f\u8fde\u63a5\u5230\u80bd\u94fe\uff0c\u831a\u4e09\u916e\u6d4b\u8bd5\u5219\u51fa\u73b0\u65e0\u8272\u6216\u9ec4\u8272\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-62.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32901 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-62.jpg\" alt=\"\" width=\"584\" height=\"308\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-62.jpg 584w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/4-62-300x158.jpg 300w\" sizes=\"(max-width: 584px) 100vw, 584px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u831a\u4e09\u916e\u663e\u8272\u540e\u7684\u6c28\u57fa\u9178\u548c\u6307\u7eb9<\/p>\n<p>\u5bf9\u9057\u7559\u5728\u7269\u4f53\u8868\u9762\u7684\u6307\u7eb9\u8fdb\u884c\u63d0\u53d6\u548c\u9274\u5b9a\u662f\u4fa6\u7834\u6848\u4ef6\u7684\u91cd\u8981\u4f9d\u636e\uff0c\u76ee\u524d\u8bc6\u522b\u6f5c\u5728\u6307\u7eb9\u7684\u65b9\u6cd5\u5927\u4f53\u4e0a\u53ef\u5206\u4e3a\u7269\u7406\u548c\u5316\u5b66\u65b9\u6cd5\uff0c\u831a\u4e09\u916e\u5c31\u662f\u4e00\u79cd\u88ab\u5e7f\u6cdb\u4f7f\u7528\u7684\u5316\u5b66\u65b9\u6cd5\u3002\u7531\u4e8e\u6307\u7eb9\u4e2d\u542b\u6709\u6c28\u57fa\u9178\u7b49\u6210\u5206\uff0c\u4e0e\u831a\u4e09\u916e\u4f5c\u7528\u540e\u5c31\u4f1a\u663e\u8272\uff0c\u539f\u7406\u6b63\u662f\u4e0a\u6587\u63d0\u5230\u7684\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\u3002\u6307\u7eb9\u7684\u831a\u4e09\u916e\u663e\u8272\u6cd5\u65e9\u57281954\u5e74\u5c31\u88ab\u745e\u5178\u79d1\u5b66\u5bb6Oden\u63d0\u51fa\u548c\u4f7f\u7528\uff0c\u73b0\u9636\u6bb5\u4ecd\u662f\u5e38\u7528\u65b9\u6cd5\u4e4b\u4e00\uff0c\u7279\u522b\u662f\u5bf9\u7eb8\u5f20\u8868\u9762\u7684\u6307\u7eb9\u68c0\u51fa\u6548\u679c\u597d\uff0c\u4f46\u8be5\u65b9\u6cd5\u4e5f\u53d7\u9650\u4e8e\u6307\u7eb9\u4e2d\u6c28\u57fa\u9178\u7684\u542b\u91cf\uff0c\u6c28\u57fa\u9178\u542b\u91cf\u5982\u679c\u8fc7\u4f4e\u5219\u4f1a\u5f71\u54cd\u6700\u7ec8\u7684\u68c0\u51fa\u6548\u679c\u3002\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u831a\u4e09\u916e\u5728\u4f7f\u7528\u7684\u65f6\u5019\u8981\u907f\u514d\u63a5\u89e6\u76ae\u80a4\uff0c\u56e0\u4e3a\u76ae\u80a4\u8868\u9762\u542b\u6709\u5fae\u91cf\u6c28\u57fa\u9178\u6210\u5206\uff0c\u4e00\u65e6\u9047\u5230\u831a\u4e09\u916e\u540c\u6837\u4f1a\u88ab\u67d3\u8272\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32902 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47.jpg\" alt=\"\" width=\"598\" height=\"431\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47.jpg 928w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47-300x216.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47-680x490.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/5-47-768x554.jpg 768w\" sizes=\"(max-width: 598px) 100vw, 598px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u76ae\u80a4\u88ab\u831a\u4e09\u916e\u67d3\u8272<\/p>\n<h4><strong>\u67d3\u6599\u4e1a\u7684\u9057\u61be<\/strong><\/h4>\n<p>19\u4e16\u7eaa\u540e\u671f\uff0c\u8bb8\u591a\u5316\u5b66\u5bb6\u90fd\u5c06\u7cbe\u529b\u96c6\u4e2d\u5728\u5408\u6210\u67d3\u6599\u9886\u57df\uff0c\u7279\u522b\u662f\u5a01\u5ec9\u2022\u73c0\u91d1\uff08William Henry Perkin\uff09\u610f\u5916\u53d1\u73b0\u7684\u82ef\u80fa\u7d2b\u67d3\u6599\u6781\u5927\u4fc3\u8fdb\u4e86\u67d3\u6599\u5de5\u4e1a\u7684\u53d1\u5c55\u30021878\u5e74\uff0c\u963f\u9053\u592b\u00b7\u51af\u00b7\u62dc\u5c14\uff08Adolf von Baeyer\uff09\u6210\u529f\u5408\u6210\u4e86\u88ab\u79f0\u4e3a\u975b\u84dd\uff08Indigo\uff09\u7684\u67d3\u6599\uff0c\u4e5f\u56e0\u6b64\u83b7\u5f971905\u5e74\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u3002\u975b\u84dd\u4e0e\u4ea7\u751f\u7f57\u66fc\u7d2b\u7684\u5316\u5408\u7269\u7ed3\u6784\u76f8\u50cf\uff0c\u4f46\u5176\u5408\u6210\u6210\u672c\u66f4\u4f4e\u5ec9\u56e0\u6b64\u66f4\u5177\u5e02\u573a\u6f5c\u529b\uff0c\u7f57\u66fc\u7d2b\u5219\u56e0\u4e3a\u9ad8\u6210\u672c\u6700\u7ec8\u9057\u61be\u6ca1\u80fd\u6210\u4e3a\u5e94\u7528\u666e\u53ca\u7684\u67d3\u6599\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32903 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36.jpg\" alt=\"\" width=\"707\" height=\"218\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36.jpg 1285w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36-300x93.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36-680x210.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/05\/6-36-768x237.jpg 768w\" sizes=\"(max-width: 707px) 100vw, 707px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">\u82ef\u80fa\u7d2bB\u548c\u975b\u84dd\u7684\u7ed3\u6784<\/p>\n<h4><strong>\u53c2\u8003\u8d44\u6599<\/strong><\/h4>\n<ul>\n<li>[1] West, Robert. &#8220;Siegfried Ruhemann and the discovery of ninhydrin.&#8221; <em>J. Chem. Educ<\/em>. <strong>1965<\/strong>, <em>42<\/em>, 386-387. DOI: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ed042p386\">10.1021\/ed042p386<\/a><\/li>\n<li>[2] \u9648\u5fe0\u4e91.a-\u6c28\u57fa\u9178\u548c\u831a\u4e09\u916e\u663e\u8272\u53cd\u5e94\u673a\u7406[J].\u6559\u6750\u901a\u8baf, 1991 (02): 36-37.<\/li>\n<li>[3] \u9648\u8273, \u5f20\u6625\u9759, \u9ad8\u4e1c\u6885, \u6768\u5e06, \u97e9\u51ac\u96ea, \u725b\u5229. \u6f5c\u6307\u7eb9\u663e\u73b0\u65b9\u6cd5\u7814\u7a76\u8fdb\u5c55[J].\u5e94\u7528\u5316\u5b66, 2011, 28 (10): 1099-1107.<\/li>\n<li>[4] Friedman, Mendel. &#8220;Applications of the ninhydrin reaction for analysis of amino acids, peptides, and proteins to agricultural and biomedical sciences.&#8221; <em>J. Agric. Food Chem.<\/em> <strong>2004<\/strong>, <em>52<\/em>, 385-406. DOI: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jf030490p\">10.1021\/jf030490p<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u5f15\u8a00 \u6709\u673a\u5408\u6210\u5b9e\u9a8c\u4e2d\uff0c\u8584\u5c42\u8272\u8c31\uff08Thin Layer Chromatography\uff0cTLC\uff09\u662f\u4e00\u79cd\u57fa\u7840\u4e14\u5e38\u7528\u7684\u5206\u6790\u5206\u79bb\u65b9\u6cd5\uff0c\u4e3a\u4e86\u89c2\u5bdf\u8fd9\u4e9b\u7269\u8d28\u5728\u8272\u8c31\u5e26\u4e0a\u7684\u4f4d\u7f6e\uff0c\u6211\u4eec\u6700\u5e38\u7528\u7684\u65b9\u6cd5\u662f\u5728\u7d2b\u5916\u706f\u4e0b\u89c2\u5bdf\u3002\u7136\u800c\uff0c\u5e76\u975e\u6240\u6709\u7684\u5316\u5408\u7269\u90fd\u5177\u6709\u7d2b\u5916\u5438\u6536\uff0c\u6709\u65f6\u6211\u4eec\u4e5f\u9700\u8981\u5bf9\u8272\u8c31\u5e26\u4e0a\u7684\u7269\u8d28\u8fdb\u884c\u521d\u6b65\u5224\u65ad\uff0c\u8fd9\u65f6TLC\u663e\u8272\u5242\u5c31\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u5b9e\u9a8c\u4e2d\u7ecf\u5e38\u7528\u5230\u7684\u663e\u8272\u5242\u5305\u62ec\u9ad8\u9530\u9178\u94be\u3001\u78f7\u94bc\u9178\u30012, 4-\u4e8c\u785d\u57fa\u82ef\u80bc\u3001\u9999\u8349\u919b\u3001\u7898\u5355\u8d28\u3001\u831a\u4e09\u916e\u7b49\uff0c\u8fd9\u4e9b\u663e\u8272\u5242\u5177\u6709\u5e7f\u8c31\u663e\u8272\u6027\u8d28\u6216\u53ea\u80fd\u548c\u7279\u5b9a\u79cd\u7c7b\u7684\u7269\u8d28\u53d1\u751f\u663e\u8272\u53cd\u5e94\uff0c\u5176\u4e2d\u831a\u4e09\u916e\u5c31\u662f\u4e00\u79cd\u6c28\u57fa\u5316\u5408\u7269\u7684\u7279\u5b9a\u663e\u8272\u5242\uff0c\u5b83\u4e0e\u6c28\u57fa\u4f5c\u7528\u540e\u4f1a\u663e\u793a\u51fa\u72ec\u7279\u7684\u84dd\u7d2b\u8272\u2014\u2014\u7f57\u66fc\u7d2b\uff08Ruhemann&#8217;s purple\uff09\uff0c\u51ed\u501f\u8fd9\u4e00\u6027\u8d28\u831a\u4e09\u916e\u88ab\u5e7f\u6cdb\u7528\u4e8e\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u7279\u522b\u662f\u6c28\u57fa\u9178\u548c\u591a\u80bd\u5316\u5408\u7269\u7684\u68c0\u6d4b\uff0c\u5728\u5211\u4fa6\u9886\u57df\u4e5f\u662f\u9274\u5b9a\u6307\u7eb9\u7684\u91cd\u8981\u624b\u6bb5\u3002 \u7ecf\u831a\u4e09\u916e\u663e\u8272\u540e\u7684\u6c28\u57fa\u9178\u7247\u6bb5 \u831a\u4e09\u916e\u7684\u53d1\u73b0 \u7eb5\u89c2\u79d1\u5b66\u53f2\uff0c\u6709\u5f88\u591a\u91cd\u8981\u7684\u53d1\u660e\u548c\u53d1\u73b0\u5747\u662f\u6e90\u4e8e\u610f\u5916\u548c\u5076\u7136\uff0c\u831a\u4e09\u916e\u4e5f\u662f\u5982\u6b64\uff0c\u53ea\u4e0d\u8fc7\u8fd9\u6bb5\u5386\u53f2\u4ee5\u53ca\u5b83\u7684\u53d1\u73b0\u8005\u90fd\u9c9c\u4e3a\u4eba\u77e5\u7f62\u4e86\u3002\u5fb7\u88d4\u82f1\u56fd\u5316\u5b66\u5bb6Siegfried Ruhemann\u53d1\u73b0\u831a\u4e09\u916e\u5176\u5b9e\u662f\u6e90\u4e8e\u4ed6\u5bf9\u70ef\u9187\u5316\u73af\u72b6\u7fb0\u57fa\u5316\u5408\u7269\u7684\u7814\u7a76\u5174\u8da3\uff0c\u90a3\u65f6\u4ed6\u53d1\u73b0\u5316\u5408\u7269I\u4e3b\u8981\u4ee5\u70ef\u9187\u5f62\u5f0f\u5b58\u5728\u5e76\u4e14\u63a8\u6d4b\u73af\u5916\u7684\u4e59\u9170\u57fa\u5bf9\u70ef\u9187\u4e92\u53d8\u6709\u5f71\u54cd\u3002\u4e3a\u4e86\u9a8c\u8bc1\u8fd9\u4e00\u731c\u60f3\uff0c\u4ed6\u8bbe\u8ba1\u4e86\u5177\u6709\u76f8\u4f3c\u7ed3\u6784\u7684\u5316\u5408\u7269II\uff0c\u5e76\u51b3\u5b9a\u91c7\u75281-\u831a\u916e\uff081-indanone\uff09\u4e3a\u8d77\u59cb\u539f\u6599\u8fdb\u884c\u5408\u6210\u3002\u6839\u636e\u6700\u521d\u8bbe\u60f3\uff0c1-\u831a\u916e\u88ab4-\u4e9a\u785d\u57fa\u4e8c\u7532\u82ef\u80fa\uff084-nitroso dimethylaniline\uff09\u6c27\u5316\u540e\u5f97\u5230\u7684\u4e9a\u80fa\u4e2d\u95f4\u4f53\u6c34\u89e3\u5373\u53ef\u5f97\u5230\u90bb\u4e8c\u916e\u4ea7\u7269\u3002\u7136\u800c\u4e8b\u4e0e\u613f\u8fdd\uff0c\u4ed6\u4eec\u59cb\u7ec8\u6ca1\u6cd5\u5408\u6210\u671f\u5f85\u7684\u4e9a\u80fa\u4e2d\u95f4\u4f53\uff0c\u540e\u6765\u624d\u53d1\u73b01-\u831a\u916e\u7684\u4e24\u4e2a\u4e9a\u7532\u57fa\u5747\u53c2\u4e0e\u4e86\u53cd\u5e94\u2014\u2014\u5b9e\u9645\u5f97\u5230\u7684\u662f\u53cc\u4e9a\u80fa\u4e2d\u95f4\u4f53\uff0c\u6c34\u89e3\u540e\u5f97\u5230\u4e86\u4e09\u916e\u7684\u5355\u6c34\u5408\u7269\uff08monohydrate of triketone\uff09\uff0cRuhemann\u6839\u636e\u4ea7\u7269\u65e0\u8272\u7684\u6027\u8d28\u6392\u9664\u4e86\u90bb\u4e8c\u916e\u7ed3\u6784\u7684\u53ef\u80fd\u3002 \u831a\u4e09\u916e\u7684\u53d1\u73b0\u8fc7\u7a0b \u831a\u4e09\u916e\u7684\u663e\u8272\u539f\u7406 \u80fa\u7c7b\u5316\u5408\u7269\u4e0e\u831a\u4e09\u916e\u4f5c\u7528\u540e\u4f1a\u663e\u8272\u7684\u72ec\u7279\u73b0\u8c61\u7a76\u7adf\u662f\u5982\u4f55\u88abRuhemann\u53d1\u73b0\u7684\u6211\u4eec\u5df2\u7ecf\u4e0d\u5f97\u800c\u77e5\uff0c\u5982\u4eca\u53ea\u80fd\u7aa5\u63a2\u5230\u4ed6\u6700\u521d\u8bb0\u8f7d\u7684\u5173\u952e\u4fe1\u606f\uff1a\u201cOf especial interest is the action of ammonia on the triketone. If the aqueous solution of the mixture of both substances is kept for a short time it turns a deep reddish-violet\u2026\u201d\u3002\u800c\u8fd9\u79cd\u6709\u989c\u8272\u7684\u7269\u8d28Ruhemann\u8ba4\u4e3a\u662f\u5305\u542b\u4e24\u4e2a\u831a\u4e09\u916e\u7247\u6bb5\u7684\u67d0\u79cd\u4e9a\u80fa\uff0c\u8fd9\u4e0e\u73b0\u4ee3\u5316\u5b66\u7684\u89c2\u70b9\u4e00\u81f4\u3002\u5f53\u4ed6\u6b63\u8981\u5bf9\u831a\u4e09\u916e\u53ca\u5176\u663e\u8272\u539f\u7406\u8fdb\u884c\u66f4\u6df1\u5165\u548c\u7cfb\u7edf\u6027\u7814\u7a76\u65f6\uff0c\u6070\u9022\u4e00\u6218\u7206\u53d1\u540e\u82f1\u56fd\u56fd\u5185\u201c\u53cd\u5fb7\u201d\u60c5\u7eea\u9ad8\u6da8\uff0cRuhemann\u4e0d\u5f97\u4e0d\u8f9e\u804c\u56de\u5230\u5fb7\u56fd\u3002 \u73b0\u5728\u4eba\u4eec\u5df2\u7ecf\u5bf9\u831a\u4e09\u916e\u4e0e\u6c28\u57fa\u9178\u4f5c\u7528\u540e\u7684\u663e\u8272\u673a\u7406\u6709\u4e86\u6e05\u695a\u8ba4\u8bc6\uff0c\u831a\u4e09\u916e\u9996\u5148\u8131\u6c34\u4e0e\u6c28\u57fa\u7f29\u5408\u5f97\u5230\u4e9a\u80fa\uff08Schiff base\uff09\uff0c\u56e0\u6b64\u53ea\u6709\u6c28\u6216\u4f2f\u80fa\u624d\u80fd\u53d1\u751f\u6b64\u6b65\u53cd\u5e94\uff0c\u968f\u540e\u4e9a\u80fa\u8131\u7fa7\u540e\u5f02\u6784\u5316\u4e3a\u53e6\u4e00\u79cd\u5f62\u5f0f\u7684\u4e9a\u80fa\uff0c\u6c34\u89e3\u540e\u91ca\u653e\u51fa\u51fa\u4e00\u5206\u5b50\u4f2f\u80fa\u548c\u4e00\u5206\u5b50\u919b\u3002\u4f2f\u80fa\u8fdb\u4e00\u6b65\u4e0e\u831a\u4e09\u916e\u53d1\u751f\u7f29\u5408\u5f97\u5230\u4e8c\u805a\u7684\u4e9a\u80fa\u884d\u751f\u7269\u4ece\u800c\u663e\u793a\u51fa\u88ab\u6211\u4eec\u79f0\u4e4b\u4e3a\u201cRuhemann&#8217;s purple\u201d\u7684\u989c\u8272\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\uff0c\u5e76\u975e\u6240\u6709\u6c28\u57fa\u9178\u53ca\u5177\u6709\u6e38\u79bba-\u6c28\u57fa\u7684\u80bd\u4e0e\u831a\u4e09\u916e\u53cd\u5e94\u90fd\u4ea7\u751f\u84dd\u7d2b\u8272\u7269\u8d28\uff0c\u4f8b\u5982\u812f\u6c28\u9178\u548c\u7f9f\u812f\u6c28\u9178\u4e0e\u831a\u4e09\u916e\u53cd\u5e94\u540e\u5219\u4f1a\u4ea7\u751f\u9ec4\u8272\u7269\u8d28\u3002\u9057\u61be\u7684\u662f\uff0c\u5c3d\u7ba1\u831a\u4e09\u916e\u4e5f\u53ef\u4ee5\u68c0\u6d4b\u4e8c\u7ea7\u80fa\uff0c\u4f46\u5bf9\u5176\u663e\u8272\u673a\u7406\u76ee\u524d\u8fd8\u6709\u5f88\u591a\u4e0d\u6e05\u695a\u7684\u5730\u65b9\uff0c\u4e5f\u5c1a\u672a\u6709\u7edf\u4e00\u7684\u8bf4\u6cd5\u3002 \u831a\u4e09\u916e\u4e0e\u6c28\u57fa\u9178\u4f5c\u7528\u7684\u663e\u8272\u539f\u7406 \u831a\u4e09\u916e\u7684\u5e94\u7528 \u831a\u4e09\u916e\u72ec\u7279\u7684\u663e\u8272\u7279\u6027\u4f7f\u5176\u5728\u80fa\u7c7b\u5316\u5408\u7269\u7684\u68c0\u6d4b\uff0c\u7279\u522b\u662f\u6c28\u57fa\u9178\u7684\u68c0\u6d4b\u4e0a\u6709\u91cd\u8981\u5e94\u7528\uff0c\u5b83\u4e0e\u6c28\u57fa\u9178\u7684\u53cd\u5e94\u88ab\u79f0\u4e3a\u831a\u4e09\u916e\u53cd\u5e94\uff08Ninhydrin Reaction\uff09\uff0c\u8be5\u53cd\u5e94\u5341\u5206\u7075\u654f\u5e76\u4e14\u53ef\u6839\u636e\u751f\u6210\u7684\u84dd\u7d2b\u8272\u6df1\u6d45\u5728\u7279\u5b9a\u6ce2\u957f\u4e0b\u8fdb\u884c\u6bd4\u8272\u6d4b\u5b9a\u6837\u54c1\u4e2d\u6c28\u57fa\u9178\u7684\u542b\u91cf\u3002\u831a\u4e09\u916e\u8fd8\u53ef\u7528\u6765\u76d1\u6d4b\u56fa\u76f8\u80bd\u5408\u6210\u4e2d\u7684\u8131\u4fdd\u62a4\u8fc7\u7a0b\uff08Kaiser\u6d4b\u8bd5\uff09\uff1a\u80bd\u94fe\u7684\u78b3\u7aef\u4e0e\u56fa\u76f8\u57fa\u8d28\u8fde\u63a5\u540e\u5229\u7528\u6c2e\u7aef\u6269\u5c55\u80bd\u94fe\uff0c\u5f53\u8131\u53bb\u6c2e\u539f\u5b50\u4e0a\u7684\u4fdd\u62a4\u540e\uff0c\u831a\u4e09\u916e\u6d4b\u8bd5\u5448\u84dd\u8272\uff0c\u6b64\u5916\u6c28\u57fa\u9178\u6b8b\u57fa\u662f\u5728\u6c2e\u7aef\u88ab\u4fdd\u62a4\u7684\u60c5\u51b5\u4e0b\u63a5\u5165\u80bd\u94fe\u7684\uff0c\u56e0\u6b64\u5982\u679c\u4e0b\u4e00\u4e2a\u6c28\u57fa\u9178\u6b8b\u57fa\u6210\u529f\u8fde\u63a5\u5230\u80bd\u94fe\uff0c\u831a\u4e09\u916e\u6d4b\u8bd5\u5219\u51fa\u73b0\u65e0\u8272\u6216\u9ec4\u8272\u3002 \u831a\u4e09\u916e\u663e\u8272\u540e\u7684\u6c28\u57fa\u9178\u548c\u6307\u7eb9 \u5bf9\u9057\u7559\u5728\u7269\u4f53\u8868\u9762\u7684\u6307\u7eb9\u8fdb\u884c\u63d0\u53d6\u548c\u9274\u5b9a\u662f\u4fa6\u7834\u6848\u4ef6\u7684\u91cd\u8981\u4f9d\u636e\uff0c\u76ee\u524d\u8bc6\u522b\u6f5c\u5728\u6307\u7eb9\u7684\u65b9\u6cd5\u5927\u4f53\u4e0a\u53ef\u5206\u4e3a\u7269\u7406\u548c\u5316\u5b66\u65b9\u6cd5\uff0c\u831a\u4e09\u916e\u5c31\u662f\u4e00\u79cd\u88ab\u5e7f\u6cdb\u4f7f\u7528\u7684\u5316\u5b66\u65b9\u6cd5\u3002\u7531\u4e8e\u6307\u7eb9\u4e2d\u542b\u6709\u6c28\u57fa\u9178\u7b49\u6210\u5206\uff0c\u4e0e\u831a\u4e09\u916e\u4f5c\u7528\u540e\u5c31\u4f1a\u663e\u8272\uff0c\u539f\u7406\u6b63\u662f\u4e0a\u6587\u63d0\u5230\u7684\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\u3002\u6307\u7eb9\u7684\u831a\u4e09\u916e\u663e\u8272\u6cd5\u65e9\u57281954\u5e74\u5c31\u88ab\u745e\u5178\u79d1\u5b66\u5bb6Oden\u63d0\u51fa\u548c\u4f7f\u7528\uff0c\u73b0\u9636\u6bb5\u4ecd\u662f\u5e38\u7528\u65b9\u6cd5\u4e4b\u4e00\uff0c\u7279\u522b\u662f\u5bf9\u7eb8\u5f20\u8868\u9762\u7684\u6307\u7eb9\u68c0\u51fa\u6548\u679c\u597d\uff0c\u4f46\u8be5\u65b9\u6cd5\u4e5f\u53d7\u9650\u4e8e\u6307\u7eb9\u4e2d\u6c28\u57fa\u9178\u7684\u542b\u91cf\uff0c\u6c28\u57fa\u9178\u542b\u91cf\u5982\u679c\u8fc7\u4f4e\u5219\u4f1a\u5f71\u54cd\u6700\u7ec8\u7684\u68c0\u51fa\u6548\u679c\u3002\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u831a\u4e09\u916e\u5728\u4f7f\u7528\u7684\u65f6\u5019\u8981\u907f\u514d\u63a5\u89e6\u76ae\u80a4\uff0c\u56e0\u4e3a\u76ae\u80a4\u8868\u9762\u542b\u6709\u5fae\u91cf\u6c28\u57fa\u9178\u6210\u5206\uff0c\u4e00\u65e6\u9047\u5230\u831a\u4e09\u916e\u540c\u6837\u4f1a\u88ab\u67d3\u8272\u3002 \u76ae\u80a4\u88ab\u831a\u4e09\u916e\u67d3\u8272 \u67d3\u6599\u4e1a\u7684\u9057\u61be 19\u4e16\u7eaa\u540e\u671f\uff0c\u8bb8\u591a\u5316\u5b66\u5bb6\u90fd\u5c06\u7cbe\u529b\u96c6\u4e2d\u5728\u5408\u6210\u67d3\u6599\u9886\u57df\uff0c\u7279\u522b\u662f\u5a01\u5ec9\u2022\u73c0\u91d1\uff08William Henry Perkin\uff09\u610f\u5916\u53d1\u73b0\u7684\u82ef\u80fa\u7d2b\u67d3\u6599\u6781\u5927\u4fc3\u8fdb\u4e86\u67d3\u6599\u5de5\u4e1a\u7684\u53d1\u5c55\u30021878\u5e74\uff0c\u963f\u9053\u592b\u00b7\u51af\u00b7\u62dc\u5c14\uff08Adolf von Baeyer\uff09\u6210\u529f\u5408\u6210\u4e86\u88ab\u79f0\u4e3a\u975b\u84dd\uff08Indigo\uff09\u7684\u67d3\u6599\uff0c\u4e5f\u56e0\u6b64\u83b7\u5f971905\u5e74\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u3002\u975b\u84dd\u4e0e\u4ea7\u751f\u7f57\u66fc\u7d2b\u7684\u5316\u5408\u7269\u7ed3\u6784\u76f8\u50cf\uff0c\u4f46\u5176\u5408\u6210\u6210\u672c\u66f4\u4f4e\u5ec9\u56e0\u6b64\u66f4\u5177\u5e02\u573a\u6f5c\u529b\uff0c\u7f57\u66fc\u7d2b\u5219\u56e0\u4e3a\u9ad8\u6210\u672c\u6700\u7ec8\u9057\u61be\u6ca1\u80fd\u6210\u4e3a\u5e94\u7528\u666e\u53ca\u7684\u67d3\u6599\u3002 \u82ef\u80fa\u7d2bB\u548c\u975b\u84dd\u7684\u7ed3\u6784 \u53c2\u8003\u8d44\u6599 [1] West, Robert. &#8220;Siegfried Ruhemann and the discovery of ninhydrin.&#8221; J. Chem. Educ. 1965, 42, 386-387. DOI: 10.1021\/ed042p386 [2] \u9648\u5fe0\u4e91.a-\u6c28\u57fa\u9178\u548c\u831a\u4e09\u916e\u663e\u8272\u53cd\u5e94\u673a\u7406[J].\u6559\u6750\u901a\u8baf, 1991 (02): 36-37. [3] \u9648\u8273, \u5f20\u6625\u9759, \u9ad8\u4e1c\u6885, \u6768\u5e06, \u97e9\u51ac\u96ea, \u725b\u5229. \u6f5c\u6307\u7eb9\u663e\u73b0\u65b9\u6cd5\u7814\u7a76\u8fdb\u5c55[J].\u5e94\u7528\u5316\u5b66, 2011, 28 (10): 1099-1107. 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