{"id":35155,"date":"2020-09-27T08:05:12","date_gmt":"2020-09-27T00:05:12","guid":{"rendered":"\/\/www.gsbet888.com\/?p=35155"},"modified":"2020-09-25T19:43:23","modified_gmt":"2020-09-25T11:43:23","slug":"yorimitsu-aromatic-metamorphosis%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2020\/09\/yorimitsu-aromatic-metamorphosis%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Yorimitsu aromatic metamorphosis\u53cd\u5e94"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>Yorimitsu aromatic metamorphosis\u53cd\u5e94 (Yorimitsu aromatic metamorphosis reaction)\u662f\u5c06\u4e8c\u82ef\u5e76\u567b\u5429 (DBT, dibenzothiophene)<sup>[1]-[2]<\/sup>\u3001\u4e8c\u82ef\u5e76\u567b\u5429\u4e8c\u6c27\u5316\u7269<sup>[3]-[5]<\/sup>\u3001\u82ef\u5e76\u544b\u5583<sup>[6]-[7]<\/sup>\u3001\u4e8c\u82ef\u5e76\u544b\u5583<sup>[8]<\/sup>\u3001\u5432\u54da<sup>[9]<\/sup>\u30013-\u6c28\u57fa\u5432\u5511<sup>[10]<\/sup>\u7b49\u82b3\u73af\u4e0e\u6742\u82b3\u73af\u9aa8\u67b6 (aromatic skeleton)\u901a\u8fc7\u4e00\u6b65\u6216\u591a\u6b65\u53cd\u5e94\u8fc7\u7a0b\uff0c\u8f6c\u5316\u4e3a\u5176\u5b83\u82b3\u9999\u4e0e\u6742\u73af\u82b3\u9999\u73af\u7cfb\u7684\u53cd\u5e94\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35156 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2.png\" alt=\"\" width=\"1293\" height=\"553\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2.png 1293w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2-300x128.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2-680x291.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-2-768x328.png 768w\" sizes=\"(max-width: 1293px) 100vw, 1293px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35157 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15.jpg\" alt=\"\" width=\"1181\" height=\"794\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15.jpg 1181w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15-300x202.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15-680x457.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-15-768x516.jpg 768w\" sizes=\"(max-width: 1181px) 100vw, 1181px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35158 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15.jpg\" alt=\"\" width=\"1251\" height=\"739\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15.jpg 1251w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15-300x177.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15-680x402.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-15-768x454.jpg 768w\" sizes=\"(max-width: 1251px) 100vw, 1251px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35159 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13.jpg\" alt=\"\" width=\"1062\" height=\"868\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13.jpg 1062w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13-300x245.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13-680x556.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-13-768x628.jpg 768w\" sizes=\"(max-width: 1062px) 100vw, 1062px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35160 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13.jpg\" alt=\"\" width=\"1249\" height=\"929\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13.jpg 1249w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13-300x223.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13-680x506.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13-768x571.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-13-265x197.jpg 265w\" sizes=\"(max-width: 1249px) 100vw, 1249px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35161 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11.jpg\" alt=\"\" width=\"1168\" height=\"987\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11.jpg 1168w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11-300x254.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11-680x575.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-11-768x649.jpg 768w\" sizes=\"(max-width: 1168px) 100vw, 1168px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35162 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8.jpg\" alt=\"\" width=\"1328\" height=\"972\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8.jpg 1328w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8-300x220.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8-680x498.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-8-768x562.jpg 768w\" sizes=\"(max-width: 1328px) 100vw, 1328px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35163 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4.jpg\" alt=\"\" width=\"1321\" height=\"861\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4.jpg 1321w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4-300x196.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4-680x443.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4-768x501.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-4-260x170.jpg 260w\" sizes=\"(max-width: 1321px) 100vw, 1321px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35164 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2.jpg\" alt=\"\" width=\"1149\" height=\"921\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2.jpg 1149w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2-300x240.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2-680x545.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-2-768x616.jpg 768w\" sizes=\"(max-width: 1149px) 100vw, 1149px\" \/><\/a><\/p>\n<p>\u8fd9\u4e00\u5168\u65b0\u7684\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u6982\u5ff5\u7531\u65e5\u672cKyoto\u5927\u5b66\u7406\u5b66\u9662\u5316\u5b66\u7cfb(\u4eac\u90fd\u5927\u5b66\u5927\u5b66\u9662\u7406\u5b66\u7814\u7a76\u79d1\u5316\u5b66\u5c02\u653b,Department of Chemistry, Graduate School of Science, Kyoto University)\u7684Yorimitsu (\u4f9d\u5149 \u82f1\u6a39, Yorimitsu Hideki)\u7814\u7a76\u5ba4\u57282015\u5e74\u9996\u6b21\u62a5\u9053<sup>[1]<\/sup>\u3002\u8be5\u65b9\u6cd5\u5b66\u7684\u5efa\u7acb\uff0c\u4e3a\u5404\u7c7b\u91cd\u8981\u7684\u82b3\u9999\u5316\u5408\u7269\u4ee5\u53ca\u6742\u73af\u82b3\u9999\u5316\u5408\u7269\u7684\u6784\u5efa\u5f00\u8f9f\u4e86\u5168\u65b0\u7684\u65b9\u6cd5<sup>[11]-[12]<\/sup>\u3002<\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 7162. doi: <a href=\"https:\/\/doi.org\/10.1002\/anie.201501992\">10.1002\/anie.201501992<\/a>.<\/li>\n<li>[2] Hayate S., K. Nogi, H. Yormitsu, Chem. Lett. 2017, 46, 1122. doi: <a href=\"http:\/\/www.journal.csj.jp\/doi\/10.1246\/cl.170415\">10.1246\/cl.170415.<\/a><\/li>\n<li>[3] M. Bhanuchandra, K. Murakami, D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 10234. doi: <a href=\"https:\/\/doi.org\/10.1002\/anie.201503671\">10.1002\/anie.201503671<\/a>.<\/li>\n<li>[4] M. Bhanuchandra, H. Yorimitsu, A. Osuka, Org. Lett. 2016, 18, 384. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.5b03384\">10.1021\/acs.orglett.5b03384.<\/a><\/li>\n<li>[5] M. Onoda, Y. Koyanagi, H. Saito, M. Bhanuchandra, Y. Matano, H. Yorimitsu, Asian J. Org. Chem. 2017, 6, 257. doi: <a href=\"https:\/\/doi.org\/10.1002\/ajoc.201600612\">10.1002\/ajoc.201600612<\/a>.<\/li>\n<li>[6] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett.\u00a02017, 19, 5557. doi: <a href=\"https:\/\/doi.org\/10.1021\/acs.orglett.7b02660\">10.1021\/acs.orglett.7b02660<\/a>.<\/li>\n<li>[7] H. Saito, S. Otsuka, K. Nogi, H. Yorimitsu, J. Am. Chem. Soc. 2016, 138, 15315. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6b10255\">10.1021\/jacs.6b10255.<\/a><\/li>\n<li>[8] Y. Kurata, S. Otsuka, N. Fukui, K. Nogi, H. Yorimitsu, A. Osuka, Org. Lett. 2017, 19, 1274. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.6b03861\">10.1021\/acs.orglett.6b03861.<\/a><\/li>\n<li>[9] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett. 2019, 21, 3855. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.orglett.9b01353\">10.1021\/acs.orglett.9b01353.<\/a><\/li>\n<li>[10] Y. Zhou, L. Lin,Y. Wang, J. Zhu, Q. Song, Org. Lett. 2019, 21, 7630. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.9b02933\">10.1021\/acs.orglett.9b02933.<\/a><\/li>\n<li>[11] H. Yorimitsu, D. Vasu, M. Bhanuchandra, K. Murakami, A. Osuka, Synlett 2016, 27, 1765. doi: <a href=\"https:\/\/www.thieme-connect.de\/products\/ejournals\/abstract\/10.1055\/s-0035-1561617\">10.1055\/s-0035-1561617.<\/a><\/li>\n<li>[12] K. Nogi, H. Yorimitsu, Chem. Commun. 2017, 53, 4055. doi: <a href=\"https:\/\/doi.org\/10.1039\/C7CC00078B\">10.1039\/C7CC00078B<\/a>.<\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><span style=\"color: #0000ff;\"><strong>1. \u4e8c\u82ef\u5e76\u567b\u5429\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<sup>[1]-[15]<\/sup><\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210\u4e09\u4e9a\u82ef<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35165 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15.jpg\" alt=\"\" width=\"1387\" height=\"792\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15.jpg 1387w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15-300x171.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15-680x388.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-15-768x439.jpg 768w\" sizes=\"(max-width: 1387px) 100vw, 1387px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u82ef\u5e76\u544b\u5583\u4e0e<\/strong><strong>oxaborin<\/strong><strong>\u53ca<\/strong><strong>azaborin<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35166 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16.jpg\" alt=\"\" width=\"1387\" height=\"558\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16.jpg 1387w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16-300x121.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16-680x274.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-16-768x309.jpg 768w\" sizes=\"(max-width: 1387px) 100vw, 1387px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35167 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16.jpg\" alt=\"\" width=\"1185\" height=\"961\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16.jpg 1185w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16-300x243.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16-680x551.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-16-768x623.jpg 768w\" sizes=\"(max-width: 1185px) 100vw, 1185px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35168 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14.jpg\" alt=\"\" width=\"1189\" height=\"961\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14.jpg 1189w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14-300x242.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14-680x550.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-14-768x621.jpg 768w\" sizes=\"(max-width: 1189px) 100vw, 1189px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35169 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14.jpg\" alt=\"\" width=\"1257\" height=\"823\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14.jpg 1257w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14-300x196.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14-680x445.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14-768x503.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-14-260x170.jpg 260w\" sizes=\"(max-width: 1257px) 100vw, 1257px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35170 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12.jpg\" alt=\"\" width=\"1325\" height=\"842\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12.jpg 1325w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12-300x191.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12-680x432.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-12-768x488.jpg 768w\" sizes=\"(max-width: 1325px) 100vw, 1325px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>2. \u4e8c\u82ef\u5e76\u567b\u5429\u4e8c\u6c27\u5316\u7269\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><strong><sup>[16]-[20]<\/sup><\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210\u5494\u5511<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35171 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9.jpg\" alt=\"\" width=\"1485\" height=\"517\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9.jpg 1485w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9-300x104.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9-680x237.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-9-768x267.jpg 768w\" sizes=\"(max-width: 1485px) 100vw, 1485px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u87ba\u73af\u4e8c\u82b3\u57fa\u82b4<\/strong><strong> (spirocyclic diarylfluorene)<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35172 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5.jpg\" alt=\"\" width=\"1396\" height=\"918\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5.jpg 1396w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5-300x197.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5-680x447.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5-768x505.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-5-260x170.jpg 260w\" sizes=\"(max-width: 1396px) 100vw, 1396px\" \/><\/a><\/p>\n<p><strong>(c) <\/strong><strong>\u751f\u6210<\/strong><strong>dibenzophosphole oxide<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35173 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3.jpg\" alt=\"\" width=\"1332\" height=\"709\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3.jpg 1332w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3-300x160.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3-680x362.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-3-768x409.jpg 768w\" sizes=\"(max-width: 1332px) 100vw, 1332px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>3. \u82ef\u5e76\u544b\u5583\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<sup>[21]-[27]<\/sup><\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210<\/strong><strong>oxaborin<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35174 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16.jpg\" alt=\"\" width=\"1184\" height=\"961\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16.jpg 1184w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16-300x243.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16-680x552.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-16-768x623.jpg 768w\" sizes=\"(max-width: 1184px) 100vw, 1184px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u5176\u5b83\u516d\u5143\u6742\u73af<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35175 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17.jpg\" alt=\"\" width=\"1250\" height=\"559\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17.jpg 1250w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17-300x134.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17-680x304.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/2-17-768x343.jpg 768w\" sizes=\"(max-width: 1250px) 100vw, 1250px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35176 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17.jpg\" alt=\"\" width=\"1259\" height=\"726\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17.jpg 1259w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17-300x173.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17-680x392.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-17-768x443.jpg 768w\" sizes=\"(max-width: 1259px) 100vw, 1259px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>4. \u4e8c\u82ef\u5e76\u544b\u5583\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<sup>[22], [28]-[36]<\/sup><\/strong><\/span><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-15.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35177 size-full\" 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\/><\/a><\/p>\n<h4>\u53c2<strong>\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] K. 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Lett. 2019, 21, 7630. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.9b02933\">10.1021\/acs.orglett.9b02933.<\/a><\/li>\n<\/ul>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>\u5494\u5511\u7684\u5408\u6210<sup>[1]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35182 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17.jpg\" alt=\"\" width=\"939\" height=\"643\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17.jpg 939w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17-300x205.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17-680x466.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/1-17-768x526.jpg 768w\" sizes=\"(max-width: 939px) 100vw, 939px\" \/><\/a><\/p>\n<p>tribenzo[b,d,f ]oxepine-1-carbonitrile\u7684\u5408\u6210<sup>[2]<\/sup><\/p>\n<p><a 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srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-18.jpg 913w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-18-300x90.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-18-680x203.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/3-18-768x230.jpg 768w\" sizes=\"(max-width: 913px) 100vw, 913px\" \/><\/a><\/p>\n<p>oxaborin\u7684\u5408\u6210<sup>[4]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35185 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16.jpg\" alt=\"\" width=\"1106\" height=\"154\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16.jpg 1106w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16-300x42.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16-680x95.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/4-16-768x107.jpg 768w\" sizes=\"(max-width: 1106px) 100vw, 1106px\" \/><\/a><\/p>\n<p>azaborin\u7684\u5408\u6210<sup>[5]<\/sup><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35186 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16.jpg\" alt=\"\" width=\"1111\" height=\"448\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16.jpg 1111w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16-300x121.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16-680x274.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/5-16-768x310.jpg 768w\" sizes=\"(max-width: 1111px) 100vw, 1111px\" \/><\/a><\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p><span style=\"color: #0000ff;\"><strong>1. \u4e8c\u82ef\u5e76\u567b\u5429\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210\u4e09\u4e9a\u82ef<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35187 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14.jpg\" alt=\"\" width=\"1258\" height=\"586\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14.jpg 1258w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14-300x140.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14-680x317.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/6-14-768x358.jpg 768w\" sizes=\"(max-width: 1258px) 100vw, 1258px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35188 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11.jpg\" alt=\"\" width=\"1251\" height=\"638\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11.jpg 1251w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11-300x153.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11-680x347.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/7-11-768x392.jpg 768w\" sizes=\"(max-width: 1251px) 100vw, 1251px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u82ef\u5e76\u544b\u5583\u4e0e<\/strong><strong>oxaborin<\/strong><strong>\u53ca<\/strong><strong>azaborin<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35189 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6.jpg\" alt=\"\" width=\"1320\" height=\"684\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6.jpg 1320w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6-300x155.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6-680x352.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/8-6-768x398.jpg 768w\" sizes=\"(max-width: 1320px) 100vw, 1320px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35190 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4.jpg\" alt=\"\" width=\"1330\" height=\"662\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4.jpg 1330w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4-300x149.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4-680x338.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/9-4-768x382.jpg 768w\" sizes=\"(max-width: 1330px) 100vw, 1330px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>2. \u4e8c\u82ef\u5e76\u567b\u5429\u4e8c\u6c27\u5316\u7269\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210\u5494\u5511<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35191 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2.jpg\" alt=\"\" width=\"1322\" height=\"279\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2.jpg 1322w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2-300x63.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2-680x144.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/10-2-768x162.jpg 768w\" sizes=\"(max-width: 1322px) 100vw, 1322px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u87ba\u73af\u4e8c\u82b3\u57fa\u82b4<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35192 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2.jpg\" alt=\"\" width=\"1321\" height=\"312\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2.jpg 1321w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2-300x71.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2-680x161.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/11-2-768x181.jpg 768w\" sizes=\"(max-width: 1321px) 100vw, 1321px\" \/><\/a><\/p>\n<p><strong>(c) <\/strong><strong>\u751f\u6210<\/strong><strong>dibenzophosphole oxide<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35193 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2.jpg\" alt=\"\" width=\"1339\" height=\"381\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2.jpg 1339w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2-300x85.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2-680x193.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/12-2-768x219.jpg 768w\" sizes=\"(max-width: 1339px) 100vw, 1339px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>3. \u82ef\u5e76\u544b\u5583\u53c2\u4e0e\u7684<\/strong><strong>aromatic m<\/strong><\/span><span style=\"color: #0000ff;\"><strong>etamorphosis<\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210<\/strong><strong>oxaborin<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35194 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1.jpg\" alt=\"\" width=\"1388\" height=\"241\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1.jpg 1388w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1-300x52.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1-680x118.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/13-1-768x133.jpg 768w\" sizes=\"(max-width: 1388px) 100vw, 1388px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210<\/strong><strong>oxasilin<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35195 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14.jpg\" alt=\"\" width=\"1396\" height=\"550\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14.jpg 1396w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14-300x118.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14-680x268.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/14-768x303.jpg 768w\" sizes=\"(max-width: 1396px) 100vw, 1396px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>4. \u4e8c\u82ef\u5e76\u544b\u5583\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><\/span><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35196 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15.jpg\" alt=\"\" width=\"1401\" height=\"782\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15.jpg 1401w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15-300x167.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15-680x380.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/15-768x429.jpg 768w\" sizes=\"(max-width: 1401px) 100vw, 1401px\" \/><\/a><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35197 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1.jpg\" alt=\"\" width=\"1395\" height=\"846\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1.jpg 1395w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1-300x182.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1-680x412.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1-768x466.jpg 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/16-1-660x400.jpg 660w\" sizes=\"(max-width: 1395px) 100vw, 1395px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>5. \u5432\u54da\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><\/span><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35198 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1.jpg\" alt=\"\" width=\"1388\" height=\"572\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1.jpg 1388w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1-300x124.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1-680x280.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/17-1-768x316.jpg 768w\" sizes=\"(max-width: 1388px) 100vw, 1388px\" \/><\/a><\/p>\n<p><span style=\"color: #0000ff;\"><strong>6. \u6c28\u57fa\u5432\u5511\u53c2\u4e0e\u7684<\/strong><strong>aromatic metamorphosis<\/strong><\/span><\/p>\n<p><strong>(a) <\/strong><strong>\u751f\u6210\u82b4<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35199 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1.jpg\" alt=\"\" width=\"1394\" height=\"307\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1.jpg 1394w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1-300x66.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1-680x150.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/18-1-768x169.jpg 768w\" sizes=\"(max-width: 1394px) 100vw, 1394px\" \/><\/a><\/p>\n<p><strong>(b) <\/strong><strong>\u751f\u6210\u4e09\u4e9a\u82ef<\/strong><\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-35200 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1.jpg\" alt=\"\" width=\"1381\" height=\"292\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1.jpg 1381w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1-300x63.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1-680x144.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/19-1-768x162.jpg 768w\" sizes=\"(max-width: 1381px) 100vw, 1381px\" \/><\/a><\/p>\n<h4>\u53c2<strong>\u8003\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>[1] M. Bhanuchandra, K. Murakami, D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 10234. doi: <a href=\"https:\/\/doi.org\/10.1002\/anie.201503671\">10.1002\/anie.201503671<\/a>.<\/li>\n<li>[2] Y. Zhou, L. Lin,Y. Wang, J. Zhu, Q. Song, Org. Lett. 2019, 21, 7630. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.9b02933\">10.1021\/acs.orglett.9b02933.<\/a><\/li>\n<li>[3] A. Kaga, K. Nogi, H. Yorimitsu, Chem. Eur. J. 2019, 25, 14780. doi: <a href=\"https:\/\/doi.org\/10.1002\/chem.201903916\">10.1002\/chem.201903916<\/a>.<\/li>\n<li>[4] H. Saito, S. Otsuka, K. Nogi, H. Yorimitsu, J. Am. Chem. Soc. 2016, 138, 15315. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6b10255\">10.1021\/jacs.6b10255.<\/a><\/li>\n<li>[5] S. Tsuchiya, H. Saito, K. Nogi, H. Yorimitsu, Org. Lett. 2019, 21, 3855. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.orglett.9b01353\">10.1021\/acs.orglett.9b01353.<\/a><\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e<strong>\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c<\/strong>\u00a0\u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 Yorimitsu aromatic metamorphosis\u53cd\u5e94 (Yorimitsu aromatic metamorphosis reaction)\u662f\u5c06\u4e8c\u82ef\u5e76\u567b\u5429 (DBT, dibenzothiophene)[1]-[2]\u3001\u4e8c\u82ef\u5e76\u567b\u5429\u4e8c\u6c27\u5316\u7269[3]-[5]\u3001\u82ef\u5e76\u544b\u5583[6]-[7]\u3001\u4e8c\u82ef\u5e76\u544b\u5583[8]\u3001\u5432\u54da[9]\u30013-\u6c28\u57fa\u5432\u5511[10]\u7b49\u82b3\u73af\u4e0e\u6742\u82b3\u73af\u9aa8\u67b6 (aromatic skeleton)\u901a\u8fc7\u4e00\u6b65\u6216\u591a\u6b65\u53cd\u5e94\u8fc7\u7a0b\uff0c\u8f6c\u5316\u4e3a\u5176\u5b83\u82b3\u9999\u4e0e\u6742\u73af\u82b3\u9999\u73af\u7cfb\u7684\u53cd\u5e94\u3002 \u8fd9\u4e00\u5168\u65b0\u7684\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u6982\u5ff5\u7531\u65e5\u672cKyoto\u5927\u5b66\u7406\u5b66\u9662\u5316\u5b66\u7cfb(\u4eac\u90fd\u5927\u5b66\u5927\u5b66\u9662\u7406\u5b66\u7814\u7a76\u79d1\u5316\u5b66\u5c02\u653b,Department of Chemistry, Graduate School of Science, Kyoto University)\u7684Yorimitsu (\u4f9d\u5149 \u82f1\u6a39, Yorimitsu Hideki)\u7814\u7a76\u5ba4\u57282015\u5e74\u9996\u6b21\u62a5\u9053[1]\u3002\u8be5\u65b9\u6cd5\u5b66\u7684\u5efa\u7acb\uff0c\u4e3a\u5404\u7c7b\u91cd\u8981\u7684\u82b3\u9999\u5316\u5408\u7269\u4ee5\u53ca\u6742\u73af\u82b3\u9999\u5316\u5408\u7269\u7684\u6784\u5efa\u5f00\u8f9f\u4e86\u5168\u65b0\u7684\u65b9\u6cd5[11]-[12]\u3002 \u57fa\u672c\u6587\u732e [1] D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 7162. doi: 10.1002\/anie.201501992. [2] Hayate S., K. Nogi, H. Yormitsu, Chem. Lett. 2017, 46, 1122. doi: 10.1246\/cl.170415. [3] M. Bhanuchandra, K. Murakami, D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed. 2015, 54, 10234. doi: 10.1002\/anie.201503671. [4] M. Bhanuchandra, H. Yorimitsu, A. Osuka, Org. Lett. 2016, 18, 384. doi: 10.1021\/acs.orglett.5b03384. [5] M. Onoda, Y. Koyanagi, H. Saito, M. Bhanuchandra, Y. Matano, H. Yorimitsu, Asian J. Org. Chem. 2017, 6, 257. [&hellip;]","protected":false},"author":21,"featured_media":35202,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2020\/09\/Yorimitsu-aromatic-metamorphosis-reaction.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-991","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/35155"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=35155"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/35155\/revisions"}],"predecessor-version":[{"id":35201,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/35155\/revisions\/35201"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/35202"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=35155"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=35155"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=35155"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}