{"id":34265,"date":"2020-08-17T08:00:12","date_gmt":"2020-08-17T00:00:12","guid":{"rendered":"\/\/www.gsbet888.com\/?p=34265"},"modified":"2020-08-15T12:26:54","modified_gmt":"2020-08-15T04:26:54","slug":"%e9%87%91%e5%9f%8e-%e7%8e%b2-rei-kinjo","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/chemists\/2020\/08\/%e9%87%91%e5%9f%8e-%e7%8e%b2-rei-kinjo.html","title":{"rendered":"\u91d1\u57ce \u73b2 Rei Kinjo"},"content":{"rendered":"<p>\u672c\u6587\u7ffb\u8bd1\u81ea\u65e5\u6587\u7248\u5316\u5b66\u7a7a\u95f4\uff1a <a href=\"https:\/\/www.chem-station.com\/chemist-db\/2018\/02\/rei-kinjo.html\">\u91d1\u57ce \u73b2 Rei Kinjo<\/a>\u00a0 \u539f\u4f5c\u8005\uff1a\u5c71\u53e3 \u7814\u7a76\u5ba4<\/p>\n<p><strong>\u7ffb\u8bd1\uff1aAlberto Caeiro\uff0c\u6821\u5bf9\uff1aHu Hao<\/strong><\/p>\n<p><a href=\"https:\/\/www.ntu.edu.sg\/home\/rkinjo\/member.html\">\u91d1\u57ce \u73b2<\/a> (Kinjo Rei\uff0c1979\u5e7411\u670827\u65e5-)\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u526f\u6559\u6388\u3002\u56fe\u7247\uff1a<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202001891\">ACIE Author Profile<\/a>.<\/p>\n<h4><strong>\u7ecf\u5386<\/strong><\/h4>\n<ul>\n<li>2002 \u5b66\u58eb\uff0c\u7b51\u6ce2\u5927\u5b66<\/li>\n<li>2005 \u4fee\u58eb\uff0c\u7b51\u6ce2\u5927\u5b66 \uff08\u6307\u5bfc\u6559\u6388\uff1a<a href=\"http:\/\/www.chem.tsukuba.ac.jp\/sekiguch\/\">\u95a2\u53e3 \u7ae0<\/a>\uff09<\/li>\n<li>2005-2007 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u7279\u522b\u7814\u7a76\u5458 \uff08DC2\uff09<\/li>\n<li>2007\u535a\u58eb, \u7b51\u6ce2\u5927\u5b66 \uff08\u6307\u5bfc\u6559\u6388\uff1a\u95a2\u53e3 \u7ae0\uff09<\/li>\n<li>2007\u20132011 Postdoctoral Fellow, University of California, Riverside (Guy Bertrand \u6559\u6388)<\/li>\n<li>2008\u20132010 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u6d77\u5916\u7279\u522b\u7814\u7a76\u5458<\/li>\n<li>2011\u20132017 Assistant professor, \u5357\u6d0b\u7406\u5de5\u5927\u5b66<\/li>\n<li>2017\u2013\u73b0\u5728 Associate Professor\u5357\u6d0b\u7406\u5de5\u5927\u5b66<\/li>\n<\/ul>\n<h4><strong>\u83b7\u5956\u7ecf\u5386<\/strong><\/h4>\n<ul>\n<li>2005 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u7279\u522b\u7814\u7a76\u5458 \uff08DC2\uff09<\/li>\n<li>2008 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u6d77\u5916\u7279\u522b\u7814\u7a76\u5458<\/li>\n<li>2009 \u7b2c59\u56deNobel Laureates\u83b7\u5956\u8005\u4f1a\u8bae(\u5316\u5b66)\u53c2\u52a0\u8005<\/li>\n<li>2010 \u7b2c26\u56de\u4e95\u4e0a\u7814\u7a76\u5956\u52b1\u5956<\/li>\n<li>2011 The Elite Nanyang Assistant Professorship Award<\/li>\n<li>2012 \u6709\u673a\u5408\u6210\u5316\u5b66\u534f\u4f1a\u7814\u7a76\u4f01\u753b\u5956 \u5b87\u90e8\u8208\u7523\u7814\u7a76\u4f01\u753b\u8cde<\/li>\n<li>2014 SPMS Teaching Excellence Award 2014<\/li>\n<li>2015 Asian Core Program Lectureship Award 2015 (Korea)<\/li>\n<li>2015 Asian Core Program Lectureship Award 2015 (Japan)<\/li>\n<li>2016 SPMS Young Researcher Award 2016<\/li>\n<li>2016 Thieme Chemistry Journal Award 2016<\/li>\n<\/ul>\n<h4><strong>\u5de5\u4f5c\u4ecb\u7ecd<\/strong><\/h4>\n<p><span style=\"color: #0000ff;\"><strong>1. Novel molecules containing heteroatom synthesis<\/strong><\/span><\/p>\n<p>Kinjo\u6559\u6388\u81f4\u529b\u4e8e\u542b\u6709\u6742\u539f\u5b50\u5982\u787c\uff0c\u78f7\uff0c\u7845\u548c\u9517\u539f\u5b50\u7684\u65b0\u578b\u6742\u73af\u7684\u5408\u6210\uff0c\u8fd9\u4e9b\u5206\u5b50\u5927\u591a\u90fd\u5229\u7528\u5230\u5361\u5bbe\u5f3a\u914d\u4f4d\u6027\u7684\u7a33\u5b9a\u4f5c\u7528\u3002\u5728\u8fd9\u5176\u4e2d\uff0c\u542bN, P\u7684\u73af\u72b6\u5316\u5408\u72691,3,2,5-diazadiborinine<sup>[1a,b]<\/sup>\uff0c1,4,2-diazaborole<sup>[1c]<\/sup>\uff0c1,4,2,5-diazadiborinine<sup>[1d]<\/sup>\u90fd\u5177\u6709\u82b3\u9999\u6027\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-9.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34266 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-9.jpg\" alt=\"\" width=\"679\" height=\"626\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-9.jpg 679w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-9-300x277.jpg 300w\" sizes=\"(max-width: 679px) 100vw, 679px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Novel molecules containing heteroatom<\/p>\n<p>\u6b64\u5916\uff0c\u4ed6\u4eec\u8fd8\u5f00\u53d1\u4e86\u8bb8\u591a\u65b0\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u542b\u6709\u6742\u539f\u5b50\u53cc\u952e\uff08C=B\uff0cB=B\u53cc\u952e\uff09\u7684\u65b0\u578b\u5316\u5408\u7269\u3002\u5982\u4ece\u787c\u539f\u5b50\u4e09\u914d\u4f4d\u5316\u5408\u72691\u51fa\u53d1\uff0c\u5408\u6210\u4e86\u9633\u79bb\u5b50\u578b\u4e8c\u787c\u70f7<sup>[2a]<\/sup> (diborane dication) 6\u548cB, C, N\u5171\u8f6d\u5316\u5408\u7269azaborabutadiene<sup>[2b]<\/sup>\uff1b\u4ee5\u53ca\u4eceazaborole 2\u51fa\u53d1\uff0c\u5408\u6210\u4e86\u975e\u5bf9\u79f0diborene<sup>[3a]<\/sup>\uff08B=B \u53cc\u952e\uff09\uff0callenic diborene<sup>[3b]<\/sup>\uff08C=B, B=B \u53cc\u952e\uff09\u548cterminal diborene<sup>[3c]<\/sup>\uff08B=B \u53cc\u952e\uff09\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34267 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8.jpg\" alt=\"\" width=\"920\" height=\"565\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8.jpg 920w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8-300x184.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8-680x418.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8-768x472.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-8-233x144.jpg 233w\" sizes=\"(max-width: 920px) 100vw, 920px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">New methodologies for molecular containing heteroatom double bonds<\/p>\n<p><span style=\"color: #0000ff;\"><strong>2. Metal-free catalysis with main group molecules<\/strong><\/span><\/p>\n<p>Kinjo\u6559\u6388\u5229\u7528\u5176\u5408\u6210\u542b\u78f7\u6742\u73af\u5316\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5408\u6210\u4e86\u51e0\u79cd\u7528\u4f5c\u5de5\u4e1a\u50ac\u5316\u5242\u7684\u4ea7\u7269\u3002\u5982\u5421\u5576\u8fd8\u539f\u5f97\u5230NADP\u7c7b\u4f3c\u7269<sup>[4]<\/sup>\uff1b\u6c28\u7684\u9170\u5316\u53cd\u5e94\u5f97\u5230\u7532\u9170\u80fa<sup>[5]<\/sup>\uff1b\u7fb0\u57fa\u7684\u6c22\u787c\u5316<sup>[6]<\/sup>\uff1b\u5076\u6c2e\u5316\u7269<sup>[7]<\/sup>\u548c\u03b1,\u03b2-\u4e0d\u9971\u548c\u916f<sup>[8]<\/sup>\u7684\u6c22\u5316\u7b49\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-8.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34268 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-8.jpg\" alt=\"\" width=\"281\" height=\"135\" \/><\/a><\/p>\n<p style=\"text-align: center;\">P-containing catalysis<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-7.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34269 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-7.jpg\" alt=\"\" width=\"546\" height=\"554\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-7.jpg 546w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-7-296x300.jpg 296w\" sizes=\"(max-width: 546px) 100vw, 546px\" \/><\/a><\/p>\n<p style=\"text-align: center;\">Reaction catalyzed phosphorus catalyst<\/p>\n<h4><strong>\u8bc4\u8bba\u53ca\u5176\u4ed6<\/strong><\/h4>\n<ol>\n<li>\u5728\u8bfb\u535a\u671f\u95f4\uff0cKinjo\u6559\u6388\u9996\u6b21\u5408\u6210\u5e76\u5206\u79bb\u4e86Disilin\uff08Si-Si\u4e09\u952e\uff09\uff0c\u5728\u56fd\u9645\u4e0a\u5f15\u8d77\u5f88\u5927\u7684\u53cd\u54cd\u3002(<em>Science<\/em> <strong>2004<\/strong>, <em>305<\/em>, 1755. <a href=\"https:\/\/science.sciencemag.org\/content\/305\/5691\/1755\">DOI:1126\/science.1102209<\/a>)<\/li>\n<li>\u9996\u6b21\u5408\u6210\u5f97\u5230Disilin\u65f6\u6ca1\u6709\u53ca\u65f6\u62a5\u9053\u7ed9\u5bfc\u5e08\uff0c\u60f3\u7740\u7ec4\u4f1a\u4e0a\u62a5\u544a\u4f1a\u6536\u5230\u5927\u5927\u7684\u8d5e\u8d4f\uff0c\u8c01\u77e5\u9053\u5f97\u5230\u7684\u5374\u662f\u5bfc\u5e08\u7684\u8d23\u5907\u3002\u7b11\uff1a\uff09<\/li>\n<li>\u57282003\u5e74\u65e5\u672c\u5316\u5b66\u4f1a\u5e74\u4f1a\u4e0a\uff0c\u4ed6\u7533\u8bf7\u4e86\u4e00\u4e2a\u4e0d\u540c\u4e3b\u9898\u7684\u8bb2\u5ea7\uff0c\u4e34\u65f6\u66f4\u6539\u4e86\u6f14\u8bb2\u5185\u5bb9\u5e76\u4f5c\u4e86\u6709\u5173Disilin\u7684\u4ecb\u7ecd\u3002\u8be5\u573a\u62a5\u9053\u53d7\u5230\u5927\u5bb6\u7684\u6ce8\u76ee\u3002<\/li>\n<li>\u5728\u4ed6\u521a\u5f00\u59cb\u81ea\u5df1\u7684\u5b9e\u9a8c\u5ba4\u65f6\uff0c\u65b0\u52a0\u5761\u7684\u6f6e\u6e7f\u5929\u6c14\u4f7f\u5f97\u5b9e\u9a8c\u5ba4\u7684\u836f\u54c1\u7ecf\u5e38\u574f\u6389\u3002<\/li>\n<li>\u6765\u81ea\u51b2\u7ef3\u7684Kinjo\u6559\u6388\u5c0f\u65f6\u5019\u4ece\u7236\u4eb2\u90a3\u91cc\u5b66\u5230\u4e86\u4e09\u5473\u7ebf\u3002\u5927\u5b66\u671f\u95f4\uff0c\u4ed6\u662f\u51b2\u7ef3\u53bf\u4f1a\u7684\u6210\u5458\uff0c\u5e38\u5e74\u5728\u5b66\u6821\u5b66\u9662\u796d\u91cc\u4f5c\u4e3aace\u6f14\u5531\u5504\u3044\u624b\uff08\u51b2\u7ef3\u53bf\u4f20\u7edf\u8868\u6f14\u827a\u672f\uff09\u3002<\/li>\n<\/ol>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] a. Kinjo, R. <em>Nat. Commun.<\/em> <strong>2015<\/strong>, <em>6<\/em>, 7340. <a href=\"https:\/\/www.nature.com\/articles\/ncomms8340\">DOI: 10.1038\/ncomms8340<\/a>; b. Kinjo, R. <em>Chem. Sci. <\/em><strong>2015<\/strong>, <em>6<\/em>, 7150. <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2015\/SC\/C5SC03174E#!divAbstract\">DOI: 10.1039\/c5sc03174e<\/a>; c. Kinjo, R. <em>J. Am. Chem. Soc.<\/em> <strong>2015<\/strong>, <em>137<\/em>, 11274. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5b07823\">DOI: 10.1021\/jacs.5b07823<\/a>; d. Kinjo, R.<em> Nat. Commun.<\/em> <strong>2016<\/strong>, <em>7<\/em>, 11871. <a href=\"https:\/\/www.nature.com\/articles\/ncomms11871\">DOI: 10.1038\/ncomms11871<\/a>.<\/li>\n<li>[2] a. Kinjo, R. <em>J. Am. Chem. Soc.<\/em> <strong>2016<\/strong>, <em>138<\/em>, 8623. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6b04858\">DOI: 10.1021\/jacs.6b04858<\/a>; b. Kinjo, R. <em>Angew. Chem. Int. Ed.<\/em> <strong>2016<\/strong>, <em>55<\/em>, 14718. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201608994\">DOI: 10.1002\/anie.201608994<\/a>.<\/li>\n<li>[3] a. Kinjo, R.<em> J. Am. Chem. Soc.<\/em> <strong>2017<\/strong>, <em>139<\/em>, 5047. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b02251\">DOI: 10.1021\/jacs.7b02251<\/a>; b. Kinjo, R. <em>Angew. Chem. Int. Ed.<\/em> <strong>2017<\/strong>, <em>56<\/em>, 9829. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201704887\">DOI: 10.1002\/anie.201704887<\/a>; c. Kinjo, R. <em>J. Am. Chem. Soc.<\/em> <strong>2018<\/strong>, <em>140<\/em>, 1255. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201704887\">DOI: 10.1021\/jacs.7b13068<\/a>.<\/li>\n<li>[4] Kinjo R. <em>J. Am. Chem. Soc.<\/em> <strong>2018<\/strong>, <em>140<\/em>, 1255. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b09754\">DOI: 10.1021\/jacs.7b09754<\/a>;<\/li>\n<li>[5] Kinjo R. <em>Angew. Chem. Int. Ed.<\/em> <strong>2015<\/strong>, <em>54<\/em>, 12116. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201505244\">DOI: 10.1002\/anie.201505244<\/a>.<\/li>\n<li>[6] Kinjo R. <em>Angew. Chem. Int. Ed.<\/em> <strong>2015<\/strong>, <em>54<\/em>, 190. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201408760\">DOI: 10.1002\/anie.201408760<\/a>.<\/li>\n<li>[7] Kinjo R. <em>Angew. Chem. Int. Ed<\/em>. <strong>2014<\/strong>, <em>53<\/em>, 3342. <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201400099\">DOI: 10.1002\/anie.201400099<\/a>.<\/li>\n<li>[8] Kinjo R. <em>ACS Catal.<\/em> <strong>2018<\/strong>, <em>7<\/em>, 5814. <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.7b01338\">DOI: 10.1021\/acscatal.7b01338<\/a>.<\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u7ffb\u8bd1\u81ea\u65e5\u6587\u7248\u5316\u5b66\u7a7a\u95f4\uff1a \u91d1\u57ce \u73b2 Rei Kinjo\u00a0 \u539f\u4f5c\u8005\uff1a\u5c71\u53e3 \u7814\u7a76\u5ba4 \u7ffb\u8bd1\uff1aAlberto Caeiro\uff0c\u6821\u5bf9\uff1aHu Hao \u91d1\u57ce \u73b2 (Kinjo Rei\uff0c1979\u5e7411\u670827\u65e5-)\uff0c\u65e5\u672c\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u73b0\u4e3a\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u526f\u6559\u6388\u3002\u56fe\u7247\uff1aACIE Author Profile. \u7ecf\u5386 2002 \u5b66\u58eb\uff0c\u7b51\u6ce2\u5927\u5b66 2005 \u4fee\u58eb\uff0c\u7b51\u6ce2\u5927\u5b66 \uff08\u6307\u5bfc\u6559\u6388\uff1a\u95a2\u53e3 \u7ae0\uff09 2005-2007 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u7279\u522b\u7814\u7a76\u5458 \uff08DC2\uff09 2007\u535a\u58eb, \u7b51\u6ce2\u5927\u5b66 \uff08\u6307\u5bfc\u6559\u6388\uff1a\u95a2\u53e3 \u7ae0\uff09 2007\u20132011 Postdoctoral Fellow, University of California, Riverside (Guy Bertrand \u6559\u6388) 2008\u20132010 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u6d77\u5916\u7279\u522b\u7814\u7a76\u5458 2011\u20132017 Assistant professor, \u5357\u6d0b\u7406\u5de5\u5927\u5b66 2017\u2013\u73b0\u5728 Associate Professor\u5357\u6d0b\u7406\u5de5\u5927\u5b66 \u83b7\u5956\u7ecf\u5386 2005 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u7279\u522b\u7814\u7a76\u5458 \uff08DC2\uff09 2008 \u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u6d77\u5916\u7279\u522b\u7814\u7a76\u5458 2009 \u7b2c59\u56deNobel Laureates\u83b7\u5956\u8005\u4f1a\u8bae(\u5316\u5b66)\u53c2\u52a0\u8005 2010 \u7b2c26\u56de\u4e95\u4e0a\u7814\u7a76\u5956\u52b1\u5956 2011 The Elite Nanyang Assistant Professorship Award 2012 \u6709\u673a\u5408\u6210\u5316\u5b66\u534f\u4f1a\u7814\u7a76\u4f01\u753b\u5956 \u5b87\u90e8\u8208\u7523\u7814\u7a76\u4f01\u753b\u8cde 2014 SPMS Teaching Excellence Award 2014 2015 Asian Core Program Lectureship Award 2015 (Korea) 2015 Asian Core Program Lectureship Award 2015 (Japan) 2016 SPMS Young Researcher Award 2016 2016 Thieme Chemistry Journal Award 2016 \u5de5\u4f5c\u4ecb\u7ecd 1. 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