{"id":33358,"date":"2020-07-03T08:05:11","date_gmt":"2020-07-03T00:05:11","guid":{"rendered":"\/\/www.gsbet888.com\/?p=33358"},"modified":"2020-06-29T22:50:30","modified_gmt":"2020-06-29T14:50:30","slug":"%e7%be%b0%e5%9f%ba%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%83%af%e4%b8%99%e5%9f%ba%e5%8c%96%ef%bc%88%e4%b8%83%ef%bc%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/07\/%e7%be%b0%e5%9f%ba%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%83%af%e4%b8%99%e5%9f%ba%e5%8c%96%ef%bc%88%e4%b8%83%ef%bc%89.html","title":{"rendered":"\u7fb0\u57fa\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u5316\uff08\u4e03\uff09"},"content":{"rendered":"

\u672c\u6587\u4f5c\u8005\uff1a\u5b59\u82cf\u8d5f<\/p>\n

\u7b2c\u4e03\u90e8\u5206<\/strong> \u91d1\u5c5e\u50ac\u5316\u7684\u7845\u8bd5\u5242\u70ef\u4e19\u57fa\u5316\u548c\u5df4\u8c46\u57fa\u5316<\/strong><\/h4>\n

1. Lewis\u9178\u50ac\u5316\u7684\u7845\u8bd5\u5242\u548c\u919b\u7684\u70ef\u4e19\u57fa\u5316\u53cd\u5e94<\/strong><\/span><\/p>\n

\u6bd4\u8f83\u7ecf\u5178\u7684\u4e00\u79cdLewis\u9178\u50ac\u5316\u4f53\u7cfb\u662fHosomi-Sakirai\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff0c\u4f7f\u7528\u94f6\u76d0\u548c\u624b\u6027\u81a6\u914d\u4f53\u662f\u5176\u4e2d\u7acb\u4f53\u5316\u5b66\u4e13\u4e00\u6027\u8f83\u597d\u7684\u53cd\u5e94\u6761\u4ef6\uff1a<\/p>\n

\"\"<\/a><\/p>\n

\u53cd\u5e94\u6709\u4e24\u79cd\u53ef\u80fd\u7684\u8fc7\u7a0b\uff0c\u4e00\u79cd\u662fLewis\u9178\u6d3b\u5316\u919b\u4f7f\u5f97\u7845\u8bd5\u5242\u6613\u4e8e\u53d1\u751f\u4eb2\u6838\u8fdb\u653b\u518d\u53d1\u751f\u6d88\u9664\u5f97\u5230\u4ea7\u7269\uff0c\u53e6\u4e00\u79cd\u5219\u662f\u7ecf\u7406\u516d\u5143\u73af\u8fc7\u6e21\u6001\u5b9e\u73b0\u9ad8\u5ea6\u7acb\u4f53\u5316\u5b66\u9009\u62e9\u6027\uff1a<\/p>\n

\"\"<\/a><\/p>\n

\u540e\u6765\uff0cYamamoto\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u4e86\u4e00\u79cd\u624b\u6027\u81a6\u914d\u4f53\u548c\u70ef\u4e19\u57fa\u4e09\u6c2f\u7845\u70f7\u4f5c\u4e3a\u70ef\u4e19\u57fa\u5316\u8bd5\u5242\u7684\u53cd\u5e94\u4f53\u7cfb\uff1a[1]\n

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THF\u662f\u6700\u4f73\u7684\u53cd\u5e94\u6eb6\u5242\u3002\u56e0\u4e3a\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4f1a\u6709Cl–<\/sup>\u751f\u6210\uff0cZnI2<\/sub>\u53ef\u4ee5\u90e8\u5206\u6e05\u9664Cl–<\/sup>\uff0c\u800c\u4e0d\u662f\u4f5c\u4e3aLewis\u9178\u3002\u540c\u65f6\u5176\u4ed6\u7684\u70ef\u4e19\u57fa\u7845\u8bd5\u5242\u5728\u6b64\u53cd\u5e94\u4e2d\u7684\u6548\u679c\u4e0d\u597d\u3002<\/p>\n

(2) \u916e\u7684\u53cd\u5e94<\/p>\n

\u916e\u7684\u70ef\u4e19\u57fa\u5316\u4e2d\uff0cYamamoto\u8bfe\u9898\u7ec4\u5f00\u53d1\u8fc7\u4e00\u4e2aAgF\u548c(R<\/em>)-DIFLUORPHOS\u53cd\u5e94\u4f53\u7cfb\uff1a[2]\n

\"\"<\/a><\/p>\n

2. Lewis\u78b1\u50ac\u5316\u7684\u7845\u8bd5\u5242\u7684\u70ef\u4e19\u57fa\u5316\u548c\u5df4\u8c46\u57fa\u5316<\/strong><\/span><\/p>\n

(1) \u919b\u7684\u53cd\u5e94<\/p>\n

\u5728\u6b64\u7c7b\u53cd\u5e94\u4e2d\uff0c\u5e38\u7528\u7684Lewis\u78b1\u6709Denmark\u8bfe\u9898\u7ec4\u5f00\u53d1\u7684\u53cc\u78f7\u9170\u80fa\u7c7b\u914d\u4f53\uff1a<\/p>\n

\"\"<\/a><\/p>\n

\u53cd\u5e94\u7684\u7acb\u4f53\u5316\u5b66\u9009\u62e9\u6027\u53ef\u4ee5\u7528\u4ee5\u4e0b\u6a21\u578b\u89e3\u91ca\uff0c\u7845\u8bd5\u5242\u53ef\u4ee5\u4eceSi<\/em>\u9762\u8fdb\u653b\uff0c\u4f46\u662f\u6905\u5f0f\u8fc7\u6e21\u6001\u53ef\u4ee5\u4f7f\u5f97\u70ef\u4e19\u57fa\u7845\u8bd5\u5242\u4eceRe<\/em>\u9762\u8fdb\u653b\uff0c\u82ef\u7532\u919b\u7684\u4f4d\u7f6e\u5728\u5de6\u4fa7\u53ef\u4ee5\u907f\u514d\u548c\u5421\u54af\u73af\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u56e0\u6b64\u8fd9\u662f\u66f4\u52a0\u6709\u5229\u7684\u8fc7\u6e21\u6001\uff1a<\/p>\n

\"\"<\/a><\/p>\n

Yomamoto\u8bfe\u9898\u7ec4\u5f00\u53d1\u51fa\u4e00\u79cd\u7528\u4e8e\u82ef\u7532\u919b\u5df4\u8c46\u57fa\u5316\u7684\u7845\u8bd5\u5242\u548c\u624b\u6027\u78f7\u9170\u80fa\u4f5c\u4e3a\u914d\u4f53\u7684\u53cd\u5e94\u4f53\u7cfb\uff1a[4]\n

\"\"<\/a><\/p>\n

References <\/strong><\/h4>\n