{"id":34655,"date":"2020-08-22T08:05:22","date_gmt":"2020-08-22T00:05:22","guid":{"rendered":"\/\/www.gsbet888.com\/?p=34655"},"modified":"2020-08-19T13:28:54","modified_gmt":"2020-08-19T05:28:54","slug":"yonemitsu%e4%b8%89%e7%bb%84%e5%88%86%e7%bc%a9%e5%90%88%ef%bc%88%e4%ba%8c%ef%bc%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/08\/yonemitsu%e4%b8%89%e7%bb%84%e5%88%86%e7%bc%a9%e5%90%88%ef%bc%88%e4%ba%8c%ef%bc%89.html","title":{"rendered":"Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\uff08\u4e8c\uff09"},"content":{"rendered":"<p>\u4e0a\u4e00\u671f\u5c0f\u7f16\u4ecb\u7ecd\u4e86\u7531\u65e5\u672cHokkaido\u5927\u5b66\u836f\u5b66\u90e8 (Faculty of Pharmaceutical Sciences, Hokkaido University, \u5317\u6d77\u9053\u5927\u5b66\u85ac\u5b66\u90e8)\u7684Yonemitsu (\u7c73\u5149 \u5bb0, Yonemitsu Osamu)\u7814\u7a76\u5ba4\u53d1\u5c55\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66<sup>[1]<\/sup>\u3002\u8be5\u65b9\u6cd5\u5b66\u4e3a\u5404\u7c7b\u4eb2\u6838\u6027\u6742\u73af\u5316\u5408\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\u5b98\u80fd\u56e2\u5316\u5f00\u8f9f\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u90e8\u5206\u5e95\u7269\uff0c\u53ef\u80fd\u9700\u8981\u91c7\u7528\u5177\u6709\u8f83\u5f3a\u6bd2\u6027\u4e0e\u8150\u8680\u6027\u7684TiCl<sub>4<\/sub>\u8bd5\u5242\u4ee5\u53ca\u5177\u6709\u6f5c\u5728\u81f4\u764c\u6027\u7684DCM\u4f5c\u4e3a\u6eb6\u5242\uff0c\u9020\u6210\u4e00\u5b9a\u7a0b\u5ea6\u7684\u73af\u5883\u95ee\u9898\u3002\u6b64\u5916\uff0c\u8fd8\u6709\u90e8\u5206\u5e95\u7269\uff0c\u5fc5\u987b\u5bf9\u7b2c\u4e00\u6b65\u7684Kn\u00f6venagel\u7f29\u5408\u4ea7\u7269\u8fdb\u884c\u5206\u79bb\u7eaf\u5316\uff0c\u56e0\u6b64\uff0c\u5177\u6709\u8f83\u5dee\u7684pot-economy\u3002\u4ece\u800c\u4f7f\u8be5\u65b9\u6cd5\u5b66\u5728\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u53d7\u5230\u9650\u5236\u3002\u4e3a\u4f7f\u8be5\u53cd\u5e94\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u8bbe\u8ba1\u7406\u5ff5\uff0c\u63d0\u9ad8\u53cd\u5e94\u7684pot-economy\uff0c\u8fdb\u800c\u66f4\u597d\u5730\u9002\u5e94\u5de5\u4e1a\u751f\u4ea7\uff0c\u8fd1\u671f\uff0c\u8bf8\u591a\u8bfe\u9898\u7ec4\u5bf9Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66\u6240\u91c7\u7528\u7684\u7684\u50ac\u5316\u5242\u3001\u6eb6\u5242\u7b49\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4e86\u8fdb\u4e00\u6b65\u6539\u8fdb\u3002\u672c\u671f\u5c0f\u7f16\u5c06\u5bf9Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66\u7684\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\u8fdb\u884c\u8be6\u7ec6\u4ecb\u7ecd\u3002<\/p>\n<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>2014\u5e74\uff0cA. Tolomelli\u5c0f\u7ec4\u53d1\u73b0\u5728\u5fae\u6ce2\u8f90\u5c04\u6761\u4ef6\u4e0b\uff0c\u91c7\u7528\u50ac\u5316\u91cf\u7684\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4fc3\u8fdb\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u53ef\u4ee5\u4f7f\u50ac\u5316\u5242\u7528\u91cf\u8fdb\u4e00\u6b65\u964d\u4f4e\uff0c\u5e76\u6781\u5927\u7f29\u77ed\u4e86\u53cd\u5e94\u65f6\u95f4 (\u9488\u5bf9\u7b2c\u4e00\u6b65\u7684Kn\u00f6venagel\u7f29\u5408)\u3002\u540c\u65f6\uff0c\u53ef\u4ee5\u907f\u514dKn\u00f6venagel\u4e2d\u95f4\u4f53\u7684\u5206\u79bb\u4e0e\u7eaf\u5316\uff0c\u5177\u6709\u826f\u597d\u7684pot-economy<sup>[2]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34656 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3.png\" alt=\"\" width=\"1310\" height=\"391\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3.png 1310w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3-300x90.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3-680x203.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-3-768x229.png 768w\" sizes=\"(max-width: 1310px) 100vw, 1310px\" \/><\/a><\/p>\n<p>\u4e0e\u6b64\u540c\u65f6\uff0cA. Renzetti\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7L-proline\u4e0e\u4e09\u6c1f\u7532\u78fa\u9178\u94d5\u50ac\u5316\u4f53\u7cfb\u4fc3\u8fdb\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u540c\u6837\u53ef\u4ee5\u83b7\u5f97\u4f18\u826f\u7684\u6536\u7387\u4e0e\u8f83\u9ad8\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027<sup>[3]<\/sup>\u3002\u540c\u65f6\uff0c\u907f\u514d\u4e86\u8150\u8680\u6027\u8bd5\u5242TiCl<sub>4<\/sub>\u4e0eTiCl<sub>2<\/sub>(O<sup>i<\/sup>Pr)<sub>2<\/sub>\u7684\u4f7f\u7528\uff0c\u5bf9\u73af\u5883\u66f4\u52a0\u53cb\u597d<sup>[3]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34657 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3.png\" alt=\"\" width=\"1329\" height=\"662\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3.png 1329w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3-300x149.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3-680x339.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-3-768x383.png 768w\" sizes=\"(max-width: 1329px) 100vw, 1329px\" \/><\/a><\/p>\n<p>\u63a5\u4e0b\u6765\uff0cGu\u53d1\u73b0\uff0c\u91c7\u7528\u624b\u6027\u7684L-\u812f\u6c28\u9178\uff0c\u53ef\u4ee5\u5c06Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u4e00\u6b65\u6269\u5c55\u81f3\u567b\u5429\u3001\u6742\u73af\u82b3\u9999\u919b\u53ca\u5404\u7c7b\u73af\u72b6\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\uff0c\u5e76\u83b7\u5f97\u8f83\u9ad8\u7684\u6536\u7387<sup>[4]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34658 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3.png\" alt=\"\" width=\"831\" height=\"1003\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3.png 831w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3-249x300.png 249w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3-680x821.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-3-768x927.png 768w\" sizes=\"(max-width: 831px) 100vw, 831px\" \/><\/a><\/p>\n<p>\u4e4b\u540e\uff0cY. He\u4e0eZ. Guan\u8fdb\u4e00\u6b65\u5c06L-\u812f\u6c28\u9178\u50ac\u5316\u7684\u6761\u4ef6\u5e94\u7528\u4e8e\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u7684\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u4ee5\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0e\u4f18\u826f\u7684\u6536\u7387\u83b7\u5f973-\u5432\u54da\u884d\u751f\u7269<sup>[5]<\/sup>\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u53d1\u73b0\u8be5\u53cd\u5e94\u6761\u4ef6\u5bf9\u4e8e\u5421\u54af\u4e0e\u4e09\u6c1f\u7532\u57fa\u82ef\u4e59\u916e\u540c\u6837\u9002\u7528\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34659 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3.png\" alt=\"\" width=\"915\" height=\"594\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3.png 915w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3-300x195.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3-680x441.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3-768x499.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-3-260x170.png 260w\" sizes=\"(max-width: 915px) 100vw, 915px\" \/><\/a><\/p>\n<p>2015\u5e74D. S. Rawat\u901a\u8fc7RGO (reduced graphene oxide)\/ZnO\u7eb3\u7c73\u7c92\u5b50\u5f02\u76f8\u50ac\u5316\u5242\uff0c\u987a\u5229\u5b8c\u6210\u6c34\u76f8\u6761\u4ef6\u4e0b\uff0c\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u6216\u6c30\u57fa\u4e59\u9178\u4e59\u916f\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[6]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34660 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3.png\" alt=\"\" width=\"1127\" height=\"676\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3.png 1127w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3-300x180.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3-680x408.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-3-768x461.png 768w\" sizes=\"(max-width: 1127px) 100vw, 1127px\" \/><\/a><\/p>\n<p>\u540c\u65f6\uff0cD. S. Rawat\u91c7\u7528\u65b0\u53d1\u5c55\u7684\u5f02\u76f8RS-HM (rectangular thin sheet hydromagnesite)\u50ac\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u5432\u54da\u3001\u919b\u53cadimedone\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u53cd\u5e94<sup>[6]<\/sup>\u3002\u7814\u7a76\u8868\u660e\uff0c\u91c7\u7528\u8be5\u50ac\u5316\u5242\u53c2\u4e0e\u7684\u7f29\u5408\u8fc7\u7a0b\u5177\u6709\u4f18\u826f\u7684\u4ea7\u7387\u4e0e\u539f\u5b50\u7ecf\u6d4e\u6027\uff0c\u53cd\u5e94\u5b8c\u6210\u540e\uff0c\u5904\u7406\u66f4\u52a0\u7b80\u4fbf\u6613\u884c\uff0c\u73af\u5883\u66f4\u4e3a\u53cb\u597d\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34661 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2.png\" alt=\"\" width=\"1081\" height=\"364\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2.png 1081w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2-300x101.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2-680x229.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6-2-768x259.png 768w\" sizes=\"(max-width: 1081px) 100vw, 1081px\" \/><\/a><\/p>\n<p>\u4e4b\u540e\uff0cD. S. Rawat\u5f00\u53d1\u51fa\u80fd\u591f\u6709\u6548\u5faa\u73af\u5229\u7528\u4e14\u53ef\u4ee5\u751f\u7269\u964d\u89e3\u7684\u79bb\u5b50\u6db2\u4f53\u6709\u673a\u50ac\u5316\u5242[TBA][Gly] (tetrabutylammonium glycinate)\uff0c\u987a\u5229\u5b8c\u6210\u5432\u54da\u4e0e\u82b3\u9999\u919b\u6216\u8102\u80aa\u919b\u53ca\u4e19\u4e8c\u8148\u4e4b\u95f4\u7684\u65e0\u6eb6\u5242Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[8]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34662 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2.png\" alt=\"\" width=\"1221\" height=\"971\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2.png 1221w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2-300x239.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2-680x541.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-2-768x611.png 768w\" sizes=\"(max-width: 1221px) 100vw, 1221px\" \/><\/a><\/p>\n<p>2017\u5e74\uff0cR. Tayebee\u7814\u7a76\u89c2\u5bdf\u5230\uff0c\u91c7\u7528\u5f02\u76f8\u7684\u65e0\u673a-\u6709\u673a\u6742\u5316\u7eb3\u7c73\u591a\u5b54\u50ac\u5316\u5242 (inorganic-organic hybrid nanoporous catalyst)\uff0c\u5373Keggin\u7ed3\u6784\u7684\u6742\u591a\u9178 (heteropolyacid Keggin structure) H<sub>5<\/sub>PW<sub>10<\/sub>V<sub>2<\/sub>O<sub>40<\/sub>@VO<sub>x<\/sub>\/SBA (Santa Barbara Amorphous, SBA\u4e3a\u9ad8\u7a33\u5b9a\u6027\u7684mesoporous silica sieve)-15-NH<sub>2<\/sub>, \u540c\u6837\u80fd\u591f\u6709\u6548\u5730\u5b8c\u6210\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u4e4b\u95f4\u7684\u65e0\u6eb6\u5242Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[9]<\/sup>\u3002\u540c\u65f6\uff0c\u8be5\u50ac\u5316\u5242\u80fd\u591f\u5faa\u73af\u4f7f\u7528\uff0c\u53cd\u5e94\u6761\u4ef6\u66f4\u52a0\u6e29\u548c\u4e14\u7ecf\u6d4e\u53cb\u597d\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34663 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2.png\" alt=\"\" width=\"1232\" height=\"250\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2.png 1232w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2-300x61.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2-680x138.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-2-768x156.png 768w\" sizes=\"(max-width: 1232px) 100vw, 1232px\" \/><\/a><\/p>\n<p>\u540c\u65f6\uff0cS. Mozumdar\u5c06\u65b0\u5408\u6210\u7684\u5f02\u76f8GO (graphene oxide)IL-NH<sub>2<\/sub>\u50ac\u5316\u5242\u6210\u529f\u5e94\u7528\u4e8e\u5432\u54da\u4e0e\u82b3\u9999\u919b\u6216\u6742\u73af\u82b3\u9999\u919b\u53cadimedone\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[10]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34664 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2.png\" alt=\"\" width=\"1205\" height=\"349\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2.png 1205w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2-300x87.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2-680x197.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/9-2-768x222.png 768w\" sizes=\"(max-width: 1205px) 100vw, 1205px\" \/><\/a><\/p>\n<p>\u968f\u540e\uff0cC. Lv\u53d1\u73b0\uff0c\u91c7\u7528\u7518\u6cb9\/\u6c34\u4f53\u7cfb\uff0c\u5728\u8d85\u58f0\u6ce2\u8f90\u5c04\u6761\u4ef6\u4e0b\uff0c\u540c\u6837\u80fd\u591f\u6709\u6548\u5730\u5b9e\u73b0\u5432\u54da\u4e0e\u919b\u53caMeldrum\u9178\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u65e0\u9700\u4f7f\u7528\u50ac\u5316\u5242\uff0c\u66f4\u52a0\u7b80\u4fbf\u5b9e\u7528\u3002\u540c\u65f6\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u5e94\u7528\u8303\u56f4\u53ca\u4e2d\u7b49\u81f3\u4f18\u826f\u7684\u53cd\u5e94\u6536\u7387<sup>[11]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34665 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10.png\" alt=\"\" width=\"1214\" height=\"352\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10.png 1214w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10-300x87.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10-680x197.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/10-768x223.png 768w\" sizes=\"(max-width: 1214px) 100vw, 1214px\" \/><\/a><\/p>\n<p>2018\u5e74\uff0cA. Beatriz\u8fdb\u4e00\u6b65\u53d1\u73b0\uff0c\u901a\u8fc7\u65b0\u53d1\u5c55\u7684Cu (I)\u50ac\u5316\u5242\uff0c\u80fd\u591f\u66f4\u4e3a\u5feb\u901f\u5730\u5728\u6c34\u76f8\u73af\u5883\u4e2d\u5b8c\u6210\u82b3\u9999\u919b\u4e0e\u5432\u54da\u53ca\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[12]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34666 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11.png\" alt=\"\" width=\"901\" height=\"280\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11.png 901w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11-300x93.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11-680x211.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/11-768x239.png 768w\" sizes=\"(max-width: 901px) 100vw, 901px\" \/><\/a><\/p>\n<p>\u540c\u65f6\uff0cE. Sabzi\u5408\u6210\u51fa\u65b0\u7684\u5177\u6709tiny mesh-like\u7ed3\u6784\u7684\u03b2-CD.NS (\u03b2-cyclodextrin-based nanosponges) \u591a\u5b54\u4e09\u7ef4\u7eb3\u7c73\u50ac\u5316\u5242 (porous three-dimensional nanocatalyst)\uff0c\u5e76\u987a\u5229\u5b8c\u6210\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u5404\u7c7b\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408<sup>[13]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34667 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12.png\" alt=\"\" width=\"1152\" height=\"845\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12.png 1152w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12-300x220.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12-680x499.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/12-768x563.png 768w\" sizes=\"(max-width: 1152px) 100vw, 1152px\" \/><\/a><\/p>\n<p>2019\u5e74\uff0cP. N. Chatterjee\u901a\u8fc7\u8d85\u58f0\u8f90\u5c04\u53ca\u5bf9\u7532\u82ef\u78fa\u9178\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\uff0c\u8fdb\u4e00\u6b65\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5c55\u81f3\u5176\u5b83\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269<sup>[14]<\/sup>\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34668 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13.png\" alt=\"\" width=\"1113\" height=\"843\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13.png 1113w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13-300x227.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13-680x515.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/13-768x582.png 768w\" sizes=\"(max-width: 1113px) 100vw, 1113px\" \/><\/a><\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] Y. Oikawa, H. Hirasawa,\u00a0O. Yonemitsu, Tetrahedron Lett. 1978, 20, 1759. doi: <a href=\"https:\/\/doi.org\/10.1016\/0040-4039(78)80037-9\">10.1016\/0040-4039(78)80037-9<\/a>.<\/li>\n<li>[2] A. Viola, L. Ferrazzano, G. Martelli, S. Ancona, L. Gentilucci, A. Tolomelli, Tetrahedron 2014, 70, 6781.doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tet.2014.07.062\">10.1016\/j.tet.2014.07.062<\/a>.<\/li>\n<li>[3] A. Renzetti, E. Boffa, M. Colazzo, S. G\u00e9rard, J. Sapi, T. Chan, H. Nakazawa, C. Villani, A. Fontana, RSC Adv. 2014, 4, 47992. doi: <a href=\"https:\/\/pubsrsc.xilesou.top\/en\/content\/articlehtml\/2014\/ra\/c4ra08853k\">10.1039\/c4ra08853k.<\/a><\/li>\n<li>[4] M. Li, A. Taheri, M. Liu, S. Sun, Y. Gu, Adv. Synth. Catal. 2014, 356, 537. doi: <a href=\"https:\/\/doi.org\/10.1002\/adsc.201300790\">10.1002\/adsc.201300790<\/a>.<\/li>\n<li>[5] Y. He, J. Cao, R. Li, Y. Xiang, D. Yang, Z. Guan, Tetrahedron 2015, 71, 9299. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tet.2015.10.027\">10.1016\/j.tet.2015.10.027<\/a>.<\/li>\n<li>[6] U. C. Rajesh, J. Wang, S. Prescott, T. Tsuzuki, D. S. Rawat, ACS Sustain. Chem. Engin. 2015, 3, 9. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/sc500594w\">10.1021\/sc500594w.<\/a><\/li>\n<li>[7] U. C. Rajesh, V. S. Pavan, D. S. Rawat, ACS Sustain. Chem. Engin. 2015, 3, 1536. doi:<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acssuschemeng.5b00236\"> 10.1021\/acssuschemeng.5b00236.<\/a><\/li>\n<li>[8] U. C. Rajesh, R. Kholiya, A. Thakur, D. S. Rawat, Tetrahedron Lett. 2015, 56, 1790. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tetlet.2015.02.058\">10.1016\/j.tetlet.2015.02.058<\/a>.<\/li>\n<li>[9] N. M. Ghohe, R. Tayebee, M. M. Amini, A. Osatiashtiani, M. A. Isaacs, A. F. Lee, Tetrahedron 2017, 73, 5862. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tet.2017.08.030\">10.1016\/j.tet.2017.08.030<\/a>.<\/li>\n<li>[10] C. Garkoti, J. Shabir, P. Gupta, M. Sharma, S. Mozumdar, New J. Chem. 2017, 41, 15545. doi: <a href=\"https:\/\/doi.org\/10.1039\/C7NJ03450D\">10.1039\/C7NJ03450D<\/a>.<\/li>\n<li>[11] C. Lv, J. Wang, Y. Liu, W. Shan, Q. Sun, L. Shi, Res. Chem. Intermed. 2017, 43, 943. doi: <a href=\"https:\/\/doi.org\/10.1007\/s11164-016-2675-8\">10.1007\/s11164-016-2675-8<\/a>.<\/li>\n<li>[12] A. N. Prasad, F. C. Braga, R. da S. Lopes, G. A. Casagrande, D. P. de Lima, A. Beatriz, Synth. Commun. 2018, 48, 104. doi: <a href=\"https:\/\/doi.org\/10.1080\/00397911.2017.1394467\">10.1080\/00397911.2017.1394467<\/a>.<\/li>\n<li>[13] E. Sabzi, A. R. Kiasat, Cat. Lett. 2018, 148, 2654. doi: <a href=\"https:\/\/doi.org\/10.1007\/s10562-018-2484-3\">10.1007\/s10562-018-2484-3<\/a>.<\/li>\n<li>[14] D. Paul, A. Borah, S. Khatua,\u00a0P. N. Chatterjee. Asian J. Org. Chem. 2019, 8, 1870. doi: <a href=\"https:\/\/xs.scihub.ltd\/https:\/doi.org\/10.1002\/ajoc.201900352\">10.1002\/ajoc.201900352<\/a>.<\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><strong>\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4fc3\u8fdb\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[1]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34679 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4.png\" alt=\"\" width=\"1522\" height=\"479\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4.png 1522w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4-300x94.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4-680x214.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-4-768x242.png 768w\" sizes=\"(max-width: 1522px) 100vw, 1522px\" \/><\/a><\/p>\n<p><strong>\u4e09\u6c1f\u7532\u78fa\u9178\u94d5\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[2]-[5]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34669 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a.png\" alt=\"\" width=\"1519\" height=\"837\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a.png 1519w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a-300x165.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a-680x375.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2a-768x423.png 768w\" sizes=\"(max-width: 1519px) 100vw, 1519px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34670 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b.png\" alt=\"\" width=\"1521\" height=\"601\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b.png 1521w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b-300x119.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b-680x269.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2b-768x303.png 768w\" sizes=\"(max-width: 1521px) 100vw, 1521px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34671 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c.png\" alt=\"\" width=\"1156\" height=\"951\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c.png 1156w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c-300x247.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c-680x559.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2c-768x632.png 768w\" sizes=\"(max-width: 1156px) 100vw, 1156px\" \/><\/a><\/p>\n<p><strong>RGO\/ZnO<\/strong><strong>\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[6]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34672 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4.png\" alt=\"\" width=\"1233\" height=\"937\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4.png 1233w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4-300x228.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4-680x517.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-4-768x584.png 768w\" sizes=\"(max-width: 1233px) 100vw, 1233px\" \/><\/a><\/p>\n<p><strong>RS-HM<\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[7]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34673 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4.png\" alt=\"\" width=\"1299\" height=\"797\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4.png 1299w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4-300x184.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4-680x417.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4-768x471.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/4-4-233x144.png 233w\" sizes=\"(max-width: 1299px) 100vw, 1299px\" \/><\/a><\/p>\n<p><strong>H<sub>5<\/sub>PW<sub>10<\/sub>V<sub>2<\/sub>O<sub>40<\/sub>@VO<sub>x<\/sub>\/SBA-15-NH<sub>2<\/sub><\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[8]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34674 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4.png\" alt=\"\" width=\"1312\" height=\"929\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4.png 1312w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4-300x212.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4-680x481.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/5-4-768x544.png 768w\" sizes=\"(max-width: 1312px) 100vw, 1312px\" \/><\/a><\/p>\n<p><strong>[TBA][Gly]<\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[9]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34675 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a.png\" alt=\"\" width=\"1371\" height=\"595\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a.png 1371w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a-300x130.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a-680x295.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6a-768x333.png 768w\" sizes=\"(max-width: 1371px) 100vw, 1371px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34676 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b.png\" alt=\"\" width=\"1399\" height=\"906\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b.png 1399w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b-300x194.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b-680x440.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/6b-768x497.png 768w\" sizes=\"(max-width: 1399px) 100vw, 1399px\" \/><\/a><\/p>\n<p><strong>GO-IL-NH<sub>2<\/sub><\/strong><strong>\u5f02\u76f8\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[10]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34677 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3.png\" alt=\"\" width=\"1090\" height=\"942\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3.png 1090w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3-300x259.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3-680x588.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/7-3-768x664.png 768w\" sizes=\"(max-width: 1090px) 100vw, 1090px\" \/><\/a><\/p>\n<p><strong>Cu (PPh<sub>3<\/sub>)Cl<\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><strong><sup>[11]<\/sup><\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34678 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3.png\" alt=\"\" width=\"1303\" height=\"794\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3.png 1303w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3-300x183.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3-680x414.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/8-3-768x468.png 768w\" sizes=\"(max-width: 1303px) 100vw, 1303px\" \/><\/a><\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] D. A. Evans, K. R. Fandrick, H. Song, K. A. Scheidt, R. Xu, J. Am. Chem. Soc. 2007, 129, 10029. doi: <a href=\"https:\/\/doi.org\/10.1021\/ja072976i\">10.1021\/ja072976i<\/a>.<\/li>\n<li>[2] A. Renzetti, E. Boffa, M. Colazzo, S. G\u00e9rard, J. Sapi, T. Chan, H. Nakazawa, C. Villani, A. Fontana, RSC Adv. 2014, 4, 47992. doi: <a href=\"https:\/\/pubsrsc.xilesou.top\/en\/content\/articlehtml\/2014\/ra\/c4ra08853k\">10.1039\/c4ra08853k.<\/a><\/li>\n<li>[3] S. Caddick, K. Jenkins, Chem. Soc. Rev. 1996, 447. doi: <a href=\"https:\/\/doi.org\/10.1039\/CS9962500447\">10.1039\/CS9962500447<\/a>.<\/li>\n<li>[4] N. K. Dutt, S. Sur, S. Rahut, J. Inorg. Nucl. Chem. 1971, 33, 1717. doi: <a href=\"https:\/\/doi.org\/10.1016\/0022-1902(71)80608-5\">10.1016\/0022-1902(71)80608-5<\/a>.<\/li>\n<li>[5] G. F. Smith, Adv. Heterocycl. Chem., 1963, 18, 287. doi: <a href=\"https:\/\/doi.org\/10.1016\/S0065-2725(08)60752-7\">10.1016\/S0065-2725(08)60752-7<\/a>.<\/li>\n<li>[6] U. C. Rajesh, V. S. Pavan, D. S. Rawat, ACS Sustain. Chem. Engin. 2015, 3, 1536. doi:<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acssuschemeng.5b00236\"> 10.1021\/acssuschemeng.5b00236.<\/a><\/li>\n<li>[7] U. C. Rajesh, V. S. Pavan, D. S. Rawat, ACS Sustain. Chem. Engin. 2015, 3, 1536. doi:<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acssuschemeng.5b00236\"> 10.1021\/acssuschemeng.5b00236.<\/a><\/li>\n<li>[8] N. M. Ghohe, R. Tayebee, M. M. Amini, A. Osatiashtiani, M. A. Isaacs, A. F. Lee, Tetrahedron 2017, 73, 5862. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tet.2017.08.030\">10.1016\/j.tet.2017.08.030<\/a>.<\/li>\n<li>[9] U. C. Rajesh, R. Kholiya, A. Thakur, D. S. Rawat, Tetrahedron Lett. 2015, 56, 1790. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tetlet.2015.02.058\">10.1016\/j.tetlet.2015.02.058<\/a>.<\/li>\n<li>[10] C. Garkoti, J. Shabir, P. Gupta, M. Sharma, S. Mozumdar, New J. Chem. 2017, 41, 15545. doi: <a href=\"https:\/\/doi.org\/10.1039\/C7NJ03450D\">10.1039\/C7NJ03450D<\/a>.<\/li>\n<li>[11] A. N. Prasad, F. C. Braga, R. da S. Lopes, G. A. Casagrande, D. P. de Lima, A. Beatriz, Synth. Commun. 2018, 48, 104. doi: <a href=\"https:\/\/doi.org\/10.1080\/00397911.2017.1394467\">10.1080\/00397911.2017.1394467<\/a>.<\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u5432\u54da\u57fa\u53d6\u4ee3-2-\u5421\u54af\u70f7\u916e\u53ca\u5176\u73af\u72b6\u884d\u751f\u7269\u7684\u5408\u6210<sup>[1]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34680 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5.png\" alt=\"\" width=\"1374\" height=\"422\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5.png 1374w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5-300x92.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5-680x209.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/1-5-768x236.png 768w\" sizes=\"(max-width: 1374px) 100vw, 1374px\" \/><\/a><\/p>\n<p>3-\u53d6\u4ee3\u5432\u54da\u7684\u5408\u6210<sup>[2]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34681 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4.png\" alt=\"\" width=\"1271\" height=\"265\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4.png 1271w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4-300x63.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4-680x142.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/2-4-768x160.png 768w\" sizes=\"(max-width: 1271px) 100vw, 1271px\" \/><\/a><\/p>\n<p>\u5432\u54da\u57fa4H-\u8272\u70ef\u7684\u5408\u6210<sup>[3]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-34682 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5.png\" alt=\"\" width=\"1104\" height=\"286\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5.png 1104w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5-300x78.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5-680x176.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/08\/3-5-768x199.png 768w\" sizes=\"(max-width: 1104px) 100vw, 1104px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p><span style=\"color: #0000ff;\"><strong>\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4fc3\u8fdb\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5728\u5fae\u6ce2\u53cd\u5e94\u74f6\u4e2d\uff0c\u5c06\u4e19\u4e8c\u9178\u4e8c\u7532\u916f (1eq.)\u6216\u4e59\u9170\u4e59\u9178\u4e59\u916f (1eq.)\u3001\u919b (1eq.)\u4e0e\u54cc\u5576 (0.15 equiv)\u8fdb\u884c\u6df7\u5408\u3002\u4e4b\u540e\uff0c\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u5728250W\u5fae\u6ce2\u8f90\u5c04\u529f\u7387\u4e0b\uff0c\u6405\u62cc7 min\u30027min\u540e\uff0c\u5c06\u4e0a\u8ff0\u6df7\u5408\u7269\u51b7\u5374\u81f3\u5ba4\u6e29\uff0c\u5e76\u52a0\u5165\u9002\u91cf\u4e59\u8148\u8fdb\u884c\u7a00\u91ca\u3002\u968f\u540e\uff0c\u52a0\u5165\u5432\u54da(1eq.)\u4e0e\u4e09\u6c1f\u7532\u78fa\u9178\u94aa (0.1eq.)\u3002 \u7ee7\u7eed\u7ef4\u6301\u5728250W\u5fae\u6ce2\u8f90\u5c04\u529f\u7387\u4e0b\uff0c\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u6405\u62cc20 min\u3002 \u968f\u540e\uff0c\u518d\u5c06\u53cd\u5e94\u6df7\u5408\u7269\u51b7\u5374\u81f3\u5ba4\u6e29\uff0c\u5e76\u52a0\u5165\u6c34\u8fdb\u884c\u7a00\u91ca\uff0c\u968f\u540e\uff0c\u52a0\u5165\u4e59\u9178\u4e59\u916f\u8fdb\u884c\u8403\u53d6\u3002\u5c06\u5408\u5e76\u7684\u6709\u673a\u76f8\u901a\u8fc7\u65e0\u6c34\u786b\u9178\u94a0\u5e72\u71e5\u540e\uff0c\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u3002\u7c97\u4ea7\u7269\u901a\u8fc7\u7845\u80f6\u67f1\u8272\u8c31 (\u73af\u5df1\u70f7\/\u4e59\u9178\u4e59\u916f 9:1v\/v\u4f5c\u4e3a\u6d17\u8131\u5242)\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u4e09\u6c1f\u7532\u78fa\u9178\u94d5\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5728\u5ba4\u6e29\u53ca4 \u00c5\u5206\u5b50\u7b5b\u5b58\u5728\u4e0b\uff0c\u5c06L-\u812f\u6c28\u9178 (0.1 eq)\u6eb6\u4e8e\u9002\u91cf\u9187\u6eb6\u5242\u4e2d\u3002\u968f\u540e\u3002\u52a0\u5165\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269 (1 eq.)\u4e0e\u5f02\u4e19\u919b (1 eq.)\u3002\u5c06\u4e0a\u8ff0\u6df7\u5408\u7269\u5728\u5ba4\u6e29\u4e0b\u6405\u62cc24h\u540e\uff0c\u518d\u52a0\u5165\u5432\u54da (1 eq.)\u4e0e\u4e09\u6c1f\u7532\u78fa\u9178\u94d5 (0.1eq.)\u3002\u7ee7\u7eed\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u8fdb\u884c\u6405\u62cc\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u53cd\u5e94\u6df7\u5408\u7269\u901a\u8fc7\u7845\u85fb\u571f\u8fc7\u6ee4\uff0c\u9664\u53bb\u5206\u5b50\u7b5b\u3002\u518d\u5c06\u5408\u5e76\u7684\u6ee4\u6db2\u8fdb\u884c\u51cf\u538b\u6d53\u7f29\u540e\uff0c\u83b7\u5f97\u7c97\u4ea7\u7269\u3002\u6700\u540e\uff0c\u5c06\u7c97\u4ea7\u7269\u901a\u8fc7\u5feb\u901f\u7845\u80f6\u67f1\u8272\u8c31\u6216\u901a\u8fc7\u91cd\u7ed3\u6676\u8fdb\u884c\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>RGO\/ZnO<\/strong><strong>\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5411\u5706\u5e95\u70e7\u74f6\u4e2d\u52a0\u5165\u5432\u54da (1eq.)\u3001\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269 (1eq.)\u3001\u919b (1eq.)\u4e0eRGO\/ZnO\u50ac\u5316\u5242 (0.05eq.)\u53ca\u9002\u91cf\u6c34\u3002\u4e4b\u540e\uff0c\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u5728\u9002\u5b9c\u6e29\u5ea6\u4e0b (\u5ba4\u6e29\u621650 <sup>o<\/sup>C)\u8fdb\u884c\u6405\u62cc\uff0c\u5e76\u901a\u8fc7TLC\u76d1\u63a7\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u6c34\u5012\u51fa\uff0c\u518d\u52a0\u5165\u9002\u91cf\u4e59\u9187\u3002\u5e76\u901a\u8fc7\u79bb\u5fc3\u5206\u79bb\uff0c\u9664\u53bbRS-HM\/MgO\u50ac\u5316\u5242\u3002\u518d\u5c06\u5408\u5e76\u7684\u4e0a\u5c42\u4e59\u9187\u76f8\u901a\u8fc7\u65e0\u6c34\u786b\u9178\u94a0\u8fdb\u884c\u540e\uff0c\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u3002\u7c97\u4ea7\u7269\u901a\u8fc7\u91cd\u7ed3\u6676 (\u4e59\u919a\u6216\u6b63\u5df1\u70f7\/\u4e59\u9178\u4e59\u916f\u4f5c\u4e3a\u6eb6\u5242)\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>RS-HM<\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5411\u53cd\u5e94\u70e7\u74f6\u4e2d\u52a0\u5165\u5432\u54da (1eq.)\u3001dimedone (1eq.)\u3001\u919b (1eq.)\u4e0eRS-HM\u50ac\u5316\u5242 (0.01eq.)\u53ca\u9002\u91cf\u6c34\u3002\u4e4b\u540e\uff0c\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u572880 \u00b0C\u4e0b\u8fdb\u884c\u6405\u62cc\uff0c\u5e76\u901a\u8fc7TLC\u76d1\u63a7\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u6c34\u5012\u51fa\uff0c\u518d\u52a0\u5165\u9002\u91cf\u4e59\u9187\u3002\u5e76\u901a\u8fc7\u79bb\u5fc3\u5206\u79bb\uff0c\u9664\u53bbRS-HM\u50ac\u5316\u5242\u3002\u518d\u5c06\u5408\u5e76\u7684\u4e0a\u5c42\u4e59\u9187\u76f8\u901a\u8fc7\u65e0\u6c34\u786b\u9178\u9541\u5e72\u71e5\u540e\uff0c\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u3002\u7c97\u4ea7\u7269\u901a\u8fc7\u91cd\u7ed3\u6676 (\u4e59\u9187\u4f5c\u4e3a\u6eb6\u5242)\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>H<sub>5<\/sub>PW<sub>10<\/sub>V<sub>2<\/sub>O<sub>40<\/sub>@VO<sub>x<\/sub>\/SBA-15-NH<sub>2<\/sub><\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5c06H<sub>5<\/sub>PW<sub>10<\/sub>V<sub>2<\/sub>O<sub>40<\/sub>@VOx\/SBA-15-NH<sub>2 <\/sub>(0.1eq.) \u52a0\u5165\u81f3\u919b (1eq.)\u4e0e\u5432\u54da (1eq.)\u53ca\u4e19\u4e8c\u8148 (1.1 eq.)\u7684\u6df7\u5408\u7269\u4e2d\u3002\u5c06\u4e0a\u8ff0\u6df7\u5408\u7269\u572880 \u00b0C\u4e0b\u8fdb\u884c\u6405\u62cc\u3002\u5e76\u901a\u8fc7TLC (\u6b63\u5df1\u70f7\/\u4e59\u9178\u4e59\u916f 3:2v\/v\u4f5c\u4e3a\u5c55\u5f00\u5242)\u76d1\u63a7\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5411\u53cd\u5e94\u6df7\u5408\u7269\u4e2d\u52a0\u5165\u9002\u91cf\u70ed\u4e59\u9187\u6eb6\u5242\uff0c\u7ee7\u7eed\u6405\u62cc10 min\u3002\u5e76\u8fc5\u901f\u8fc7\u6ee4\uff0c\u9664\u53bbH<sub>5<\/sub>PW<sub>10<\/sub>V<sub>2<\/sub>O<sub>40<\/sub>@VOx\/SBA-15-NH<sub>2<\/sub>\u50ac\u5316\u5242\u3002\u4e4b\u540e\uff0c\u5c06\u6ee4\u6db2\u51b7\u5374\u81f35 \u00b0C\uff0c\u518d\u5c06\u6790\u51fa\u7684\u56fa\u4f53\u901a\u8fc7\u6b63\u5df1\u70f7\u8fdb\u884c\u8fc7\u6ee4\u6d17\u6da4\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>GO-IL-NH<sub>2<\/sub><\/strong><strong>\u5f02\u76f8\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5411\u5706\u5e95\u70e7\u74f6\u4e2d\u52a0\u5165\u5432\u54da (1eq.)\u3001dimedone (1eq.)\u3001\u919b (1eq.)\u4e0eGO-IL-NH<sub>2<\/sub>\u50ac\u5316\u5242 (0.01eq.)\u53ca\u9002\u91cf\u6c34\u3002\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u572850 <sup>o<\/sup>C\u4e0b\u8fdb\u884c\u6405\u62cc\uff0c\u5e76\u901a\u8fc7TLC\u76d1\u63a7\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u5c06\u6c34\u5012\u51fa\uff0c\u518d\u52a0\u5165\u9002\u91cf\u4e59\u9187\u3002\u5e76\u901a\u8fc7\u79bb\u5fc3\u5206\u79bb\uff0c\u9664\u53bbGO-IL-NH<sub>2<\/sub>\u50ac\u5316\u5242\u3002\u5c06\u5408\u5e76\u7684\u4e0a\u5c42\u4e59\u9187\u76f8\u901a\u8fc7\u65e0\u6c34\u786b\u9178\u94a0\u5e72\u71e5\u540e\uff0c\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u3002\u7c97\u4ea7\u7269\u901a\u8fc7\u91cd\u7ed3\u6676\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>Cu (PPh<sub>3<\/sub>)Cl<\/strong><strong>\u50ac\u5316\u7684<\/strong><strong>Yonemitsu<\/strong><strong>\u4e09\u7ec4\u5206\u7f29\u5408<\/strong><\/span><\/p>\n<p>\u5411\u53cd\u5e94\u70e7\u74f6\u4e2d\u52a0\u5165\u5432\u54da (1eq.)\u3001\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269 (1eq.)\u3001\u919b (1eq.)\u4e0eCu(PPh<sub>3<\/sub>)Cl\u50ac\u5316\u5242 (0.1eq.)\u53ca\u9002\u91cf\u6c34\u3002\u5c06\u4e0a\u8ff0\u53cd\u5e94\u6df7\u5408\u7269\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\u6405\u62cc\uff0c\u5e76\u901a\u8fc7TLC\u76d1\u63a7\uff0c\u76f4\u81f3\u53cd\u5e94\u7ed3\u675f\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u52a0\u5165\u4e59\u9178\u4e59\u916f\u8fdb\u884c\u8403\u53d6\u3002\u5c06\u5408\u5e76\u7684\u6709\u673a\u76f8\u91c7\u7528\u65e0\u6c34\u786b\u9178\u94a0\u5e72\u71e5\u540e\uff0c\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u3002\u7c97\u4ea7\u7269\u901a\u8fc7\u7845\u80f6\u67f1\u8272\u8c31 (\u6b63\u5df1\u70f7\/\u4e59\u9178\u4e59\u916f 9:1 v\/v\u4f5c\u4e3a\u6d17\u8131\u5242)\u5206\u79bb\u7eaf\u5316\uff0c\u83b7\u5f97\u76f8\u5e94\u7f29\u5408\u4ea7\u7269\u3002<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] M. Boisbrun, L. Jeannin, L. Toupet, J.-Y. Laronze, Eur. J. Org. Chem. 2000, 3051. doi: <a href=\"https:\/\/sci-hub.tw\/10.1002\/1099-0690%28200009%292000%3A17%3C3051%3A%3Aaid-ejoc3051%3E3.0.co%3B2-3\">10.1002\/1099-0690(200009)2000:17&lt;3051::aid-ejoc3051&gt;3.0.co;2-3. <\/a><\/li>\n<li>[2] A. Renzetti, E. Boffa, M. Colazzo, S. G\u00e9rard, J. Sapi, T. Chan, H. Nakazawa, C. Villani, A. Fontana, RSC Adv. 2014, 4, 47992. doi: <a href=\"https:\/\/pubsrsc.xilesou.top\/en\/content\/articlehtml\/2014\/ra\/c4ra08853k\">10.1039\/c4ra08853k.<\/a><\/li>\n<li>[3] U. C. Rajesh, R. Kholiya, A. Thakur, D. S. Rawat, Tetrahedron Lett. 2015, 56, 1790. doi: <a href=\"https:\/\/doi.org\/10.1016\/j.tetlet.2015.02.058\">10.1016\/j.tetlet.2015.02.058<\/a>.<\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u4e0a\u4e00\u671f\u5c0f\u7f16\u4ecb\u7ecd\u4e86\u7531\u65e5\u672cHokkaido\u5927\u5b66\u836f\u5b66\u90e8 (Faculty of Pharmaceutical Sciences, Hokkaido University, \u5317\u6d77\u9053\u5927\u5b66\u85ac\u5b66\u90e8)\u7684Yonemitsu (\u7c73\u5149 \u5bb0, Yonemitsu Osamu)\u7814\u7a76\u5ba4\u53d1\u5c55\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66[1]\u3002\u8be5\u65b9\u6cd5\u5b66\u4e3a\u5404\u7c7b\u4eb2\u6838\u6027\u6742\u73af\u5316\u5408\u7269\u7684\u533a\u57df\u9009\u62e9\u6027\u5b98\u80fd\u56e2\u5316\u5f00\u8f9f\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u90e8\u5206\u5e95\u7269\uff0c\u53ef\u80fd\u9700\u8981\u91c7\u7528\u5177\u6709\u8f83\u5f3a\u6bd2\u6027\u4e0e\u8150\u8680\u6027\u7684TiCl4\u8bd5\u5242\u4ee5\u53ca\u5177\u6709\u6f5c\u5728\u81f4\u764c\u6027\u7684DCM\u4f5c\u4e3a\u6eb6\u5242\uff0c\u9020\u6210\u4e00\u5b9a\u7a0b\u5ea6\u7684\u73af\u5883\u95ee\u9898\u3002\u6b64\u5916\uff0c\u8fd8\u6709\u90e8\u5206\u5e95\u7269\uff0c\u5fc5\u987b\u5bf9\u7b2c\u4e00\u6b65\u7684Kn\u00f6venagel\u7f29\u5408\u4ea7\u7269\u8fdb\u884c\u5206\u79bb\u7eaf\u5316\uff0c\u56e0\u6b64\uff0c\u5177\u6709\u8f83\u5dee\u7684pot-economy\u3002\u4ece\u800c\u4f7f\u8be5\u65b9\u6cd5\u5b66\u5728\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u53d7\u5230\u9650\u5236\u3002\u4e3a\u4f7f\u8be5\u53cd\u5e94\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u8bbe\u8ba1\u7406\u5ff5\uff0c\u63d0\u9ad8\u53cd\u5e94\u7684pot-economy\uff0c\u8fdb\u800c\u66f4\u597d\u5730\u9002\u5e94\u5de5\u4e1a\u751f\u4ea7\uff0c\u8fd1\u671f\uff0c\u8bf8\u591a\u8bfe\u9898\u7ec4\u5bf9Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66\u6240\u91c7\u7528\u7684\u7684\u50ac\u5316\u5242\u3001\u6eb6\u5242\u7b49\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4e86\u8fdb\u4e00\u6b65\u6539\u8fdb\u3002\u672c\u671f\u5c0f\u7f16\u5c06\u5bf9Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u65b9\u6cd5\u5b66\u7684\u8fd1\u671f\u7814\u7a76\u8fdb\u5c55\u8fdb\u884c\u8be6\u7ec6\u4ecb\u7ecd\u3002 \u6982\u8981 2014\u5e74\uff0cA. Tolomelli\u5c0f\u7ec4\u53d1\u73b0\u5728\u5fae\u6ce2\u8f90\u5c04\u6761\u4ef6\u4e0b\uff0c\u91c7\u7528\u50ac\u5316\u91cf\u7684\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4fc3\u8fdb\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u53ef\u4ee5\u4f7f\u50ac\u5316\u5242\u7528\u91cf\u8fdb\u4e00\u6b65\u964d\u4f4e\uff0c\u5e76\u6781\u5927\u7f29\u77ed\u4e86\u53cd\u5e94\u65f6\u95f4 (\u9488\u5bf9\u7b2c\u4e00\u6b65\u7684Kn\u00f6venagel\u7f29\u5408)\u3002\u540c\u65f6\uff0c\u53ef\u4ee5\u907f\u514dKn\u00f6venagel\u4e2d\u95f4\u4f53\u7684\u5206\u79bb\u4e0e\u7eaf\u5316\uff0c\u5177\u6709\u826f\u597d\u7684pot-economy[2]\u3002 \u4e0e\u6b64\u540c\u65f6\uff0cA. Renzetti\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7L-proline\u4e0e\u4e09\u6c1f\u7532\u78fa\u9178\u94d5\u50ac\u5316\u4f53\u7cfb\u4fc3\u8fdb\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u540c\u6837\u53ef\u4ee5\u83b7\u5f97\u4f18\u826f\u7684\u6536\u7387\u4e0e\u8f83\u9ad8\u7684\u975e\u5bf9\u6620\u9009\u62e9\u6027[3]\u3002\u540c\u65f6\uff0c\u907f\u514d\u4e86\u8150\u8680\u6027\u8bd5\u5242TiCl4\u4e0eTiCl2(OiPr)2\u7684\u4f7f\u7528\uff0c\u5bf9\u73af\u5883\u66f4\u52a0\u53cb\u597d[3]\u3002 \u63a5\u4e0b\u6765\uff0cGu\u53d1\u73b0\uff0c\u91c7\u7528\u624b\u6027\u7684L-\u812f\u6c28\u9178\uff0c\u53ef\u4ee5\u5c06Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u4e00\u6b65\u6269\u5c55\u81f3\u567b\u5429\u3001\u6742\u73af\u82b3\u9999\u919b\u53ca\u5404\u7c7b\u73af\u72b6\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\uff0c\u5e76\u83b7\u5f97\u8f83\u9ad8\u7684\u6536\u7387[4]\u3002 \u4e4b\u540e\uff0cY. He\u4e0eZ. Guan\u8fdb\u4e00\u6b65\u5c06L-\u812f\u6c28\u9178\u50ac\u5316\u7684\u6761\u4ef6\u5e94\u7528\u4e8e\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u7684\u4e09\u7ec4\u5206\u7f29\u5408\uff0c\u4ee5\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0e\u4f18\u826f\u7684\u6536\u7387\u83b7\u5f973-\u5432\u54da\u884d\u751f\u7269[5]\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u53d1\u73b0\u8be5\u53cd\u5e94\u6761\u4ef6\u5bf9\u4e8e\u5421\u54af\u4e0e\u4e09\u6c1f\u7532\u57fa\u82ef\u4e59\u916e\u540c\u6837\u9002\u7528\u3002 2015\u5e74D. S. Rawat\u901a\u8fc7RGO (reduced graphene oxide)\/ZnO\u7eb3\u7c73\u7c92\u5b50\u5f02\u76f8\u50ac\u5316\u5242\uff0c\u987a\u5229\u5b8c\u6210\u6c34\u76f8\u6761\u4ef6\u4e0b\uff0c\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u6216\u6c30\u57fa\u4e59\u9178\u4e59\u916f\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[6]\u3002 \u540c\u65f6\uff0cD. S. Rawat\u91c7\u7528\u65b0\u53d1\u5c55\u7684\u5f02\u76f8RS-HM (rectangular thin sheet hydromagnesite)\u50ac\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u5432\u54da\u3001\u919b\u53cadimedone\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u53cd\u5e94[6]\u3002\u7814\u7a76\u8868\u660e\uff0c\u91c7\u7528\u8be5\u50ac\u5316\u5242\u53c2\u4e0e\u7684\u7f29\u5408\u8fc7\u7a0b\u5177\u6709\u4f18\u826f\u7684\u4ea7\u7387\u4e0e\u539f\u5b50\u7ecf\u6d4e\u6027\uff0c\u53cd\u5e94\u5b8c\u6210\u540e\uff0c\u5904\u7406\u66f4\u52a0\u7b80\u4fbf\u6613\u884c\uff0c\u73af\u5883\u66f4\u4e3a\u53cb\u597d\u3002 \u4e4b\u540e\uff0cD. S. Rawat\u5f00\u53d1\u51fa\u80fd\u591f\u6709\u6548\u5faa\u73af\u5229\u7528\u4e14\u53ef\u4ee5\u751f\u7269\u964d\u89e3\u7684\u79bb\u5b50\u6db2\u4f53\u6709\u673a\u50ac\u5316\u5242[TBA][Gly] (tetrabutylammonium glycinate)\uff0c\u987a\u5229\u5b8c\u6210\u5432\u54da\u4e0e\u82b3\u9999\u919b\u6216\u8102\u80aa\u919b\u53ca\u4e19\u4e8c\u8148\u4e4b\u95f4\u7684\u65e0\u6eb6\u5242Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[8]\u3002 2017\u5e74\uff0cR. Tayebee\u7814\u7a76\u89c2\u5bdf\u5230\uff0c\u91c7\u7528\u5f02\u76f8\u7684\u65e0\u673a-\u6709\u673a\u6742\u5316\u7eb3\u7c73\u591a\u5b54\u50ac\u5316\u5242 (inorganic-organic hybrid nanoporous catalyst)\uff0c\u5373Keggin\u7ed3\u6784\u7684\u6742\u591a\u9178 (heteropolyacid Keggin structure) H5PW10V2O40@VOx\/SBA (Santa Barbara Amorphous, SBA\u4e3a\u9ad8\u7a33\u5b9a\u6027\u7684mesoporous silica sieve)-15-NH2, \u540c\u6837\u80fd\u591f\u6709\u6548\u5730\u5b8c\u6210\u53d6\u4ee3\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u4e19\u4e8c\u8148\u4e4b\u95f4\u7684\u65e0\u6eb6\u5242Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[9]\u3002\u540c\u65f6\uff0c\u8be5\u50ac\u5316\u5242\u80fd\u591f\u5faa\u73af\u4f7f\u7528\uff0c\u53cd\u5e94\u6761\u4ef6\u66f4\u52a0\u6e29\u548c\u4e14\u7ecf\u6d4e\u53cb\u597d\u3002 \u540c\u65f6\uff0cS. Mozumdar\u5c06\u65b0\u5408\u6210\u7684\u5f02\u76f8GO (graphene oxide)IL-NH2\u50ac\u5316\u5242\u6210\u529f\u5e94\u7528\u4e8e\u5432\u54da\u4e0e\u82b3\u9999\u919b\u6216\u6742\u73af\u82b3\u9999\u919b\u53cadimedone\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[10]\u3002 \u968f\u540e\uff0cC. Lv\u53d1\u73b0\uff0c\u91c7\u7528\u7518\u6cb9\/\u6c34\u4f53\u7cfb\uff0c\u5728\u8d85\u58f0\u6ce2\u8f90\u5c04\u6761\u4ef6\u4e0b\uff0c\u540c\u6837\u80fd\u591f\u6709\u6548\u5730\u5b9e\u73b0\u5432\u54da\u4e0e\u919b\u53caMeldrum\u9178\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u65e0\u9700\u4f7f\u7528\u50ac\u5316\u5242\uff0c\u66f4\u52a0\u7b80\u4fbf\u5b9e\u7528\u3002\u540c\u65f6\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u5e94\u7528\u8303\u56f4\u53ca\u4e2d\u7b49\u81f3\u4f18\u826f\u7684\u53cd\u5e94\u6536\u7387[11]\u3002 2018\u5e74\uff0cA. Beatriz\u8fdb\u4e00\u6b65\u53d1\u73b0\uff0c\u901a\u8fc7\u65b0\u53d1\u5c55\u7684Cu (I)\u50ac\u5316\u5242\uff0c\u80fd\u591f\u66f4\u4e3a\u5feb\u901f\u5730\u5728\u6c34\u76f8\u73af\u5883\u4e2d\u5b8c\u6210\u82b3\u9999\u919b\u4e0e\u5432\u54da\u53ca\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[12]\u3002 \u540c\u65f6\uff0cE. Sabzi\u5408\u6210\u51fa\u65b0\u7684\u5177\u6709tiny mesh-like\u7ed3\u6784\u7684\u03b2-CD.NS (\u03b2-cyclodextrin-based nanosponges) \u591a\u5b54\u4e09\u7ef4\u7eb3\u7c73\u50ac\u5316\u5242 (porous three-dimensional nanocatalyst)\uff0c\u5e76\u987a\u5229\u5b8c\u6210\u5432\u54da\u4e0e\u82b3\u9999\u919b\u53ca\u5404\u7c7b\u6d3b\u6cfc\u4e9a\u7532\u57fa\u5316\u5408\u7269\u4e4b\u95f4\u7684Yonemitsu\u4e09\u7ec4\u5206\u7f29\u5408[13]\u3002 2019\u5e74\uff0cP. N. Chatterjee\u901a\u8fc7\u8d85\u58f0\u8f90\u5c04\u53ca\u5bf9\u7532\u82ef\u78fa\u9178\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\uff0c\u8fdb\u4e00\u6b65\u5c06\u5e95\u7269\u8303\u56f4\u6269\u5c55\u81f3\u5176\u5b83\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269[14]\u3002 \u57fa\u672c\u6587\u732e [1] Y. Oikawa, H. Hirasawa,\u00a0O. Yonemitsu, Tetrahedron Lett. 1978, 20, 1759. doi: 10.1016\/0040-4039(78)80037-9. [2] A. Viola, L. Ferrazzano, G. Martelli, S. Ancona, L. Gentilucci, A. Tolomelli, Tetrahedron 2014, 70, 6781.doi: 10.1016\/j.tet.2014.07.062. 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