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\u672c\u6587\u4f5c\u8005\uff1a\u7af9\u60a0<\/p>\n

\u5bfc\u8a00<\/strong><\/h4>\n

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\u6b63\u6587<\/strong><\/h4>\n

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\u6781\u5316\u7684\u03c0\u952e\uff0c\u5982C=O\u3001C=N\u952e\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u518d\u65e9\u671f\u5c31\u5df2\u7ecf\u6709\u4e86\u8be6\u5c3d\u7684\u7814\u7a76\uff0c\u4f46C=C\u53cc\u952e\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u6848\u4f8b\u5f88\u5c11\uff0c\u5728\u65e9\u671f\u5408\u6210naproxen\u7684\u6848\u4f8b\u4e2d\uff0c\u66fe\u7528\u8fc7\u6e21\u6001\u91d1\u5c5eNi\u50ac\u5316\u3002\u4f46\u662f\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u80fd\u8fbe\u5230\u65e2\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u9614\uff0c\u53c8\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u53cd\u5e94\u8fd8\u662f\u51e4\u6bdb\u9e9f\u89d2\u3002<\/p>\n

\u7535\u5316\u5b66\u5408\u6210\u7684\u7814\u7a76\u5728\u8fd1\u51e0\u5e74\u5f02\u519b\u7a81\u8d77\u3002\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u50ac\u5316\u5242\u63a7\u5236\u81ea\u7531\u57fa\u52a0\u6210\u5230\u70ef\u70c3\u4e0a\uff0c\u53ef\u7528\u4e8e\u70ef\u70c3\u7684\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u3002\u6700\u8fd1Cornell University\u7684Song Lin\u6559\u6388\u7b49\u91c7\u7528\u4e86Co\/Cu\u53cc\u7535\u50ac\u5316\uff0c\u7acb\u4f53\u9009\u62e9\u6027\u8fdb\u884c\u70ef\u70c3\u7684\u6c22\u6c30\u5316\u53cd\u5e94\uff0c\u8bba\u6587\u53d1\u8868\u5728\u9876\u7ea7\u671f\u520aNature Chemistry\u4e0a\u3002<\/p>\n

Lu Song, Niankai Fu, Brian G. Ernst, Wai Hang Lee , Michael O. Frederick<\/p>\n

Robert A. DiStasio Jr. Song Lin.<\/p>\n

Dual electrocatalysis enables enantioselective hydrocyanation of conjugated alkenes<\/p>\n

Nature Chemistry. 2020, ASAP, https:\/\/doi.org\/10.1038\/s41557-020-0469-5<\/a><\/p><\/blockquote>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\u8868 1. \u53cd\u5e94\u5e95\u7269\u7684\u8303\u56f4<\/p>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005\uff1a\u7af9\u60a0 \u5bfc\u8a00 \u624b\u6027\u8148\u53ca\u884d\u751f\u7269\u5e7f\u6cdb\u5b58\u5728\u4e8e\u836f\u7269\u53ca\u6709\u751f\u7269\u6d3b\u6027\u7684\u5316\u5408\u7269\u4e2d\u3002\u7acb\u4f53\u9009\u62e9\u7684\u70ef\u70c3\u6c22\u6c30\u5316\u53cd\u5e94\u867d\u662f\u5408\u6210\u8fd9\u7c7b\u5316\u5408\u7269\u7684\u5e38\u89c4\u548c\u6709\u6548\u65b9\u5f0f\uff0c\u7136\u800c\u8fd9\u4e9b\u65b9\u6cd5\u666e\u904d\u53ef\u4ee5\u5e7f\u6cdb\u5e94\u7528\u3001\u9ad8\u5ea6\u517c\u5bb9\u5b98\u80fd\u56e2\u65b9\u6cd5\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u957f\u671f\u5b58\u5728\u7684\u96be\u9898\uff0c\u4f5c\u8005\u5229\u7528\u7535\u5316\u5b66\u7ec4\u5408\u4e24\u4e2a\u9633\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u5c06\u94b4\u4ecb\u5bfc\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\u548c\u94dc\u50ac\u5316\u7684\u81ea\u7531\u57fa\u6c30\u5316\u53cd\u5e94\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86\u70ef\u70c3\u9ad8\u5ea6\u9009\u62e9\u6027\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u3002\u7535\u5316\u5b66\u65e2\u4e0d\u4e0d\u9700\u8981\u5316\u5b66\u8ba1\u91cf\u7684\u6c27\u5316\u5242\uff0c\u8fd8\u53ef\u4ee5\u7cbe\u51c6\u63a7\u5236\u7535\u538b\uff0c\u4ee5\u4f18\u5316\u5316\u5b66\u9009\u62e9\u6027\u3002\u5e76\u4e14DFT\u5206\u6790\u53d1\u73b0\uff0c\u624b\u6027\u50ac\u5316\u5242\u7684\u5438\u5f15\u548c\u6392\u65a5\u4f5c\u7528\uff0c\u51b3\u5b9a\u4e86C-CN\u952e\u751f\u6210\u65f6\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002 \u6b63\u6587 \u70ef\u70c3\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u53ef\u4ee5\u5f15\u6c30\u57fa\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u5728\u751f\u4ea7\u805a\u5408\u7269\u3001\u519c\u7528\u5316\u5b66\u54c1\u3001\u5316\u5986\u54c1\u3001\u836f\u7269\u4e2d\u90fd\u6709\u91cd\u8981\u7684\u5b9e\u7528\u4ef7\u503c\uff0c\u56e0\u6b64\u5f00\u53d1\u5177\u6709\u5e7f\u6cdb\u7684\u5e95\u7269\u8303\u56f4\uff0c\u7cbe\u51c6\u7684\u5316\u5b66\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u70ef\u70c3\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u5177\u6709\u5341\u5206\u91cd\u8981\u610f\u4e49\u3002 \u56fe1a. \u533b\u836f\u548c\u519c\u4e1a\u5316\u5b66\u54c1\u4e2d\u7684\u82b3\u9999\u57fa\u4e19\u8148\u884d\u751f\u7269 \u6781\u5316\u7684\u03c0\u952e\uff0c\u5982C=O\u3001C=N\u952e\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u518d\u65e9\u671f\u5c31\u5df2\u7ecf\u6709\u4e86\u8be6\u5c3d\u7684\u7814\u7a76\uff0c\u4f46C=C\u53cc\u952e\u7684\u6c22\u6c30\u5316\u53cd\u5e94\u6848\u4f8b\u5f88\u5c11\uff0c\u5728\u65e9\u671f\u5408\u6210naproxen\u7684\u6848\u4f8b\u4e2d\uff0c\u66fe\u7528\u8fc7\u6e21\u6001\u91d1\u5c5eNi\u50ac\u5316\u3002\u4f46\u662f\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u80fd\u8fbe\u5230\u65e2\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u9614\uff0c\u53c8\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u5ea6\u7acb\u4f53\u9009\u62e9\u6027\u7684\u53cd\u5e94\u8fd8\u662f\u51e4\u6bdb\u9e9f\u89d2\u3002 \u7535\u5316\u5b66\u5408\u6210\u7684\u7814\u7a76\u5728\u8fd1\u51e0\u5e74\u5f02\u519b\u7a81\u8d77\u3002\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u81ea\u7531\u57fa\uff0c\u50ac\u5316\u5242\u63a7\u5236\u81ea\u7531\u57fa\u52a0\u6210\u5230\u70ef\u70c3\u4e0a\uff0c\u53ef\u7528\u4e8e\u70ef\u70c3\u7684\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u3002\u6700\u8fd1Cornell University\u7684Song Lin\u6559\u6388\u7b49\u91c7\u7528\u4e86Co\/Cu\u53cc\u7535\u50ac\u5316\uff0c\u7acb\u4f53\u9009\u62e9\u6027\u8fdb\u884c\u70ef\u70c3\u7684\u6c22\u6c30\u5316\u53cd\u5e94\uff0c\u8bba\u6587\u53d1\u8868\u5728\u9876\u7ea7\u671f\u520aNature Chemistry\u4e0a\u3002 Lu Song, Niankai Fu, Brian G. Ernst, Wai Hang Lee , Michael O. Frederick Robert A. DiStasio Jr. Song Lin. 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