J. Org. Chem. 1989<\/em>, 54, 3816-3819. Doi: 10.1021\/jo00277a014<\/li>\n<\/ul>\n\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u5b59\u82cf\u8d5f \u7b2c\u5341\u90e8\u5206 \u624b\u6027\u949b\u8bd5\u5242\u548c\u70ef\u4e19\u57fa\u5316\u5728\u5168\u5408\u6210\u4e2d\u7684\u5e94\u7528 1. \u624b\u6027\u949b\u8bd5\u5242\u7684\u70ef\u4e19\u57fa\u5316\u548c\u5df4\u8c46\u57fa\u5316[1] \u5e38\u7528\u7684\u624b\u6027\u949b\u8bd5\u5242\u662f\u4ece\u624b\u6027\u4e8c\u9187\u5236\u5907\u7684\uff1a \u5df4\u8c46\u57fa\u5316\u53cd\u5e94\u4e2d\u4e00\u822c(E)-\u5df4\u8c46\u57fa\u5f97\u5230anti\u4ea7\u7269\uff0c(Z)-\u5df4\u8c46\u57fa\u5f97\u5230syn\u4ea7\u7269\uff1a \u6b64\u5916\uff0c\u7cd6\u7684\u884d\u751f\u7269\u4e5f\u53ef\u4f5c\u4e3a\u949b\u8bd5\u5242\u4e2d\u7684\u624b\u6027\u914d\u4f53\uff1a 2. \u5728\u5168\u5408\u6210\u4e2d\u7684\u5e94\u7528 (1) \u5728Fostriecin\u7684\u5168\u5408\u6210\u4e2d\uff0c\u7845\u8bd5\u5242\u7684\u70ef\u4e19\u57fa\u5316\u662f\u5173\u952e\u6b65\u9aa4\u4e4b\u4e00\uff0c\u6b64\u5916\u4f5c\u8005\u8fd8\u662f\u7528\u4e86Ag\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u5316\uff0c\u4f46\u662f\u7ed3\u679c\u4e0d\u7406\u60f3\uff1a[2, 3] (2) \u5728ctytocaryol A\u7684\u5168\u5408\u6210\u4e2d\uff0c\u4f7f\u7528\u4e86\u4e24\u6b21Krische\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff0c\u4ee5\u6784\u7b51\u4e24\u4e2a\u7247\u6bb5\uff1a[4] (3) \u4e0d\u9971\u548c\u919b\u7684\u53cd\u5e94\uff1a[5] (4) \u5728manoalide\u7684\u5408\u6210\u4e2d\u4f7f\u7528\u8054\u70ef\u9521\u8bd5\u5242\u8fdb\u884c\u7094\u4e19\u57fa\u5316\u53cd\u5e94\uff0c\u4f46\u662f\u4e3a\u4e86\u5f97\u5230\u9ad8e.e.\u503c\u9700\u8981\u5f88\u957f\u7684\u53cd\u5e94\u65f6\u95f4\u548c\u5f88\u4f4e\u7684\u53cd\u5e94\u6e29\u5ea6\uff1a[6] (5) Keck\u70ef\u4e19\u57fa\u5316\u7684\u5e94\u7528\uff1a[7] (6) \u5728Krische\u7ec4\u62a5\u9053\u7684roxaticin\u7684\u5168\u5408\u6210\u4e2d\uff0c\u4f7f\u7528\u4e86\u8fde\u7eed\u7684\u70ef\u4e19\u57fa\u5316\u4ee5\u6784\u7b51\u591a\u7acb\u4f53\u5316\u5b66\u4e2d\u5fc3\u7684\u94fe\u72b6\u591a\u9187\u884d\u751f\u7269\u9aa8\u67b6\uff1a[8] References [1] J. Am. Chem. Soc. 1992, 114, 7, 2321-2336. Doi: 10.1021\/ja00033a005 [2] Org. Lett. 2003, 5, 733-736. Doi: 10.1021\/ol027528o [3] J. Am. Chem. Soc. 2005, 127, 17111-17117. Doi: 10.1021\/ja0562043 [4] Angew. Chem. Int. Ed.. 2016, 55, 5049 \u20135052. Doi: 10.1002\/anie.201600591 [5] Org. Lett. 2005, 7, 2153-2156. Doi: 10.1021\/ol050512o [6] J. Org. Chem. 2003, 68, 4008-4013. Doi: 10.1021\/jo0268097 [7] Tetrahedron Lett. 2004, 45, 9299. Doi: 1016\/j.tetlet.2004.10.059 [8] J. Org. Chem. 1989, 54, 3816-3819. 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